International Journal of Electrochemical Science最新文献

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Early detection of internal short circuit faults in lithium-ion battery packs using dynamic time warping and Gaussian mixture clustering 基于动态时间扭曲和高斯混合聚类的锂离子电池组内部短路故障早期检测
IF 1.3 4区 化学
International Journal of Electrochemical Science Pub Date : 2025-06-25 DOI: 10.1016/j.ijoes.2025.101107
Qi Zuo , Meng Zhang , Ke Fu , Xiaogang Du , Zhuang Liu , Chao Lyu
{"title":"Early detection of internal short circuit faults in lithium-ion battery packs using dynamic time warping and Gaussian mixture clustering","authors":"Qi Zuo ,&nbsp;Meng Zhang ,&nbsp;Ke Fu ,&nbsp;Xiaogang Du ,&nbsp;Zhuang Liu ,&nbsp;Chao Lyu","doi":"10.1016/j.ijoes.2025.101107","DOIUrl":"10.1016/j.ijoes.2025.101107","url":null,"abstract":"<div><div>Internal short circuit (ISC) faults are a primary trigger for thermal runaway in energy storage lithium-ion battery systems. Timely detection of ISC faults at their early stage can effectively prevent severe safety incidents, thereby ensuring the safe and stable operation of battery energy storage systems. To address this challenge, this study proposes a novel early ISC identification method for lithium-ion battery packs based on dynamic time warping (DTW) sequences and Gaussian mixture model (GMM) clustering. First, the median terminal voltage curve is derived from sorted terminal voltage measurements, serving as a reference representing the normal state of cells within the battery pack. Subsequently, sliding time windows are applied to extract subsequences of the median terminal voltage and individual cell terminal voltages. On this basis, the DTW sequences of each cell are computed and utilized as an indicator to characterize abnormal battery behavior, thereby amplifying the discrepancy between early ISC-affected cells and normal ones. Furthermore, an automatic early ISC fault detection model is developed using a GMM-based clustering algorithm to distinguish between normal and early ISC cells within the battery pack. Experimental validation and analysis under various early ISC fault scenarios with different severity levels demonstrate that the proposed method achieves accurate identification of early ISC cells when the short-circuit resistance is less than or equal to1000 Ω.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 10","pages":"Article 101107"},"PeriodicalIF":1.3,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144549963","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrosion behavior of 7A09 aluminum alloy exposed to propylene glycol coolant at different conditions 7A09铝合金在不同条件下丙二醇冷却液的腐蚀行为
IF 1.3 4区 化学
International Journal of Electrochemical Science Pub Date : 2025-06-24 DOI: 10.1016/j.ijoes.2025.101105
Hao Miao , Hao Yu , Heqian Wang , Jinqiao Zheng , Cong Shao , Kui Xiao
{"title":"Corrosion behavior of 7A09 aluminum alloy exposed to propylene glycol coolant at different conditions","authors":"Hao Miao ,&nbsp;Hao Yu ,&nbsp;Heqian Wang ,&nbsp;Jinqiao Zheng ,&nbsp;Cong Shao ,&nbsp;Kui Xiao","doi":"10.1016/j.ijoes.2025.101105","DOIUrl":"10.1016/j.ijoes.2025.101105","url":null,"abstract":"<div><div>Aluminum alloys possess high strength and hardness, making them widely utilized in cooling systems. However, prolonged use can result in corrosion failure. To address the corrosion failure of 7A09 aluminum alloy in propylene glycol coolant, this study systematically investigates the synergistic effects of temperature (50–80 ℃), pH value (4–9), and Cl<sup>-</sup> concentration (30–90 mg/L) on the corrosion behavior of the aluminum alloy. A comprehensive approach was employed, integrating corrosion testing, electrochemical polarization curve measurements, surface morphology characterization via scanning electron microscopy, and surface composition analysis using X-ray photoelectron spectroscopy (XPS). The results showed that increasing temperature promotes the thermal oxidation of propylene glycol, resulting in the generation of organic acids and an exponential increase in the corrosion rate (I<sub>corr</sub> reached 3040 nA cm<sup>−2</sup> at 80 ℃). Elevated Cl<sup>-</sup> concentration