Environmental Geochemistry and Health最新文献

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Biosorption performance toward Co(II) and Cd(II) by irradiated Fusarium solani biomass. 辐照太阳镰刀菌生物量对Co(II)和Cd(II)的吸附性能。
IF 3.2 3区 环境科学与生态学
Environmental Geochemistry and Health Pub Date : 2025-01-09 DOI: 10.1007/s10653-024-02342-3
Abeer M Mousa, Ezzat A Abdel-Galil, Mostafa Zhran, Mohamed G Moussa
{"title":"Biosorption performance toward Co(II) and Cd(II) by irradiated Fusarium solani biomass.","authors":"Abeer M Mousa, Ezzat A Abdel-Galil, Mostafa Zhran, Mohamed G Moussa","doi":"10.1007/s10653-024-02342-3","DOIUrl":"10.1007/s10653-024-02342-3","url":null,"abstract":"<p><p>Fusarium solani biomass plays a significant role in water pollution remediation due to its ability to sequester heavy metals, particularly cobalt (Co(II)) and cadmium (Cd(II)), which pose severe environmental and health risks. This study aimed to identify fungi from sewage-contaminated sites and evaluate their efficiency in absorbing and reducing Co(II) and Cd(II) ions. The biosorption potential of irradiated Fusarium solani biomass for removing Co(II) and Cd(II) ions from aqueous solutions was investigated. Six fungal isolates were screened, and the most promising isolate, identified as F. solani, was selected for further research. The biomass was exposed to different gamma irradiation doses (0, 1, 3, and 5 kGy), and its biosorption efficiency was assessed. The highest biosorption efficiencies were observed with the biomass exposed to 5 kGy (FS-5), achieving 37% for Co(II) and 90% for Cd(II) removal within 25 min. The surface area of the biosorbent increased from 13.12 m<sup>2</sup> g<sup>-1</sup> for unexposed biomass (FS-0) to 34.87 m<sup>2</sup> g<sup>-1</sup> for FS-5, enhancing the biosorption capacity. The adsorption kinetics followed a pseudo second order model with high correlation coefficients (R<sup>2</sup> > 0.993), indicating chemisorption as the rate-limiting step. Isotherm studies showed that the Langmuir model provided a better fit to the experimental data, with maximum adsorption capacities of 4.44 mg g<sup>-1</sup> for Co(II) and 21.00 mg g<sup>-1</sup>. This study provides valuable insights into the effective removal of Cd and Co from polluted sites, underscoring the potential of developing eco-friendly and cost-effective bioremediation approaches.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 2","pages":"47"},"PeriodicalIF":3.2,"publicationDate":"2025-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142946704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling the impact of biodegradable polylactic acid microplastics on meadow soil health. 揭示可生物降解聚乳酸微塑料对草甸土壤健康的影响。
IF 3.2 3区 环境科学与生态学
Environmental Geochemistry and Health Pub Date : 2025-01-08 DOI: 10.1007/s10653-025-02358-3
Shuming Liu, Binglin Chen, Kaili Wang, Jinghuizi Wang, Kaili Wang, Yan Suo, Xiaoyu Yang, Yaokun Zhu, Jiaxing Zhang, Mengchu Lu, Yunqing Liu
{"title":"Unveiling the impact of biodegradable polylactic acid microplastics on meadow soil health.","authors":"Shuming Liu, Binglin Chen, Kaili Wang, Jinghuizi Wang, Kaili Wang, Yan Suo, Xiaoyu Yang, Yaokun Zhu, Jiaxing Zhang, Mengchu Lu, Yunqing Liu","doi":"10.1007/s10653-025-02358-3","DOIUrl":"10.1007/s10653-025-02358-3","url":null,"abstract":"<p><p>Soil microplastics (MPs) pollution has garnered considerable attention in recent years. The use of biodegradable plastics for mulching has led to significant quantities of plastic entering agro-ecosystems. However, the effects of biodegradable polylactic acid (PLA) plastics on meadow soils remain underexplored. This study investigates the impacts of PLA-MPs of varying particle sizes and concentrations on soil physicochemical properties, enzyme activities, and microbial communities through a 60-day incubation experiment. PLA-MPs increased the pH, soil organic matter, total nitrogen (TN) and available potassium (AK) content, as well as enhanced the activities of superoxide dismutase (S-SOD), peroxidase (S-POD), soil catalase (S-CAT), β-glucosidase (S-β-GC) and urease (S-UE) activities. Conversely, a decrease in alkaline phosphatase (S-ALP) activity was observed. The influence of PLA-MPs on soil physicochemical properties was more pronounced with larger particle sizes, whereas smaller particles had a greater effect on enzyme activities. Additionally, PLA-MPs