International Journal of Adhesion and Adhesives最新文献

{"title":"The latest research progress of polyurethane modified asphalt binder: synthesis, characterization, and applications","authors":"Jinyuan Lu ,&nbsp;Shaofeng Xu ,&nbsp;Chuanqiang Li ,&nbsp;Chaoliang Fu ,&nbsp;Mengjie Gao ,&nbsp;Zhimei Wang ,&nbsp;Fan Yang ,&nbsp;Gang Zhou ,&nbsp;Rukai Li ,&nbsp;Tianqing Ling","doi":"10.1016/j.ijadhadh.2025.104035","DOIUrl":"10.1016/j.ijadhadh.2025.104035","url":null,"abstract":"<div><div>Polyurethane (PU) is widely used in the automotive, furniture, and aviation industries. Recently, an increasing number of researchers used PU as a modifier for asphalt pavement modification due to its excellent wear resistance, high-low temperature performance and elasticity. Herein, the latest research progress of PU modified asphalt (PUMA) was reviewed through the following aspects: The preparation process of PU and PUMA; Analyzes the mechanism of polyurethane modified asphalt from a microscopic point of view; The use of molecular dynamics simulation to study the performance of polyurethane modified asphalt. The use of PU as a modifier, such as PU emulsified asphalt, PU foam asphalt, PU recycled asphalt, PU solid-solid phase change asphalt, bio-based PU-modified asphalt, self-repairing PU-modified asphalt; The use of PU and other modifiers composite modify asphalt. For example, PU/nano-materials, PU/SBS, PU/epoxy resin, and PU/warm mix additive modified asphalt; The use of PUMA in tunnels, bridge deck pavements, functional pavements, and special scenarios for crack and pothole maintenance. Furthermore, the challenges and future trends in PU-modified asphalt were reviewed drawing on current research findings.</div></div>","PeriodicalId":13732,"journal":{"name":"International Journal of Adhesion and Adhesives","volume":"140 ","pages":"Article 104035"},"PeriodicalIF":3.2,"publicationDate":"2025-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143845096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The interaction of focused ultrasound and dentin: Thermal, structural and chemo-mechanical characterization","authors":"Cheryl Fu ,&nbsp;Sheetal M. Rajan ,&nbsp;Mohamed M. Awad ,&nbsp;Wanlu Ouyang ,&nbsp;Peta L. Clode ,&nbsp;Amr S. Fawzy","doi":"10.1016/j.ijadhadh.2025.104033","DOIUrl":"10.1016/j.ijadhadh.2025.104033","url":null,"abstract":"<div><h3>Objective</h3><div>This laboratory study aimed to develop an <em>ex vivo</em> model simulating pulpal micro-circulation to characterize temperature variations within the pulpal space following high intensity focused ultrasound (HIFU) exposure. In addition, to assess the interaction and effect of HIFU exposure parameters on human dental pulp stem cells (hDPSCs) response and the variations in dentin surface microstructure and chemo-mechanical characteristics.</div></div><div><h3>Methods</h3><div>Thermal camera mapping and intra-pulpal temperature measurements with thermocouples were conducted (continuous measurement of 60 s) at HIFU intensities of 20 and 25 W with varying active-duty ratios. hDPSCs tolerance and viability were assessed via acid-phosphatase assay and live/dead fluorescence imaging. Subsequently the effect of HIFU exposure on the structure, chemical composition and nano-mechanical properties of dentin was characterised by scanning electron microscopy, atomic force microscopy, transmission electron microscopy, Raman spectroscopy and nano-indentation testing.</div></div><div><h3>Results</h3><div>Thermal analyses revealed two potentially thermally favourable HIFU exposure parameters: 20 W and 25 W at active-duty ratio of 1/6 ms. The two identified HIFU parameters were further investigated at 30 and 60 s treatment time on dentin surface. HIFU treatment did not result in statistically detrimental effects on the viability of hDPSCs (p &gt; 0.05). HIFU treatment for 60 s effectively removed the overlying smear layer exposing dentin-tubules orifices and partial revealed collagen fibril's structure. No significant change in roughness or chemical composition (960/1450 cm⁻¹ mineral/organic ratio) was detected after HIFU treatment (p &gt; 0.05). However, HIFU treatment at 25 W for 60 s resulted in a significant decrease (p &lt; 0.05) in surface hardness compared to sound dentin.