Max Bibrack, Andreas Distler, Michael Wagner, Karen Forberich, Christoph Brabec, Hans-Joachim Egelhaaf
{"title":"Silver Electrodes for Organic Solar Cells Printed via Laser-Induced Forward Transfer","authors":"Max Bibrack, Andreas Distler, Michael Wagner, Karen Forberich, Christoph Brabec, Hans-Joachim Egelhaaf","doi":"10.1002/ente.202401815","DOIUrl":"https://doi.org/10.1002/ente.202401815","url":null,"abstract":"<p>Laser-induced forward transfer (LIFT) is presented as a new, contactless, and roll-to-roll compatible method for the deposition of silver top electrodes for organic solar cells (OSCs). Employing a nanosecond laser, highly reflective silver electrodes are printed by LIFT onto OSCs with P3HT:o-IDTBR bulk heterojunction layers. Upon optimization of ink composition, source film thickness, and laser parameters, the resulting organic solar cells reach efficiencies of more than 5%, which are similar to those of reference devices with vapor-deposited silver electrodes.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 5","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ente.202401815","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143939659","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fangfang Zhao, Ruixian Tang, Liming Yu, Lei Ma, Liangming Wei
{"title":"An Innovative Polydopamine/Polyvinyl Alcohol Binder System for High-Performance Micro-Sized Silicon Anodes","authors":"Fangfang Zhao, Ruixian Tang, Liming Yu, Lei Ma, Liangming Wei","doi":"10.1002/ente.202401591","DOIUrl":"https://doi.org/10.1002/ente.202401591","url":null,"abstract":"<p>Micro-sized silicon (Si) is expected to be widely used in the future lithium-ion battery industry due to its abundant resources, low price, and high energy density. However, the rapid capacity degradation resulting from its significant volume expansion remains a critical challenge. Herein, an innovative binder system for micro-sized Si anodes is presented. Utilizing a high-energy ball milling reaction, Si particles are coated with a thin polydopamine (PDA) layer, forming Si@PDA particles. Subsequently, a polyvinyl alcohol (PVA) binder is incorporated to form the Si@PDA/PVA binder system. The numerous hydroxyl groups in PDA form hydrogen bonds with PVA binder, establishing robust interactions among electrode components, thereby stabilizing the overall structure of the Si anode and maintaining the integrity of its electrical contacts. As a result, the obtained Si@PDA/PVA anode exhibits a high specific capacity of 1215 mAh g<sup>−1</sup> at 0.2 C after 100 cycles. In addition, the rate performance test demonstrates that it delivers a high capacity of over 800 mAh g<sup>−1</sup> at 3 C. This approach provides a promising strategy for the overall design of micro-sized Si electrodes, offering enhanced cyclic performance and durability.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 4","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143793770","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Selin Gümrükçü, Ekrem Kaplan, Melih Beşir Arvas, Nilüfer Koçyiğit, Mukaddes Özçeşmeci, Yücel Şahin, İbrahim Özçeşmeci
{"title":"Palladium (II)-NNN Pincer Complex Embedded Carbon Felt Electrode for High-Performance Symmetrical Supercapacitor Applications","authors":"Selin Gümrükçü, Ekrem Kaplan, Melih Beşir Arvas, Nilüfer Koçyiğit, Mukaddes Özçeşmeci, Yücel Şahin, İbrahim Özçeşmeci","doi":"10.1002/ente.202400915","DOIUrl":"https://doi.org/10.1002/ente.202400915","url":null,"abstract":"<p>Pincer-type ligands are coated on the carbon felt (CF) surface in one step via the electrodeposition method, and their use as supercapacitor electrode materials is reported for the first time in this research study. Raman spectroscopy, X-ray diffraction, scanning electron microscopy-energy dispersive X-ray analysis and mapping, and X-ray photoelectron spectroscopy are used to characterize the bis(pyridyl) iminoisoindoline (BPI) derivates/CF electrodes. The galvanostatic charge–discharge study indicates that the calculated specific capacitance (<i>C</i><sub>s</sub>) of the PdBPI/CF electrode is 271.2 F g<sup>−1</sup> at 1.0 mA current. The symmetrical supercapacitor has a high capacitance retention of up to 80.6% after 10 000 cycles, showing extended cycle life and strong electrochemical stability. The highest energy and power density values obtained for the PdBPI/CF symmetric supercapacitor are calculated to be 25.9 Wh kg<sup>−1</sup> and 981.8 W kg<sup>−1</sup>, respectively.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 5","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143939213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cong Li, Yan Yuan, Zhengqian Li, Yaxin Kong, Hai Lu