led to an increase in the abundance of Acidobacteriota, Chloroflexi, and Gemmatimonadota, while the abundance of Proteobacteria, Actinobacteriota, and Patescibacteria declined. Mantel test analysis showed that changes in microbial community composition affected soil properties such as pH, AK, S-UE and S-β-GC. Phylogenetic Investigation of Communities by Reconstruction of Unobserved States (PICRUSt2) analysis demonstrated that PLA-MPs modify bacterial metabolic pathways. Our results suggest that particle size and concentration of PLA-MPs differentially affect soil nutrients and microbial community structure and function, with more significant effects observed at larger particle sizes and higher concentrations.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 2","pages":"45"},"PeriodicalIF":3.2,"publicationDate":"2025-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142946482","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of sources, spatial and temporal distribution, ecological and health risk associated with CAF (Caffeine) and DEET (N, N-diethyl-meta-toluamide) contamination in the urban groundwater parts of Vellore city, Tamilnadu, India. 评价印度泰米尔纳德邦Vellore市城市地下水中CAF(咖啡因)和DEET (N, N-二乙基-间甲酰胺)污染的来源、时空分布、生态和健康风险
IF 3.2 3区 环境科学与生态学
Environmental Geochemistry and Health Pub Date : 2025-01-08 DOI: 10.1007/s10653-024-02351-2
Daggupati Sridhar, Sundaram Parimalarenganayaki
{"title":"Evaluation of sources, spatial and temporal distribution, ecological and health risk associated with CAF (Caffeine) and DEET (N, N-diethyl-meta-toluamide) contamination in the urban groundwater parts of Vellore city, Tamilnadu, India.","authors":"Daggupati Sridhar, Sundaram Parimalarenganayaki","doi":"10.1007/s10653-024-02351-2","DOIUrl":"10.1007/s10653-024-02351-2","url":null,"abstract":"<p><p>Urban environments are heavily influenced by various activities, leading to contamination of water sources by emerging contaminants (ECs). Among these, caffeine (CAF) and N, N-diethyl-meta-toluamide (DEET) are notable ECs frequently found in domestic sewage due to human activities. Despite extensive research on emerging contaminants, limited studies have focused on the seasonal variations, human health and ecological risks of CAF and DEET in urban groundwater, particularly in Indian cities. This study aimed to analyze the occurrence, spatial distribution, ecological and health risks of CAF and DEET in groundwater in Vellore city, Tamil Nadu, India. A total of 96 groundwater samples were collected across four seasons in 2022 and analyzed using Hichrom HPLC in an 844 UV/VIS compact Ion Chromatography system. CAF and DEET were detected in 95% and 96% of samples, with mean concentrations of 34 μg/L and 30 μg/L, respectively. Contamination levels were higher during the Southwest Monsoon (SWM) and Northeast Monsoon (NEM) seasons. Health risk assessments for children, women, and men showed that CAF posed significant risks, particularly to children during the NEM season, followed by women and men. Although DEET exhibited lower health risks overall, children remained the most vulnerable group. Statistical analysis confirmed significant differences in exposure levels, with children showing the highest variations. Ecological risk assessment revealed that 96.88% of samples containing CAF posed moderate ecological risks, while 6.25% of DEET samples fell into the same category. This study highlights the widespread presence of CAF and DEET in urban groundwater and their associated health and ecological risks. The findings emphasize the need for effective strategies to monitor and mitigate EC contamination in urban water systems.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 2","pages":"44"},"PeriodicalIF":3.2,"publicationDate":"2025-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142946558","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluating major element hydrogeochemistry and fluoride occurrence in groundwater of crystalline bedrock aquifers and associated controlling factors of Eumseong basin area, South Korea. 韩国阴城盆地结晶基岩含水层地下水主要元素水文地球化学和氟化物赋存及其控制因素评价
IF 3.2 3区 环境科学与生态学
Environmental Geochemistry and Health Pub Date : 2025-01-08 DOI: 10.1007/s10653-024-02356-x
Jong Hyun Oh, Dong-Chan Koh, Hyo-Sik Seo, Nayeon Koh, Sung Won Kim