</div></div><div><h3>Significance</h3><div>HIFU treatment at 25 W for 60 s demonstrates effective removal of the dentin smear layer and partial exposure of dentin collagen fibrils without significantly altering the dentin chemical composition without adversely affecting the underlying hDPSCs.</div></div>","PeriodicalId":13732,"journal":{"name":"International Journal of Adhesion and Adhesives","volume":"140 ","pages":"Article 104033"},"PeriodicalIF":3.2,"publicationDate":"2025-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143825588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mechanism of improving the shear strength of EVA hot melt adhesives by fumed silica and microsilica powder","authors":"Congyun Shi ,&nbsp;Bilian Chen ,&nbsp;Danjun Wang ,&nbsp;Daolei Zhang","doi":"10.1016/j.ijadhadh.2025.104030","DOIUrl":"10.1016/j.ijadhadh.2025.104030","url":null,"abstract":"<div><div>Modification of EVA hot melt adhesives by using inorganic powder is a common method to improve the mechanical properties of hot melt adhesives. In this paper, porous fumed silica with large specific surface area and solid non-porous microsilica powder with small specific surface area were added to EVA hot melt adhesives respectively. The magnitude of the enhancement of the shear strength of EVA hot melt adhesives was explored, and the mechanisms that the two kinds of powders enhance the shear strength were investigated by XPS, ATR-IR, ¹HNMR, FE-SEM and DSC. The addition of fumed silica increased the shear strength of the composite hot melt adhesives, and reached the maximum value when the powder content was 2 %, which increased by about 14.3 % compared with pure EVA hot melt adhesives. Through XPS, ATR-IR and ¹HNMR it was found that the Si-OH on the surface of SiO₂ particles reacted with the ester carbonyl group in EVA to produce polymer alcohol, and the strong polar hydroxyl group on the surface of SiO₂ was changed to an acyl oxygen group. The acylation of the particles surface is conducive to reducing the agglomeration of SiO₂ particles and improving the compatibility between inorganic particles and organic polymers. The composite hot melt adhesive with 1 %, 2 %, and 3 % fumed silica content shows slight agglomeration of inorganic powder, while the agglomeration is significantly severe when the content is 4 %. DSC analysis showed that the crystallinity of EVA composite hot melt adhesives decreased first and then increased with the increase of powder content, and the decrease of crystallinity increased the shear strength. The improvement of the shear strength can be attributed to the enhancement of the compatibility caused by the reaction between fumed silica and EVA organic, as well as the decrease in crystallinity. The addition of microsilica powder improved the shear strength of the composite hot melt adhesives also, and the maximum value was reached when the powder content is 25 %, which was about 10.6 % higher than that of pure EVA hot melt adhesives. The increase amplitude is smaller than that of fumed silica. The reaction between microsilica powder particles and EVA pure hot melt adhesives was not found by XPS and ATR-IR detection, however, the ¹HNMR spectrum showed that there is a partial reaction between them, the degree of reaction was less than that between fumed silica and EVA hot melt adhesive. The crystallinity also showed a trend of first decreasing and then increasing with the increase of powder addition, with the minimum crystallinity at 10 %. The enhancement of the shear strength of hot melt adhesives by microsilica powder may be mainly attributed to the decrease in crystallinity.