Dávid Tőzsér, Jennifer Damilola Osazuwa, John Sule Elias, Deborah Osariemen Idehen, Daniela Isabel Gutiérrez Pérez, Ágota Zsófia Ragyák, Zsófi Sajtos, Tibor Magura
{"title":"Comparative analysis of the short-term germination and metal accumulation patterns of two Sorghum hybrids.","authors":"Dávid Tőzsér, Jennifer Damilola Osazuwa, John Sule Elias, Deborah Osariemen Idehen, Daniela Isabel Gutiérrez Pérez, Ágota Zsófia Ragyák, Zsófi Sajtos, Tibor Magura","doi":"10.1007/s10653-025-02485-x","DOIUrl":"https://doi.org/10.1007/s10653-025-02485-x","url":null,"abstract":"<p><p>Metal contamination poses a high risk for organisms, especially those with extensive food chain relevancy. Thus, elevated concentration of metals is considered a major cause for concern in crops. This study aimed to evaluate the short-term responses of sorghum and Sudan grass to different Cd/Zn doses in a complex germination test by assessing growth parameters, tissue metal concentrations, and metal interaction accountant for the ecophysiological and elemental alterations. To do so, radicle and hypocotyl length were measured, and Ca, K, Mg, Cd, Cu, Fe, and Zn concentrations were determined after 24, 72, and 120 h. Our results indicated significant (p < 0.05) differences in the radicle and hypocotyl length by species, contaminant dose, and exposure time. Further, the applied doses along the exposure time gradient significantly and variously affected tissue concentrations. Out of the comparisons involving single metal doses, two significant interactions were revealed: the concentrations of both Cu and Fe were significantly reduced by the increase in Cd concentration in Sudan grass tissues. It was concluded that both species have an excellent potential to indicate metal contamination and accumulate metals in the short term, however, with differences in their responses along the exposure gradient. Additionally, this study filled a literature gap by revealing major patterns and limitations in growth and metal accumulation for sorghum and Sudan grass, thereby supporting further research and practical implications.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 5","pages":"178"},"PeriodicalIF":3.2,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12011658/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143987112","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hengbo Liu, Xu Cao, Zhiyue Gao, Yi Wu, Yongfang Sa, Qinying Yao, Jianzhou Han, Jinyan Yang, Jiang Hou, Tao Xing
{"title":"Integrating spatial heterogeneity and speciation dynamics in source apportionment of toxic metal(loid)s at an abandoned hydrometallurgical zinc smelting site.","authors":"Hengbo Liu, Xu Cao, Zhiyue Gao, Yi Wu, Yongfang Sa, Qinying Yao, Jianzhou Han, Jinyan Yang, Jiang Hou, Tao Xing","doi":"10.1007/s10653-025-02469-x","DOIUrl":"https://doi.org/10.1007/s10653-025-02469-x","url":null,"abstract":"<p><p>Zinc hydrometallurgy sites are critical hotspots for combined toxic metal(loid)s (TMs) pollution, yet the integration of spatial heterogeneity and migration dynamics into source apportionment remains underexplored. This study investigated the concentrations, speciation, and spatial distribution of nine TMs (As, Cd, Cu, Hg, Mn, Ni, Pb, Sb, Zn) in soils at an abandoned zinc smelter in southwest China. Multivariate statistical methods and the Positive matrix factorization (PMF) model were applied to disentangle primary sources and secondary redistribution. Spatial analysis revealed that As, Cd, Cu, Pb, Sb, and Zn shared similar contamination patterns, concentrated in slag storage and comprehensive recovery areas, whereas Hg and Mn exhibited distinct hotspots near sulfuric acid production and electrolysis zones. Vertical migration was most pronounced for Cd and Zn (> 8 m depth), followed by Hg and Mn (4-8 m), while As, Cu, Pb, and Sb were restricted to 0-4 m due to adsorption in clay-rich layers. Speciation analysis indicated high mobility of Cd and Zn (acid-soluble fraction: 66.96 and 52.10%, respectively), contrasting with reducible Pb and Mn (51.59 and 48.32%) and residual As, Hg, Ni, Sb (60.74-76.64%). The results from PMF model identified aqueous-phase (Cd, Zn, Mn) and solid-phase (As, Cu, Pb, Sb) migration pathways, validated by spatial correlations with topography and functional zones. Aqueous-phase contributions dominated low-lying areas, while solid-phase contributions aligned with elevated regions, reflecting topography-driven redistribution. This study advances source apportionment of TM in soil by unifying spatial heterogeneity, speciation dynamics, and receptor modeling, offering a framework for targeted risk assessment and remediation of industrial sites.