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Engineering a Low-Cost and Sustainable Electrochemical Cell Using Sericin as a Bio-Electrolyte 利用丝胶蛋白作为生物电解质设计一种低成本、可持续的电化学电池
IF 3.1 4区 工程技术
Fuel Cells Pub Date : 2026-06-03 DOI: 10.1002/fuce.70117
Prajwal Battampara, Nandhini Dhanavel, Narendra Reddy, Pornanong Aramwit
{"title":"Engineering a Low-Cost and Sustainable Electrochemical Cell Using Sericin as a Bio-Electrolyte","authors":"Prajwal Battampara,&nbsp;Nandhini Dhanavel,&nbsp;Narendra Reddy,&nbsp;Pornanong Aramwit","doi":"10.1002/fuce.70117","DOIUrl":"https://doi.org/10.1002/fuce.70117","url":null,"abstract":"<div>\u0000 \u0000 <p>Sericin, a water-soluble protein derived as a byproduct of silk processing, was investigated as a bio electrolyte in a single chambered cell. As a byproduct of silk processing, sericin is a natural, biodegradable, and sustainable biopolymer. Sericin extracted from <i>Bombyx mori</i> cocoons was dispersed in water at concentrations ranging from 0.5% to 8% and the homogeneous solution was used as an electrolyte with graphite serving as both cathode and anode. The performance of the electrolyte (sericin) in the electrochemical cell (SEC) was evaluated by varying the applied voltage, charging time, and electrolyte concentration. Further, the ability of the electrolyte to store and release electrical energy was studied. Sericin contains both positively and negatively charged amino acids and exhibited a maximum voltage retention of 2.8 V. The performance of the SEC was strongly dependent on the operating parameters, particularly sericin concentration and applied voltage. A sericin concentration of 2% and applied voltage of 15 V for 60 min provided the maximum potential. A maximum discharge time of approximately 7 min was obtained when the SEC was fully charged and connected to a standard LED (forward voltage ∼1.8–2 V, current ∼20 mA). Electrochemical studies confirmed that the performance of the battery was mainly dependent on the sericin concentration, attributed to ionizable amino acid residues that facilitate ionic conduction through hydrogen-bonded networks within the protein matrix. The SEC could be charged and discharged multiple times without loss of potential. In addition, ionic properties of the SEC were investigated using impedance studies, dielectric analysis, and transport number measurements. Sericin-based electrochemical systems show promise as sustainable energy sources for low powered electronics, such as medical devices and personal care devices.</p>\u0000 </div>","PeriodicalId":12566,"journal":{"name":"Fuel Cells","volume":"26 3","pages":""},"PeriodicalIF":3.1,"publicationDate":"2026-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148174202","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Voltage Stability Enhancement in DFIG Systems Through IOT-Based Adaptive Control Using Neural Network Technique 基于物联网的神经网络自适应控制增强DFIG系统电压稳定性
IF 3.1 4区 工程技术
Fuel Cells Pub Date : 2026-06-03 DOI: 10.1002/fuce.70112
Angala Parameswari G., Arunsankar G.
{"title":"Voltage Stability Enhancement in DFIG Systems Through IOT-Based Adaptive Control Using Neural Network Technique","authors":"Angala Parameswari G.,&nbsp;Arunsankar G.","doi":"10.1002/fuce.70112","DOIUrl":"https://doi.org/10.1002/fuce.70112","url":null,"abstract":"<div>\u0000 \u0000 <p>Doubly fed induction generator (DFIG) systems can enhance voltage stability through Internet of Things (IoT)-based monitoring and control, enabling effective analysis and proactive grid management. However, voltage stability in DFIG systems with IoT can be affected by communication delays that slow control actions, reducing the effectiveness of voltage regulation. This manuscript presents a novel framework for voltage stability enhancement in DFIG systems through IoT-based adaptive control. The proposed method integrates the capabilities of logarithmic differential convolutional neural network (LDCNN) with a reindeer cyclone optimization (RCO) algorithm, forming a model termed LDCNN–RCO. The primary goals of the proposed technique are to maximize efficiency, develop system stability, develop forecasting accuracy, and minimize estimation errors. LDCNN is employed to forecast the dynamic behavior of DFIG-driven wind turbines (WTs) throughout voltage dips, whereas RCO optimizes the distribution of reactive power. The proposed method demonstrates better performance than existing techniques, including Tasmanian devil optimization algorithm with multiresolution sinusoidal neural network (MSNN–TDO), artificial neural network (ANN), and sparrow search algorithm (SSA), as evaluated and compared using the MATLAB platform. The proposed technique achieves a lower torque ripple of 0.13%, response time of 1 ms, and higher accuracy of 99.3%, along with a higher computational efficiency of 97%, indicating superior performance and effectiveness compared to existing methods. The proposed LDCNN–RCO framework significantly enhances voltage stability and control efficiency in DFIG systems, outperforming existing methods in accuracy and response time.</p>\u0000 </div>","PeriodicalId":12566,"journal":{"name":"Fuel Cells","volume":"26 3","pages":""},"PeriodicalIF":3.1,"publicationDate":"2026-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148174257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Quaternary Ammonium-Functionalized Siloxane Semi-IPN for SPEEK Membranes: Decoupling the Conductivity–Stability Trade-Off 用于SPEEK膜的季铵功能化硅氧烷半ipn:电导率-稳定性的解耦