significantly enhances the sensitivity of the passivation film pitting, with the corrosion current density rising by 24.3 times under 90 mg/L compared to the 30 mg/L conditions. A strongly acidic environment with pH= 4 induces acidic dissolution of the oxide film, whereas, under near-neutral conditions (pH=6–8), the aluminum passivation film synergizes with the Al<sub>2</sub>O<sub>3</sub> oxide film to effectively reduce the corrosion rate. XPS analysis further confirmed that Cl<sup>-</sup> attacks the C-O bond in propylene glycol molecules, leading to the formation of C-Cl compounds, which compromises the integrity of the protective film and accelerates localized pitting processes.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 9","pages":"Article 101105"},"PeriodicalIF":1.3,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144470712","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Beta vulgaris L. extracts as an additive on the electrodeposition of zinc on mild steel in chloride solution: coating characterization and corrosion behavior in seawater 甜菜提取物作为添加剂对氯化物溶液中低碳钢电沉积锌的影响:涂层表征和海水腐蚀行为
IF 1.3 4区 化学
International Journal of Electrochemical Science Pub Date : 2025-06-21 DOI: 10.1016/j.ijoes.2025.101104
Karima Hanini , Chabbi Kawther , Sameh Boudiba , Habiba Soltani , Louiza Boudiba , Merzoug Benahmed , Okba Louafi , Tayeb Bouarroudj , Selcuk Kucukaydin , Alfred Ngenge Tamfu
{"title":"Effect of Beta vulgaris L. extracts as an additive on the electrodeposition of zinc on mild steel in chloride solution: coating characterization and corrosion behavior in seawater","authors":"Karima Hanini ,&nbsp;Chabbi Kawther ,&nbsp;Sameh Boudiba ,&nbsp;Habiba Soltani ,&nbsp;Louiza Boudiba ,&nbsp;Merzoug Benahmed ,&nbsp;Okba Louafi ,&nbsp;Tayeb Bouarroudj ,&nbsp;Selcuk Kucukaydin ,&nbsp;Alfred Ngenge Tamfu","doi":"10.1016/j.ijoes.2025.101104","DOIUrl":"10.1016/j.ijoes.2025.101104","url":null,"abstract":"<div><div>Mild steel (MS), characterized by its low carbon content (0.05–0.25 %), is widely used in various industries but is vulnerable to corrosion, which limits its durability. Zinc electroplating, a well-established technique to protect MS, involves the deposition of a thin layer of zinc onto a metal substrate. This forms a corrosion-resistant zinc coating. In this study, natural phenolic extracts from <em>Beta vulgaris</em> L., specifically methanolic (ME), dichloromethane (MDE), ethyl acetate (EAE), and <em>n</em>-butanol (BE) extracts, were analyzed via HPLC-DAD and utilized as eco-friendly additives in zinc electroplating baths composed of ZnCl<sub>2</sub>, KCl, and H<sub>3</sub>BO<sub>4</sub>, to improve the quality and corrosion resistance of zinc coatings on MS. Incorporation of these extracts into the plating bath significantly improved the quality of zinc deposits. The enhanced brightness and refined surface morphology observed through scanning electron microscopy (SEM) and profilometry not only indicate the enhanced quality of the coatings but also suggest potential applications in industries where aesthetics and surface finish are important. Gravimetric corrosion tests and electrochemical evaluations, including potentiodynamic polarization (PP) and electrochemical impedance spectroscopy (EIS), demonstrated that zinc coatings formed in the presence of Beta vulgaris L. extracts exhibited remarkable corrosion resistance compared to conventional coatings. In addition, density functional theory (DFT)-based calculations were performed to investigate the adsorption behavior and chemical reactivity of the main phenolic compounds identified. Theoretical results revealed that ellagic acid exhibits the highest chemical activity, highlighting its key role in improving deposition efficiency and corrosion protection. This research underscores the potential of <em>Beta vulgaris</em> L. phenolic extracts as sustainable, natural additives for enhancing zinc electroplating processes. This offers a novel, environmentally friendly approach, addressing both performance enhancement and sustainability, and instilling hope for a more sustainable future in industrial plating processes.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 9","pages":"Article 101104"},"PeriodicalIF":1.3,"publicationDate":"2025-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144470740","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrochemical and computational study of the epicatechin-3-gallate isolated from green tea leaves as a corrosion inhibitor for 1018 carbon steel in sulfuric acid 从绿茶中分离的表儿茶素-3-没食子酸酯作为1018碳钢在硫酸中的缓蚀剂的电化学和计算研究
