Composites Communications最新文献

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Uniform carbon nanotube growth on carbon felt preforms: Enhancing mechanical and electromagnetic shielding properties of C/SiC composites 在碳毡预制件上均匀生长碳纳米管:增强碳/碳化硅复合材料的机械和电磁屏蔽性能
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-04-08 DOI: 10.1016/j.coco.2025.102403
Jiaxiang Cai , DengHao Ma , Yuqing Peng , Zhiwei Li , Miao Miao , Bingbing Fan , Xin Feng , Aijun Li
{"title":"Uniform carbon nanotube growth on carbon felt preforms: Enhancing mechanical and electromagnetic shielding properties of C/SiC composites","authors":"Jiaxiang Cai ,&nbsp;DengHao Ma ,&nbsp;Yuqing Peng ,&nbsp;Zhiwei Li ,&nbsp;Miao Miao ,&nbsp;Bingbing Fan ,&nbsp;Xin Feng ,&nbsp;Aijun Li","doi":"10.1016/j.coco.2025.102403","DOIUrl":"10.1016/j.coco.2025.102403","url":null,"abstract":"<div><div>Carbon fiber-reinforced silicon carbide composites (C/SiC) face challenges in achieving concurrent structural and electromagnetic interference (EMI) shielding enhancements while maintaining excellent mechanical properties and thermal stability. This investigation introduces a meticulously designed catalytic chemical vapor deposition (CCVD) approach to enable the in situ growth of carbon nanotubes (CNTs) on carbon fiber preforms. By methodically fine-tuning the process parameters, we achieved precise control over the CNTs’ morphology, density, and spatial distribution. The CNT-modified C/SiC composites demonstrated remarkable multifunctional performance: the bridging effect of CNTs enhanced flexural strength to 122.64 ± 11.65 MPa and fracture toughness to 14.05 ± 2.32 MPa m<sup>1/2</sup>. Simultaneously, EMI shielding effectiveness in the X-band reached 38.14 dB, attributed to synergistic effects including three-dimensional conductive network formation, heterogeneous interface effects, and the high specific surface area of CNTs. This work establishes a novel methodology for developing tailor-made ceramic matrix composites with structure-property coordination, showing significant potential for aerospace applications that require integrated electromagnetic protection and mechanical robustness.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"56 ","pages":"Article 102403"},"PeriodicalIF":6.5,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143828517","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A study of the penetration behavior of bio-inspired CFRP composite laminates with intralaminar and interlaminar hard-and-soft structures 具有层内和层间软硬结构的仿生CFRP复合材料层压板的渗透行为研究
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-04-08 DOI: 10.1016/j.coco.2025.102405
Xiaoyu Zhang , Guojun Zhao , T.X. Yu , Xin Zhang
{"title":"A study of the penetration behavior of bio-inspired CFRP composite laminates with intralaminar and interlaminar hard-and-soft structures","authors":"Xiaoyu Zhang ,&nbsp;Guojun Zhao ,&nbsp;T.X. Yu ,&nbsp;Xin Zhang","doi":"10.1016/j.coco.2025.102405","DOIUrl":"10.1016/j.coco.2025.102405","url":null,"abstract":"<div><div>Novel and cost-effective bio-inspired composite laminates, including hard and soft structures, were designed to improve impact resistance. The regular hexagonal TPU frames and TPU film interleaves were inserted into carbon fabrics and interface as intralaminar and interlaminar soft phases. The impact response and material damage influenced by intralaminar and interlaminar TPU were investigated separately through low-velocity impact. Experimental results show penetration energy for the laminates with TPU soft phase was significantly enhanced, with the value of 5 J, 12.5 J, and 10 J for type A, B, and C, respectively, in which the type B with TPU films inserted between layers has the maximum increase percentage by 38 %. Thus, TPU interleaves can improve penetration energy more effectively than the intralaminar TPU phase. Failure is divided into three categories including no penetration, tough penetration, and brittle penetration, as characterized by different failure modes. Interestingly, the