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Exploring the high elongation at break of windmill palm fiber 探索风车棕榈纤维的高断裂伸长率
IF 5.6 1区 农林科学
Industrial Crops and Products Pub Date : 2024-10-31 DOI: 10.1016/j.indcrop.2024.119912
Zhong Wang , Guohe Wang , Jingjing Shi , Hongyun Guo , Changjie Chen
{"title":"Exploring the high elongation at break of windmill palm fiber","authors":"Zhong Wang ,&nbsp;Guohe Wang ,&nbsp;Jingjing Shi ,&nbsp;Hongyun Guo ,&nbsp;Changjie Chen","doi":"10.1016/j.indcrop.2024.119912","DOIUrl":"10.1016/j.indcrop.2024.119912","url":null,"abstract":"<div><div>The windmill palm tree, renowned for its exceptional wind resistance, boasts the highest tensile elongation among plant fibers. Despite this, the origin of its remarkable tensile properties remains uncertain due to the intricate microstructure of the fibers and the short length (less than 1 mm) for each single fiber. This study focuses on windmill palm materials, investigating their fiber bundles and single fibers to examine microstructure, chemical composition, mechanical properties, and thermal characteristics. Findings reveal that windmill palm fiber possess a multicellular structure, with spindle-shaped single fiber parallelly aligned to create the overall fiber. By eliminating lignin and hemicellulose, highly crystalline (76.5 %) single fibers can be isolated. By loading resin microspheres at both ends of the fibers, the mechanical properties of single fibers can be successfully tested. The windmill palm single fibers exhibited a tensile strength in the range of 263±127 MPa, demonstrating a robust resistance to breaking under tension. Additionally, these fibers showcased a tensile elongation of 25.1±10.2 %, indicating a notable capacity for deformation before failure. The large strain fracture of windmill palm fibers mainly originates from the high tensile elongation of single fibers for the low molecular chain orientation, followed by the stretching of the amorphous regions such as lignin and hemicellulose at the connections between single fibers.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142553044","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Regulation of rhizosphere microorganisms on the quality of Scutellaria baicalensis: From wild and cultivated perspectives 根瘤微生物对黄芩质量的影响:从野生和栽培的角度看
IF 5.6 1区 农林科学
Industrial Crops and Products Pub Date : 2024-10-30 DOI: 10.1016/j.indcrop.2024.119917
Kailin Yang , Yaping Zheng , Kangmeng Sun , Xinyuan Sun , Peigen Xiao , Chunnian He
{"title":"Regulation of rhizosphere microorganisms on the quality of Scutellaria baicalensis: From wild and cultivated perspectives","authors":"Kailin Yang ,&nbsp;Yaping Zheng ,&nbsp;Kangmeng Sun ,&nbsp;Xinyuan Sun ,&nbsp;Peigen Xiao ,&nbsp;Chunnian He","doi":"10.1016/j.indcrop.2024.119917","DOIUrl":"10.1016/j.indcrop.2024.119917","url":null,"abstract":"<div><div>Radix Scutellariae (the root of <em>Scutellaria baicalensis</em>), an important traditional Chinese medicine, has extensive pharmacological activities and is widely used in clinic. With the gradual depletion of wild <em>Scutellaria baicalensis</em> (WS) resources, artificial cultivated <em>Scutellaria baicalensis</em> (CS) has gradually become the main source of Radix Scutellariae. However, it is believed that WS has better quality, and there are some problems in the artificial cultivation process, such as unreasonable planting mode leading to quality decline, which makes the production of high-quality Radix Scutellariae become an urgent need. It’s proved that rhizosphere microorganisms can affect the growth of medicinal plants, the accumulation of secondary metabolites and the ability to resist stress. However, how CS and WS affect the quality formation through the recruitment of rhizosphere microorganisms remains to be further explained. Therefore, UPLC was performed to explore the differences of flavonoids in different growth modes of <em>S. baicalensis</em>. Amplification sequencing technology was used to analyze the differences of rhizosphere microorganisms in different growth modes. Functional prediction, co-occurrence network analysis and correlation analysis between rhizosphere microorganisms and pharmacologically active ingredient were also used to explore the effects of rhizosphere microorganisms on quality formation of CS and WS. The results showed that though compared with CS, the contents of flavonoids in WS decreased, the relative abundance of stress-resistant rhizosphere microorganisms in WS increased significantly, the stress-resistant and adaptive-related pathways of WS rhizosphere microbial communities were significantly up-regulated. In addition, many microorganisms enriched in rhizosphere of CS were significant positive correlation with baicalin and wogonoside. Therefore, CS has higher flavonoid content, while WS has stronger resistance to stress. This study explored the differences of flavonoids and rhizosphere microorganisms between CS and WS, and revealed how the growth modes affected the interaction between rhizosphere microorganisms and <em>S. baicalensis</em>, which had guiding value for high-quality cultivation of <em>S. baicalensis</em>.