ChemCatChemPub Date : 2025-08-29DOI: 10.1002/cctc.202500831
Zhouxiao Zhai, Jingce Bi, Yi Wang, Ningning Liu, Linshan Wang, Xia Zhang, Zhuopeng Wang, Yide Han
{"title":"Regulating Si/Al Role of MCM-41 with Graphite Carbon-Coated Co NPs for Efficient Hydrogenation of Furfural to Furfuryl Alcohol","authors":"Zhouxiao Zhai, Jingce Bi, Yi Wang, Ningning Liu, Linshan Wang, Xia Zhang, Zhuopeng Wang, Yide Han","doi":"10.1002/cctc.202500831","DOIUrl":"https://doi.org/10.1002/cctc.202500831","url":null,"abstract":"<p>The catalytic hydrogenation of furfural (FF) to furfuryl alcohol (FOL) using metal-loaded mesoporous molecular sieves represents a significant research area. In this work, a mesoporous molecular sieve with graphite carbon-coated Co NPs (Co@CN/Al-MCM-41) was successfully synthesized by vacuum-injecting the precursor solution into the MCM-41 molecular sieve and subsequent calcination. Using Co@CN/Al<sub>0.1</sub>-MCM-41 as the catalyst, the selective hydrogenation of FF to FOL achieved a conversion rate of 91.2% under mild conditions at 120 °C, which is 2.85 times higher than that of Al-free Co@CN/MCM-41, with an FOL selectivity of 97.2%. The experimental results revealed a strong correlation between FF conversion and the Si/Al ratio of MCM-41 molecular sieve. Increasing the Al species content facilitated the formation of more Co NPs active sites because of the strong electrostatic interaction, thereby promoting the activation of FF and hydrogen and enhancing the catalytic activity of Co@CN/Al<sub>0.1</sub>-MCM-41. Additionally, Co@CN/Al<sub>0.1</sub>-MCM-41also exhibited stable performance over five consecutive cycles, which was attributed to the formation of graphite carbon-coated Co NPs structure during the synthesis process. This simple fabrication strategy provides a novel approach for the modification of mesoporous molecular sieves with excellent catalytic activities.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 20","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145317709","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemCatChemPub Date : 2025-08-29DOI: 10.1002/cctc.202500832
Yunjin Song, Zhixiao Du, Chuanting Sun, Liangkun Qiu, Yan Zhang, Yawen Luan, Xue Yang, Junwei Ma, Hongtao Gao
{"title":"Cobalt-Based Catalysts for Electrocatalytic Water-Splitting Reactions: Mini Review of Material Synthesis, HER, and OER Catalytic Performance","authors":"Yunjin Song, Zhixiao Du, Chuanting Sun, Liangkun Qiu, Yan Zhang, Yawen Luan, Xue Yang, Junwei Ma, Hongtao Gao","doi":"10.1002/cctc.202500832","DOIUrl":"https://doi.org/10.1002/cctc.202500832","url":null,"abstract":"<p>With the aggravation of the energy crisis, the development of efficient catalysts for hydrogen production from electrolyzed water to promote the development of clean hydrogen energy has become a hot research topic. Cobalt-based catalysts have received much attention in recent years due to their excellent catalytic activity and good stability in the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). This paper focuses on the synthesis methods of cobalt-based catalysts, such as hydrothermal method, thermal decomposition reduction method, electrodeposition method, etc, to provide theoretical basis and technical references for the design and development of subsequent high-performance electrolytic water catalysts. In addition, the future development direction of cobalt-based catalysts is also envisioned to provide valuable theoretical references for the design and preparation of highly efficient and low-cost cobalt-based catalysts and enhance their practical application value.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 19","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145237314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Nickel-Catalyzed Selective Hydrazoarenes and Aminoarenes Formation from Azoarenes Using Ammonia–Borane","authors":"Aisa Mohanty, Gowtham Kenguva, Rambabu Dandela, Prosenjit Daw","doi":"10.1002/cctc.202501005","DOIUrl":"https://doi.org/10.1002/cctc.202501005","url":null,"abstract":"<p>Herein, we report the synthesis of an air-stable, phosphine-free NNN-based nickel(II) pincer complex that catalyzed the generation of diverse hydrogenated products from azoarenes using ammonia borane (AB) as a transfer hydrogenating source, facilitating at room temperature. The synthetic protocol tolerates the transfer hydrogenation (TH) of various azo-derived substrates, especially bearing reducible functional groups. The preliminary mechanistic investigation studies revealed the crucial role of nickel catalyst in the TH of the azo-substrates using AB and ethanol, which generates the boron-alkoxide by-products. The significant advantage of this study highlights the utilization of nickel catalyst for the complete N═N cleavage of azoarenes to generate aminoarenes, assisted at base-free, mild reaction conditions.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 20","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145317706","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemCatChemPub Date : 2025-08-27DOI: 10.1002/cctc.202401691