laminates with TPU phase displayed tough penetration while baselines without TPU can only present brittle penetration with even more fabrics included. Permanent deformation was observed for specimens with TPU phase after penetration instead of obvious delamination and fiber bundle breakage appeared in baselines. In general, hard and soft strategies with TPU phase can prevent sudden catastrophic failure under high-energy impact. This study demonstrates the important influence of soft phase, provides cost-effective strategies of improving impact resistance for composite laminates, and acquires a deeper understanding of penetration failure modes and mechanisms.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"56 ","pages":"Article 102405"},"PeriodicalIF":6.5,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143823342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation on the synergistic effect mechanism of hydroxyl-terminated PES/Nano-SiO2 on the mechanical properties of epoxy resin at ultra-low temperatures 端羟基PES/纳米sio2对环氧树脂超低温力学性能协同作用机理的研究
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-04-08 DOI: 10.1016/j.coco.2025.102401
Jinghua Wang , Zhishen Yin , Jie Sun , Yeqing Liu , Ruoxi Fan , Jialiang Li , Duo Chen , Jia Yan , Shichao Li , Zhanjun Wu
{"title":"Investigation on the synergistic effect mechanism of hydroxyl-terminated PES/Nano-SiO2 on the mechanical properties of epoxy resin at ultra-low temperatures","authors":"Jinghua Wang ,&nbsp;Zhishen Yin ,&nbsp;Jie Sun ,&nbsp;Yeqing Liu ,&nbsp;Ruoxi Fan ,&nbsp;Jialiang Li ,&nbsp;Duo Chen ,&nbsp;Jia Yan ,&nbsp;Shichao Li ,&nbsp;Zhanjun Wu","doi":"10.1016/j.coco.2025.102401","DOIUrl":"10.1016/j.coco.2025.102401","url":null,"abstract":"<div><div>The mechanical properties of resin matrixes are predominant factors influencing the overall performance of fiber-reinforced composites. In this study, the high brittleness and low toughness of epoxy resin (EP) are addressed by incorporating hydroxyl-terminated polyether-sulfone (PES-OH) and nano-silica (Nano-SiO<sub>2</sub>) into the EP. The incorporation of PES-OH into EP led to a 22.6 % increase in tensile strength and a 27.8 % improvement in elongation at break at ultra-low temperatures. These enhancements are attributed to the formation of a semi-interpenetrating polymer network (SIPN) during the curing process, which strengthens the molecular network of the epoxy resin matrix through physical entanglement, interfacial reinforcement, and stress dispersion, enhancing crack resistance. The simultaneous introduction of PES-OH and Nano-SiO<sub>2</sub> synergistically improves the mechanical properties of EP at ultra-low temperatures (90 K). Specifically, the tensile strength, elongation at break, and modulus of elasticity of the modified EP were increased by 30.63 %, 19.6 %, 20.9 % and a 65.61 % improvement in fracture toughness (K<sub>IC</sub>), respectively, compared to the pure EP. The synergistic effect arises from the covalent bonding between the hydroxyl groups on Nano-SiO<sub>2</sub> and those in PES-OH and EP, thereby toughening and strengthening the epoxy molecular structure. Additionally, microdroplet debonding tests of carbon fiber with EP showed a 25.22 % increase in interfacial shear strength after introducing PES-OH and Nano-SiO<sub>2</sub>. Dynamic thermo-mechanical analysis confirmed that the incorporation of PES-OH and Nano-SiO<sub>2</sub> does not compromise the thermal stability of EP.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"56 ","pages":"Article 102401"},"PeriodicalIF":6.5,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143817499","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Composition-structure coupling reinforcement to engineer stretchable and conductive composite nanofibrous helix with fully wrapped structure for green fiber electronics 复合-结构耦合增强,为绿色光纤电子制造可拉伸、导电、全缠绕结构的复合纳米纤维螺旋
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-04-08 DOI: 10.1016/j.coco.2025.102404