{"title":"High-Sulfur-Loading Gel Cathode Employing a Self-Supporting Composite Matrix for Lithium-Polysulfide Batteries","authors":"Cong Li, Yan Yuan, Zhengqian Li, Yaxin Kong, Hai Lu","doi":"10.1002/ente.202401556","DOIUrl":"https://doi.org/10.1002/ente.202401556","url":null,"abstract":"<p>Aimed at the application drawbacks of lithium-polysulfide semiflow battery involved with low utilization of active material and inevitable shuttle effect, a self-supporting porous substrate characterized by high porosity and outstanding conductivity is developed in this study, which consists of cotton-derived nanofiber and graphene wrapped on the nanofiber. Then a gelable polymer poly-(vinylidenefluoride-hexafluoropropylene) is further integrated into the porous substrate for fabricating novel PS gel cathode. The as-prepared composite matrix possesses strong PS adsorption/loading ability by gelation as well as favorable electron/ion transport pathway, which not only provides effective restriction toward PS migration and shuttle, but also actualizes rapid redox conversion of the localized active species. Consequently, the resultant PS gel cathode demonstrates high reversible capacity, and excellent cycle and rate capability even at a high sulfur loading up to 9.0 mg cm<sup>−2</sup>.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 5","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143939296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shin Wook Kang, Hack-Keun Lee, Je Man Park, Jongkyu Kang, Kyung Hee Oh, Ji Chan Park, Su Ha, Jung-Il Yang, Oscar Marin-Flores
{"title":"Synergistic Effect of a Ni/Al2O3+YSZ Nanocomposite for the Steam Reforming of Biogas in the Presence of Electric Fields","authors":"Shin Wook Kang, Hack-Keun Lee, Je Man Park, Jongkyu Kang, Kyung Hee Oh, Ji Chan Park, Su Ha, Jung-Il Yang, Oscar Marin-Flores","doi":"10.1002/ente.202401074","DOIUrl":"https://doi.org/10.1002/ente.202401074","url":null,"abstract":"<p>\u0000There is an increasing interest in using biogas as a renewable energy source to produce green hydrogen via steam reforming. The high-energy consumption associated with this process has motivated the pursuit of alternative approaches to process raw biogas at lower operating temperatures and without the need for large amounts of steam to prevent catalyst deactivation. The present study discusses the results obtained for the steam reforming of raw biogas in the presence of electric fields, using a nanocomposite catalytic material prepared by physically mixing yttria-stabilized zirconia and a Ni/Al<sub>2</sub>O<sub>3</sub> catalyst. The experiments are conducted using a parallel plate capacitor reactor operated at 700 °C and 1 atm. The results indicate that by applying an external electric field (EEF) with a DC voltage of 1.9 kV and a current of 9 mA, a substantial increase in the rates of reaction can be attained. The conversions obtained for CH<sub>4</sub> and CO<sub>2</sub> are higher than the equilibrium values calculated in the absence of an EEF by 23% and 17%, respectively. This shift in the equilibrium is attributed to internal electric fields (IEFs) resulting from the interaction between YSZ and Ni/Al<sub>2</sub>O<sub>3</sub>, which leads to the creation of an interfacial nanopore structure that could increase the local IEF strength.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 4","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ente.202401074","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143793845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis and Characterization of Erythritol-Based Nanoencapsulated Phase-Change Materials for High-Temperature Latent Functional Thermal Fluid","authors":"Yingbiao Yuan, Jun Li, Piao Wang, Liyuan Zhang, Haidong Ju, Renjie Chen","doi":"10.1002/ente.202401370","DOIUrl":"https://doi.org/10.1002/ente.202401370","url":null,"abstract":"<p>Erythritol-based nanocapsules with a phase-change temperature of 120 °C are successfully prepared under very mild conditions. The nanocapsules are produced via multiple crystallization precipitations from a saturated erythritol aqueous solution, followed by SiO<sub>2</sub> coating using a sol–gel method. Their nanostructure and elemental composition are characterized using scanning electron microscopy and energy-dispersive X-ray spectroscopy. The latent heat of the nanocapsules is measured with a differential scanning calorimeter. The erythritol nanocapsules, with an average