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 5","pages":"177"},"PeriodicalIF":3.2,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143957377","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Seasonal patterns of air pollution in Delhi: interplay between meteorological conditions and emission sources.","authors":"Najib Ansari, Preeti Kumari, Rahul Kumar, Pavan Kumar, Aquib Shamshad, Saddam Hossain, Ashutosh Sharma, Yogeshwar Singh, Maya Kumari, Varun Narayan Mishra, Rukhsana, Akram Javed","doi":"10.1007/s10653-025-02474-0","DOIUrl":"https://doi.org/10.1007/s10653-025-02474-0","url":null,"abstract":"<p><p>Air pollution (AP) poses a significant public health risk, particularly in developing countries, where it contributes to a growing prevalence of health issues. This study investigates seasonal variations in key air pollutants, including particulate matter, nitrogen dioxide (NO<sub>2</sub>), sulfur dioxide (SO<sub>2</sub>), carbon monoxide (CO), and ozone (O<sub>3</sub>), in New Delhi during 2024. Utilizing Sentinel-5 satellite data processed through the Google earth engine (GEE), a cloud-based geospatial analysis platform, the study evaluates pollutant dynamics during pre-monsoon and post-monsoon seasons. The methodology involved programming in JavaScript to extract pollution parameters, applying cloud filters to eliminate contaminated data, and generating average pollution maps at monthly, seasonal, and annual intervals. The results revealed distinct seasonal pollution patterns. Pre-monsoon root mean square error (RMSE) values for CO, NO<sub>2</sub>, SO<sub>2</sub>, and O<sub>3</sub> were 0.13, 2.58, 4.62, and 2.36, respectively, while post-monsoon values were 0.17, 2.41, 4.31, and 4.60. Winter months exhibited the highest pollution levels due to increased emissions from biomass burning, vehicular activity, and industrial operations, coupled with atmospheric inversions. Conversely, monsoon months saw a substantial reduction in pollutant levels due to wet deposition and improved dispersion driven by stronger winds. Additionally, post-monsoon crop residue burning emerged as a major episodic pollution source. This study underscores the utility of Sentinel-5 products in monitoring urban air pollution and provides valuable insights for policymakers to develop targeted mitigation strategies, particularly for urban megacities like Delhi, where seasonal and source-specific interventions are crucial for reducing air pollution and its associated health risks.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 5","pages":"175"},"PeriodicalIF":3.2,"publicationDate":"2025-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143996833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Muhammad Shafique Khalid, Nimra Farooq, Muhammad Amjad, Muhammad Shahid, Muhammad Imran, Samina Khalid, Hafiz Faiq Bakht, Ghulam Mustafa Shah, Muhammad Asif Naeem, Ghulam Abbas, Behzad Murtaza
{"title":"Ecotoxicological investigation of arsenic contamination within the water-soil-fruit-human continuum.","authors":"Muhammad Shafique Khalid, Nimra Farooq, Muhammad Amjad, Muhammad Shahid, Muhammad Imran, Samina Khalid, Hafiz Faiq Bakht, Ghulam Mustafa Shah, Muhammad Asif Naeem, Ghulam Abbas, Behzad Murtaza","doi":"10.1007/s10653-025-02483-z","DOIUrl":"https://doi.org/10.1007/s10653-025-02483-z","url":null,"abstract":"<p><p>Arsenic (As) contamination of water, soil, and plants has become a global critical concern owing to its ecological consequences and human health risks. This study investigated As contamination in soil-irrigation water-fruit plant systems from previously unexplored fruit orchards in Vehari District, Pakistan. A total of 193 samples, comprising irrigation water, soil, and plants, were collected from three tehsils of district Vehari: Mailsi, Vehari, and Burewala. Results showed As concentrations ranging from 0.2 to 69.9 µg/L (mean: 16.2 µg/L) in water, 0.1-83.6 µg/L (mean: 44.6 µg/L) in soil, and 0-50.6 µg/L (mean: 9.18 µg/L) in plants. Notably, the world of water, 91.6% of soil, 28.3% of plant leaves, and 15.28% of fruit samples exceeded the permissible limit of 10 µg/L set by the World Health Organization (WHO). Moreover, 11.6% of irrigation water, 45% of soil, and 1.67% of plant leaf samples surpassed the hazardous threshold of 50 µg/L. To evaluate health risks, target hazard quotients, estimated daily intake, and cancer risk values for As were calculated as 1.54E-03, 4.63E-04, and 6.94E-07, respectively. Principal component analysis (PCA) revealed a strong correlation among water quality parameters including As carbonate (CO₃<sup>2-</sup>), bicarbonate (HCO₃<sup>-</sup>), and pH, which significantly influenced As uptake by plants. A triangular heatmap indicated associations of water and soil As with pH, CO₃<sup>2-</sup> (r<sup>2</sup>: 0.08, 0.17, 0.46), and plant As (r<sup>2</sup>: - 0.04), supporting the concept of reduced As absorption in high-carbonate soils. This study underscores widespread As contamination in groundwater, soil, and vegetation in Vehari District, Pakistan. The findings highlight the urgent need to improve irrigation water quality or implement systematic evaluations to mitigate risks to human health.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 5","pages":"176"},"PeriodicalIF":3.2,"publicationDate":"2025-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143985681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cagla Celebi, Huseyin Sen, Hasan Susar, Murat Celebi, Izzet Karahan