IF 1.3 4区 化学
International Journal of Electrochemical Science Pub Date : 2025-06-20 DOI: 10.1016/j.ijoes.2025.101092
Elizabeth America Flores-Frías , Horacio Martínez-Valencia , Victor Barba-López , Jesús Baldenebro-López , Linda Lucila Landeros-Martinez
{"title":"Electrochemical and computational study of the epicatechin-3-gallate isolated from green tea leaves as a corrosion inhibitor for 1018 carbon steel in sulfuric acid","authors":"Elizabeth America Flores-Frías ,&nbsp;Horacio Martínez-Valencia ,&nbsp;Victor Barba-López ,&nbsp;Jesús Baldenebro-López ,&nbsp;Linda Lucila Landeros-Martinez","doi":"10.1016/j.ijoes.2025.101092","DOIUrl":"10.1016/j.ijoes.2025.101092","url":null,"abstract":"<div><div>Camellia sinensis has been previously studied as a green corrosion inhibitor; most studies have focused on using the extract on low-carbon steels. However, this study aims to examine epicatechin-3-gallate, isolated from the group of catechins abundant in Camellia sinensis, demonstrating its greater efficacy as a corrosion inhibitor than green tea leaf extract. The almost complete isolation of epicatechin-3-gallate is easily reproducible and inexpensive, its main advantage compared to other corrosion inhibitors: it is easy to use and obtain, non-polluting, and completely biodegradable.</div><div>The compound was characterized by FTIR, <span><math><msup><mrow></mrow><mrow><mn>1</mn></mrow></msup></math></span>H-NMR, and Gas Chromatography-Mass Spectrometry, which corroborated the isolated catechins. The results in Electrochemical Impedance Spectroscopy (EIS) highlight the pseudo-inductive effect that decreases with increasing inhibitor concentration, thus increasing the resistance to charge transfer and inhibitory effectiveness. Potentiodynamic polarization curves (PPC) show passivations at 80 and 100 ppm that continue when polarized to higher potentials. The gravimetric test (wt ) was used to determine the corrosion rate, and the values obtained were used to obtain the adsorption isotherms. It was found that the adsorption of epicatechin-3-gallate follows the Langmuir method through physisorption; this finding was confirmed by scanning electron microscopy, which highlighted the high oxygen and carbon contents in the samples at 100 ppm. The optimized structure of Epicatechin-3-gallate was obtained using Density Functional Theory (DFT). The values obtained in the HOMO and LUMO orbitals showed that the inhibitor is most likely an electron donor concerning the metallic surface. The theoretical and experimental results will facilitate the application of epicatechin-3-gallate to inhibit the corrosion of 1018 carbon steel in acidic media.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 9","pages":"Article 101092"},"PeriodicalIF":1.3,"publicationDate":"2025-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144470711","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research on state of charge estimation of lithium battery based on adaptive forgetting factor recursive least squares and multi-innovation adaptive unscented Kalman filter 基于自适应遗忘因子递归最小二乘法和多创新自适应无气味卡尔曼滤波的锂电池充电状态估计研究
IF 1.3 4区 化学
International Journal of Electrochemical Science Pub Date : 2025-06-17 DOI: 10.1016/j.ijoes.2025.101103
Qiao Zhang, Fengyi Wang, Qijue Zhen