Gabriel C. da Fonseca, Fhysmélia F. de Albuquerque, Rafael N. P. Colombo, Rodrigo M. Iost, Frank N. Crespilho, João C. P. de Souza
{"title":"Photosynthetic Biomimetic System: Nickel Phthalocyanine and Biomass-Derived Carbon Quantum Dots for Enhanced Water Oxidation","authors":"Gabriel C. da Fonseca, Fhysmélia F. de Albuquerque, Rafael N. P. Colombo, Rodrigo M. Iost, Frank N. Crespilho, João C. P. de Souza","doi":"10.1002/cctc.202401691","DOIUrl":"https://doi.org/10.1002/cctc.202401691","url":null,"abstract":"<p>Efficient water oxidation is a crucial challenge for artificial photosynthesis and solar energy conversion. Here, we introduce a biomimetic photosynthetic system that combines Nickel(II) phthalocyanine-tetrasulfonic acid (NiPc) with carbon quantum dots (CQDs) derived from sugarcane biomass to enhance photoelectrochemical water oxidation. The CQDs effectively absorb UV and visible light, aiding electron transfer to NiPc, which significantly boosts photocurrent generation and reduces the overpotential. Electrochemical tests, including cyclic voltammetry and chronoamperometry under UV and blue light, show that the NiPc/CQD hybrid system delivers a notable increase in photocurrent density and stability compared to bare NiPc electrodes. By a membrane-free Clark-type electrode, molecular oxygen generated during photoelectrochemical water oxidation was detected. This sustainable system underscores the potential of biomass-derived CQDs as efficient, low-cost nanomaterials for solar-driven water oxidation, advancing renewable energy technologies.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 20","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.202401691","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145317707","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemCatChemPub Date : 2025-08-27DOI: 10.1002/cctc.202501116
Gousia Begum, Rakesh Chilivery, Krishna Kanthi Gudimella, S. Mohanapriya, Mallesham Baithy
{"title":"Recent Advancements in the Hydrodeoxygenation of Lignin-Derived Phenols to Cyclohexane-Based Products Over Supported Ruthenium Catalysts","authors":"Gousia Begum, Rakesh Chilivery, Krishna Kanthi Gudimella, S. Mohanapriya, Mallesham Baithy","doi":"10.1002/cctc.202501116","DOIUrl":"10.1002/cctc.202501116","url":null,"abstract":"<p>Lignin, being an underutilized component of cellulosic biomass has the potential to be converted into value-added chemicals and fuels. However, the recalcitrant nature of lignin to degradation has been a major hurdle in the valorization of lignin. The depolymerization (catalytic and pyrolytic) of lignin results in the formation of lignin-derived bio-oil comprising low-molecular-weight phenolic compounds (monomers, dimers, and oligomers) with much higher oxygen content than that required for the fuels. The catalytic hydrodeoxygenation (HDO) of lignin-derived phenolic compounds is one of the alluring opportunities for converting biomass materials to chemicals and fuels. The current article systematically reviews the advancement in the production of cyclohexane-based compounds from five primary lignin-derived monomers, phenol (PHE), guaiacol (GUA), cerulignol (CER), eugenol (EUG), and vanillin (VAN) using supported ruthenium (Ru) catalysts. The carbon-based zeolites and TiO<sub>2</sub>-based materials with distinguished properties are explored as the support for Ru nanoparticles. Understanding the characteristics of metal and its supports, along with the catalytic mechanisms and structure-activity relationships is crucial in developing HDO catalysts to produce selective products from lignin-derived phenolic monomers for practical applications. This review particularly highlights the significance of the synergistic interactions between ruthenium and the support materials during HDO reactions.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 18","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.202501116","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145102358","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemCatChemPub Date : 2025-08-27DOI: 10.1002/cctc.202500893
Angelika Owsienko, Philipp Stangl, Nnamdi Madubuko, Richard Lenz, Marco Haumann