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142553036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancements in renewable energy: Achieving milder reaction conditions in biodiesel synthesis from green seed canola oil with pristine ZIF-8 可再生能源的进步:用纯净 ZIF-8 从绿色菜籽油合成生物柴油时实现更温和的反应条件
IF 5.6 1区 农林科学
Industrial Crops and Products Pub Date : 2024-10-30 DOI: 10.1016/j.indcrop.2024.119926
Fahimeh Esmi, Philip Boahene, Ajay K. Dalai
{"title":"Advancements in renewable energy: Achieving milder reaction conditions in biodiesel synthesis from green seed canola oil with pristine ZIF-8","authors":"Fahimeh Esmi,&nbsp;Philip Boahene,&nbsp;Ajay K. Dalai","doi":"10.1016/j.indcrop.2024.119926","DOIUrl":"10.1016/j.indcrop.2024.119926","url":null,"abstract":"<div><div>This study explores the enhancement of reaction conditions for biodiesel production from green seed canola oil through the methanolysis reaction using pristine ZIF-8 as a catalyst. The research focused on the effects of varying the methanol-to-oil molar ratio, temperature, and reaction time as well as their combined effects on biodiesel yield. To analyze these factors, Response Surface Methodology (RSM) paired with Central Composite Design (CCD) was employed. The quadratic model was identified as the best fit for the experimental data, evidenced by a high determination coefficient (R²) of 0.99, with all model parameters proving significant. A comprehensive characterization of the catalyst was conducted using various techniques. The surface and pore properties were examined using N<sub>2</sub> adsorption-desorption measurements. X-ray diffractometry (XRD) was employed for structural analysis, while X-ray photoelectron spectroscopy (XPS) presented the binding information of the sample. Fourier transform infrared spectroscopy (FT-IR) provided insights into the functional groups present. Thermal gravimetric analysis (TGA) assessed the thermal stability of the catalyst. Results revealed that ZIF-8 significantly improved biodiesel production, with optimal conditions identified at a reaction temperature of 160 °C, a duration of 2.5 h, and methanol to oil (M/O) molar ratio of 26, resulting in a biodiesel yield of 85 %. This yield is close to the predicted value, demonstrating the reliability of the developed model. The kinetic analysis was performed under optimal reaction conditions. From this, the activation energy (E<sub>a</sub>) and the pre-exponential factor (A) were obtained to be 14.5 kJ/mol and 3.4×10<sup>−7</sup> min<sup>−1</sup>, respectively. The use of pristine ZIF-8 in biodiesel production from a low-quality and cheap oil offers a more efficient and milder reaction conditions, with potential for significant reductions in production costs and environmental impact.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142553041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
PagSWEET17a mediates sucrose allocation to xylem during wood formation in poplar PagSWEET17a 在杨木形成过程中介导木质部的蔗糖分配
IF 5.6 1区 农林科学
Industrial Crops and Products Pub Date : 2024-10-30 DOI: 10.1016/j.indcrop.2024.119929
Xinyi Hao , Jifu Li , Li Zhang , Zhibin Fan , Zheshu Wang , Luxuan Hou , Lijuan Wang
{"title":"PagSWEET17a mediates sucrose allocation to xylem during wood formation in poplar","authors":"Xinyi Hao ,&nbsp;Jifu Li ,&nbsp;Li Zhang ,&nbsp;Zhibin Fan ,&nbsp;Zheshu Wang ,&nbsp;Luxuan Hou ,&nbsp;Lijuan Wang","doi":"10.1016/j.indcrop.2024.119929","DOIUrl":"10.1016/j.indcrop.2024.119929","url":null,"abstract":"<div><div>Wood is recognized as the primary storage tissue in trees. During the process of wood formation, the xylem actively assimilates carbon from photosynthetic tissues to satisfy its developmental requirements. The photosynthetic product, sucrose, provides precursors and energy for cell wall synthesis, and its transportation significantly impacts the yield and quality of wood. The radial