ACS Central Science最新文献_第2页

Materials Science and Environmental Applicability 材料科学与环境适用性

IF 10.8 1区化学

ACS Central Science Pub Date : 2024-11-12 DOI: 10.1021/acs.est.4c1125710.1021/acs.est.4c11257

Peng Wang*, Jiang Xu, Wenbin Wang, Tanju Karanfil, Michael S. Wong, Virender K. Sharma and Rajnish Kumar,

引用次数: 0

Multimaterial Thermoset Synthesis: Switching Polymerization Mechanism with Light Dosage.

IF 12.7 1区化学

ACS Central Science Pub Date : 2024-11-12 eCollection Date: 2024-11-27 DOI: 10.1021/acscentsci.4c01507

Yuting Ma, Reagan J Dreiling, Elizabeth A Recker, Ji-Won Kim, Shelby L Shankel, Jenny Hu, Alexandra D Easley, Zachariah A Page, Tristan H Lambert, Brett P Fors

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引用次数: 0

Multimaterial Thermoset Synthesis: Switching Polymerization Mechanism with Light Dosage 多材料热固性合成：用光剂量切换聚合机制

IF 12.7 1区化学

ACS Central Science Pub Date : 2024-11-12 DOI: 10.1021/acscentsci.4c0150710.1021/acscentsci.4c01507

Yuting Ma, Reagan J. Dreiling, Elizabeth A. Recker, Ji-Won Kim, Shelby L. Shankel, Jenny Hu, Alexandra D. Easley, Zachariah A. Page*, Tristan H. Lambert* and Brett P. Fors*,

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引用次数: 0

Structural Gating Enhances Long-Distance Light-Driven Interfacial Electron Transfer 结构门控可增强长距离光驱动的界面电子转移

IF 12.7 1区化学

ACS Central Science Pub Date : 2024-11-11 DOI: 10.1021/acscentsci.4c0110610.1021/acscentsci.4c01106

Quentin R. Loague, Marzieh Heidari, Hayden J. Mann, Evgeny O. Danilov, Felix N. Castellano, Elena Galoppini* and Gerald J. Meyer*,

{"title":"Structural Gating Enhances Long-Distance Light-Driven Interfacial Electron Transfer","authors":"Quentin R. Loague, Marzieh Heidari, Hayden J. Mann, Evgeny O. Danilov, Felix N. Castellano, Elena Galoppini* and Gerald J. Meyer*, ","doi":"10.1021/acscentsci.4c0110610.1021/acscentsci.4c01106","DOIUrl":"https://doi.org/10.1021/acscentsci.4c01106https://doi.org/10.1021/acscentsci.4c01106","url":null,"abstract":"Structural gating provides a molecular means to transfer electrons preferentially in one desired vectorial direction, a behavior needed for applications in artificial photosynthesis. At the interfaces utilized herein, visible-light absorption by a transition metal complex opens a “structural gate” by planarization of otherwise rotating phenyl rings in p-phenylene ethynylene (PE) bridge units. Planarization provides a conjugated pathway for electron flow toward a conductive oxide surface. Interfacial electron transfer to the oxide restores rotation and closes the gate to the unwanted recombination reaction. This structural gating results in nearly quantitative long-distance (>20 Å) interfacial electron transfer that occurs ∼1000 times faster than transfer in the opposite direction. A comparative kinetic study of these complexes with those that contain ionic bridge units, without gating function, as a function of the applied potential and hence −ΔG° provided a physical basis for the structural gating. A small distance-dependent reorganization energy with weak electronic coupling underlies the success of this gate that enables efficient long-distance electron transfer and slow recombination.A light-triggered structural gate provides a conjugated pathway for efficient long-distance vectorial electron transfer to a conductive oxide and inhibits transfer from the oxide.","PeriodicalId":10,"journal":{"name":"ACS Central Science","volume":"10 11","pages":"2132–2144 2132–2144"},"PeriodicalIF":12.7,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acscentsci.4c01106","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142713521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Structural Gating Enhances Long-Distance Light-Driven Interfacial Electron Transfer.

