Advanced Synthesis & Catalysis最新文献_第7页

Ruthenium(II)-Catalyzed Annulative C?H Activation of α-Carbonyl Phosphoniums with CF3-Imidoyl Sulfoxonium Ylides: Synthesis of 3-Trifluoromethyl-Isoquinolones 钌(II)-催化环结C？α-羰基膦与cf3 -咪酰基亚砜酰脲的活化：3-三氟甲基异喹诺酮类化合物的合成

IF 5.4 2区化学

Advanced Synthesis & Catalysis Pub Date : 2025-09-25 DOI: 10.1002/adsc.70080

Honglin Chen, Yulong Ran, He Wang, Jing Sun, Yujia Wang, Ran Sun, Lei Li, Ming-Dong Zhou

引用次数: 0

Thiazolium Salts: From Thiamine to Cutting-Edge Organocatalysts 噻唑盐：从硫胺素到尖端的有机催化剂

IF 5.4 2区化学

Advanced Synthesis & Catalysis Pub Date : 2025-09-25 DOI: 10.1002/adsc.70087

Ilan Garcin, Ludovic Maillard, Jean-Marc Campagne, Renata Marcia de Figueiredo

{"title":"Thiazolium Salts: From Thiamine to Cutting-Edge Organocatalysts","authors":"Ilan Garcin, Ludovic Maillard, Jean-Marc Campagne, Renata Marcia de Figueiredo","doi":"10.1002/adsc.70087","DOIUrl":"https://doi.org/10.1002/adsc.70087","url":null,"abstract":"In this comprehensive review, the history of thiazolium salts as N-Heterocyclic Carbenes (NHC) in organocatalytic reactions is intended to be presented. Although the subject (i.e., NHC in organocatalysis) has been covered in several reviews in past years, the idea here stands on the exclusive use of thiazolium salts in such transformations. Indeed, thiazoliums and their related NHCs are the first identified as efficient mediators for the CC bond formation through its peculiar ability to reverse the classical reactivity (umpolung) of carbonyl groups. However, they are relatively quickly overtaken by other classes of NHCs generated from imidazolium and triazolium salts. Even though, thiazolylidenes are still better catalysts in some particular reactions affording outstanding results in terms of conversion and selectivity. Owing to the remarkably high number of reactions that are made possible thanks to the very characteristic properties of such NHCs, the aim of this review is to provide a full account on the discovery and evolution of thiazolium salts and thiazolylidenes in NHC organocatalysis. Information is first provided on their synthesis, structural evolution, physicochemical and electronic properties, and then reactivity and application in various organocatalytic methodologies.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"41 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145134302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis of Functionalized Cyclic Ethers via Gold‐Catalyzed Cyclization and Rearrangement 金催化环化和重排合成功能化环醚

IF 5.4 2区化学

Advanced Synthesis & Catalysis Pub Date : 2025-09-24 DOI: 10.1002/adsc.70012

Akiko Fujii, Kwihwan Kobayashi, Tomoki Hyodo, Tsuyoshi Yamada, Takashi Ikawa, Hironao Sajiki

引用次数: 0

Electro-Oxidative Alkoxylation-Thiolation of Vinyl Ethers 乙烯基醚的电氧化烷氧基-巯基化

IF 5.4 2区化学

Advanced Synthesis & Catalysis Pub Date : 2025-09-23 DOI: 10.1002/adsc.70132

Zhuang Wang, Rongxin Yang, Yuxiu Liu, Hongjian Song, Qingmin Wang

引用次数: 0

Photoinduced Copper-Catalyzed Radical Ring-Opening Azidation of Cyclic Oxime Esters 光诱导铜催化环肟酯自由基开环叠氮化反应

IF 5.4 2区化学

Advanced Synthesis & Catalysis Pub Date : 2025-09-22 DOI: 10.1002/adsc.70133

Li-Bo Yang, Jia Hu, Tian-Tian Zou, Xin-Song Zhou, Jing Li, Yuan Qu, Ya-Min Li

引用次数: 0

Photoinduced Ligated Boryl Radical‐Mediated Functionalization of Organic Halides 光诱导结合硼酸基介导的有机卤化物功能化

IF 5.4 2区化学

Advanced Synthesis & Catalysis Pub Date : 2025-09-22 DOI: 10.1002/adsc.70094

Alisha Rani Tripathy, Akash Bisoyi, Ramsiya Poolamanna, Ananthakrishna Panuganti, Veera Reddy Yatham

{"title":"Photoinduced Ligated Boryl Radical‐Mediated Functionalization of Organic Halides","authors":"Alisha Rani Tripathy, Akash Bisoyi, Ramsiya Poolamanna, Ananthakrishna Panuganti, Veera Reddy Yatham","doi":"10.1002/adsc.70094","DOIUrl":"https://doi.org/10.1002/adsc.70094","url":null,"abstract":"Halogen atom transfers (XATs) represent a valuable class of reactions that facilitate the functionalization of CX bonds in alkyl and aryl halides. Historically, these transformations relied on tin‐ or silicon‐based reagents, which are plagued by several drawbacks, including toxicity, complex synthesis, and high costs. In response to these limitations, ligated boranes have recently emerged as a greener alternative, functioning as efficient halogen abstractors through the generation of reactive boryl radical species. This approach enables the selective and straightforward formation of alkyl and aryl radicals from their halide precursors, opening the door to a wide range of chemical transformations. This review highlights the most recent progress in ligated boryl radical‐mediated XAT chemistry, focusing on the variety of accessible reactions, the underlying mechanisms, and the mechanistic insights gained. To the best of the authors’ knowledge, this is the first comprehensive review dedicated to boryl radical‐mediated XAT processes. With growing interest in this area among synthetic chemists, the authors aim to provide both researchers and students with a clear overview of current advancements and inspire future exploration of ligated boryl radical chemistry.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"82 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145116730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent Advances In The Multicomponent Reactions of CS2 or S8 Under Photo/Electrocatalysis 光/电催化下CS2或S8多组分反应的研究进展