transport is a critical step in the accumulation of photosynthetic products to xylem, yet research on the involved sugar transporters and their roles remains limited. In the present study, <em>PagSWEET17a</em>, a sugar transporter gene with pronounced expression in the xylem, was examined for its expression pattern, substrate specificity, subcellular localization, and the consequential effects on wood formation. The present findings revealed that PagSWEET17a exhibited specificity for sucrose transport, and has triple subcellular localizations, including the plasma membrane, tonoplast, and endoplasmic reticulum membrane. <em>PagSWEET17a</em> expressed in the phloem cells of the stem, as well as in the developing xylem vessels and fiber cells, suggesting its potential involvement in various steps of radial transport. By mediating the accumulation of carbon in the xylem, PagSWEET17a influenced the width of the xylem, as well as the thickness and composition of the secondary cell walls in xylem cells. These insights contribute to a deeper understanding of the molecular mechanisms underlying wood formation and highlight the importance of sugar transporters in this process.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142553043","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Establishment of a system for tissue culture regeneration and isolation of Camellia yubsienensis, and PEG-mediated transient expression of mesophyll protoplasts 建立山茶花组织培养再生和分离系统,以及 PEG 介导的叶肉原生质体瞬时表达系统
IF 5.6 1区 农林科学
Industrial Crops and Products Pub Date : 2024-10-30 DOI: 10.1016/j.indcrop.2024.119897
Silu Hou, Ziyu Li, Dandan Yi, Juntao Wu, Yingjie Hu, Xiaoming Fan, Shixin Xiao, Deyi Yuan
{"title":"Establishment of a system for tissue culture regeneration and isolation of Camellia yubsienensis, and PEG-mediated transient expression of mesophyll protoplasts","authors":"Silu Hou,&nbsp;Ziyu Li,&nbsp;Dandan Yi,&nbsp;Juntao Wu,&nbsp;Yingjie Hu,&nbsp;Xiaoming Fan,&nbsp;Shixin Xiao,&nbsp;Deyi Yuan","doi":"10.1016/j.indcrop.2024.119897","DOIUrl":"10.1016/j.indcrop.2024.119897","url":null,"abstract":"<div><div><em>Camellia yubsienensis</em> has several distinctive characteristics, including thin fruiting shells, high seed yield, and a notable degree of resilience to adverse conditions. In the present study, <em>C. yubsienensis</em> stem segments with buds were used as explants. Single-factor experiments and orthogonal experimental designs were employed to identify the optimal conditions for establishing a tissue culture regeneration system for <em>C. yubsienensis</em> and optimal conditions for the isolation and PEG-mediated transient expression of its mesophyll protoplasts. The results showed that the optimal disinfection method involved 75 % C<sub>2</sub>H<sub>5</sub>OH for 60 s, followed by 0.1 % HgCl for 20 min, resulting in a low contamination rate of 9.3 %. The best culture medium for bud induction of stem segments was WPM supplemented with 2 mg/L 6-BA, 1.5 mg/L IBA, 1 mg/L GA<sub>3</sub>, 7 g/L agar, and 30 g/L sucrose, which achieved a high induction rate of 88.73 %. The optimal sampling time was April 20th, with a high induction rate of 85.56 %. The most favorable genotype was YZ<sub>2</sub>, which exhibited faster bud formation and robust growth, with an induction rate of 87.69 %. The best proliferation culture medium consisted of WPM supplemented with 4 mg/L 6-BA, 0.1 mg/L IAA, 2 mg/L GA<sub>3</sub>, 7 g/L agar, and 30 g/L sucrose, resulting in a proliferation coefficient of approximately 3.56. The preferred rooting method involved dipping the stem segments in 10 mg/mL IBA for 10 s and 1 mg/mL salicylic acid for 10 s, followed by planting in the optimal culture medium: 1/2 MS supplemented with 0.01 mM GABA, 5 g/L agar, and 30 g/L sucrose, achieving a rooting rate of 83 % after approximately 20 days. The optimum conditions for mesophyll protoplast isolation were 2.5 % Cellulase R-10 + 1.5 % Macerozyme R-10 + 0.45 % snailase with 8 h of enzymatic digestion at an osmotic pressure of 0.4 M, and the production and viability of protoplasts were 9.95×10<sup>6</sup>/g·FW and 93.52 %. The maximum transfection efficiency (68.1 %) was obtained with the incubation of the protoplasts with 25 µg plasmid and 40 % PEG4000 for 30 min. This study established a regeneration system for <em>C. yubsienensis</em> and explored the optimal conditions for the isolation and PEG-mediated transient expression of mesophyll protoplasts, laying the foundation for factory-scale breeding of superior varieties of <em>C. yubsienensis</em>. It also provides technical support for research on somatic cell hybridization and the establishment of genetic transformation systems for <em>C. yubsienensis.</em></div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142553123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Camelina sativa (L.) Crantz straw and pomace as a green filler for integral skin polyurethane foam 荠菜(L. Crantz)秸秆和渣作为自结皮聚氨酯泡沫塑料的绿色填料