{"title":"Research on state of charge estimation of lithium battery based on adaptive forgetting factor recursive least squares and multi-innovation adaptive unscented Kalman filter","authors":"Qiao Zhang,&nbsp;Fengyi Wang,&nbsp;Qijue Zhen","doi":"10.1016/j.ijoes.2025.101103","DOIUrl":"10.1016/j.ijoes.2025.101103","url":null,"abstract":"<div><div>State of charge (SOC) estimation is critical to battery management and mileage prediction of electric vehicles. Model-based SOC estimation supply an effective solution to computation efficiency, but its accuracy highly dependent on model parameters. Three key technical contributions are made. First, the traditional model parameter identification method based on recursive least squares with forgetting factor (FFRLS) often sets its forgetting factor to be a constant during the iterative process, while disregarding estimated voltage accuracy. In this study, an adaptive forgetting factor recursive least squares method (AFFRLS) is proposed based on the adaptive theory. The core idea is that the forgetting factor is adaptively adjusted according to preset adaptive formula of the voltage error. In this way, both robustness and identification accuracy of the algorithm can be improved effectively. Second, a multi-innovation adaptive unscented Kalman filter (MIAUKF) is proposed to utilize historical voltage data and weaken the impact of voltage cumulative error on SOC accuracy. Finally, the performance of the proposed approach is evaluated by comparison simulations considering three different temperature scenarios based on two standard driving cycles. The results show that the proposed approach can obtain higher accuracy in SOC estimation with maximum relative error below 2 %.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 9","pages":"Article 101103"},"PeriodicalIF":1.3,"publicationDate":"2025-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144365676","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dynamic double similarity fusion based on ΔQ power law for early-cycle RUL prediction of lithium-ion batteries 基于ΔQ幂律的锂离子电池早期RUL预测动态双相似融合
IF 1.3 4区 化学
International Journal of Electrochemical Science Pub Date : 2025-06-17 DOI: 10.1016/j.ijoes.2025.101102
Yisheng He , Rongchun Hu , Yue Jia , Pu Ren , Xianpei Chen , Peng Shi
{"title":"Dynamic double similarity fusion based on ΔQ power law for early-cycle RUL prediction of lithium-ion batteries","authors":"Yisheng He ,&nbsp;Rongchun Hu ,&nbsp;Yue Jia ,&nbsp;Pu Ren ,&nbsp;Xianpei Chen ,&nbsp;Peng Shi","doi":"10.1016/j.ijoes.2025.101102","DOIUrl":"10.1016/j.ijoes.2025.101102","url":null,"abstract":"<div><div>Accurately predicting the remaining useful life (RUL) of lithium-ion batteries is essential for ensuring system safety and minimizing economic losses. However, existing methods generally rely on numerous feature parameters while underutilizing the potential of historical sample data. Additionally, in the early stages of RUL, the weak correlation between capacity and historical samples often compromises prediction accuracy. To address these challenges, this paper proposes a novel prediction framework, DDSF-QD (Dynamic Double Similarity Fusion model incorporating ΔQ Power Law and Dynamic Time Warping). First, the original data are denoised using the CFK method (CEEMDAN-Fuzzy Entropy-K-means) to improve data quality. Then, the proposed ΔQ(V) power law is constructed to evaluate lifetime similarity, and combined with the DTW (Dynamic Time Warping) algorithm to calculate the initial spatial similarity. High-quality historical samples are used to train the network, and then their corresponding weights are dynamically fused within the DDSF (Dynamic Double Similarity Fusion model) framework to update sample weights. This enables the prediction network to estimate future capacity degradation trends and predict RUL based on a predefined failure threshold. Experimental results on classical lithium-ion battery aging datasets demonstrate the superior performance of the proposed method, achieving a coefficient of determination (R²) of 99.85 %. To the best of our knowledge, both the ΔQ(V) power law and the DDSF framework are proposed for the first time, highlighting their potential in battery health management.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 10","pages":"Article 101102"},"PeriodicalIF":1.3,"publicationDate":"2025-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144549955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of electrochemical polishing on the surface properties of laser-cut Ni–Ti alloy cardiovascular stents 电化学抛光对激光切割镍钛合金心血管支架表面性能的影响
