{"title":"Mechanistic impact of sodium nitrate on the characteristics of MWCNTS oxidation and potential application on methylene blue adsorption from wastewater","authors":"Parul Dwivedi , Ashwani Kumar Rathore , Deepak Srivastava , R.P. Vijayakumar","doi":"10.1016/j.wmb.2025.01.005","DOIUrl":"10.1016/j.wmb.2025.01.005","url":null,"abstract":"<div><div>Effect of oxidizing agents on plastic waste derived multi-walled carbon nanotubes (MWCNTs) was investigated in this study. It was investigated whether a single oxidizing agent is sufficient for the desired oxidation or if the use of multiple agents is required. Typically, the modified Hummers method employs several oxidizing agents such as H<sub>2</sub>SO<sub>4</sub>, NaNO<sub>3</sub>, H<sub>2</sub>O<sub>2</sub>, and KMnO<sub>4</sub>, contributing to increased production costs and posing challenges for scalability. The investigation focused on the presence or absence of NaNO<sub>3</sub> while altering the ratio of KMnO<sub>4</sub> and reaction time. The synthesized materials were analysed using UV–VIS spectrophotometry and FTIR. The shifted peaks of the XRD pattern were analysed for the surface modification of the MWCNTOs surfaces with the degree of oxidation. Surface morphology of the samples was obtained using FESEM and found comparable changes with the degree of oxidation. The percentage of Methylene Blue (MB) dye removal was examined using oxidized samples, and the impact of oxidation on the efficacy of dye adsorption was investigated. The results showed that maximum 79% removal occurred for lowest oxidised MWCNTs compared to others as maximum oxidation leads to agglomeration of particles. The Freundlich isotherm and pseudo 1st order reaction order models exhibited optimal compatibility with pristine MWCNTs. In contrast, Langmuir and pseudo 2nd order kinetics models demonstrated superior fitment with oxidized MWCNTs. This suggests a transition in the adsorption phenomenon from physisorption to chemisorption.</div></div>","PeriodicalId":101276,"journal":{"name":"Waste Management Bulletin","volume":"3 1","pages":"Pages 207-218"},"PeriodicalIF":0.0,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143153725","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Advancements in characterization Techniques, empirical Models, and Artificial intelligence for comprehensive understanding of heavy metal adsorption on sewage sludge biochar","authors":"Bhavana Shanmughan , Amrita Nighojkar , Balasubramanian Kandsubramanian","doi":"10.1016/j.wmb.2025.01.003","DOIUrl":"10.1016/j.wmb.2025.01.003","url":null,"abstract":"<div><div>Heavy metal-containing industrial effluents, such as Pb<sup>2+</sup>, Cd<sup>2+</sup>, and Cu<sup>2+</sup>, pose serious threats to the environment and public health since they are not biodegradable and can accumulate over time. Biochar, particularly sewage sludge-derived biochar (SSBC), has arisen as a promising and cost-effective material for heavy metal removal from wastewater due to its high adsorption capacity, large surface area, and rich porous structure. This review explores the use of SSBC for the adsorption of heavy metals, highlighting the impact of pyrolysis temperature on its surface properties, such as specific surface area and functional groups. Characterization techniques, including SEM, FTIR, XRD, XPS, AES, GC–MS, ICP, and ESR, are employed to analyze the chemical and structural properties of SSBC, providing insights into the changes that enhance its adsorption performance. Additionally, Artificial Neural Network (ANN) models are utilized to portend the adsorption efficiency of SSBC, offering a quantitative understanding of the relationship between heavy metal removal efficiency and biochar properties. This review emphasizes the importance of pyrolysis in optimizing SSBC for wastewater treatment and demonstrates how advanced characterization techniques and predictive models can guide the progress of more efficient biochar-based adsorbents for environmental remediation. The results highlight the promising role of SSBC in providing a sustainable remedy for heavy metal contamination in industrial wastewater.</div></div>","PeriodicalId":101276,"journal":{"name":"Waste Management Bulletin","volume":"3 1","pages":"Pages 193-206"},"PeriodicalIF":0.0,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143153724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Recycling waste materials in construction: Mechanical properties and predictive modeling of Waste-Derived cement substitutes","authors":"Moutaman M. Abbas","doi":"10.1016/j.wmb.2025.01.004","DOIUrl":"10.1016/j.wmb.2025.01.004","url":null,"abstract":"<div><div>Increased industrialization has resulted in a shortage of natural building materials, thus increasing awareness of sustainable approaches by construction companies. This research explains how waste materials—Ceramic Waste Powder, Waste Glass Powder, Waste Granite Dust, Waste Marble Powder, and Waste Brick Powder—can be employed as environmentally friendly cement alternatives in concrete mixtures. The objective is to study the mechanical characteristics of these supplementary cementitious materials with continuous industrial waste recycling for environmentally sustainable development. In addition to experimental findings, a neural network model was developed to predict the compressive strength of concrete containing these