IF 3.1 4区 工程技术
Fuel Cells Pub Date : 2026-05-29 DOI: 10.1002/fuce.70115
Chuyu Zhou, Didi Chu, Wenxing Zeng, Jingze Cheng, Zhengdong Fei
{"title":"Quaternary Ammonium-Functionalized Siloxane Semi-IPN for SPEEK Membranes: Decoupling the Conductivity–Stability Trade-Off","authors":"Chuyu Zhou,&nbsp;Didi Chu,&nbsp;Wenxing Zeng,&nbsp;Jingze Cheng,&nbsp;Zhengdong Fei","doi":"10.1002/fuce.70115","DOIUrl":"https://doi.org/10.1002/fuce.70115","url":null,"abstract":"<div>\u0000 \u0000 <p>Balancing high proton conductivity with dimensional stability remains a persistent “trade-off” for sulfonated poly(ether ether ketone) (SPEEK) electrolytes. Herein, an amine-triggered self-catalyzed strategy is reported to construct a quaternary ammonium-functionalized siloxane semi-interpenetrating polymer network (semi-IPN) within SPEEK matrix. The in-situ formed rigid Si─O─Si scaffold effectively confines membrane swelling, while the tethered quaternary ammonium sites synergistically facilitate efficient proton hopping through acid–base interactions with sulfonic acid groups. The optimized membrane (GTM-2) yields a peak conductivity of 277.8 mS cm<sup>−1</sup> at 80°C, achieves a power density of 746.26 mW·cm<sup>−2</sup> in a single fuel cell. Moreover, the semi-IPN membranes maintain favorable mechanical strength (up to 23.3 MPa). This architectural design provides a robust pathway for developing high-performance, non-fluorinated proton exchange membranes.</p>\u0000 </div>","PeriodicalId":12566,"journal":{"name":"Fuel Cells","volume":"26 3","pages":""},"PeriodicalIF":3.1,"publicationDate":"2026-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148174769","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Quaternary Ammonium-Functionalized Siloxane Semi-IPN for SPEEK Membranes: Decoupling the Conductivity–Stability Trade-Off 用于SPEEK膜的季铵功能化硅氧烷半ipn:电导率-稳定性的解耦
IF 3.1 4区 工程技术
Fuel Cells Pub Date : 2026-05-29 DOI: 10.1002/fuce.70115
Chuyu Zhou, Didi Chu, Wenxing Zeng, Jingze Cheng, Zhengdong Fei
{"title":"Quaternary Ammonium-Functionalized Siloxane Semi-IPN for SPEEK Membranes: Decoupling the Conductivity–Stability Trade-Off","authors":"Chuyu Zhou,&nbsp;Didi Chu,&nbsp;Wenxing Zeng,&nbsp;Jingze Cheng,&nbsp;Zhengdong Fei","doi":"10.1002/fuce.70115","DOIUrl":"https://doi.org/10.1002/fuce.70115","url":null,"abstract":"<div>\u0000 \u0000 <p>Balancing high proton conductivity with dimensional stability remains a persistent “trade-off” for sulfonated poly(ether ether ketone) (SPEEK) electrolytes. Herein, an amine-triggered self-catalyzed strategy is reported to construct a quaternary ammonium-functionalized siloxane semi-interpenetrating polymer network (semi-IPN) within SPEEK matrix. The in-situ formed rigid Si─O─Si scaffold effectively confines membrane swelling, while the tethered quaternary ammonium sites synergistically facilitate efficient proton hopping through acid–base interactions with sulfonic acid groups. The optimized membrane (GTM-2) yields a peak conductivity of 277.8 mS cm<sup>−1</sup> at 80°C, achieves a power density of 746.26 mW·cm<sup>−2</sup> in a single fuel cell. Moreover, the semi-IPN membranes maintain favorable mechanical strength (up to 23.3 MPa). This architectural design provides a robust pathway for developing high-performance, non-fluorinated proton exchange membranes.</p>\u0000 </div>","PeriodicalId":12566,"journal":{"name":"Fuel Cells","volume":"26 3","pages":""},"PeriodicalIF":3.1,"publicationDate":"2026-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148166951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hybrid Thermal Management of Proton Exchange Membrane Fuel Cells for Energy Efficient Applications 质子交换膜燃料电池节能应用的混合热管理
IF 3.1 4区 工程技术
Fuel Cells Pub Date : 2026-05-28 DOI: 10.1002/fuce.70111
Aamir Sohail