IF 1.3 4区 化学
International Journal of Electrochemical Science Pub Date : 2025-06-15 DOI: 10.1016/j.ijoes.2025.101101
Yizhi Zhou , Mingxia Chai , Fengjie Yan , Zhiyong Li
{"title":"Effects of electrochemical polishing on the surface properties of laser-cut Ni–Ti alloy cardiovascular stents","authors":"Yizhi Zhou ,&nbsp;Mingxia Chai ,&nbsp;Fengjie Yan ,&nbsp;Zhiyong Li","doi":"10.1016/j.ijoes.2025.101101","DOIUrl":"10.1016/j.ijoes.2025.101101","url":null,"abstract":"<div><div>The Ni–Ti alloy, known for its shape memory effect, superelasticity, and remarkable biocompatibility, has emerged as a promising biomedical material. Its favourable surface properties have resulted in the requirements for its usage growing significantly, including in applications with small structures and complex geometries such as cardiovascular stents. Compared to sandblasting, grinding, and other surface treatment methods for such complex applications, electrochemical polishing offers the advantages of non-contact processing and uniform treatment; consequently, it has become a key surface treatment technique for cardiovascular stents. To further clarify the overall influence of electrochemical polishing on the service performance of cardiovascular stents, this study investigates the effects of electrochemical polishing parameters, such as the current density, electrode spacing, polishing temperature, and polishing time, on the surface performance of Ni–Ti alloy cardiovascular stents. This was achieved through orthogonal and one-factor experiments conducted on a custom-built cardiovascular stent polishing platform, with the goal of identifying the optimal process parameters. The results reveal that electrochemical polishing effectively reduces the surface roughness of the stent, eliminates defects such as thermal damage remaining after laser cutting, and improves the surface quality. Additionally, the oxide film formed on the surface after polishing enhances the corrosion resistance and prevents Ni ion precipitation. Overall, these findings provide a valuable reference for improving the serviceability and biocompatibility of Ni–Ti alloy cardiovascular stents.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 9","pages":"Article 101101"},"PeriodicalIF":1.3,"publicationDate":"2025-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144307541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Plasmon-enhanced electrochemistry: Fundamentals and potential applications 等离子体增强电化学:基本原理和潜在应用
IF 1.3 4区 化学
International Journal of Electrochemical Science Pub Date : 2025-06-14 DOI: 10.1016/j.ijoes.2025.101100
Zhixuan Lu
{"title":"Plasmon-enhanced electrochemistry: Fundamentals and potential applications","authors":"Zhixuan Lu","doi":"10.1016/j.ijoes.2025.101100","DOIUrl":"10.1016/j.ijoes.2025.101100","url":null,"abstract":"<div><div>Plasmon-enhanced electrochemistry is an interdisciplinary field integrating photonic excitation, plasmonic nanostructures, and applied electrochemical potentials. Building upon the established applications of plasmonic phenomena in photocatalysis and electrocatalysis, plasmon-enhanced electrochemistry has emerged as a novel research frontier attracting significant scientific attention. While numerous systematic investigations have been conducted to elucidate both theoretical frameworks and experimental manifestations of plasmon-enhanced electrochemical systems, fundamental understanding of their underlying physicochemical mechanisms remains incomplete. This review aims to establish a mechanistic foundation for plasmon-enhanced electrochemical processes, and propose strategic perspectives for harnessing plasmon-enhanced electrochemical principles in reaction engineering. Such advancements could ultimately enable innovative approaches to energy conversion technologies.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 9","pages":"Article 101100"},"PeriodicalIF":1.3,"publicationDate":"2025-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144307600","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on Corrosion Behaviour and Corrosion Inhibitor of X65 Subsea Pipelines X65海底管道腐蚀行为及缓蚀剂研究