{"title":"Relationship between distance to boron mine and exposure in cattle.","authors":"Cagla Celebi, Huseyin Sen, Hasan Susar, Murat Celebi, Izzet Karahan","doi":"10.1007/s10653-025-02484-y","DOIUrl":"https://doi.org/10.1007/s10653-025-02484-y","url":null,"abstract":"<p><p>Boron, a valuable underground mineral whose usage area is increasing day by day, has been identified as an essential trace element in plant development. However, research on its usage for humans and animals is still ongoing. Recommended doses are physiologically involved in many systems, but excess boron can be risky for living organisms and the environment. Boron moves in an endless cycle between air, water, soil, and food, and can accumulate. Concentration can rise too much, especially in areas with boron mines. This situation causes contamination in the environment and directly affects human, animal and plant health. There is a paucity of research on the residue status of boron mineral, which is extensively mined and frequently used in certain regions, notably Turkey. In our study, we sought to ascertain the effects of proximity to boron mines on boron concentration in blood, urine, water, and feed in animals. In the study, 60 (20*3) cattle living in areas 0-5, 5-15 and 15-30 km away from the boron mine site were used. Blood and urine samples were taken from cattle. Boron concentrations were determined by sampling the feed and water they consumed. The results of the analyses demonstrated that boron levels in all samples were influenced by the distance to the mine. A statistically significant decrease was observed, particularly in drinking water and blood boron levels. This situation is a major risk factor, especially for living organisms in proximity to boron and other mines. It is also recommended to establish more comprehensive studies investigating the effects of boron concentration on living organisms.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 5","pages":"173"},"PeriodicalIF":3.2,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12000215/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143974138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Source identification of polycyclic aromatic hydrocarbons (PAHs) in river sediments within a hilly agricultural watershed of Southwestern China: an integrated study based on Pb isotopes and PMF method.","authors":"Fen Xu, Chunmei Jiang, Qiang Liu, Rui Yang, Weiwei Li, Yao Wei, Linlin Bao, Hongjin Tong","doi":"10.1007/s10653-025-02481-1","DOIUrl":"https://doi.org/10.1007/s10653-025-02481-1","url":null,"abstract":"<p><p>Polycyclic aromatic hydrocarbons (PAHs) in sediments represent a pervasive environmental issue that poses significant ecological risks. This study employed a combination of geographic information systems, diagnostic ratios, correlation analysis, Pb isotope ratios, and positive matrix factorization (PMF) to elucidate the potential sources of 16 priority PAHs in river sediments from a hilly agricultural watershed in Southwestern China. The results indicated that PAHs concentrations ranged from 55.9 to 6083.5 ng/g, with a mean value of 1582.1 ± 1528.9 ng/g, reflecting high levels of contamination throughout the watershed. The predominant class of PAHs identified was high molecular weight (HMW) PAHs. Diagnostic ratios and correlation analysis suggested that the presence of PHAs is likely attributed primarily to emissions from industrial dust and combustion of coal and petroleum. Furthermore, correlation analysis revealed a significant association between Pb and PAHs, indicating potential shared sources for both pollutants. Additionally, Pb isotopic analysis demonstrated that aerosols may be the primary contributor to Pb accumulation within this environment. Given the similarity in origins between Pb and PAHs, it can be inferred that PAHs predominantly originate from aerosols associated with coal combustion, industrial dust emissions, and vehicle exhaust. This inference is further supported by PMF results which yielded consistent findings with those derived from Pb isotopes analysis. Moreover, PMF estimated three major sources contributing 57.63%, 23.57%, and 18.80%, respectively. These findings provide novel insights into identifying the sources of PAHs in river sediments within hilly agricultural watersheds in Southwest China, thereby establishing a scientific foundation for enhancing environmental quality in agricultural regions.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 5","pages":"174"},"PeriodicalIF":3.2,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143970769","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jianting Feng, Ian T Burke, Felipe E Sepúlveda Olea, Xiaohui Chen, Douglas I Stewart
