Hydrological Processes最新文献

{"title":"Quantifying Streamflow Prediction Uncertainty Through Process-Aware Data-Driven Models","authors":"Abhinanda Roy,&nbsp;K. S. Kasiviswanathan","doi":"10.1002/hyp.15310","DOIUrl":"https://doi.org/10.1002/hyp.15310","url":null,"abstract":"<div>\u0000 \u0000 <p>The hydrological model simulation accompanied with uncertainty quantification helps enhance their overall reliability. Since uncertainty quantification including all the sources (input, model structure and parameter) is challenging, it is often limited to only addressing model parametric uncertainty, neglecting other uncertainty sources. This paper focuses on exploiting the potential of state-of-the-art data-driven models (or DDMs) in quantifying the prediction uncertainty of process-based hydrological models. This is achieved by integrating the robust predictive ability of the DDMs with the process understanding ability of the hydrological models. The Bayesian-based data assimilation (DA) technique is used to quantify uncertainty in process-based hydrological models. This is accomplished by choosing two DDMs, random forest algorithm (RF) and support vector machine (SVM), which are distinctly integrated with two process-based hydrological models: HBV and HyMOD. Particle filter algorithm (PF) is chosen for uncertainty quantification. All these combinations led to four different process-aware DDMs: HBV-PF-RF, HBV-PF-SVM, HyMOD-PF-RF and HyMOD-PF-SVM. The assessment of these models on the Baitarani, Beas and Sunkoshi river basins exemplified an improvement in the accuracy of the daily streamflow simulations with a reduction in the prediction uncertainty across all the models for all the basins. For example, the nash-sutcliffe efficiency improved by 54.69% and 10.61% in calibration and validation of the Baitarani river basin, respectively. Equivalently, average bandwidth improved by 79.37% and 71.59%, respectively. This signified the (a) potential of the DDMs in quantifying and reducing the prediction uncertainty of the hydrological model simulations, (b) transferability of the model with an appreciable performance irrespective of the choice of basins having varying topography and climatology and (c) ability to perform significantly irrespective of different process-based and DDMs being involved, thereby ensuring generalizability. Thus, the framework is expected to assist in effective decision-making, including various environmental management and disaster preparedness.</p>\u0000 </div>","PeriodicalId":13189,"journal":{"name":"Hydrological Processes","volume":"38 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142641828","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Submarine Groundwater Discharge at a Mega-Tidal Beach","authors":"Raymond D. Craddock,&nbsp;Aaron A. Mohammed,&nbsp;Joseph J. Tamborski,&nbsp;Barret L. Kurylyk","doi":"10.1002/hyp.15319","DOIUrl":"https://doi.org/10.1002/hyp.15319","url":null,"abstract":"<p>Tidally influenced groundwater systems in coastal environments represent important mixing zones of fresh groundwater and circulating seawater, manifesting as submarine groundwater discharge (SGD). Water circulation induced by tidal pumping enhances the exchange of chemicals between aquifers and coastal waters and thereby influences the biogeochemistry of coastal zones. Here, we report the results of an SGD field study conducted at a steep, mega-tidal sand and gravel beach along the Canadian coast of the Bay of Fundy, a region with the world's highest tides (semi-diurnal tidal ranges exceeding 10 m). Several physical and geochemical measurement techniques were employed to document the spatiotemporal SGD variability. SGD was directly sampled from seepage meters installed over multiple tidal cycles and two summer campaigns. SGD rates were estimated from tracer mass balances for radon (August 2020) and radium isotopes (July 2021) over multiple tidal cycles. Tidally averaged SGD estimates from seepage meters ranged from 12 to 87 cm d⁻¹, with an average of 42 cm d⁻¹, while radon tracing yielded a tidally averaged rate of 86 cm d⁻¹. SGD estimates from radium tracing ranged from 23 to 43 cm d⁻¹ along the shoreline and 6 to 71 cm d⁻¹ offshore, depending on the estimated residence times. Radionuclide analyses of seepage meter waters suggest that the residence time of seawater circulation through the aquifer is less than 1 day. SGD measurements in mega-tidal settings are rare, and the results suggest that the combination of the steep slopes, highly permeable sediments and high tidal range drive very high seepage rates for diffusive SGD. Salinity gradients in the intertidal zone demonstrate that SGD is primarily comprised of circulated seawater with negligible fresh groundwater. Although the freshwater proportion of SGD is relatively low, the large volumetric rates of total SGD can still contribute large amounts of terrestrially derived and remineralized nutrients to coastal waters.