Zuxian Zhang , Rongman Gao , Yutao Lu , Guanhua Zhang , Jie Xiong , Yong Zhao , Fengyun Guo
{"title":"Composition-structure coupling reinforcement to engineer stretchable and conductive composite nanofibrous helix with fully wrapped structure for green fiber electronics","authors":"Zuxian Zhang ,&nbsp;Rongman Gao ,&nbsp;Yutao Lu ,&nbsp;Guanhua Zhang ,&nbsp;Jie Xiong ,&nbsp;Yong Zhao ,&nbsp;Fengyun Guo","doi":"10.1016/j.coco.2025.102404","DOIUrl":"10.1016/j.coco.2025.102404","url":null,"abstract":"<div><div>Emerging fiber electronics have shown great potential in various fields owing to their integration of unique fiber components and advanced electronics. With the increasing environmental pollution caused by electronic waste, the demand for green electronic is increasing. Meanwhile, how to balance and improve the stable conductivity and stretchability simultaneously remains challenging due to the intrinsic counteraction. Herein, based on composition-structure coupling reinforcement strategy, a super-stretchable, highly conductive and green composite nanofibrous helix was prepared by conjugate electrospinning and one-step twisting. Through the blend of ductile composition, the mechanical properties are improved without sacrificing green properties. By designing a fully wrapped helical structure, the conductivity and stretchability are improved simultaneously enabling it works well without failure especially at large strains. As we demonstrated, compared with SF and membrane, the composite nanofibrous helix show great advantages in green fiber electronic devices, such as stretchable conductor for light-controlled safety protection switch and stable sensor for human motion monitoring.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"56 ","pages":"Article 102404"},"PeriodicalIF":6.5,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143821076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CoFe-PBA decorated P-N flame retardant for catalytic carbonization, smoke suppression, toxicity reduction and antimicrobial properties of TPU 咖啡- pba修饰P-N阻燃剂用于TPU的催化碳化、抑烟、降毒和抗菌性能
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-04-07 DOI: 10.1016/j.coco.2025.102393
Gaoyuan Li , Biyu Huang , Haopeng Zhang , Jirui Qu , Yiwei Geng , Lei Liu , Xilei Chen , Chuanmei Jiao , Xiaolong Zhao
{"title":"CoFe-PBA decorated P-N flame retardant for catalytic carbonization, smoke suppression, toxicity reduction and antimicrobial properties of TPU","authors":"Gaoyuan Li ,&nbsp;Biyu Huang ,&nbsp;Haopeng Zhang ,&nbsp;Jirui Qu ,&nbsp;Yiwei Geng ,&nbsp;Lei Liu ,&nbsp;Xilei Chen ,&nbsp;Chuanmei Jiao ,&nbsp;Xiaolong Zhao","doi":"10.1016/j.coco.2025.102393","DOIUrl":"10.1016/j.coco.2025.102393","url":null,"abstract":"<div><div>Thermoplastic polyurethane (TPU), as a typical thermoplastic elastomer, is highly flammable, posing significant safety challenges. Phosphorus-nitrogen flame retardants (P-N FRs) are commonly employed to reduce the fire hazard of TPU but limited by low flame retardant efficiency and production of toxic gases during combustion. In this study, a novel multifunctional flame retardant (P-N@CoFe-PBA) was synthesized by decorating cobalt-iron Prussian blue analogue (CoFe-PBA) onto the surface of a P-N FR. The results showed that P-N@CoFe-PBA significantly improves the flame retardancy, smoke suppression, toxicity reduction, and antimicrobial properties of TPU composites. For TPU-6 %P-N@CoFe-PBA, the peak heat release rate (pHRR) and total smoke production (TSP) values were reduced by 59.2 % and 51.9 % compared with pure TPU, respectively. Meanwhile, the total CO production (TCOP) and total CO<sub>2</sub> production (TCO<sub>2</sub>P) values were reduced by 43.9 % and 51.7 %, respectively. The improvement in flame retardant performance of TPU-6 %P-N@CoFe-PBA is due to the catalytic carbonization ability of P-N@CoFe-PBA, which promotes TPU composites to form an excellent char residue layer structure, providing effective thermal insulation and preventing mass transfer. Furthermore, P-N@CoFe-PBA suppresses the generation of toxic gases and flammable volatiles during combustion and imparts antimicrobial properties to TPU. This work is significant for the preparation of multifunctional flame retardant TPU composites and expanding the application fields of TPU.