{"title":"Statistical and Predictive Analysis of Supported Catalytically Active Metal Solutions (SCALMS) in Propane Dehydrogenation","authors":"Angelika Owsienko, Philipp Stangl, Nnamdi Madubuko, Richard Lenz, Marco Haumann","doi":"10.1002/cctc.202500893","DOIUrl":"https://doi.org/10.1002/cctc.202500893","url":null,"abstract":"<p>Propane dehydrogenation (PDH) is limited by rapid catalyst deactivation. Supported catalytically active liquid metal solutions (SCALMS) based on Ga–Pt alloys offer high selectivity and coke resistance, yet their vast compositional and operational design space hampers efficient optimization. We compiled and FAIR-formatted 198 PDH experiments on Ga-Pt SCALMS, distilling 149 complete cases with 20 descriptors covering synthesis, support, metal loadings, reaction conditions, and four key performance indicators: low deactivation, high selectivity, conversion, and productivity. Exploratory statistics revealed strong Ga–Pt loading covariance, pretreatment-temperature effects on stability, and a distinctive high-conversion/high-selectivity but fast-deactivating regime for Ga<sub>2</sub>O<sub>3</sub>-Pt catalysts prepared reductively on CARiACT silica. Principal-component analysis captured 34% of variance in two dimensions, isolating clusters linked to support and pretreatment protocols. Feature-reduced datasets fed three machine-learning regressors; extreme gradient boosting achieved the best extrapolation for productivity (<i>R</i><sup>2</sup> = 0.58), Random forests best predicted deactivation (<i>R</i><sup>2</sup> = 0.43), while support vector regression yielded the most accurate conversion predictions (<i>R</i><sup>2</sup> = 0.68). SHAP analysis ranked pretreatment temperature, Ga/Pt ratio, and time-on-stream as dominant drivers of KPI variance, aligning with SCALMS mechanistic expectations. Validation on six new experiments confirmed model fidelity within ± 15% for conversion, productivity, and deactivation. The combined statistical-predictive workflow constitutes a catalyst-informatics framework that guides catalyst development based on experimental data and highlights the need for larger, standardized datasets to reach truly predictive design of liquid–metal catalysts.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 20","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.202500893","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145317752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemCatChemPub Date : 2025-08-27DOI: 10.1002/cctc.202501219
Qiaoqiao Li, Rui Zhang, Yuqiu Lan, Yulian Li, Chunping Tang, Changqiang Ke, Yang Ye, Cangsong Liao
{"title":"Asymmetric Radical Alkylation Enabled by Synergistic Photoredox Enamine Biocatalysis","authors":"Qiaoqiao Li, Rui Zhang, Yuqiu Lan, Yulian Li, Chunping Tang, Changqiang Ke, Yang Ye, Cangsong Liao","doi":"10.1002/cctc.202501219","DOIUrl":"https://doi.org/10.1002/cctc.202501219","url":null,"abstract":"<p>Class I aldolases, a unique link among biochemistry, organic chemistry, and computational chemistry are powerful C─C bond-forming enzymes in synthetic chemistry and industry because of their unparalleled selectivity, extensive substrate scope and scalability. However, the types of reactions catalyzed by class I aldolases are restricted and radical reactions have yet to be accomplished. Here, we demonstrate a proof-of-concept study in which a synergistic photoredox biocatalysis strategy can be applied to realize new catalytic functions of enamine-dependent aldolases. This new reactivity enables asymmetric alkylation of a prochiral radical under exclusive stereocontrol, a challenging task for amine catalysts. Both enantiomeric products were obtained in a stereoconvergent fashion from wild-type and engineered aldolases. This synergistic photoredox biocatalysis strategy has resulted in a new-to-nature enzymatic reaction and led to an asymmetric transformation that is not feasible for organocatalysis. We envision that this discovery will motivate the development of enzymatic enamine and iminium catalysis for valuable asymmetric radical transformations, complementing the prevailing organocatalysts.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 20","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145317805","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemCatChemPub Date : 2025-08-27DOI: 10.1002/cctc.70272
Raghavendra Meena, Koen Marcus Draijer, Bastiaan van Dam, Prof. Han Zuilhof, Prof. Johannes Hendrik Bitter, Dr. Guanna Li