IF 5.4 2区化学

Advanced Synthesis & Catalysis Pub Date : 2025-09-19 DOI: 10.1002/adsc.70129

Yi-Yun Huang, Xin-Yu Lin, Run Xiong, Bi-Yuan Yang, Ning Ma, Ru-An Chi, Zhi-Peng Guan, Jian Lv, Zhi-Bing Dong

引用次数: 0

Charge Controlled Engineering: Constructing Built-in Electric Fields at CoCu-ZIF/Cu3P-GDY Interfaces for Enhanced Photocatalytic Hydrogen Evolution 电荷控制工程：在CoCu-ZIF/Cu3P-GDY界面上构建增强光催化析氢的内置电场

IF 5.4 2区化学

Advanced Synthesis & Catalysis Pub Date : 2025-09-19 DOI: 10.1002/adsc.70126

Jieyuan Du, Yuyu Wang, Guoping Jiang, Fei Jin, Zhiliang Jin

{"title":"Charge Controlled Engineering: Constructing Built-in Electric Fields at CoCu-ZIF/Cu3P-GDY Interfaces for Enhanced Photocatalytic Hydrogen Evolution","authors":"Jieyuan Du, Yuyu Wang, Guoping Jiang, Fei Jin, Zhiliang Jin","doi":"10.1002/adsc.70126","DOIUrl":"https://doi.org/10.1002/adsc.70126","url":null,"abstract":"Rational design of interfacial electric fields in nanostructures for accelerated photogenerated carrier transfer and separation. First, Cu+-mediated self-assembly engineering narrows the bandgap of ZIF-67 while extending the light absorption range of CoCu-ZIF. Furthermore, hierarchical architecture is constructed to incorporate the cocatalyst Cu3P-GDY. The staggered energy levels in the resulting CoCu-ZIF/Cu3P-GDY composite generate a strong driving force. Comprehensive characterization, including density functional theory calculations and Mott–Schottky analysis, confirm the formation of an S-scheme heterojunction between GDY and CoCu-ZIF. Cu3P acts as an electron bridge to promote the directional transfer of photogenerated carriers driven by interfacial electric fields. Differential surface photovoltage signals demonstrate that the robust interfacial electric field enables efficient carrier separation in the CoCu-ZIF/Cu3P-GDY composite. This work establishes a new paradigm for enhancing catalytic performance through broadened light absorption and rationally engineered interfacial electric fields.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"105 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145083948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cyclization Reactions of N-Aminopyridinium Salts: Synthetic Scope and Mechanistic Insights n -氨基吡啶盐的环化反应：合成范围和机理

IF 5.4 2区化学

Advanced Synthesis & Catalysis Pub Date : 2025-09-19 DOI: 10.1002/adsc.70040

Suijie Zhong, Yitai Fu, Xingyue Wang, Xiang Liu

{"title":"Cyclization Reactions of N-Aminopyridinium Salts: Synthetic Scope and Mechanistic Insights","authors":"Suijie Zhong, Yitai Fu, Xingyue Wang, Xiang Liu","doi":"10.1002/adsc.70040","DOIUrl":"https://doi.org/10.1002/adsc.70040","url":null,"abstract":"N-Aminopyridinium salts are readily available and bench-stable nitrogen-containing precursors that have demonstrated broad synthetic utility in diverse cyclization reactions. As practical 1,3-dipoles, N-aminopyridinium salts can engage with dipolarophiles in cycloaddition reactions to construct nitrogen-containing heterocycles. Moreover, as a class of novel aminating or bifunctional aminating reagents, they are capable of generating nitrogen-centered radicals under visible-light irradiation, which can initiate amination-cyclization processes. In recent years, cyclization strategies involving N-aminopyridinium salts have made remarkable progress and garnered significant attention. This review highlights recent advances in the cyclization chemistry of N-aminopyridinium salts and their derivatives, with a particular focus on transition-metal catalyzed, transition-metal-free systems and visible-light-induced transformations. The scope, limitations, and synthetic applications of various cyclization strategies are critically discussed, aiming to reveal the innovative potential of N-aminopyridinium salts as nitrogen-based precursors in synthetic chemistry. We hope this review provides valuable insights and inspiration for future research in synthetic methodology, drug discovery, and the design of functional materials.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"1 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145083953","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Iron-Catalyzed Stereoselective C–H Acylation of 2-Acetamido Acrylates 铁催化的2-乙酰氨基丙烯酸酯的立体选择性C-H酰化

IF 4 2区化学

Advanced Synthesis & Catalysis Pub Date : 2025-09-19 DOI: 10.1002/adsc.70047

Constantinos Kyriacou, Thanh V. Q. Nguyen, Werngard Czechtizky, Enrique Gómez-Bengoa, Arkaitz Correa

引用次数: 0