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"56 ","pages":"Article 102393"},"PeriodicalIF":6.5,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143790894","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel insights into the morphological effects of micron-scale inorganic fillers on polyethylene composites 微米尺度无机填料对聚乙烯复合材料形态影响的新见解
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-04-07 DOI: 10.1016/j.coco.2025.102394
Erika Varga, László Tóth, Balázs Ádám, Ferenc Tajti, Pál Hansághy
{"title":"Novel insights into the morphological effects of micron-scale inorganic fillers on polyethylene composites","authors":"Erika Varga,&nbsp;László Tóth,&nbsp;Balázs Ádám,&nbsp;Ferenc Tajti,&nbsp;Pál Hansághy","doi":"10.1016/j.coco.2025.102394","DOIUrl":"10.1016/j.coco.2025.102394","url":null,"abstract":"<div><div>Thermoplastic composites with inorganic fillers are increasingly studied for their tunable physical properties, yet fundamental insights into chemically unmodified matrix-filler interfaces at micron scales remain limited. This research examines the effect of filler morphology on polyethylene with varying branching degrees through incorporation of natural mica and calcium carbonate in the micrometer range.</div><div>Uniform dispersion and orientation of fillers were validated through SEM and DMA, while thermal, mechanical, and thermomechanical properties were analyzed using DSC, DMA, tensile testing, and Charpy impact tests. The results showed reduced crystallinity and impact strength, irrespective of filler morphology, while elastic modulus increased with higher filler aspect ratios. Matrix properties influenced composite strength, and DMA demonstrated increased energy dissipation driven by filler aspect ratio.</div><div>Mathematical models for predicting elastic modulus and tensile strength were also evaluated. This study provides key insights into the interplay of filler morphology, matrix structure, and composite performance in thermoplastic systems.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"56 ","pages":"Article 102394"},"PeriodicalIF":6.5,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143807369","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
One-step fabrication of mechanically robust and fluorine-free nanofiber membranes for waterproofness and breathability 一步制造机械坚固和无氟纳米纤维膜防水和透气性
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-04-06 DOI: 10.1016/j.coco.2025.102396
Ni Yao , Fei Wang , Shichao Zhang , Jianyong Yu , Bin Ding
{"title":"One-step fabrication of mechanically robust and fluorine-free nanofiber membranes for waterproofness and breathability","authors":"Ni Yao ,&nbsp;Fei Wang ,&nbsp;Shichao Zhang ,&nbsp;Jianyong Yu ,&nbsp;Bin Ding","doi":"10.1016/j.coco.2025.102396","DOIUrl":"10.1016/j.coco.2025.102396","url":null,"abstract":"<div><div>Waterproof and breathable membranes (WBMs) find widespread uses in various fields, such as garments, buildings, medical supplies, and electronic devices. Yet, the addition of fluorinated materials and complex post-treatment processes often restricts their practical use. Here, we report an in-situ inter fiber bonding structured fluorine-free polyurethane/poly(styrene-butadiene-styrene)/polydimethylsiloxane (PU/SBS/PDMS) nanofiber membrane with robust mechanical properties using a one-step electrospinning technique. The incorporation of PU significantly enhanced the spinnability and mechanical properties of SBS, while the in-situ introduction of PDMS provided the necessary waterproofness and improved inter fiber bonding. The resulting membrane exhibited satisfactory waterproofness, with a hydrostatic pressure of 58.95 kPa, and moisture permeability of 4.38 kg m<sup>-2</sup> d<sup>-1</sup> (upright cup method). Additionally, it also exhibited excellent mechanical properties with a tensile strain of 352.5%, breaking stress of 10.04 MPa, and impressive toughness of 19.94 MJ m<sup>-3</sup>. These intriguing attributes make it an ideal choice for wearable and textiles, particularly those products requiring high durability and comfortability. The successful fabrication of mechanically robust membranes opens a new avenue for developing eco-friendly and high-performance functional textiles.