{"title":"Evaluating major element hydrogeochemistry and fluoride occurrence in groundwater of crystalline bedrock aquifers and associated controlling factors of Eumseong basin area, South Korea.","authors":"Jong Hyun Oh, Dong-Chan Koh, Hyo-Sik Seo, Nayeon Koh, Sung Won Kim","doi":"10.1007/s10653-024-02356-x","DOIUrl":"10.1007/s10653-024-02356-x","url":null,"abstract":"<p><p>Long-term intake of high-fluoride water can cause fluorosis in bones and teeth or damage to organs. Fluoride in groundwater is primarily derived from reactions with rocks containing fluorine-related minerals, and fluoride concentrations are elevated in groundwater that has been reacting with these rocks for a long time. The purpose of this study is to investigate the origin and distribution of fluoride in groundwater and to assess the influence of various factors, including geology, on fluoride concentrations in groundwater. The Eumseong basin and surrounding areas were selected as the study area due to the diversity of geologic factors. 139 groundwater samples and 14 rock samples were collected, with groundwater samples subjected to field water quality measurements, chemical analysis, and statistical analysis, and rock samples subjected to microscopic observation and chemical analysis. Fluoride concentration in groundwater increased with well depth, and was highest in groundwater associated with granitic rocks rich in biotite. The fluoride concentration in groundwater showed a negative correlation with the distance to the fault, suggesting that deep groundwater may preferentially flow along fault zones in certain areas. In addition, high-fluoride groundwater had depleted water-stable isotope values, which is likely to be resulted from higher degree of water-rock interaction in groundwater recharged at higher elevations. Calcite precipitation in most groundwater appears to weaken fluorite solubility control on fluoride concentration. Multivariate statistical analysis revealed that water-rock interactions generally governed fluoride and major element concentrations, with high-fluoride groundwater clearly distinguished. These findings can aid in assessing fluoride occurrence in groundwater and managing water quality in areas with similar geological characteristics.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 2","pages":"43"},"PeriodicalIF":3.2,"publicationDate":"2025-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142946557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Associations of phthalate and phthalate alternative metabolites in urine with the risk of gallstones in adults: a cross-sectional analysis. 成人尿中邻苯二甲酸酯和邻苯二甲酸酯替代代谢物与胆结石风险的关系:横断面分析
IF 3.2 3区 环境科学与生态学
Environmental Geochemistry and Health Pub Date : 2025-01-06 DOI: 10.1007/s10653-024-02354-z
Tianshan Shi, Di Li, Donghua Li, Peng Xie, Jin Sun, Tingrong Wang, Rui Li, Zixuan Zou, Zhenjuan Li, Xiaowei Ren
{"title":"Associations of phthalate and phthalate alternative metabolites in urine with the risk of gallstones in adults: a cross-sectional analysis.","authors":"Tianshan Shi, Di Li, Donghua Li, Peng Xie, Jin Sun, Tingrong Wang, Rui Li, Zixuan Zou, Zhenjuan Li, Xiaowei Ren","doi":"10.1007/s10653-024-02354-z","DOIUrl":"10.1007/s10653-024-02354-z","url":null,"abstract":"<p><p>It remains unclear whether phthalates are associated with gallstones and whether the associations of phthalate alternatives with gallstones are different from traditional phthalates. In this study, 1735 participants from the NHANES 2017-2018 were included and their urine was used to detect phthalate metabolites. We used logistic and restricted cubic spline regressions to assess individual associations and dose-response relationships between phthalate metabolites and gallstones, quantile g-computation and Bayesian kernel machine regression to assess mixed associations of phthalate metabolites with gallstones, and subgroup analyses to explore potential effect modifiers. We observed that individual associations of cyclohexane-1,2-dicarboxylic acid-mono(carboxyoctyl) ester phthalate (MCOCHP) (OR: 1.423, 95% CI: 1.098-1.844) and cyclohexane 1,2-dicarboxylic acid monohydroxy isononyl ester (MHNCH) (OR: 1.380, 95% CI: 1.080-1.763) with gallstones were linearly positive, mixed association of phthalate metabolites (OR: 2.453, 95% CI: 1.054-5.708) with gallstones was also positive, and MCOCHP and MHNCH had positive weights. The associations of phthalate metabolites with gallstones