size of ≈220 nm, exhibit a melting enthalpy of 192.7 J g<sup>−1</sup>. Notably, the supercooling degree of the nanocapsules is reduced by ≈30.0 °C compared to pure erythritol. After 200 thermal cycles, the heat storage performance of the nanocapsules shows only a 7.6% decrease. A latent heat functional thermal fluid, suitable for high-temperature heat transfer, is prepared by dispersing the nanocapsules in silicone oil. The thermal conductivity and specific heat capacity of this fluid increase by 20.5% and 283.3%, respectively, compared to pure silicone oil. These findings demonstrate that erythritol nanocapsules significantly enhance the thermal properties of high-temperature heat transfer fluids, highlighting their potential for high-temperature heat storage and transfer application.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 5","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143938923","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Satyanarayana Reddy Battula, Prasanta Kumar Das, Ramkrishna Sen
{"title":"Scope of Utilizing Carotenoids for Enhanced Performance in Biohybrid Perovskite Solar Cells: A Computational Study","authors":"Satyanarayana Reddy Battula, Prasanta Kumar Das, Ramkrishna Sen","doi":"10.1002/ente.202401829","DOIUrl":"https://doi.org/10.1002/ente.202401829","url":null,"abstract":"<p>Natural photosynthesis, driven by molecular machines that have continuously evolved over a long period, is the best-known efficient process of harvesting sunlight. Photosynthetic pigments in plants, algae, and cyanobacteria have remarkably higher quantum efficiencies than corresponding synthetic and semisynthetic materials used in photovoltaic cells. The antioxidative and intrinsic properties of natural pigments like carotenoids make them suitable for new-generation sustainable energy and green electronics applications. In this computational study, an attempt has been made to understand the scope of carotenoids as an additive to the active layer and/or eco-friendly alternatives to the hole transport materials (HTM) like Spiro-MeOTAD in preparing perovskite solar cells. Accordingly, quantum and moleculer mechanical simulations are done to evaluate and compare the optoelectronic parameters of some easily available carotenoids vis-à-vis some noncarotenoids like betacyanin, xylindein, and Spiro-MeOTAD. HOMO–LUMO energy levels of carotenoids aligned well with those of perovskite. In addition, their light absorption spectra are also found to be complementary, and hence, the carotenoids can exhibit tandem behavior in absorbing visible light along with perovskite materials. Hole reorganization energies (<i>λ</i>) of some carotenoids like capsorubin, capsanthin, and violaxanthin are almost equivalent to Spiro-MeOTAD's. Calculated glass transition temperatures (<i>T</i><sub>g</sub>) of carotenoids indicate their thermophysical stability during peak summer.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 4","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143793871","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Real-Time Energy Management Strategy for Fuel Cell/Battery Plug-In Hybrid Electric Buses Based on Deep Reinforcement Learning and State of Charge Descent Curve Trajectory Control","authors":"Jing Lian, Deyao Li, Linhui Li","doi":"10.1002/ente.202401696","DOIUrl":"https://doi.org/10.1002/ente.202401696","url":null,"abstract":"<p>In order to reduce the energy consumption of fuel cell/battery plug-in hybrid electric buses and prolong the service life of fuel cell and power battery, this article proposes a multiobjective real-time energy management strategy (EMS) based on deep reinforcement learning and state of charge (SOC) descent curve trajectory control. First, the demand curve based on power is derived from the operational data collected from a bus in Dalian, and a set of SOC reference decline curves based on mileage is formulated. Second, a multiobjective cost function is constructed to consider hydrogen consumption cost, power consumption cost, fuel cell lifespan, and power battery lifespan. Finally, a comprehensive dynamic decision Q network (CDDQN) framework based on double deep Q network (DDQN) is established, a series of deep reinforcement learning EMS that integrate CDDQN with SOC trajectory control are designed, and they are validated through experimental analysis. The results demonstrate that this strategy exhibits excellent real-time performance and economic efficiency. Compared with the comparison algorithms rule algorithm, equivalent consumption minimization strategy, finite-step dynamic programming (DP), and DDQN proposed herein, the economy is increased by 15.08, 13.48, 8.81, and 3.07%, respectively, and reaches 94.00% of the economy of the ideal optimal solution DP.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 4","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143793873","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yuta Nakayasu, Hiroto Nakano, Masaki Umetsu, Koji Yokoyama, Hideyuki Takahashi, Chika Tada