IF 12.7 1区化学

ACS Central Science Pub Date : 2024-11-11 eCollection Date: 2024-11-27 DOI: 10.1021/acscentsci.4c01106

Quentin R Loague, Marzieh Heidari, Hayden J Mann, Evgeny O Danilov, Felix N Castellano, Elena Galoppini, Gerald J Meyer

{"title":"Structural Gating Enhances Long-Distance Light-Driven Interfacial Electron Transfer.","authors":"Quentin R Loague, Marzieh Heidari, Hayden J Mann, Evgeny O Danilov, Felix N Castellano, Elena Galoppini, Gerald J Meyer","doi":"10.1021/acscentsci.4c01106","DOIUrl":"10.1021/acscentsci.4c01106","url":null,"abstract":"Structural gating provides a molecular means to transfer electrons preferentially in one desired vectorial direction, a behavior needed for applications in artificial photosynthesis. At the interfaces utilized herein, visible-light absorption by a transition metal complex opens a \"structural gate\" by planarization of otherwise rotating phenyl rings in p-phenylene ethynylene (PE) bridge units. Planarization provides a conjugated pathway for electron flow toward a conductive oxide surface. Interfacial electron transfer to the oxide restores rotation and closes the gate to the unwanted recombination reaction. This structural gating results in nearly quantitative long-distance (>20 Å) interfacial electron transfer that occurs ∼1000 times faster than transfer in the opposite direction. A comparative kinetic study of these complexes with those that contain ionic bridge units, without gating function, as a function of the applied potential and hence -ΔG° provided a physical basis for the structural gating. A small distance-dependent reorganization energy with weak electronic coupling underlies the success of this gate that enables efficient long-distance electron transfer and slow recombination.","PeriodicalId":10,"journal":{"name":"ACS Central Science","volume":"10 11","pages":"2132-2144"},"PeriodicalIF":12.7,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11613339/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142778867","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ecofriendly, Highly Selective Lithium Extraction by Redox-Mediated Electrodialysis.

IF 12.7 1区化学

ACS Central Science Pub Date : 2024-11-09 eCollection Date: 2024-11-27 DOI: 10.1021/acscentsci.4c01373

Rongxuan Xie, Danyi Sun, Jinyao Tang, Xiaochen Shen, Parsa Pishva, Yanlin Zhu, Kevin Huang, Zhenmeng Peng

引用次数: 0

Ecofriendly, Highly Selective Lithium Extraction by Redox-Mediated Electrodialysis 利用氧化还原电渗析技术进行生态友好型高选择性锂萃取

IF 12.7 1区化学

ACS Central Science Pub Date : 2024-11-09 DOI: 10.1021/acscentsci.4c0137310.1021/acscentsci.4c01373

Rongxuan Xie, Danyi Sun, Jinyao Tang, Xiaochen Shen, Parsa Pishva, Yanlin Zhu, Kevin Huang* and Zhenmeng Peng*,

{"title":"Ecofriendly, Highly Selective Lithium Extraction by Redox-Mediated Electrodialysis","authors":"Rongxuan Xie, Danyi Sun, Jinyao Tang, Xiaochen Shen, Parsa Pishva, Yanlin Zhu, Kevin Huang* and Zhenmeng Peng*, ","doi":"10.1021/acscentsci.4c0137310.1021/acscentsci.4c01373","DOIUrl":"https://doi.org/10.1021/acscentsci.4c01373https://doi.org/10.1021/acscentsci.4c01373","url":null,"abstract":"The rapid proliferation of lithium battery applications has underscored the critical role of lithium supply in the transition to industrial electrification. Existing lithium production methods encounter significant challenges in efficiency, scalability, environmental impact, and cost. The integration of redox-mediated electrodialysis with a dense ceramic Li6/16Sr7/16Ta3/4Hf1/4O3 perovskite membrane, distinguished by its unique lattice structure allowing only lithium-ion exchange and transport, enables efficient, highly lithium-selective extraction directly from a diversity of resources including seawater and various brines. This approach offers continuous operation capability, can utilize renewable power, and has notable advantages, including chemical-free operation and little waste generation. Overall, this innovative solution presents a one-step, ecofriendly, highly selective lithium extraction method.The one-step redox-mediated electrodialysis (rm-ED) strategy for direct lithium extraction from brines with LSTH membrane is employed for high selectivity powered by solar panels.","PeriodicalId":10,"journal":{"name":"ACS Central Science","volume":"10 11","pages":"2119–2124 2119–2124"},"PeriodicalIF":12.7,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acscentsci.4c01373","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142719388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Stimuli-Responsive Polymers Prevent Severe Hypoglycemia.

IF 12.7 1区化学

ACS Central Science Pub Date : 2024-11-07 eCollection Date: 2024-11-27 DOI: 10.1021/acscentsci.4c01834

Kaden C Stevens, Brent S Sumerlin

引用次数: 0

Stimuli-Responsive Polymers Prevent Severe Hypoglycemia 刺激响应聚合物可预防严重低血糖症

IF 12.7 1区化学

ACS Central Science Pub Date : 2024-11-07 DOI: 10.1021/acscentsci.4c0183410.1021/acscentsci.4c01834

Kaden C. Stevens, and , Brent S. Sumerlin*,

引用次数: 0

The Fight Against Frostbite Progresses 抗击冻伤的斗争取得进展