IF 1.3 4区 化学
International Journal of Electrochemical Science Pub Date : 2025-06-13 DOI: 10.1016/j.ijoes.2025.101098
Ninghua Wen , Haiyuan Yao , Yongfei Liu , Dan Li , Xiuyun Wang , Maomao Wang , Lu Minxu
{"title":"Study on Corrosion Behaviour and Corrosion Inhibitor of X65 Subsea Pipelines","authors":"Ninghua Wen ,&nbsp;Haiyuan Yao ,&nbsp;Yongfei Liu ,&nbsp;Dan Li ,&nbsp;Xiuyun Wang ,&nbsp;Maomao Wang ,&nbsp;Lu Minxu","doi":"10.1016/j.ijoes.2025.101098","DOIUrl":"10.1016/j.ijoes.2025.101098","url":null,"abstract":"<div><div>In this study, the corrosion behaviour and corrosion mechanisms of X65 pipeline steel was examined in different production processes by using high-temperature and high-pressure autoclaves, conducting electrochemical testing, and employing multiphase flow loops. In addition, the protective effect of a corrosion inhibitor was examined. The results indicated that at a CO<sub>2</sub> partial pressure of 0.04 MPa, the corrosion rate of X65 pipeline steel increased from 0.023 to 0.183 mm/a as the flow rate was increased from 0 to 4 m/s. This increase in the corrosion rate was attributable to an increase in wall shear stress caused by fluid flow, highlighting the effect of flow-accelerated corrosion. Under a CO<sub>2</sub> content of 0.39 %–10 % (with a partial pressure of 0.04–1 MPa), the corrosion rate of X65 pipeline steel increased from 0.085 to 0.293 mm/a with increasing CO<sub>2</sub> content. The addition of an LS-A-type imidazoline-based corrosion inhibitor concentration of 200 ppm, the corrosion inhibition efficiency reached 86.69 %.Study indicating high corrosion inhibition performance under field production conditions with temperatures not exceeding 40°C and flow rates not exceeding 4 m/s.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 9","pages":"Article 101098"},"PeriodicalIF":1.3,"publicationDate":"2025-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144297569","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Boron-doped SiOC anode material with an yolk shell multistage structure for lithium-ion batteries 锂离子电池蛋黄壳多级结构掺硼SiOC负极材料
IF 1.3 4区 化学
International Journal of Electrochemical Science Pub Date : 2025-06-13 DOI: 10.1016/j.ijoes.2025.101099
Lei Chen , Qiaoqiao Ye , Chengxuan Han , Minjie Pu , Hongying Ma , Xiuji Weng , Jianping Yang
{"title":"Boron-doped SiOC anode material with an yolk shell multistage structure for lithium-ion batteries","authors":"Lei Chen ,&nbsp;Qiaoqiao Ye ,&nbsp;Chengxuan Han ,&nbsp;Minjie Pu ,&nbsp;Hongying Ma ,&nbsp;Xiuji Weng ,&nbsp;Jianping Yang","doi":"10.1016/j.ijoes.2025.101099","DOIUrl":"10.1016/j.ijoes.2025.101099","url":null,"abstract":"<div><div>In this work, a boron-doped yolk-shell structured B-YS@C was constructed on the surface of SiOC anodes with yolk-shell structures via a combination of redox processes, freeze-drying, and heteroatom infiltration. Multilevel pore formation was achieved by controlling experimental conditions. The structure and morphology of the materials were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results demonstrate that boron was successfully doped into the material structure, and the yolk-shell structure exhibits good integrity and multilevel pore characteristics. Electrochemical tests show that the boron-doped yolk-shell multilevel structured anode composite delivers excellent specific capacity (473 mAh g<sup>−1</sup>), rate performance, and cycling stability (retaining 99.9 % average coulombic efficiency after 300 cycles) at a current density of 0.5 A g<sup>−1</sup>. Compared with YS@C, the B-YS@C electrode maintains a specific capacity of 473 mAh g<sup>−1</sup> and 99.9 % average coulombic efficiency with almost no capacity decay after 300 cycles at 0.5 A g<sup>−1</sup>, demonstrating ultra-strong cycling stability. These results highlight its broad application prospects.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 9","pages":"Article 101099"},"PeriodicalIF":1.3,"publicationDate":"2025-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144320851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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