were higher in the males and participants with age ≥ 60 years, BMI ≥ 30 kg/m<sup>2</sup>, hypertension, and diabetes. MCOCHP and MHNCH had the highest groupPIP (groupPIP: 0.941), mono(2-ethyl-5-carboxypentyl) terephthalate (MECPTP) had the highest condPIP (condPIP: 0.721), and mono(2-ethyl-5-carboxypentyl) phthalate (MECPP), MCOCHP, and mono-isobutyl phthalate (MiBP) also had high condPIPs (condPIP > 0.5). The trend in mixed associations of phthalate metabolites with gallstones was positive. Our study suggests that traditional phthalates and phthalate alternatives are associated with gallstones, especially in the elderly, men, obese, hypertensive populations, and diabetic populations, and phthalate alternatives are associated with a higher risk of gallstones.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 2","pages":"41"},"PeriodicalIF":3.2,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142930975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Spatial distribution of heavy metal assessment in beach sediment due to bauxite mining in Kuantan, Pahang, Peninsular Malaysia. 马来西亚半岛彭亨关丹铝土矿开采滩地沉积物重金属评价的空间分布
IF 3.2 3区 环境科学与生态学
Environmental Geochemistry and Health Pub Date : 2025-01-06 DOI: 10.1007/s10653-024-02347-y
Mohd Talha Anees, Ahmad Farid Bin Abu Bakar, Mohammad Muqtada Ali Khan, Naseem Akhtar, Mohammad Rashid Khan, Mohd Shahnawaz Khan
{"title":"Spatial distribution of heavy metal assessment in beach sediment due to bauxite mining in Kuantan, Pahang, Peninsular Malaysia.","authors":"Mohd Talha Anees, Ahmad Farid Bin Abu Bakar, Mohammad Muqtada Ali Khan, Naseem Akhtar, Mohammad Rashid Khan, Mohd Shahnawaz Khan","doi":"10.1007/s10653-024-02347-y","DOIUrl":"10.1007/s10653-024-02347-y","url":null,"abstract":"<p><p>The effect of open-pit bauxite mining on beach sediment contamination in the urban coastal environment of Kuantan City, Malaysia, was investigated. The contents of 11 heavy metals (Pb, Cd, Al, Mn, Cu, Zn, Fe, As, Ni, Cr, and Ag) in 30 samples from Kuantan beach sediment zones (supratidal, intertidal, and subtidal) were determined using inductively coupled plasma optical emission spectrometry followed by contamination indexes, Pearson's correlation analysis, and principal component analysis (PCA). The results indicated that Cd, As, Ni, and Ag values in beach sediment zones were significantly higher compared to background values. Contamination indexes suggest that Cd, As, Ni, and Ag were highly contaminated, and moderate to extremely enriched near the Kuantan Port. However, these heavy metal concentrations are lower compared to previous studies in the region. Sediment quality guidelines highlighted the occasional presence of Cd and Ag. Based on Pearson's correlation analysis, PCA, and cluster analysis, sources of these heavy metals in beach sediments were likely from agricultural runoff, uncontrolled industrial and residential discharge, and unprotected mine waste near the Kuantan Port. Furthermore, effective management of mining practices and ongoing monitoring are essential to reduce contamination risks.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 2","pages":"42"},"PeriodicalIF":3.2,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142930977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Native mercury, hydrargyrism and the birth of occupational toxicology in Colombia. 哥伦比亚的原生汞、水合作用和职业毒理学的诞生。
IF 3.2 3区 环境科学与生态学
Environmental Geochemistry and Health Pub Date : 2025-01-05 DOI: 10.1007/s10653-024-02301-y
Juan-Sebastián Bonilla, Alexander Rojas, Camilo A Rojas Velandia, Helwar Figueroa, Daniela Núñez-Alarcón, Katherine A León-Palma, Alvaro J Idrovo
{"title":"Native mercury, hydrargyrism and the birth of occupational toxicology in Colombia.","authors":"Juan-Sebastián Bonilla, Alexander Rojas, Camilo A Rojas Velandia, Helwar Figueroa, Daniela Núñez-Alarcón, Katherine A León-Palma, Alvaro J Idrovo","doi":"10.1007/s10653-024-02301-y","DOIUrl":"10.1007/s10653-024-02301-y","url":null,"abstract":"<p><p>The \"La Esperanza\" native mercury mine in Aranzazu, (Caldas, Colombia) was active from 1948 until 1975. Before the final closure of the mine, the company began using dimercaprol (BAL, British Anti-Lewisite) and penicillamine for the treatment of hydrargyrism among workers. Mercury poisoning among miners was frequent due to precarious working conditions, inadequate technology, difficult terrain, and the high toxicity of native mercury within the mine. The costs associated with the treatment was one of the causes of the closure of the mine. The early use of these chelators corresponds to the first systematic use of an antidote in occupational health in Colombia. This paper describes the context in which dimercaprol and penicillamine were used, a milestone in the history of toxicology, medical geology and occupational health in Colombia and Latin America.