</p>","PeriodicalId":13189,"journal":{"name":"Hydrological Processes","volume":"38 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/hyp.15319","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142641488","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Quantification of the Effect of Soil and Biophysical Parameters on Water Balance Modelling Using SWAT+ in Forested Catchments","authors":"Ehsan Qasemipour,&nbsp;Markus Pahlow,&nbsp;Thomas A. Cochrane,&nbsp;Clemens Altaner","doi":"10.1002/hyp.15332","DOIUrl":"https://doi.org/10.1002/hyp.15332","url":null,"abstract":"<div>\u0000 \u0000 <p>Accurate simulation of water balance components is crucial for effective water and land management practices. The performance of process-based hydrological models relies on the accurate determination of input variables. The objective of this study is to quantify the magnitude of the effect of soil properties (depth and texture) and biophysical parameters on water balance simulation for a forested catchment using the Soil and Water Assessment Tool (SWAT+). Simulations were carried out for a baseline scenario using the default soil inputs, followed by extending the soil profile depth up to 15 m under three different rainfall scenarios. Sensitivity analysis of model outputs was performed using the SENSitivity ANalysis (SENSAN) programme of the Parameter ESTimation (PEST) suite, coupled with SWAT+. The results showed that increasing soil profile depth to 15 m led to around 50% increase in water yield, and around 20% reduction in percolation with slight variations across the three rainfall scenarios. Evapotranspiration rates were slightly increased in deeper soil profiles. The sensitivity of evapotranspiration, surface runoff, and percolation to LAI-related biophysical parameters was pronounced, highlighting the need to include such parameters in SWAT+ model calibration. The water uptake from deeper soil layers by deep roots, even in rocky substrates, as documented in the literature, is not adequately captured by the SWAT+ model. Our work showed that in general, developing local soil databases with detailed information on deeper layers is needed, to improve the accuracy and reliability of hydrological models in predicting water fluxes, thereby supporting informed water resources management decisions.</p>\u0000 </div>","PeriodicalId":13189,"journal":{"name":"Hydrological Processes","volume":"38 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142641494","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Quantifying the Impacts of Fire-Related Perturbations in WRF-Hydro Terrestrial Water Budget Simulations in California's Feather River Basin","authors":"Ronnie Abolafia-Rosenzweig,&nbsp;David Gochis,&nbsp;Andrew Schwarz,&nbsp;Thomas H. Painter,&nbsp;Jeffery Deems,&nbsp;Aubrey Dugger,&nbsp;Matthew Casali,&nbsp;Cenlin He","doi":"10.1002/hyp.15314","DOIUrl":"https://doi.org/10.1002/hyp.15314","url":null,"abstract":"<div>\u0000 \u0000 <p>Wildfire activity in the western United States (WUS) is increasingly impacting water supply, and land surface models (LSMs) that do not explicitly account for fire disturbances can have critical uncertainties in burned areas. This study quantified responses from the Weather Research and Forecasting Hydrological modelling system (WRF-Hydro) to a suite of fire-related perturbations to hydrologic soil and runoff parameters, vegetation area, land cover classifications and associated vegetation properties, and snow albedo across the heavily burned Feather River Basin in California. These experiments were used to quantify the impacts of fire-related perturbations in model simulations under the observed meteorological conditions during the 2000–2022 water years and determine whether applying these fire-related perturbations enhanced post-fire model accuracy across the 11–12 post-fire months evaluated herein. The most comprehensive fire-aware simulation consistently modelled enhanced annual catchment streamflow (by 8%–37%), subsurface flow (by 72%–116%), and soil moisture (by 4%–9%), relative to the <i>baseline</i> simulation which neglected fire impacts. Simulated fire-enhanced streamflow was predominately attributable to fire-induced vegetation area reductions that reduced transpiration. Simulated streamflow enhancements occurred throughout the water year, excluding early-summer (e.g., May–June) when the <i>baseline</i> simulation modelled relatively more snowmelt and streamflow because fire perturbations caused earlier model snow depletion. Vegetation area reductions favoured increased model ground snow accumulation and enhanced snow ablation while imposed snow albedo darkening enhanced ablation, ultimately resulting in similar peak SWE and earlier snow disappearance (on average by 8-days) from the most comprehensive fire-aware simulation relative to the <i>baseline</i> simulation. The <i>baseline</i> simulation had large degradations in streamflow accuracy following major fire events that were likely partially attributable to neglecting fire disturbances. Applying fire-related perturbations reduced post-fire streamflow anomaly biases across the three study catchments. However, remaining large post-fire streamflow uncertainties in the fire-perturbed simulation underscores the importance of additional observationally constrained fire-disturbance model developments.