{"title":"Hybrid Thermal Management of Proton Exchange Membrane Fuel Cells for Energy Efficient Applications","authors":"Aamir Sohail","doi":"10.1002/fuce.70111","DOIUrl":"https://doi.org/10.1002/fuce.70111","url":null,"abstract":"<div>\u0000 \u0000 <p>Proton exchange membrane fuel cells’ (PEMFCs) performance and durability are strongly constrained by thermal management challenges associated with high power densities and nonuniform heat generation. Conventional active cooling strategies can reduce peak temperatures by approximately 20°C–40°C but often incur high parasitic power consumption and temperature nonuniformities exceeding 5°C–10°C across the active area. Passive approaches, including heat pipes, vapor chambers (VCs), and phase change materials (PCMs), substantially enhance thermal uniformity, achieving temperature gradient reductions of up to 60%–70%, yet remain limited under sustained high-load operation. Consequently, hybrid thermal management strategies integrating active and passive mechanisms have emerged as a promising solution. This review critically synthesizes recent advances in hybrid PEMFC thermal management, encompassing heat-spreading structures, multi-heat-pipe and VC architectures, and PCM-assisted cooling concepts. Numerical modeling approaches are assessed alongside experimental validations at both cell and stack levels. Comparative analysis demonstrates that hybrid systems can reduce maximum operating temperatures by 10°C–25°C, restrict temperature nonuniformity to below 2°C–4°C, and decrease auxiliary power consumption by 15%–30% relative to conventional active cooling. Finally, design-oriented insights are proposed to guide optimized hybrid thermal regulation across diverse operating conditions.</p>\u0000 </div>","PeriodicalId":12566,"journal":{"name":"Fuel Cells","volume":"26 3","pages":""},"PeriodicalIF":3.1,"publicationDate":"2026-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148174850","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hybrid Thermal Management of Proton Exchange Membrane Fuel Cells for Energy Efficient Applications 质子交换膜燃料电池节能应用的混合热管理
IF 3.1 4区 工程技术
Fuel Cells Pub Date : 2026-05-28 DOI: 10.1002/fuce.70111
Aamir Sohail
{"title":"Hybrid Thermal Management of Proton Exchange Membrane Fuel Cells for Energy Efficient Applications","authors":"Aamir Sohail","doi":"10.1002/fuce.70111","DOIUrl":"https://doi.org/10.1002/fuce.70111","url":null,"abstract":"<div>\u0000 \u0000 <p>Proton exchange membrane fuel cells’ (PEMFCs) performance and durability are strongly constrained by thermal management challenges associated with high power densities and nonuniform heat generation. Conventional active cooling strategies can reduce peak temperatures by approximately 20°C–40°C but often incur high parasitic power consumption and temperature nonuniformities exceeding 5°C–10°C across the active area. Passive approaches, including heat pipes, vapor chambers (VCs), and phase change materials (PCMs), substantially enhance thermal uniformity, achieving temperature gradient reductions of up to 60%–70%, yet remain limited under sustained high-load operation. Consequently, hybrid thermal management strategies integrating active and passive mechanisms have emerged as a promising solution. This review critically synthesizes recent advances in hybrid PEMFC thermal management, encompassing heat-spreading structures, multi-heat-pipe and VC architectures, and PCM-assisted cooling concepts. Numerical modeling approaches are assessed alongside experimental validations at both cell and stack levels. Comparative analysis demonstrates that hybrid systems can reduce maximum operating temperatures by 10°C–25°C, restrict temperature nonuniformity to below 2°C–4°C, and decrease auxiliary power consumption by 15%–30% relative to conventional active cooling. Finally, design-oriented insights are proposed to guide optimized hybrid thermal regulation across diverse operating conditions.</p>\u0000 </div>","PeriodicalId":12566,"journal":{"name":"Fuel Cells","volume":"26 3","pages":""},"PeriodicalIF":3.1,"publicationDate":"2026-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148174684","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cultivation of Electrogens With Cost-Effective Membrane-Less Bioreactor Designs 具有成本效益的无膜生物反应器的培养
IF 3.1 4区 工程技术
Fuel Cells Pub Date : 2026-05-27 DOI: 10.1002/fuce.70114
Aswathi Mahesh, Ganesh Mahidhara