</div></div>","PeriodicalId":13732,"journal":{"name":"International Journal of Adhesion and Adhesives","volume":"140 ","pages":"Article 104030"},"PeriodicalIF":3.2,"publicationDate":"2025-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143823593","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Optimization design and curing behaviors of polyurethane (PU) modified asphalt from the perspective of cohesion-adhesion variations","authors":"Jianhua Yang ,&nbsp;Ke Zhang ,&nbsp;Yuanyuan Wang ,&nbsp;Fei Zhou ,&nbsp;Zhongnan Tian","doi":"10.1016/j.ijadhadh.2025.104034","DOIUrl":"10.1016/j.ijadhadh.2025.104034","url":null,"abstract":"<div><div>Interface properties of asphalt and aggregate intimately affect the service-performance and durability of asphalt pavement. The research aimed to explore the cohesion-adhesion characteristics of polyurethane (PU) modified asphalt, and thus optimizing its constituent proportion and understanding its curing behaviors. To this end, several proportion schemes of PU modified asphalt were first designed with response surface methodology (RSM), and the corresponding asphalt binders were prepared and their cohesion-adhesion features were characterized based on contact angle test and thermodynamic theory. On this basis, the effects of composition ratio and its interactions on the cohesion-adhesion features were analyzed and the optimal composition ratio was determined. Lastly, the adhesion features of PU modified asphalt during its curing period were measured using pull-out test and atomic force microscopy (AFM), and thus the curing behaviors were expounded. The results showed that the composition-associated factors had interactive impacts on the cohesion and adhesion of PU modified asphalt, wherein the influence of PU prepolymer on the adhesion was more significant as the curing agent was incorporated at the high ratio. Further, the increase of compatibilizer and diluent adversely affected the cohesion-adhesion capacity of PU modified asphalt, and for obtaining the favorable cohesion-adhesion competence, the optimal constituent proportion was determined as PU prepolymer: curing agent: compatibilizer: diluent = 14: 1.80: 1.88: 3.12. During the curing process, the adhesion performance and microscopic phase structure of PU modified asphalt exhibited the character of an initially visible ascending variation followed by a tendency to stabilize, and the eventual adhesion properties were not related to the solidification temperature set in the research. The research is of great significance for guiding the development of PU modified asphalt with satisfactory interfacial properties and understanding its curing process.</div></div>","PeriodicalId":13732,"journal":{"name":"International Journal of Adhesion and Adhesives","volume":"140 ","pages":"Article 104034"},"PeriodicalIF":3.2,"publicationDate":"2025-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143825589","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Flaw classification in bonded joints using multivariate statistical analysis and artificial intelligence","authors":"Carlos Tais ,&nbsp;Juan M. Fontana ,&nbsp;Leonardo Molisani ,&nbsp;Ronald O'Brien ,&nbsp;Yolanda Ballesteros ,&nbsp;Raquel Caro Carretero ,&nbsp;Juan C. del Real-Romero","doi":"10.1016/j.ijadhadh.2025.104032","DOIUrl":"10.1016/j.ijadhadh.2025.104032","url":null,"abstract":"<div><div>Adhesives play an important role in multiple industries, offering versatile bonding solutions for diverse applications. However, their incorporation in structures where safety is critical has been met with hesitation due to potential degradation risks. Addressing this concern, this study introduces the preliminary assessment of a pattern recognition method aimed at automatically identifying damage in adhesive joints through acoustic signal analysis. This method was tested on experimental samples consisting of aluminum substrates bonded with an acrylic adhesive. Artificially generated defects on the samples was related to the percentage of bonded surface. Damaged samples contained either 25 %, 50 %, or 75 % of bonded surface, whereas healthy samples contained 100 % of bonded surface. Experiments involved applying an impulsive load at one end of the sample and recording the acoustic signal emitted in response to the load using a microphone located at the opposite end. Two classification algorithms were evaluated for discriminating the amount of damage of the samples. First, a multivariate statistical analysis extracted the