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"56 ","pages":"Article 102396"},"PeriodicalIF":6.5,"publicationDate":"2025-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143800051","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on FDM preparation and properties of carbon black/ nickel/ polylactic acid/ thermoplastic polyurethane electromagnetic wave absorbing composites 碳黑/镍/聚乳酸/热塑性聚氨酯电磁波吸波复合材料FDM制备及性能研究
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-04-06 DOI: 10.1016/j.coco.2025.102384
Fangxin Zhang , Shaokang Liu , Bin Chao , Shixiong Deng , Yanming Zhou , Haihua Wu , Qingshan Wang
{"title":"Study on FDM preparation and properties of carbon black/ nickel/ polylactic acid/ thermoplastic polyurethane electromagnetic wave absorbing composites","authors":"Fangxin Zhang ,&nbsp;Shaokang Liu ,&nbsp;Bin Chao ,&nbsp;Shixiong Deng ,&nbsp;Yanming Zhou ,&nbsp;Haihua Wu ,&nbsp;Qingshan Wang","doi":"10.1016/j.coco.2025.102384","DOIUrl":"10.1016/j.coco.2025.102384","url":null,"abstract":"<div><div>Developing microwave-absorbing materials characterized by \"broadband, lightweight, thin thickness, and strength\" poses a formidable challenge within the realm of electromagnetic wave absorption. The optimal absorbent should exhibit exemplary dielectric and magnetic loss characteristics. This study utilized polylactic acid (PLA) and thermoplastic polyurethane (TPU) as the matrix and carbon black (CB) and nickel (Ni) as the absorbers, employing Fused Deposition Modelling (FDM) technology to fabricate CB/Ni/PLA/TPU composite electromagnetic wave absorbing materials. When the CB content is 5 %, the strongest absorption reaches −34.14 dB (2 mm), and it exhibits an effective absorption bandwidth spanning 5.92 GHz (12.08–18 GHz). Concurrently, the corresponding material exhibited certain mechanical properties, including flexural strength, compressive strength, and tensile strength reaching 6.38 MPa, 27.48 MPa, and 18.26 MPa, respectively. Additionally, the tensile elongation at break was 5.1 %. The electromagnetic wave absorption mechanism reveals that the outstanding absorbing property is mainly due to the synergy of carbon/magnetic materials. This is mainly contributed to by the following aspects: conduction losses induced by CB, polarization losses due to internal defects in the material, interface polarization and multiple reflections of electromagnetic waves resulting from the numerous interfaces, magnetic losses generated by Ni, and more importantly, the excellent impedance matching achieved by the carbon/magnetic synergy. The work has developed carbon/magnetic composite materials that exhibit outstanding absorption performance and possess certain mechanical capabilities, enabling the development of effective electromagnetic wave absorber architectures.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"56 ","pages":"Article 102384"},"PeriodicalIF":6.5,"publicationDate":"2025-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143783056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
3D printing of continuous carbon fibre reinforced high-temperature epoxy composites 连续碳纤维增强高温环氧复合材料的3D打印
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-04-05 DOI: 10.1016/j.coco.2025.102397
Yahui Lyu, Aonan Li, Jiang Wu, Dongmin Yang