{"title":"Distribution and speciation of Cu and Zn near spring barley (Hordeum vulgare) roots in digested sewage sludge-amended soil.","authors":"Jianting Feng, Ian T Burke, Felipe E Sepúlveda Olea, Xiaohui Chen, Douglas I Stewart","doi":"10.1007/s10653-025-02482-0","DOIUrl":"https://doi.org/10.1007/s10653-025-02482-0","url":null,"abstract":"<p><p>Risk management for agricultural use of digested sewage sludge requires better understanding of the behaviour and fate of contaminant metals in the plant root zone. A study employing rhizo-pot and plug-tray experiments was conducted to identify the zone near spring barley roots (Hordeum vulgare) where concentration and speciation of Cu and Zn are affected. Cu and Zn bonding environments in the root epidermis/cortex and vascular tissue were also identified. In the digested sludge-amended soil, spring barley absorbed Cu only from the immediate vicinity of the roots (<< 1 mm), but Zn was taken up from further afield (> 1 mm). In the rhizosphere Cu was predominately present as Cu(I) oxides or as Cu(II) absorbed/bonded to phosphate, whereas Zn was present as Zn(II) in inner-sphere complexes with metal oxide surfaces, as Zn(II) sulphides or Zn(II) bonded to/incorporated into carbonates. Cu taken-up by spring barley roots was largely sequestered in the root epidermis and/or cortex predominately in the coordination environments similar to those seen in the rhizosphere. Only a small proportion of the Cu was translocated into the vascular tissue (where it is in the same two bonding environments). Zn taken-up by spring barley roots was present as Zn(II) sulphides, Zn(II) absorbed to/incorporated into carbonates, or Zn(II)-organic complexes. Zn was readily translocated from roots to shoots. Better understanding of these differences in the mobility and uptake of Cu and Zn in sludge-amended agricultural soils could be used to undertake element specific risk assessments.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 5","pages":"172"},"PeriodicalIF":3.2,"publicationDate":"2025-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11994537/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144003832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Soil quality, risk assessment and source identification of heavy metals in native and improved paddy soil and rice grains from Tamil Nadu, India.","authors":"Palanisamy Vasudhevan, Ganapathi Sridevi, Sandhanasamy Devanesan, Saurav Dixit, Subhav Singh, Palaniswamy Thangavel","doi":"10.1007/s10653-025-02447-3","DOIUrl":"https://doi.org/10.1007/s10653-025-02447-3","url":null,"abstract":"<p><p>The present study aims to assess the soil quality, source analysis, and risk assessment of heavy metals in native and improved rice paddies in Tamil Nadu, India. The mean values of DTPA-extractable heavy metal levels in native paddy soil were 0.06, 0.52, 2.61, 3.15, 0.48, 39.48, 97.61 mg kg<sup>-1</sup>, while improved paddy soil had values of 0.11, 1.98, 0.91, 3.21, 1.54, 20.30, 7.78 mg kg<sup>-1</sup> for Cd, Pb, Ni, Cu, Zn, Fe and Mn. These levels were below the acceptable limits set by Indian and European Union soil quality guidelines. All native rice varieties had grain Pb concentration ranging from 0.71 to 1.34 mg kg<sup>-1</sup>, but all improved rice varieties had higher levels of Cd, Pb, and Fe then prescribed limits. Nemerow pollution index (NPI) level of Ni indicated high pollution in native soil. Potential ecological risk index (RI) values of Cd indicated moderate risk in improved soil. Based on the EF and TF values, the paddy fields and rice plants are classified as 'severe enrichment' and 'accumulator' of heavy metals (Cd and Pb), respectively. The HI and THQ levels (Ni, Cd and Pb) were > 1 for both adults and children. Principal component analysis (PCA) found that PC1 eigenvalue of 5.63 (40.21%) and 6.91 (49.37%) and PC2 with 4.84 eigenvalue of 5.63 (34.56%) and 3.97 (28.37%) for native and improved soil, respectively, while cluster analysis (CA) revealed three distinct groups between the metals studied.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 5","pages":"169"},"PeriodicalIF":3.2,"publicationDate":"2025-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143975656","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Raphaël Bentegeac, Djamal Achour, Céline Grare, Manon Muntaner, Victoria Gauthier, Philippe Amouyel, Regis Matran, Farid Zerimech, Jean-Marc Lo Guidice, Luc Dauchet
