Study on Corrosion Behaviour and Corrosion Inhibitor of X65 Subsea Pipelines

IF 2.4 4区 化学 Q4 ELECTROCHEMISTRY
Ninghua Wen , Haiyuan Yao , Yongfei Liu , Dan Li , Xiuyun Wang , Maomao Wang , Lu Minxu
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Abstract

In this study, the corrosion behaviour and corrosion mechanisms of X65 pipeline steel was examined in different production processes by using high-temperature and high-pressure autoclaves, conducting electrochemical testing, and employing multiphase flow loops. In addition, the protective effect of a corrosion inhibitor was examined. The results indicated that at a CO2 partial pressure of 0.04 MPa, the corrosion rate of X65 pipeline steel increased from 0.023 to 0.183 mm/a as the flow rate was increased from 0 to 4 m/s. This increase in the corrosion rate was attributable to an increase in wall shear stress caused by fluid flow, highlighting the effect of flow-accelerated corrosion. Under a CO2 content of 0.39 %–10 % (with a partial pressure of 0.04–1 MPa), the corrosion rate of X65 pipeline steel increased from 0.085 to 0.293 mm/a with increasing CO2 content. The addition of an LS-A-type imidazoline-based corrosion inhibitor concentration of 200 ppm, the corrosion inhibition efficiency reached 86.69 %.Study indicating high corrosion inhibition performance under field production conditions with temperatures not exceeding 40°C and flow rates not exceeding 4 m/s.
X65海底管道腐蚀行为及缓蚀剂研究
在本研究中,通过高温高压高压灭菌器、电化学测试和多相流回路等方法,研究了X65管道钢在不同生产工艺下的腐蚀行为和腐蚀机理。此外,还考察了缓蚀剂的保护作用。结果表明:当CO2分压为0.04 MPa时,随着流速从0 ~ 4 m/s增加,X65管线钢的腐蚀速率从0.023 ~ 0.183 mm/a增加;腐蚀速率的增加是由于流体流动引起的壁面剪切应力的增加,突出了流动加速腐蚀的影响。在CO2含量为0.39 % ~ 10 %(分压为0.04 ~ MPa)条件下,随着CO2含量的增加,X65管线钢的腐蚀速率由0.085增加到0.293 mm/a。添加浓度为200 ppm的ls - a型咪唑啉基缓蚀剂,缓蚀效率达到86.69 %。研究表明,在温度不超过40℃、流速不超过4 m/s的现场生产条件下,具有较高的缓蚀性能。
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来源期刊
CiteScore
3.00
自引率
20.00%
发文量
714
审稿时长
2.6 months
期刊介绍: International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry
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