IF 5.6 1区 农林科学
Industrial Crops and Products Pub Date : 2024-10-30 DOI: 10.1016/j.indcrop.2024.119931
Przemysław Bartczak , Weronika Ejm , Ola Bacik , Anna Przybylska-Balcerek , Sławomir Borysiak
{"title":"Camelina sativa (L.) Crantz straw and pomace as a green filler for integral skin polyurethane foam","authors":"Przemysław Bartczak ,&nbsp;Weronika Ejm ,&nbsp;Ola Bacik ,&nbsp;Anna Przybylska-Balcerek ,&nbsp;Sławomir Borysiak","doi":"10.1016/j.indcrop.2024.119931","DOIUrl":"10.1016/j.indcrop.2024.119931","url":null,"abstract":"<div><div>The development of efficient methods for obtaining cellular materials with improved functional properties is a constant challenge for the plastics industry, including the polyurethane industry. In recent years, efforts have been made to obtain cheap and easily available raw materials that can be used as foam fillers. In addition to commercially used synthetic fillers, more and more attention is paid to materials of natural origin, in particular to agricultural and industrial waste. This solution not only meets the assumptions of the \"Green Chemistry\" concept but also creates the opportunity to improve the properties of plastics while reducing their production costs. This study focuses on the use of naturally derived materials as fillers in flexible integral polyurethane foams (Integral Skin Foams, ISFs) to produce economically advantageous and ecologically sustainable composite materials. Waste materials such as <em>Camelina sativa (L.) Crantz</em> straw and pomace were used as biofillers. The obtained samples were used to determine the processing parameters and functional properties of the foams: hardness, tensile strength, elongation at break and permanent deformation after compression. In the case of both straw and pomace, an increase in growth time and an increase in the free density of the foams were observed with an increase in the amount of added plant material. The analysis of morphology and chemical structure of the obtained composites led to the conclusion that the cellular structure, skin thickness, and functional groups present in biofillers had a direct impact on the functional properties of ISF. For most composites, a significant improvement in mechanical parameters was observed compared to the reference foam. The obtained results confirmed the utility potential of <em>Camelina sativa (L.) Crantz</em> straw and pomace. The main research assumption has been fully implemented that focused on obtaining innovative polyurethane composites with improved functional properties.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142553042","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Drying temperature and conditions affect the Origanum dubium Boiss. and Salvia fruticosa Mill. quality attributes and impact the essential oil composition, antimicrobial and antioxidant activities 干燥温度和条件对牛至(Origanum dubium Boiss.)和丹参(Salvia fruticosa Mill.)质量属性的影响,以及对精油成分、抗菌和抗氧化活性的影响
IF 5.6 1区 农林科学
Industrial Crops and Products Pub Date : 2024-10-30 DOI: 10.1016/j.indcrop.2024.119898
Antonios Chrysargyris, Panayiota Xylia, Nikolaos Tzortzakis
{"title":"Drying temperature and conditions affect the Origanum dubium Boiss. and Salvia fruticosa Mill. quality attributes and impact the essential oil composition, antimicrobial and antioxidant activities","authors":"Antonios Chrysargyris,&nbsp;Panayiota Xylia,&nbsp;Nikolaos Tzortzakis","doi":"10.1016/j.indcrop.2024.119898","DOIUrl":"10.1016/j.indcrop.2024.119898","url":null,"abstract":"<div><div>Drying conditions need to be optimized for each medicinal and aromatic plant (MAP) since their composition varies greatly. The present study evaluated the different drying temperatures (20, 35, 42, and 49 °C) and drying conditions (sun, shade, and oven drying) on the quality (chlorophylls and colour indices) of dried <em>Origanum dubium</em> Boiss., <em>Salvia fruticosa</em> Mill. and their essential oil (EO) yield, composition and properties. Both cultivated plants are of industrial interest due to their significant bioactive properties. Results showed that the