负载钌催化剂上木质素衍生苯酚加氢脱氧制环己烷产品的研究进展

IF 3.9 3区 化学 Q2 CHEMISTRY, PHYSICAL
ChemCatChem Pub Date : 2025-08-27 DOI:10.1002/cctc.202501116
Gousia Begum, Rakesh Chilivery, Krishna Kanthi Gudimella, S. Mohanapriya, Mallesham Baithy
{"title":"负载钌催化剂上木质素衍生苯酚加氢脱氧制环己烷产品的研究进展","authors":"Gousia Begum,&nbsp;Rakesh Chilivery,&nbsp;Krishna Kanthi Gudimella,&nbsp;S. Mohanapriya,&nbsp;Mallesham Baithy","doi":"10.1002/cctc.202501116","DOIUrl":null,"url":null,"abstract":"<p>Lignin, being an underutilized component of cellulosic biomass has the potential to be converted into value-added chemicals and fuels. However, the recalcitrant nature of lignin to degradation has been a major hurdle in the valorization of lignin. The depolymerization (catalytic and pyrolytic) of lignin results in the formation of lignin-derived bio-oil comprising low-molecular-weight phenolic compounds (monomers, dimers, and oligomers) with much higher oxygen content than that required for the fuels. The catalytic hydrodeoxygenation (HDO) of lignin-derived phenolic compounds is one of the alluring opportunities for converting biomass materials to chemicals and fuels. The current article systematically reviews the advancement in the production of cyclohexane-based compounds from five primary lignin-derived monomers, phenol (PHE), guaiacol (GUA), cerulignol (CER), eugenol (EUG), and vanillin (VAN) using supported ruthenium (Ru) catalysts. The carbon-based zeolites and TiO<sub>2</sub>-based materials with distinguished properties are explored as the support for Ru nanoparticles. Understanding the characteristics of metal and its supports, along with the catalytic mechanisms and structure-activity relationships is crucial in developing HDO catalysts to produce selective products from lignin-derived phenolic monomers for practical applications. This review particularly highlights the significance of the synergistic interactions between ruthenium and the support materials during HDO reactions.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 18","pages":""},"PeriodicalIF":3.9000,"publicationDate":"2025-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.202501116","citationCount":"0","resultStr":"{\"title\":\"Recent Advancements in the Hydrodeoxygenation of Lignin-Derived Phenols to Cyclohexane-Based Products Over Supported Ruthenium Catalysts\",\"authors\":\"Gousia Begum,&nbsp;Rakesh Chilivery,&nbsp;Krishna Kanthi Gudimella,&nbsp;S. Mohanapriya,&nbsp;Mallesham Baithy\",\"doi\":\"10.1002/cctc.202501116\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Lignin, being an underutilized component of cellulosic biomass has the potential to be converted into value-added chemicals and fuels. However, the recalcitrant nature of lignin to degradation has been a major hurdle in the valorization of lignin. The depolymerization (catalytic and pyrolytic) of lignin results in the formation of lignin-derived bio-oil comprising low-molecular-weight phenolic compounds (monomers, dimers, and oligomers) with much higher oxygen content than that required for the fuels. The catalytic hydrodeoxygenation (HDO) of lignin-derived phenolic compounds is one of the alluring opportunities for converting biomass materials to chemicals and fuels. The current article systematically reviews the advancement in the production of cyclohexane-based compounds from five primary lignin-derived monomers, phenol (PHE), guaiacol (GUA), cerulignol (CER), eugenol (EUG), and vanillin (VAN) using supported ruthenium (Ru) catalysts. The carbon-based zeolites and TiO<sub>2</sub>-based materials with distinguished properties are explored as the support for Ru nanoparticles. Understanding the characteristics of metal and its supports, along with the catalytic mechanisms and structure-activity relationships is crucial in developing HDO catalysts to produce selective products from lignin-derived phenolic monomers for practical applications. This review particularly highlights the significance of the synergistic interactions between ruthenium and the support materials during HDO reactions.</p>\",\"PeriodicalId\":141,\"journal\":{\"name\":\"ChemCatChem\",\"volume\":\"17 18\",\"pages\":\"\"},\"PeriodicalIF\":3.9000,\"publicationDate\":\"2025-08-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.202501116\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemCatChem\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.202501116\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemCatChem","FirstCategoryId":"92","ListUrlMain":"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.202501116","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

摘要

木质素是纤维素生物质中未充分利用的成分,有潜力转化为增值化学品和燃料。然而,木质素的顽固性降解一直是木质素增值的主要障碍。木质素的解聚(催化和热解)导致木质素衍生的生物油的形成,包括低分子量酚类化合物(单体,二聚体和低聚物),其氧含量远高于燃料所需的氧含量。木质素衍生酚类化合物的催化加氢脱氧(HDO)是将生物质材料转化为化学品和燃料的诱人机会之一。本文系统地综述了以木质素为原料的酚(PHE)、愈创木酚(GUA)、木质素醇(CER)、丁香酚(EUG)和香兰素(VAN)为催化剂制备环己烷基化合物的研究进展。研究了具有不同性能的碳基沸石和tio2基材料作为Ru纳米颗粒的载体。了解金属及其载体的特性,以及催化机理和构效关系对于开发HDO催化剂以从木质素衍生的酚类单体中产生具有实际应用价值的选择性产物至关重要。本文特别强调了在HDO反应中钌与载体材料之间的协同相互作用的意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Recent Advancements in the Hydrodeoxygenation of Lignin-Derived Phenols to Cyclohexane-Based Products Over Supported Ruthenium Catalysts

Recent Advancements in the Hydrodeoxygenation of Lignin-Derived Phenols to Cyclohexane-Based Products Over Supported Ruthenium Catalysts

Recent Advancements in the Hydrodeoxygenation of Lignin-Derived Phenols to Cyclohexane-Based Products Over Supported Ruthenium Catalysts

Recent Advancements in the Hydrodeoxygenation of Lignin-Derived Phenols to Cyclohexane-Based Products Over Supported Ruthenium Catalysts

Lignin, being an underutilized component of cellulosic biomass has the potential to be converted into value-added chemicals and fuels. However, the recalcitrant nature of lignin to degradation has been a major hurdle in the valorization of lignin. The depolymerization (catalytic and pyrolytic) of lignin results in the formation of lignin-derived bio-oil comprising low-molecular-weight phenolic compounds (monomers, dimers, and oligomers) with much higher oxygen content than that required for the fuels. The catalytic hydrodeoxygenation (HDO) of lignin-derived phenolic compounds is one of the alluring opportunities for converting biomass materials to chemicals and fuels. The current article systematically reviews the advancement in the production of cyclohexane-based compounds from five primary lignin-derived monomers, phenol (PHE), guaiacol (GUA), cerulignol (CER), eugenol (EUG), and vanillin (VAN) using supported ruthenium (Ru) catalysts. The carbon-based zeolites and TiO2-based materials with distinguished properties are explored as the support for Ru nanoparticles. Understanding the characteristics of metal and its supports, along with the catalytic mechanisms and structure-activity relationships is crucial in developing HDO catalysts to produce selective products from lignin-derived phenolic monomers for practical applications. This review particularly highlights the significance of the synergistic interactions between ruthenium and the support materials during HDO reactions.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
ChemCatChem
ChemCatChem 化学-物理化学
CiteScore
8.10
自引率
4.40%
发文量
511
审稿时长
1.3 months
期刊介绍: With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信