</p>\u0000 </div>","PeriodicalId":13189,"journal":{"name":"Hydrological Processes","volume":"38 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142641829","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Estimation and Restoration of Dried Soil Layers in a Slope-Gully Unit of the Chinese Loess Plateau","authors":"Shuang Dong,&nbsp;Xiangguo Fan,&nbsp;Tongchuan Li,&nbsp;Jingling Zhang,&nbsp;Yuhua Jia","doi":"10.1002/hyp.15318","DOIUrl":"https://doi.org/10.1002/hyp.15318","url":null,"abstract":"<div>\u0000 \u0000 <p>Dried soil layer (DSL) is a phenomenon of deep soil desiccation caused by soil water content (SWC) deficiency. Relevant studies in the fragmented terrain of Chinese Loess Plateau (CLP) remain limited. In a typical slope-gully unit near the Liudaogou catchment, SWC was measured using neutron probes on 19 occasions at 15 observational locations. In order to reveal the temporal stability and elimination degree of DSLs, available soil moisture (ASM) and DSL were estimated by representative sites which were determined through the temporal stability method, and the reliability of simulating mean condition of the study area via representative locations was assessed. Results show that: (1) the dynamics of DSL was characterised by complexity and diversity. The ASM within the DSL (DSL-ASM), ASM within the sandwiched DSL (SDSL-ASM) and quantitative index (QI) varied within the range of 2.75%–3.11%, 2.98%–4.22% and 0.254–0.356, respectively. (2) The possibility of development and recovery for DSL and SDSL in deep layers were less than that in shallow layers. The maximum depth of DSL (DSLMD) was significantly and negatively related to the standard deviation of relative difference (SDRD) of DSL-ASM, the maximum depth of SDSL (SDSLMD) was negatively related to the SDRD of SDSL-ASM. (3) The prediction results of ASM above 300 cm depth were more accurate than other layers (<i>R</i>² = 0.89). The DSL-ASM had more accurate ability of prediction than SDSL-ASM and QI. On the analysis of time stability characteristics of ASM and DSLs, the locations of A2 and C3 can better represent the mean conditions of ASM at three and four soil layers, respectively. C2, A1 and A1 can better represent the average levels of DSL-ASM, SDSL-ASM and QI, respectively (<i>R</i>² = 0.43, 0.14 and 0.18). (4) The restoration degrees of DSLs mainly showed no elimination and slight elimination, the DSLs cannot be completely eliminated within a short time. We proposed that scientific regulation of SWC can alleviate the formation and development of DSLs at a certain extent, and provide the possibility for DSLs nonoccurrence.</p>\u0000 </div>","PeriodicalId":13189,"journal":{"name":"Hydrological Processes","volume":"38 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142641830","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hydrology on Solid Grounds? Integration Is Key to Closing Knowledge Gaps Concerning Landscape Subsurface Water Storage Dynamics","authors":"Sascha E. Oswald,&nbsp;Lisa Angermann,&nbsp;Heye R. Bogena,&nbsp;Michael Förster,&nbsp;Almudena García-García,&nbsp;Gunnar Lischeid,&nbsp;Eva N. Paton,&nbsp;Daniel Altdorff,&nbsp;Sabine Attinger,&nbsp;Andreas Güntner,&nbsp;Andreas Hartmann,&nbsp;Harrie-Jan Hendricks Franssen,&nbsp;Anke Hildebrandt,&nbsp;Birgit Kleinschmit,&nbsp;Rene Orth,&nbsp;Jian Peng,&nbsp;Masahiro Ryo,&nbsp;Martin Schrön,&nbsp;Wolfgang Wagner,&nbsp;Thorsten Wagener","doi":"10.1002/hyp.15320","DOIUrl":"https://doi.org/10.1002/hyp.15320","url":null,"abstract":"<p>Individual approaches to observe water dynamics across our landscape, from the land surface to groundwater, are many though they individually only provide glimpses into the real world due to their specific space–time scales. Comprehensive integration across all available observations is still largely lacking, limiting both our ability to reduce scientific knowledge gaps, and to guide land and water management using the best available scientific evidence. We argue that a stronger focus on integration of observational products, while utilising machine learning and accounting for current perceptual understanding is urgently needed to overcome this limitation. Since Europe is warming faster than any other continent, central Europe is undergoing a dramatic hydroclimatic transition about which such integrated observations would provide timely and valuable insights. Here, we present potential and gaps of current and planned observational methods. We argue that hyperresolution (sub km) integrated estimates of landscape water dynamics are feasible, which could significantly improve our ability to simulate vadose zone and groundwater dynamics, ultimately closing gaps in our current perception of hydrological processes in a temperate region under strong influence from climate change. We close by arguing that an interdisciplinary effort of various scientific communities is needed to enable this advancement.