{"title":"3D printing of continuous carbon fibre reinforced high-temperature epoxy composites","authors":"Yahui Lyu,&nbsp;Aonan Li,&nbsp;Jiang Wu,&nbsp;Dongmin Yang","doi":"10.1016/j.coco.2025.102397","DOIUrl":"10.1016/j.coco.2025.102397","url":null,"abstract":"<div><div>This study presents a novel high-temperature solid epoxy system and investigates its use for 3D printing of continuous carbon fibre reinforced thermoset composites. The solid epoxy system was formulated using a mixture of novolak epoxy resin and amine hardener. It was deposited on the continuous carbon fibres to produce impregnated filament, which was then used for fused filament fabrication (FFF) based 3D printing, followed by a curing process. The resulting printed composite exhibited a high glass transition temperature (<em>T</em><sub><em>g</em></sub>) of 279.24 °C, along with a longitudinal tensile strength of 1006 MPa and a flexural strength of 431.8 MPa, making it suitable for high-temperature load-bearing applications. Additionally, a lightweight honeycomb composite structure was printed and cured in a 3D printed bespoke mould made from a high-temperature thermoplastic composite material. The final cured part demonstrated excellent thermal stability under isothermal loading at 200 °C, showcasing the potential of this system for advanced structural applications in aerospace and related fields.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"56 ","pages":"Article 102397"},"PeriodicalIF":6.5,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143807368","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Zinc oxide whisker-loaded antibacterial 3D-printed polylactic acid based composite bone scaffolds with enhanced biological and mechanical performance 负载氧化锌晶须的抗菌3d打印聚乳酸复合骨支架,具有增强的生物和机械性能
IF 6.5 2区 材料科学
Composites Communications Pub Date : 2025-04-05 DOI: 10.1016/j.coco.2025.102398
Wang Guo , Bowen Li , Sidan Feng , Chao Liu , Enyu Wang , Ping Li , Xiaotong Ye , Yanjian Huang , Bin Liu , Shan Wang , Huaming Mai , Hui You , Yu Long
{"title":"Zinc oxide whisker-loaded antibacterial 3D-printed polylactic acid based composite bone scaffolds with enhanced biological and mechanical performance","authors":"Wang Guo ,&nbsp;Bowen Li ,&nbsp;Sidan Feng ,&nbsp;Chao Liu ,&nbsp;Enyu Wang ,&nbsp;Ping Li ,&nbsp;Xiaotong Ye ,&nbsp;Yanjian Huang ,&nbsp;Bin Liu ,&nbsp;Shan Wang ,&nbsp;Huaming Mai ,&nbsp;Hui You ,&nbsp;Yu Long","doi":"10.1016/j.coco.2025.102398","DOIUrl":"10.1016/j.coco.2025.102398","url":null,"abstract":"<div><div>A bone scaffold for addressing infectious bone defects should possess not only good mechanical and biological performance but also effective antibacterial function. In this study, we developed a bone scaffold based on polylactic acid (PLA) loaded with zinc oxide (ZnO) whiskers using FDM 3D printing and systematically investigated the impact of varying loading content of ZnO on the antibacterial performance, biological performance, mechanical properties, and physicochemical properties of the composite scaffold. Antibacterial experiments using optical density and spread plate method revealed that the ZnO-loaded scaffolds exhibited high antibacterial activity both against <em>E</em>. <em>coli</em> and <em>S</em>. <em>aureus</em>, positively correlating with the content. SEM characterization revealed obvious deformation and rupture in the morphology of bacteria under the action of ZnO, which was mainly attributed to the production of ROS. Cell culture indicated the cell proliferation and osteogenic differentiation was enhanced with appropriate content of ZnO. Mechanical test results demonstrated that appropriate content of ZnO enhanced the compression strength of the composite scaffold. This study demonstrates that ZnO whiskers can be utilized as a versatile inorganic filler for simultaneously enhancing antibacterial, mechanical, and biological performance of 3D-printed polymer bone scaffolds designed for addressing infectious bone defects.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"56 ","pages":"Article 102398"},"PeriodicalIF":6.5,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143823373","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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