Gousia Begum, Rakesh Chilivery, Krishna Kanthi Gudimella, S. Mohanapriya, Mallesham Baithy
{"title":"负载钌催化剂上木质素衍生苯酚加氢脱氧制环己烷产品的研究进展","authors":"Gousia Begum, Rakesh Chilivery, Krishna Kanthi Gudimella, S. Mohanapriya, Mallesham Baithy","doi":"10.1002/cctc.202501116","DOIUrl":null,"url":null,"abstract":"<p>Lignin, being an underutilized component of cellulosic biomass has the potential to be converted into value-added chemicals and fuels. However, the recalcitrant nature of lignin to degradation has been a major hurdle in the valorization of lignin. The depolymerization (catalytic and pyrolytic) of lignin results in the formation of lignin-derived bio-oil comprising low-molecular-weight phenolic compounds (monomers, dimers, and oligomers) with much higher oxygen content than that required for the fuels. The catalytic hydrodeoxygenation (HDO) of lignin-derived phenolic compounds is one of the alluring opportunities for converting biomass materials to chemicals and fuels. The current article systematically reviews the advancement in the production of cyclohexane-based compounds from five primary lignin-derived monomers, phenol (PHE), guaiacol (GUA), cerulignol (CER), eugenol (EUG), and vanillin (VAN) using supported ruthenium (Ru) catalysts. The carbon-based zeolites and TiO<sub>2</sub>-based materials with distinguished properties are explored as the support for Ru nanoparticles. Understanding the characteristics of metal and its supports, along with the catalytic mechanisms and structure-activity relationships is crucial in developing HDO catalysts to produce selective products from lignin-derived phenolic monomers for practical applications. This review particularly highlights the significance of the synergistic interactions between ruthenium and the support materials during HDO reactions.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 18","pages":""},"PeriodicalIF":3.9000,"publicationDate":"2025-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.202501116","citationCount":"0","resultStr":"{\"title\":\"Recent Advancements in the Hydrodeoxygenation of Lignin-Derived Phenols to Cyclohexane-Based Products Over Supported Ruthenium Catalysts\",\"authors\":\"Gousia Begum, Rakesh Chilivery, Krishna Kanthi Gudimella, S. Mohanapriya, Mallesham Baithy\",\"doi\":\"10.1002/cctc.202501116\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Lignin, being an underutilized component of cellulosic biomass has the potential to be converted into value-added chemicals and fuels. However, the recalcitrant nature of lignin to degradation has been a major hurdle in the valorization of lignin. The depolymerization (catalytic and pyrolytic) of lignin results in the formation of lignin-derived bio-oil comprising low-molecular-weight phenolic compounds (monomers, dimers, and oligomers) with much higher oxygen content than that required for the fuels. The catalytic hydrodeoxygenation (HDO) of lignin-derived phenolic compounds is one of the alluring opportunities for converting biomass materials to chemicals and fuels. The current article systematically reviews the advancement in the production of cyclohexane-based compounds from five primary lignin-derived monomers, phenol (PHE), guaiacol (GUA), cerulignol (CER), eugenol (EUG), and vanillin (VAN) using supported ruthenium (Ru) catalysts. The carbon-based zeolites and TiO<sub>2</sub>-based materials with distinguished properties are explored as the support for Ru nanoparticles. Understanding the characteristics of metal and its supports, along with the catalytic mechanisms and structure-activity relationships is crucial in developing HDO catalysts to produce selective products from lignin-derived phenolic monomers for practical applications. This review particularly highlights the significance of the synergistic interactions between ruthenium and the support materials during HDO reactions.</p>\",\"PeriodicalId\":141,\"journal\":{\"name\":\"ChemCatChem\",\"volume\":\"17 18\",\"pages\":\"\"},\"PeriodicalIF\":3.9000,\"publicationDate\":\"2025-08-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cctc.202501116\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemCatChem\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.202501116\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemCatChem","FirstCategoryId":"92","ListUrlMain":"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.202501116","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Recent Advancements in the Hydrodeoxygenation of Lignin-Derived Phenols to Cyclohexane-Based Products Over Supported Ruthenium Catalysts
Lignin, being an underutilized component of cellulosic biomass has the potential to be converted into value-added chemicals and fuels. However, the recalcitrant nature of lignin to degradation has been a major hurdle in the valorization of lignin. The depolymerization (catalytic and pyrolytic) of lignin results in the formation of lignin-derived bio-oil comprising low-molecular-weight phenolic compounds (monomers, dimers, and oligomers) with much higher oxygen content than that required for the fuels. The catalytic hydrodeoxygenation (HDO) of lignin-derived phenolic compounds is one of the alluring opportunities for converting biomass materials to chemicals and fuels. The current article systematically reviews the advancement in the production of cyclohexane-based compounds from five primary lignin-derived monomers, phenol (PHE), guaiacol (GUA), cerulignol (CER), eugenol (EUG), and vanillin (VAN) using supported ruthenium (Ru) catalysts. The carbon-based zeolites and TiO2-based materials with distinguished properties are explored as the support for Ru nanoparticles. Understanding the characteristics of metal and its supports, along with the catalytic mechanisms and structure-activity relationships is crucial in developing HDO catalysts to produce selective products from lignin-derived phenolic monomers for practical applications. This review particularly highlights the significance of the synergistic interactions between ruthenium and the support materials during HDO reactions.
期刊介绍:
With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.