higher temperature led into faster moisture loss (i.e. 49 °C), and resulted into a darker product (higher browning index). For <em>O. dubium</em>, the proper drying temperature was at 35–42 °C and resulted in producing EO with high antioxidant and antimicrobial activities, due to the increased carvacrol (up to 117 %) and <em>p</em>-cymene (up to 35.4 %) content (oregano EO major compounds). Additionally, <em>O. dubium</em> EO derived from plants dried in an air forced oven (42 °C) revealed greater antimicrobial activity against the four foodborne pathogens investigated compared to sun and shade drying. For <em>S. fruticosa</em>, the optimum drying temperature was at 42–49 °C that produced EOs of significantly higher biological activities (antioxidant and antimicrobial), even though EO yield and main compounds were similar among the investigated temperatures. Shade and oven drying conditions produced EOs with increased biological activities compared to sun drying. Even though drying at 42 °C resulted into a final product of acceptable colour quality indices and EOs with high biological activity, the energy consumption and the calculated carbon dioxide production were the highest. These findings suggest that more traditional methods (i.e. sun and shade drying) can also result into products with appreciated bioactive properties and with a lower environmental carbon footprint, while the drying duration needs to be considered, as valuable factor for industrial applications.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142553035","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mathematical modeling of enzymatic esterification process between essential oil from Cymbopogon winterianus and cinnamic acid 冬凌草精油与肉桂酸之间酶法酯化过程的数学建模
IF 5.6 1区 农林科学
Industrial Crops and Products Pub Date : 2024-10-30 DOI: 10.1016/j.indcrop.2024.119919
Guilherme Sabadin Piva , Bruno Fischer , Marcielli Peruzzolo , Bruna Maria Saorin Puton , Thiago Weschenfelder , Alexander Junges , Clarice Steffens , Rogério Luis Cansian , Natalia Paroul
{"title":"Mathematical modeling of enzymatic esterification process between essential oil from Cymbopogon winterianus and cinnamic acid","authors":"Guilherme Sabadin Piva ,&nbsp;Bruno Fischer ,&nbsp;Marcielli Peruzzolo ,&nbsp;Bruna Maria Saorin Puton ,&nbsp;Thiago Weschenfelder ,&nbsp;Alexander Junges ,&nbsp;Clarice Steffens ,&nbsp;Rogério Luis Cansian ,&nbsp;Natalia Paroul","doi":"10.1016/j.indcrop.2024.119919","DOIUrl":"10.1016/j.indcrop.2024.119919","url":null,"abstract":"<div><div>To explore esterification processes via enzymatic catalysis, mathematical models represent an innovative and indispensable tool. This study aims to investigate the esterification process of monoterpene alcohols, specifically geraniol and citronellol, which are key components of citronella essential oil (<em>Cymbopogon winterianus</em>). The focus lies in understanding the complex dynamics of their reaction with cinnamic acid within an organic solvent system, employing the immobilized commercial lipase NS 88011 as the biocatalyst. The independent variables investigated in this study were as follows: temperature (50, 60, and 70 °C), enzyme concentration (1, 5, 10, and 15 %), agitation speed (50, 125, and 200 rpm), and the molar ratio of cinnamic acid to alcohol (geraniol/citronellol) (1:2, 1:3, 1:6, 1:9, and 1:12). The optimized conditions were found to be 10 % catalyst concentration, 60 °C, 50 rpm agitation speed, and a molar ratio of 1:3 (acid:alcohol). Under these conditions, the production yielded 7845 mg/L (52.3 %) of citronellyl cinnamate and 15089 mg/L (48.3 %) of geranyl cinnamate within 120 h of the reaction time. The best-fitting model that accurately described the reaction kinetics was determined to be the Ping Pong bi bi model. This research underscores the critical importance of systematic parameter optimization and the selection of kinetic models to enhance the efficiency of enzymatic esterification processes, thereby making a substantial contribution to the progress of the field of enzymatic catalysis.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142553628","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enriched extensin and cellulose for non-collapse biochar assembly to maximize carbon porosity and dye adsorption with high bioethanol production 用于非塌陷生物炭组装的富集延伸素和纤维素可最大限度地提高碳孔隙率和染料吸附性,同时提高生物乙醇产量
IF 5.6 1区 农林科学
Industrial Crops and Products Pub Date : 2024-10-30 DOI: 10.1016/j.indcrop.2024.119924