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 2","pages":"40"},"PeriodicalIF":3.2,"publicationDate":"2025-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142926653","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Spatial distribution and driving factors of soil selenium on the Leizhou Peninsula, southern China. 雷州半岛土壤硒的空间分布及其驱动因素
IF 3.2 3区 环境科学与生态学
Environmental Geochemistry and Health Pub Date : 2025-01-04 DOI: 10.1007/s10653-024-02349-w
Xiaomeng Cheng, Li Zhang, Chen Zhao, Min Peng, Yuanli Qin, Wei Han, Fugui Zhang, Daoming Zeng, Fan Yang
{"title":"Spatial distribution and driving factors of soil selenium on the Leizhou Peninsula, southern China.","authors":"Xiaomeng Cheng, Li Zhang, Chen Zhao, Min Peng, Yuanli Qin, Wei Han, Fugui Zhang, Daoming Zeng, Fan Yang","doi":"10.1007/s10653-024-02349-w","DOIUrl":"10.1007/s10653-024-02349-w","url":null,"abstract":"<p><p>Selenium (Se) is an essential element for humans, playing a critical role in the functioning of the immune system. The global prevalence of dietary Se deficiency is a significant public health concern, largely attributed to the low levels of Se present in crops. The sufficient Se in plants and humans is determined by the presence of stable Se sources in the soil. The Leizhou Peninsula is an important agricultural region in China, but the concentration and spatial distribution of Se in its soils remain unclear. To address this issue, we analyzed Se concentration data from 3333 soil samples collected at the depth of 0-20 cm from the Leizhou Peninsula, covering an area of 13,225 km<sup>2</sup>. The results indicate that the mean soil Se concentration was 0.50 mg kg<sup>-1</sup>, with Se-enriched soils being widely distributed. This provides prospects for the development of Se-enriched crops. Using random forest (RF) modeling and correlation analysis, the clay minerals (Fe-Al oxides), chemical index of alteration (CIA), and soil organic carbon (SOC) have been identified as the principal determinants of Se distribution in soil. During the weathering processes of the basalts, Fe-Al oxides serve as a crucial factor in Se accumulation in the red soils. Furthermore, the tropical climate further contributes to increasing the degree of weathering and the proportion of clay minerals and SOC in the soil. Atmospheric deposition derived from marine and precipitation is another important factor that promotes Se flux into soils. In conclusion, the distribution pattern of Se is jointly determined by the weathering process of basalt and climatic conditions. The results of the geographically weighted regression (GWR) analysis revealed that SOC, Al<sub>2</sub>O<sub>3</sub>, TFe<sub>2</sub>O<sub>3</sub> and CIA change spatially and exhibit a spatial non-stationarity relationship with Se. This study offers a theoretical foundation and practical guidance for the sustainable development of Se-enriched agriculture and similar climate settings worldwide.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 2","pages":"39"},"PeriodicalIF":3.2,"publicationDate":"2025-01-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142926667","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption properties and mechanisms of Cd by co-pyrolysis composite material derived from peanut biochar and tailing waste. 花生生物炭与尾砂共热解复合材料对Cd的吸附性能及机理
IF 3.2 3区 环境科学与生态学
Environmental Geochemistry and Health Pub Date : 2025-01-03 DOI: 10.1007/s10653-024-02352-1
Xiaoqing Zhang, Jiong Li, Xin Li, Zhihua Chen, Dajun Ren, Shuqin Zhang