{"title":"Associations between air pollution and biomarkers of oxidative stress and lung damage in a large population-based sample of non-smoking adults in northern France.","authors":"Raphaël Bentegeac, Djamal Achour, Céline Grare, Manon Muntaner, Victoria Gauthier, Philippe Amouyel, Regis Matran, Farid Zerimech, Jean-Marc Lo Guidice, Luc Dauchet","doi":"10.1007/s10653-025-02472-2","DOIUrl":"https://doi.org/10.1007/s10653-025-02472-2","url":null,"abstract":"<p><p>Air pollution is an environmental risk factor associated with lung and cardiovascular disease that may be mediated by physiological pathways such as oxidative stress. Previous studies have identified associations between air pollution and biomarkers of oxidative stress (8-OHdG, 4-HNE, and fluorescent oxidation products (FOPs)), as well as lung health marker CC16, in younger and asthmatic populations. The objective of this study of a large population-based sample of non-smoking adults was to explore the relationship between long-term and short-term atmospheric pollution exposures and plasma or urine levels of these biomarkers. Our study was a post-hoc analysis of the cross-sectional ELISABET study from 2011 to 2013. We included non-smoking inhabitants of Lille, France from the ELISABET study. We assessed mean pluri-annual residential and short-term exposures to atmospheric pollution components (PM<sub>10</sub>, NO<sub>2</sub>, and O<sub>3</sub>) and collected several biomarkers (CC16, 8-OHdG, 4-HNE, and fluorescent oxidation products (FOPs)). We searched for associations between pollutants and biomarkers using log-linear robust multivariate regressions. Our work did not show any association between short- or long-term exposure to air pollution components and CC16, 8-OHdG, 4-HNE or FOP in a large (980 subjects) sample of Lille's general population, despite having sufficient statistical power to replicate previous findings of associations between air pollution and these biomarkers found in younger or asthmatic populations.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 5","pages":"166"},"PeriodicalIF":3.2,"publicationDate":"2025-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11993482/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144002732","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Federica Lo Medico, Daniela Varrica, Marino Vetuschi Zuccolini, Marianna Miola, Giovanna Scopelliti, Maria Grazia Alaimo
{"title":"Geochemical baseline values and spatial distribution of major, trace, and rare earth elements in unpolluted soils of the Sicily region (Italy).","authors":"Federica Lo Medico, Daniela Varrica, Marino Vetuschi Zuccolini, Marianna Miola, Giovanna Scopelliti, Maria Grazia Alaimo","doi":"10.1007/s10653-025-02475-z","DOIUrl":"https://doi.org/10.1007/s10653-025-02475-z","url":null,"abstract":"<p><p>This study presents a comprehensive investigation of the geochemical baseline values and the spatial distribution of major, trace elements, and rare earth elements in the unpolluted soils of Sicily region. The concentrations of elements were quantified by ICP-OES and ICP-MS. The distribution patterns of major and trace elements are closely linked to the geological features of the area. The major elements Fe, Ca, Al, Mg, and K exhibit the highest concentrations. The order of abundance for trace elements follows this trend: Ba, Sr, Zn, V, Cr, Cu, Rb, Ni, Pb, B, Li, Co, As, Mo, U, Sb, Se, Cd, and Bi. Regional geochemical baseline values were calculated using the UTL95 - 95 method with BCA bootstrap, demonstrating that the regional approach provides a more accurate assessment compared to European and Italian threshold values. A geostatistical approach was used to produce spatial geochemical maps, which allow the prediction of element distributions in unsampled areas. This integrated approach establishes a benchmark for more detailed studies on environmental risk assessment, providing a solid foundation for identifying and understanding natural and anthropogenic geochemical anomalies in the soils of the Sicily region.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 5","pages":"167"},"PeriodicalIF":3.2,"publicationDate":"2025-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11993483/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143990645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}