fundamental frequencies from the acoustic signals to create a model that achieved 95 % of classification accuracy. Second, an Artificial Neural Network (ANN) model was trained and validated with features extracted from the sound pressure level (SPL) signal obtaining an average accuracy of 97.1 % for a 9-fold cross-validation. The results indicate that there is potential for further exploration of the proposed approach, leading to the development of a robust system capable of automatically detecting damage in bonded joints. Future work will explore the performance of the classification techniques for detecting other types of defects related to the lack of adhesion and inadequate curing times.</div></div>","PeriodicalId":13732,"journal":{"name":"International Journal of Adhesion and Adhesives","volume":"140 ","pages":"Article 104032"},"PeriodicalIF":3.2,"publicationDate":"2025-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhancing adhesion strength of protein-based adhesives through plywood heat treatment","authors":"Yizhou Chen ,&nbsp;Roselle Barretto ,&nbsp;Guangyan Qi ,&nbsp;Christopher Jones ,&nbsp;Donghai Wang ,&nbsp;Xiuzhi Susan Sun","doi":"10.1016/j.ijadhadh.2025.104029","DOIUrl":"10.1016/j.ijadhadh.2025.104029","url":null,"abstract":"<div><div>Heat treatment of wood in the absence of oxygen is widely used in industry to enhance raw wood properties, but cannot be broadly applied to engineered wood like plywood. Most synthetic adhesives, particularly formaldehyde-based ones, degrade at high-temperatures and release toxic substances, harming the environment. This study explored protein-based adhesives for heat-treated plywood, inspired by high-temperature, controlled oxygen or non-oxygen conditions in baking. Three adhesive formulations—soy flour (SF), polyamide-epichlorohydrin modified soy flour (PAE/SF), and urea formaldehyde (UF)—were used with yellow pine wood and heat-treated at 190–200 °C for 1–4 h. Untreated UF plywood demonstrated good dry and wet strength, but significant strength loss and complete delamination after heat treatment. Conversely, heat-treated SF plywood showed substantial improvements in wet strength, reaching 1.31 MPa at 190 °C for 2 h and 1.48 MPa at 200 °C for 1.5 h. PAE/SF plywood maintained high wet strength, peaking at 1.74 MPa at 190 °C for 1 h. The enhanced water resistance resulted from protein denaturation, loss of hydrophilic groups, and crosslinking during heat treatment. Maillard reactions further improved water resistance by forming covalent bonds and melanoidins. Heat treatment at 200 °C for 2 h also improved the dimensional stability of the plywood while maintaining acceptable bending and tensile strengths. This study highlights the potential of protein-based adhesives as an eco-friendly alternative for improving heat-treated plywood properties.</div></div>","PeriodicalId":13732,"journal":{"name":"International Journal of Adhesion and Adhesives","volume":"140 ","pages":"Article 104029"},"PeriodicalIF":3.2,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143823594","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Waterborne polyurethane adhesives grafted with carbon dots for enhancing dispersion, cohesion, and adhesion","authors":"Jing Wan,&nbsp;Daiyong Ye","doi":"10.1016/j.ijadhadh.2025.104031","DOIUrl":"10.1016/j.ijadhadh.2025.104031","url":null,"abstract":"<div><div>Carbon dots (CDs) possess abundant functional groups on their surfaces and can be easily modified, allowing for covalent bonding with waterborne polyurethane (WPU) to create eco-friendly adhesives that exhibit both high cohesion and strong adhesion. However, as a type of nanofiller, CDs often aggregate, hindering effective dispersion. To address this dispersion challenge and enhance the properties of WPU adhesives, CDs were chemically grafted onto the macromolecular chains of WPUs using a silane coupling agent (KH550) as a linking agent. This method improved the adhesion strength of the resulting WPU nanocomposite adhesives, demonstrating the scientific validity of the approach. The successful grafting was confirmed through Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and