Yunong Li , Boyang He , Huiyi Zhang , Jingyuan Liu , Sufang Li , Hailang Wang , Hao Peng , Yongtai Wang , Jun Dai , Yanting Wang , Liangcai Peng , Heng Kang
{"title":"Enriched extensin and cellulose for non-collapse biochar assembly to maximize carbon porosity and dye adsorption with high bioethanol production","authors":"Yunong Li ,&nbsp;Boyang He ,&nbsp;Huiyi Zhang ,&nbsp;Jingyuan Liu ,&nbsp;Sufang Li ,&nbsp;Hailang Wang ,&nbsp;Hao Peng ,&nbsp;Yongtai Wang ,&nbsp;Jun Dai ,&nbsp;Yanting Wang ,&nbsp;Liangcai Peng ,&nbsp;Heng Kang","doi":"10.1016/j.indcrop.2024.119924","DOIUrl":"10.1016/j.indcrop.2024.119924","url":null,"abstract":"<div><div>Although extensin is a typical wall protein functional for plant cell wall construction and biomass production, its regulation on lignocellulose conversion into biofuels and bioproducts remains elusive. By collecting two extensin-overproduced rice straws (<em>OsEXTLs</em>), this study determined their cellulose levels significantly increased by 10 % along with soluble sugars and starch accumulation raised by 1–3.6 folds. After mild 0.5 % NaOH pretreatment, the <em>OsEXTLs</em> straws showed relatively enhanced biochemical conversion into total bioethanol production. Further under classic thermal-chemical conversion with the <em>OsEXTLs</em> enzyme-undigested lignocelluloses, this study generated the non-collapse biochar with more active chemical groups and the highest porosity, which caused mostly raised adsorption capacities with methylene blue (1162 mg/g) and Congo red (2714 mg/g) as a comparison with the previously-reported ones. Therefore, we proposed a mechanism model to illuminate how the extensin-enriched lignocellulose favors for higher-yield bioethanol conversion and better-performance biochar assembly, providing a novel strategy for desirable lignocellulose modification and effective biomass process.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142553040","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Quasi-static – cyclic and fatigue properties of carbon-innegra/pineapple multi-material laminates 碳-黑/菠萝多材料层压板的准静态-循环和疲劳特性
IF 5.6 1区 农林科学
Industrial Crops and Products Pub Date : 2024-10-30 DOI: 10.1016/j.indcrop.2024.119894
Vinod Ayyappan , Jirratti Tengsuthiwat , Vijay Raghunathan , Mavinkere Rangappa Sanjay , Suchart Siengchin
{"title":"Quasi-static – cyclic and fatigue properties of carbon-innegra/pineapple multi-material laminates","authors":"Vinod Ayyappan ,&nbsp;Jirratti Tengsuthiwat ,&nbsp;Vijay Raghunathan ,&nbsp;Mavinkere Rangappa Sanjay ,&nbsp;Suchart Siengchin","doi":"10.1016/j.indcrop.2024.119894","DOIUrl":"10.1016/j.indcrop.2024.119894","url":null,"abstract":"<div><div>Natural fiber-reinforced polymer composites possess impressive advantages; however, they often fall short of meeting the demand for high-strength applications. Consequently, hybrid composites, combining natural and synthetic fibers, have gained significant attention for their tailorable properties. In this study, carbon-innegra hybrid fabrics (CI) and pineapple fabrics were utilized to fabricate hybrid multi-material compo sites. The use of CI hybrid fabrics in hybrid composites has yet to be explored. Composite laminates with varied stacking sequences of CI and pineapple fabrics were developed. Mechanical testing demonstrated that composites with high-stiff materials as the skin layer exhibited superior tensile and flexural strengths of 136.28 MPa and 284.08 MPa, respectively. Complex mechanical analyses, including quasi-cyclic flexural analysis, revealed promising properties, with the composite showing a lower strain of 0.029 and a maximum flexural strength of 147.48 MPa after the 50th cycle. Dynamic mechanical analysis revealed that the storage modulus was almost similar for pure CI composites and with CI layers in the outer stacks. Fatigue analysis demonstrated the durability of the composites, with the CI outer stack exhibiting lower deformative strain at the 4×10<sup>4th</sup> cycle. At the same time, the alternate sequence of CI and pineapple layers displayed enhanced energy absorption during puncture impact. These findings suggest that the developed composite holds promise for semi-structural applications, with the flexibility to adjust stacking sequences based on specific requirements. A motorcycle battery cover was fabricated using the composite with CI as the outer stack to validate its potential.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142553045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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