{"title":"Methanogen Biocathode Microbial Fuel Cell System That Simultaneously Achieves Cattle-Barn Wastewater Treatment and Carbon Dioxide Utilization","authors":"Yuta Nakayasu, Hiroto Nakano, Masaki Umetsu, Koji Yokoyama, Hideyuki Takahashi, Chika Tada","doi":"10.1002/ente.202401558","DOIUrl":"https://doi.org/10.1002/ente.202401558","url":null,"abstract":"<p>Microbial fuel cells (MFCs) present a promising alternative to traditional activated sludge treatment for livestock wastewater, offering a carbon-neutral, sustainable approach to wastewater management. Activated sludge treatment requires significant energy input for aeration and produces unpleasant odors. MFCs eliminate the need for energy-intensive aeration, simultaneously generating energy during wastewater treatment. Platinum-based electrodes commonly used in the cathode of MFCs pose a significant cost barrier, necessitating advancements in electrode materials for practical, large-scale application. This study reports on the performance of a continuous methanogen biocathode MFC system engineered to simultaneously treat cattle-barn wastewater and utilize carbon dioxide without 2-bromoethanesulfonic acid (BES). Carbon felt treated with nitric acid without BES successfully reduces methane production by 93%. An MFC configuration utilizing nitric acid-treated carbon felt as the anode and an oak-derived carbon electrode as the cathode effectively treat wastewater and convert CO<sub>2</sub> to methane, yielding a power density of 5.5 mW m<sup>−2</sup> and Coulombic efficiency of 7.3%, approximately twice those without nitric acid treatment and surpassing even the performance of the system with BES treatment. This system represents a promising, low-cost, and environmentally sustainable approach to renewable energy production and livestock wastewater treatment.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 4","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ente.202401558","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143793872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Anique Ahmed, Muhammad Ramzan Abdul Karim, Muhammad Usman
{"title":"Synthesis-Driven Enhancement in Energy Storage Performance of Copper Transition Metal Phosphates for Hybrid Battery-Supercapacitor Systems","authors":"Anique Ahmed, Muhammad Ramzan Abdul Karim, Muhammad Usman","doi":"10.1002/ente.202401761","DOIUrl":"https://doi.org/10.1002/ente.202401761","url":null,"abstract":"<p>The tremendous advancements in science and technology have resulted in the invention of electronic devices that require greater energy storage capabilities. Hybrid supercapacitors (SCs) gain promising interest due to their exceptional electrochemical performance similar to batteries (high-energy density) and SCs (high-power density). The excellent performance of the electrode material is significantly influenced by the employed synthesis route. The copper phosphate (Cu<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub>) nanomaterials are synthesized using hydrothermal and sonochemical techniques. Two- and three-electrode configurations are utilized to evaluate the electrochemical performance of the as-prepared nanomaterials. An incredible specific capacity of 443.86 C g<sup>−1</sup> at 1.4 A g<sup>−1</sup> is achieved through sonochemically obtained nanomaterial (S2). In two-electrode configuration, S2 is used as a positive electrode material to fabricate an asymmetric device, which provides an energy density of 51.2 Wh kg<sup>−1</sup> and power density of 6800 W kg<sup>−1</sup> at 0.9 and 8.0 A g<sup>−1</sup>, respectively. The device also demonstrates an exceptional capacity retention of 93.45% after 1000 galvanostatic charge–discharge cycles at 5 A g<sup>−1</sup>. Overall, the outcomes suggest that the sonochemical method is the most effective approach for the preparation of nanomaterials for next-generation energy storage applications.</p>","PeriodicalId":11573,"journal":{"name":"Energy technology","volume":"13 4","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143793421","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}