energy-dispersive spectroscopy. Optimizing the material ratios between the silane coupling agent and CDs significantly reduced CD aggregation in the WPU adhesives, as shown by scanning electron microscopy images that indicated efficient dispersion of the CDs. Malvern particle size analysis and thermogravimetric analysis revealed that when the CDs-to-KH550 mass ratio was 1:10, the water dispersion particle size of silane-modified CDs (KCD) decreased from 447.7 nm to 160.0 nm, and the total weight loss reduced from 53.07 % to 35.55 %. Furthermore, the adhesion properties of WPU adhesives modified with KCDs (KCD-WPU) were notably enhanced. The U-peel strength of the KCD-WPU adhesive on the steel test sheet increased by 31.8 %–510 N m⁻¹ when the KCD content was 0.1 wt.%. The tensile strength of the KCD-WPU adhesive was 62.6 % greater than that of the original WPU adhesive. We proposed a mechanism for the improvement of properties in WPU adhesives grafted with a small amount of CDs. This research presents an effective solution to the agglomeration of CDs in WPU adhesives, thereby enhancing both cohesive and adhesive strength. This study lays the groundwork for designing high-performance WPU adhesives.</div></div>","PeriodicalId":13732,"journal":{"name":"International Journal of Adhesion and Adhesives","volume":"140 ","pages":"Article 104031"},"PeriodicalIF":3.2,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143858874","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Adhesive properties of universal adhesives systems containing zinc oxide and copper nanoparticles on sound dentine: A 2-year evaluation","authors":"Mario Felipe Gutiérrez ,&nbsp;Romina Aliaga-Gálvez ,&nbsp;Carolina Pardo-Diaz ,&nbsp;Alejandra Nuñez ,&nbsp;Sofía Cavagnaro ,&nbsp;Rocío Maturana ,&nbsp;Alessandra Reis ,&nbsp;Eduardo Fernández ,&nbsp;Alessandro D. Loguercio","doi":"10.1016/j.ijadhadh.2025.104023","DOIUrl":"10.1016/j.ijadhadh.2025.104023","url":null,"abstract":"<div><h3>Objectives</h3><div>This study evaluated the effect of adding zinc oxide and copper nanoparticles (ZnO/CuNp) to universal adhesives (UA) on resin-dentine microtensile bond strength (μTBS), nanoleakage (NL), and the presence of ZnO/CuNp within the hybrid layer at immediate time (IM) and after 2 years of water storage (2y).</div></div><div><h3>Methods</h3><div>ZnO/CuNp (commercial adhesive [control]; 5/0.1 and 5/0.2 wt%) were added to Prime&amp;Bond Active (PBA) and Ambar Universal (AMB). The UAs were applied to flat dentine surfaces, followed by composite resin build-ups. These were then sectioned into resin–dentine bonded sticks. μTBS, NL and presence of ZnO/CuNp in the hybrid layer were evaluated at IM and after 2y. Data were analyzed with three-way ANOVA and Tukey's post hoc test (α = 0.05).</div></div><div><h3>Results</h3><div>The addition of ZnO/CuNp to UAs did not affect μTBS at IM (p &gt; 0.05). After 2y, μTBS values were higher in the 5/0.1 and 5/0.2 wt% groups for AMB (p &lt; 0.05), with values maintained for the PB (p &gt; 0.05). All groups showed a decrease in μTBS over time (p &lt; 0.05), except for the AMB-5/0.1 wt% group in etch-and-rinse mode. NL was lower in the ZnO/CuNp groups at both IM and 2y compared to control (p &lt; 0.05). NL increased over time for all groups (p &lt; 0.05). ZnO/CuNp remained in the hybrid layer after 2y.</div></div><div><h3>Conclusions</h3><div>ZnO/CuNp improves adhesive interface stability and remains effective in the hybrid layer after 2 years of water storage.</div></div>","PeriodicalId":13732,"journal":{"name":"International Journal of Adhesion and Adhesives","volume":"140 ","pages":"Article 104023"},"PeriodicalIF":3.2,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143790882","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Aging resistance and adhesion strength of cold plasma treated aluminum-polypropylene joints: The role of surface treatments and curing agents","authors":"Zümre Oymak ,&nbsp;Omur Aras","doi":"10.1016/j.ijadhadh.2025.104027","DOIUrl":"10.1016/j.ijadhadh.2025.104027","url":null,"abstract":"<div><div>With the developing technology, Aluminum (Al) - Polypropylene (PP) composite materials, which combine lightness and high durability, are widely used especially in the aviation and automotive sectors. In this study, different combinations of surface treatment methods such as; sanding, sandblasting, chemical etching, anodization and cold vacuum plasma, were applied to the surface of PP and Al plates. After treatment procedures, these surfaces bonded with epoxy adhesives prepared with Triethylenetetramine (Teta), m-Xylenediamine (Mx) and Phenalkamine (PA) curing agents. The effect of the aging process on the bonding strength was investigated on various samples kept in a hot water bath for 2 months. Contact angle measurement, topography analyses, FTIR and tensile test measurements were conducted for evaluation of the given effects. In the experiments, the highest strength was obtained by bonding of sanded/plasma-treated PP plates with the chemical etched/anodized/plasma-treated Al plates. Compared to the non-surface treatment plates, an increase of 558.72 % was achieved and a tensile strength of 1840 N (9.2 MPa) was handled. According to the aging results, it was determined that the greatest decrease in adhesion strength occurred in the plates bonded with Teta, while the least decrease occurred with PA curing agent. More resistant structures to the aging were obtained by first sandblasted, then anodized and then plasma applied aluminum plates bonded with sanded and plasma activated PP surfaces. It was determined that especially plasma-treated surfaces were more resistant to the aging than non-plasma activated surfaces.</div></div>","PeriodicalId":13732,"journal":{"name":"International Journal of Adhesion and Adhesives","volume":"140 ","pages":"Article 104027"},"PeriodicalIF":3.2,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143806842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Acid-base properties of polydimethylsiloxane based adhesives and their influence on adhesion to polymer surfaces","authors":"Raul Renken ,&nbsp;Theresia Köhler ,&nbsp;Sascha Schäfer ,&nbsp;Andreas Hartwig","doi":"10.1016/j.ijadhadh.2025.104028","DOIUrl":"10.1016/j.ijadhadh.2025.104028","url":null,"abstract":"<div><div>This work aimed to investigate the adhesive properties of polysiloxanes (silicones) on polymer surfaces in relation to their acid-base properties. To adjust the acid-base properties of polydimethylsiloxane (PDMS) based formulations, (3-aminopropyl)-trimethoxysilane (AMMO) and [(3-triethoxysilyl)-propyl]succinic anhydride (SAS) were added as silane coupling agents. The acid-base properties of the resulting formulations were investigated by measuring the isoelectric point (IEP) via zeta potential measurements as well as by measuring the contact angle on cured samples with probe liquids of different pH. The IEP could be increased gradually from 5.7 to 9.3 by addition of AMMO and decreased gradually from 5.7 to 2.7 by addition of SAS. The adhesion to various polymers was determined by tensile lap shear strength measurements on HDPE, PET, PMMA, PVC and PA as well as on glass. Silicones containing AMMO showed a higher shear strength on all polymers compared to the acidic SAS containing silicones. The IEP leading to maximum shear strength depends on the respective polymer surface, which makes the adjustment of the acid-base properties a useful tool for optimizing adhesion. Furthermore, measuring the zeta potential as well as the surface energy of the substrate surfaces revealed significant differences in their polarity. In addition, an approximately linear increase of the maximum shear strength measured on each substrate could be observed with increasing zeta potential of the substrate at pH 9.7. These findings show that zeta potential measurements of both adhesive and substrate have the potential to be a powerful tool for predicting adhesive interactions.</div></div>","PeriodicalId":13732,"journal":{"name":"International Journal of Adhesion and Adhesives","volume":"140 ","pages":"Article 104028"},"PeriodicalIF":3.2,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143790883","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}