{"title":"Adsorption properties and mechanisms of Cd by co-pyrolysis composite material derived from peanut biochar and tailing waste.","authors":"Xiaoqing Zhang, Jiong Li, Xin Li, Zhihua Chen, Dajun Ren, Shuqin Zhang","doi":"10.1007/s10653-024-02352-1","DOIUrl":"10.1007/s10653-024-02352-1","url":null,"abstract":"<p><p>Cadmium (Cd) contamination in aquatic systems is a widespread environmental issue. In this study, a solid waste iron tailings and biochar hybrid (Fe-TWBC) was successfully synthesized derived from co-pyrolysis of peanut shell and tailing waste (Fe-TW). Characterization analyses showed that the metal oxides from solid waste iron tailings successfully loaded onto the biochar surface, with more functional groups in Fe-TWBC. The Fe-TWBC had a maximum capacity of 95.06 mg·g<sup>-1</sup> on Cd<sup>2+</sup> adsorption, which was 1.40 times to pristine BC (70.46 mg·g<sup>-1</sup>) and 2.53 times to Fe-TW (37.51 mg·g<sup>-1</sup>). The adsorption behavior followed the pseudo-second-order kinetics and Freundlich models. DFT calculations revealed that the O-top of Fe-O group was the most chemically reactive site for Cd<sup>2+</sup> adsorption with the high adsorption energy values of - 4.05 eV, short O-Cd bond lengths (2.133 Å), low electrostatic potentials in small blue regions near the O atom of Fe-O group, low energy gap (0.22 eV) and large electrophilic Fukui index (f<sup>-</sup> = 0.18). Overall, these findings suggest that Fe-TWBC is effective in removing Cd<sup>2+</sup> from aqueous solution and promotes the utilization of biowaste and solid waste iron tailing waste for cleaner production.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 2","pages":"37"},"PeriodicalIF":3.2,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142921093","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Integrated environmental and health assessment from hydrogeochemistry and radiogeology parameters of hydrothermal spring attractions in Southern Thailand. 基于泰国南部热液温泉景点水文地球化学和放射地质参数的综合环境与健康评价。
IF 3.2 3区 环境科学与生态学
Environmental Geochemistry and Health Pub Date : 2025-01-03 DOI: 10.1007/s10653-024-02350-3
Wipada Ngansom, Prapat Mahapattanathai, Dumrongsak Rodphothong, Thawatchai Itthipoonthanakorn, Saroh Niyomdecha, Helmut Dürrast, Kunyarut Junjoung, Monthon Yongprawat
{"title":"Integrated environmental and health assessment from hydrogeochemistry and radiogeology parameters of hydrothermal spring attractions in Southern Thailand.","authors":"Wipada Ngansom, Prapat Mahapattanathai, Dumrongsak Rodphothong, Thawatchai Itthipoonthanakorn, Saroh Niyomdecha, Helmut Dürrast, Kunyarut Junjoung, Monthon Yongprawat","doi":"10.1007/s10653-024-02350-3","DOIUrl":"10.1007/s10653-024-02350-3","url":null,"abstract":"<p><p>The present study aimed to investigate the hydrogeochemical patterns and contamination of the radiogeology, especially radon activity, related to geothermal aquifer properties and to perform a risk assessment of annual effective doses covering all hydrothermal spring attractions in Southern Thailand. Radon is an established lung carcinogen; especially longer term exposure to radioactive radon through inhalation could be a cause of lung cancer risk. Altogether 22 hydrothermal spring samples were collected from the six hydrothermal provinces in Southern Thailand in early November of 2023. Geochemical data represented by calcium chloride and sodium chloride type, most of which were influenced by seawater intrusion. In addition, the hydrothermal springs that located along local fault zones were mainly controlled by water‒rock interactions, indicating that hydrothermal spring quality was influenced by weathering. Hydrothermal springs located along the coastlines of the Gulf of Thailand and Andaman Sea were dominated by evaporation. Radon activity concentrations show value levels from 9 Bq/L (PG1) to 7,070 Bq/L (SR3), with an average of 580 Bq/L. Radon levels of hydrothermal spring attractions can be divided into three categories: (a) low radon levels below 100 Bq/L, (b) moderate to high radon levels between 100 and 580 Bq/L, and (c) very high radon levels greater than 580 Bq/L. The total annual effective doses for adults due to ingestion and dominantly inhalation of radon at hydrothermal spring attractions varied from 0.01 to 19.30 mSv/year. These results highlight the usefulness of this method as an essential tool for delineating radon concentrations, which could be used to introduce guidelines for health risk assessment.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"47 2","pages":"38"},"PeriodicalIF":3.2,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142921114","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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