{"title":"Cultivation of Electrogens With Cost-Effective Membrane-Less Bioreactor Designs","authors":"Aswathi Mahesh,&nbsp;Ganesh Mahidhara","doi":"10.1002/fuce.70114","DOIUrl":"https://doi.org/10.1002/fuce.70114","url":null,"abstract":"<p>Rational improvements in bioreactor design for scaling up power generation in microbial fuel cells (MFCs) are discussed in this study. The potential of autoclavable MFCs for isolating electroactive bacteria that produce sustainable electricity is being investigated. Dual-chamber sterilizable fuel cells were constructed to evaluate the electrogenic performance of microorganisms collected from marine environments. Voltage generation was monitored using multimeters, and electrogens were identified through 16S rRNA sequencing. Two-chambered fuel cell systems were upgraded to single-chambered configurations, which effectively reduced electrode spacing and internal resistance. The bioreactor designs incorporated natural alternatives for expensive ion exchange membranes. Anoxygenic phototrophic bacteria (APBs), known for their ability to generate electrons under anaerobic conditions without oxygen evolution, were investigated as potential electrogens. These bacteria are primarily found in the genera <i>Rhodobacter</i>, <i>Rhodopseudomonas</i>, <i>Rubrivivax</i>, and <i>Chloroflexus</i>. Marine environments are appealing for mining electrogenic bacteria within APBs. Given their likely evolution from marine origins, local beach areas of the Bay of Bengal were investigated using a metagenomic approach to identify potential sources rich in electrogenic bacteria. Distinct electrogenic bacterial colonies exhibited differential electrogenicity despite being isolated from the same source. The proposed cost-effective, scalable, and membrane-less designs demonstrate improved power output and hold promise for sustainable energy generation and wastewater treatment applications.</p>","PeriodicalId":12566,"journal":{"name":"Fuel Cells","volume":"26 3","pages":""},"PeriodicalIF":3.1,"publicationDate":"2026-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/fuce.70114","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148096657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 3.1 4区 工程技术
Fuel Cells Pub Date : 2026-05-27
{"title":"","authors":"","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":12566,"journal":{"name":"Fuel Cells","volume":"26 3","pages":""},"PeriodicalIF":3.1,"publicationDate":"2026-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148096656","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 3.1 4区 工程技术
Fuel Cells Pub Date : 2026-05-26
{"title":"","authors":"","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":12566,"journal":{"name":"Fuel Cells","volume":"26 3","pages":""},"PeriodicalIF":3.1,"publicationDate":"2026-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148096061","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Flow-Field Optimization and Thermal Management of a Plate-Type Methane Steam Reformer for SOFC Applications 板式SOFC甲烷蒸汽转化炉流场优化与热管理
IF 3.1 4区 工程技术
Fuel Cells Pub Date : 2026-05-26 DOI: 10.1002/fuce.70109
Jenn-Kun Kuo, Rusdan Aditya Aji Nugroho, Wei-Fan Chen, Wei-Cheng Wang, Ching-Neng Huang, Kamil Krpec
{"title":"Flow-Field Optimization and Thermal Management of a Plate-Type Methane Steam Reformer for SOFC Applications","authors":"Jenn-Kun Kuo,&nbsp;Rusdan Aditya Aji Nugroho,&nbsp;Wei-Fan Chen,&nbsp;Wei-Cheng Wang,&nbsp;Ching-Neng Huang,&nbsp;Kamil Krpec","doi":"10.1002/fuce.70109","DOIUrl":"https://doi.org/10.1002/fuce.70109","url":null,"abstract":"<p>This study presents a multiphysics numerical investigation of a plate-type methane steam reformer (MSR) intended for solid oxide fuel cell (SOFC) applications. The focus is placed on resolving the coupled thermo-fluidic behavior, species transport, and reaction kinetics associated with MSR and water–gas shift (WGS) reactions within the reformer. A three-dimensional CFD model was developed to analyze internal flow distribution, heat transfer characteristics, and catalytic performance under different configurations. Three MSR configurations—baseline (Ver.1), dual-baffle (Ver.2), and four-baffle S-shaped (Ver.3)—were constructed to examine the effects of flow-field design on gas distribution, catalytic utilization, and temperature uniformity. Model validation using industrial data confirmed the reliability of the simulation, with an average composition error of only 4.58%.</p><p>Results show that the baseline configuration exhibits significant dead zones and severe thermal nonuniformity, limiting reaction efficiency. The dual-baffle design improves temperature distribution but introduces a substantial pressure drop. The optimized S-shaped Ver.3 model demonstrates the best overall performance, achieving near-complete elimination of stagnant regions, enhanced WGS activity, a 31.2% reduction in CO concentration, and a 4.3% increase in hydrogen yield compared to the baseline. In addition, Ver.3 reduces the maximum temperature gradient by 32.7%, highlighting significant improvements in thermal management and system stability.</p>","PeriodicalId":12566,"journal":{"name":"Fuel Cells","volume":"26 3","pages":""},"PeriodicalIF":3.1,"publicationDate":"2026-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/fuce.70109","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148096059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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