</p>","PeriodicalId":13189,"journal":{"name":"Hydrological Processes","volume":"38 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/hyp.15320","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142641451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Special Seepage Paths Among Nested Groundwater Flow Systems Linking Surface Water Bodies","authors":"Peng-Fei Han,&nbsp;Hongbin Zhan,&nbsp;Li Wan,&nbsp;Xu-Sheng Wang,&nbsp;Jun-Zhi Wang,&nbsp;Xiao-Wei Jiang","doi":"10.1002/hyp.15304","DOIUrl":"https://doi.org/10.1002/hyp.15304","url":null,"abstract":"<div>\u0000 \u0000 <p>A surface water body fed by groundwater is normally known as a terminal place of groundwater flow systems originating from precipitation recharge on highlands. The theory of Tóth predicted that these flow systems form a hierarchically nested structure of groundwater circulation in a composite basin. In this study, we will report new flow paths among groundwater flow systems that were unknown in Tóth's theory, identified as special seepage paths linking different surface water bodies. These seepage paths do not start from the groundwater table but can transmit water between lakes or streams that already serve as discharge zones of traditional local flow systems. As indicated in theoretical models and two real-world cases, special seepage paths are developed if some parametric conditions are satisfied, especially when surface water bodies cut deeply below the water table or are large enough. Different surface water bodies or different river reaches can directly exchange water, chemicals and heat through deep seepage paths even when both surface and subsurface water divides exist between them. Special seepage paths may play a role in the regional scale hyporheic flow or contribute to inter-basin groundwater flow. The knowledge of special seepage paths could greatly improve our conventional perception of surface water-groundwater interaction, groundwater age and geochemical and heat transport at the river basin scale.</p>\u0000 </div>","PeriodicalId":13189,"journal":{"name":"Hydrological Processes","volume":"38 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142641490","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Wildfire Impacts for Temperature Index Snowpack Model Parameters","authors":"Jeremy Giovando,&nbsp;Jeffrey D. Niemann,&nbsp;Steven R. Fassnacht","doi":"10.1002/hyp.15334","DOIUrl":"https://doi.org/10.1002/hyp.15334","url":null,"abstract":"<p>Streamflow derived from snowmelt is a key source of water for communities and agricultural producers in the western U.S. As wildfires become larger and more frequent in the West (due in part to climate change), it is increasingly important to understand their potential impacts on snowpack. Temperature-index models remain widely used to simulate snowpack in post-wildfire assessments due to their low data requirements. However, there is limited information on how the key parameters of such models change due to wildfires. The objectives of this study are to (1) quantify the observed changes in the melt-rate function and the rain-snow temperature threshold due to wildfires and (2) develop methods to adjust the melt-rate function and rain-snow temperature threshold (or Px Temperature) to simulate the potential impacts of wildfires on snowpack. To accomplish these goals, snow water equivalent data from 42 SNOTEL sites that have been impacted by wildfire are used to estimate the changes in the melt-rate functions and Px Temperatures between the pre-and post-wildfire periods. Then, general linear models (GLMs) are developed to estimate the changes in the model parameters based on readily available topographic, climatic, and land cover information. The results indicate that late season melt-rates typically increase after a wildfire for sites in northern and central ecoregions of the western U.S. Px Temperature also changes for many sites, but the direction and magnitude of change is highly variable between sites. Nearly all the GLMs can estimate the observed parameter changes better than simply using the average observed changes. However, substantial variation in the parameter values is not explained by the GLMs.