{"title":"Front Cover: Rationalizing Catalytic Performances of Mo/W-(Oxy)Carbides for Hydrodeoxygenation Reaction (ChemCatChem 16/2025)","authors":"Raghavendra Meena, Koen Marcus Draijer, Bastiaan van Dam, Prof. Han Zuilhof, Prof. Johannes Hendrik Bitter, Dr. Guanna Li","doi":"10.1002/cctc.70272","DOIUrl":"10.1002/cctc.70272","url":null,"abstract":"<p><b>The Front Cover</b> illustrates the catalytic dynamics of transition metal carbide catalysts during the hydrodeoxygenation (HDO) reaction and highlights that the transition metal oxycarbide species formed during the reaction play a key role in governing both HDO activity and selectivity. This study underscores the need to investigate the nature of active sites under operando conditions to establish rational structure-activity relationships. Further details can be found in the Research Article by G. Li and co-workers (DOI: 10.1002/cctc.202500659).\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 16","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.70272","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144905436","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemCatChemPub Date : 2025-08-24DOI: 10.1002/cctc.202500964
Violetta A. Ionova, Dr. Elizaveta V. Ermakova, Kirill S. Zazerin, Dr. Anton S. Abel, Dr. Vladislav M. Korshunov, Dr. Ilya V. Taydakov, Dr. Vitaly A. Roznyatovsky, Dr. Alexei D. Averin, Prof. Irina P. Beletskaya
{"title":"Molecular Hybrid Catalysts in Ni/Photoredox C–N Coupling: Comparison of “in Batch” and “in Flow” Irradiation Techniques","authors":"Violetta A. Ionova, Dr. Elizaveta V. Ermakova, Kirill S. Zazerin, Dr. Anton S. Abel, Dr. Vladislav M. Korshunov, Dr. Ilya V. Taydakov, Dr. Vitaly A. Roznyatovsky, Dr. Alexei D. Averin, Prof. Irina P. Beletskaya","doi":"10.1002/cctc.202500964","DOIUrl":"https://doi.org/10.1002/cctc.202500964","url":null,"abstract":"<p>Molecular hybrid catalysts [(ppy)<sub>2</sub>Ir(<b>BL</b>)](PF<sub>6</sub>), [(dFCF<sub>3</sub>)Ir(<b>BL</b>)](PF<sub>6</sub>), and [(bpy)<sub>2</sub>Ru(<b>BL</b>)](PF<sub>6</sub>)<sub>2</sub> (where <b>BL</b> = <i>N,N</i>-di(pyridin-2-yl)-1,10-phenanthrolin-4-amine), have been investigated in Ni-catalyzed C(sp<sup>2</sup>)–N coupling under visible light irradiation. The impact of the irradiation method—“in batch” or “in flow”—on the activity of hybrid and known dual catalytic systems was initially examined. The hybrid Ru(II) system demonstrated superior efficiency “in flow” compared to dual catalytic systems. The influence of the chelating moiety on the photophysical and electrochemical properties of the photocatalysts was analyzed to elucidate the observed catalytic activity. The hybrid photocatalysts could be utilized for the successful arylation of aromatic or aliphatic amines with moderate to excellent yields (21 examples), ranging from 33% to 91%. Hybrid photocatalysts facilitated the coupling of 4,7-dichloroquinoline and 5-iodopyridin-2-amine with piperazine in the synthesis of precursors for piperaquine and ribociclib.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 20","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145317737","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Tailoring the Acidity of Ru Supported on Sepiolite for Enhanced Catalytic Reductive Amination of Furfural to Furfurylamine","authors":"Kanika Saini, Supan, Neeraj Sharma, Rahul Gautam, Shunmugavel Saravanamurugan","doi":"10.1002/cctc.202500982","DOIUrl":"https://doi.org/10.1002/cctc.202500982","url":null,"abstract":"<p>The catalytic reductive amination of bio-based carbonyls has emerged as a promising route for producing N-containing compounds, having a wide range of applications in pharmaceuticals and agrochemicals. In this work, Ru supported on acid-treated sepiolite (Ru/ASep) is designed for the reductive amination of furfural (FUR) to furfurylamine (FUA) using H<sub>2</sub> and NH<sub>3</sub> as reductant and nitrogen source, respectively. Ru/ASep exhibited two times higher catalytic activity compared to its counterpart, that is, Ru supported on parent sepiolite (Ru/Sep), yielding 98.4% FUA. The NH<sub>3</sub>-temperature-programmed desorption (TPD) and NH<sub>3</sub>-diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy studies show that Ru/ASep exhibited an increase in total acidic sites with relatively more Lewis acidic sites than Ru/Sep, contributing to C═N bond activation and leading to the formation of FUA in high yield. The CO<sub>2</sub>-TPD results indicate that ASep possesses a large amount of basic sites, which contribute to a facile reduction of RuO<sub>x</sub> to Ru<sup>0</sup> in Ru/ASep, as confirmed by H<sub>2</sub>-temperature programmed reduction (TPR) studies. H<sub>2</sub>-TPD studies indicate a higher amount of H<sub>2</sub> activated over Ru/ASep, favoring the intermediate hydrogenation step to form FUA. Furthermore, the poisoning studies with KSCN indicated that Lewis acidic sites on the surface of Ru/ASep played a crucial role in the formation of FUA.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 20","pages":""},"PeriodicalIF":3.9,"publicationDate":"2025-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145317735","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}