</p>","PeriodicalId":13189,"journal":{"name":"Hydrological Processes","volume":"38 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/hyp.15334","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142641447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Subsurface Sediment Transport in the Shallow Vadose Zone of Fine-Textured Soils With Heterogenous Preferential Flows","authors":"William Ford,&nbsp;Mark Williams,&nbsp;Rose Mumbi","doi":"10.1002/hyp.15327","DOIUrl":"https://doi.org/10.1002/hyp.15327","url":null,"abstract":"<div>\u0000 \u0000 <p>Subsurface sediment transport in tile-drained landscapes occurs through macropores; however, little is known regarding how heterogeneous preferential flows influence fluxes. We performed laboratory rainfall simulations on 10 intact core lysimeters from a tile-drained field in Indiana, USA to study the impacts of surface and subsurface erosion on sediment leachate in heterogeneous preferential flow paths. Seven rainfall simulations were conducted to assess the impact of rainfall intensity on the leachate of surface eroded sediments (three events), and the impact of antecedent conditions on subsurface eroded sediments (four events). Cumulative sediment yield, linear mixed effects modelling, and hysteresis analyses were performed for all events. Results were presented in a series of four case studies. Results showed that surface sediment leachate concentration and yield were tightly linked to the filtration capacity of lysimeters, with more than 2/3rd of sediment originating from a single lysimeter, despite similar flow leachate volumes from each. Rainfall intensity significantly impacted the transport of surface eroded sediment at the highest intensity. Subsurface sediment erosion from undisturbed macropores was low compared to surface soils, but we found contrasting controls on sediment concentrations at low and high antecedent moistures that were equally important to sediment leachate yields. Disturbed macropores produced comparable sediment yields to surface erosion and behaved similarly to soil pipes in terms of erosion mechanics. Hysteresis results generally highlighted contrasting results for surface and subsurface sources but suggest that the prominence of slow flow, low-concentration leachate sources can alter the interpretation of results in field-scale applications. Our findings underscore an array of processes and pathways for sediment transport in the shallow vadose zone, and results will be useful for evaluating new model formulations.</p>\u0000 </div>","PeriodicalId":13189,"journal":{"name":"Hydrological Processes","volume":"38 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142641492","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Neutralisation of Acid Rock Drainage by Youngest Toba Tuff Leachate Revealed by Hydrogeochemistry","authors":"Kannan J. Prakash,&nbsp;V. R. Rani,&nbsp;K. S. Sajinkumar","doi":"10.1002/hyp.15335","DOIUrl":"https://doi.org/10.1002/hyp.15335","url":null,"abstract":"<div>\u0000 \u0000 <p>The Youngest Toba Tuff (YTT) supervolcanic eruption occurred 75000 years ago, and resulted in distinctive ash fall deposition in different locations encompassing marine, estuarine, lacustrine, and fluvial sedimentary basins. Of the different sedimentary basins, the YTT crypto-tephra horizon preserved in the South Kerala Sedimentary Basin (SKSB) of the western coast of India is hosted by a paleo-estuarine carbonaceous clay layer. Along the eastern margin of SKSB, confined aquifers hosting highly acidic groundwater is associated with this YTT ash and associated organic matter (OM)-rich carbonaceous clay layer, creating worse acid rock drainage (ARD), which eventually gets neutralised during summer, signalled by the crystallisation of halotrichite. Hydrogeological investigation gave insights on some of the unique geochemical processes, which facilitated the neutralisation of ARD. The main aquifers in the area include laterite and clayey-sand, which is separated by this impervious layer hosting YTT ash. Wells tapping the clayey-sand aquifer, beneath this layer, is affected by the ARD condition due to the interaction with pyrite, manifested as low pH of groundwater (3.7). Simultaneously, leaching from YTT ash, which constitutes 11.91% of Al₂O₃, facilitates Al content to reach groundwater in high concentration (2879.97 ppb). During dry season, when the surface of YTT-hosting OM-rich carbonaceous clay layer is exposed, the leached Al interacts with the acid derived from the YTT-hosting OM-rich carbonaceous clay layer and results in the precipitation of halotrichite. The two processes, one resulting in ARD condition and the other as formation of halotrichite, occur in succession. Thus, the crystallisation of halotrichite signals the neutralisation of water as well as heralding the potability of water.</p>\u0000 </div>","PeriodicalId":13189,"journal":{"name":"Hydrological Processes","volume":"38 11","pages":""},"PeriodicalIF":3.2,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142641448","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}