materials, trained on data collected from the literature. The model successfully demonstrated its ability to replicate trends in compressive strength results across varying replacement levels, validating the findings and enhancing the study’s reliability. Tests were carried out for replacement levels of cement by the materials in concrete, from 5 % to 50 %, on compressive and tensile strengths at various curing periods. The test results show that a 10–15 % replacement level is within the optimum range for most of the waste materials. It is also observed that compressive and tensile strength improvement tends to be maximum around 28 days of curing. Increases in dosage lead to a loss in mechanical properties, indicating limited viability for higher replacement percentages. The present review, supported by machine learning predictions, highlights the potential of these materials to improve sustainable practices in the building industries, toward manufacturing Supplementary Cementitious Materials (SCMs) with low environmental impact coupled with resource efficiency.</div></div>","PeriodicalId":101276,"journal":{"name":"Waste Management Bulletin","volume":"3 1","pages":"Pages 168-192"},"PeriodicalIF":0.0,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143153727","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A novel circular agriculture model with low cost, easy operation, and rapid scalability in rural areas","authors":"Huiyong Yu , Di Huang , Guoming Shen , Beitao Xie","doi":"10.1016/j.wmb.2024.12.013","DOIUrl":"10.1016/j.wmb.2024.12.013","url":null,"abstract":"<div><div>Plant Jiaosu, referred to as “enzyme” over the past decades, constitutes the fermentation liquid derived from organic plant matter through fermentation. Circular agriculture is a type of agricultural production mode characterized by efficient resource utilization and environmental friendliness. This paper introduces a novel, low-cost, and easy-to-operate circular agriculture model, known as the “fruit and vegetable waste–agricultural Jiaosu–compost–crop”. The results showed that the addition of agricultural Jiaosu during the composting process prolonged the thermophilic stage, promoted the humification degree of compost, and reduced nitrogen loss. As demonstrated in this study, using compost made from agricultural Jiaosu and organic wastes could replace the commercial organic fertilizer in traditional cultivation of grapes. This would promote the growth of grapes, improve yield, and enhance grape quality. This substitution directly and indirectly resulted in an increase of 1400 yuan per 666.7 m<sup>2</sup> of grape planting area. This circular agriculture model will ensure the rapid utilization of organic wastes in rural areas and improve the rural environment.</div></div>","PeriodicalId":101276,"journal":{"name":"Waste Management Bulletin","volume":"3 1","pages":"Pages 163-167"},"PeriodicalIF":0.0,"publicationDate":"2025-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143153720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Maria do Céu de Sena Moura , Geórgia Patrícia da Silva Ferko , Marcos Felipe Falcão Sobral , Pedro Alves da Silva Filho
{"title":"Workers’ perception of solid waste management in higher education institutions in the Amazon region of Brazil","authors":"Maria do Céu de Sena Moura , Geórgia Patrícia da Silva Ferko , Marcos Felipe Falcão Sobral , Pedro Alves da Silva Filho","doi":"10.1016/j.wmb.2025.01.002","DOIUrl":"10.1016/j.wmb.2025.01.002","url":null,"abstract":"<div><div>Higher education institutions (HEIs) offer promising opportunities to develop strategies and actions for managing Solid Waste (SW). This study aimed to analyze the perceptions of employees working at HEIs in Boa Vista, Roraima, Brazil, on how their institutions manage SW. HEIs 1 and 2 (public) and HEI 3 (private) were evaluated. The study method was qualitative and quantitative. Face-to-face interviews were conducted using a questionnaire addressing five domains of Waste Management: I − Recycling program; II − Treatment of organic waste; III − Campaign to reduce the use of paper and plastic; IV − Treatment of inorganic waste; and V − Treatment of toxic waste. A multidimensional similarity analysis was carried out between the HEIs. HEI2 showed better overall performance when compared to the other HEIs (p = 0.012). In domain I, only HEI 2 has a selective waste collection program and disposes of waste properly (score = 150, p < 0.001). None of the HEIs treat organic waste (domain II). In Domain III, only public HEIs dematerialize administrative procedures and processes. Only HEI2 and HEI3 maintained similar behavior on domain IV (score = 300). In domain V, all HEIs have outsourced companies specialized in waste collection. The multidimensional analysis showed a high similarity among the HEIs. In conclusion, the HEI 2 showed slightly better waste management practices according to the worker’s perception. However, all HEIs in Roraima still need to make progress in managing their SWs.</div></div>","PeriodicalId":101276,"journal":{"name":"Waste Management Bulletin","volume":"3 1","pages":"Pages 153-162"},"PeriodicalIF":0.0,"publicationDate":"2025-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143153719","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Non-Conventional fuels from thermocatalytic pyrolysis of waste tube rubber using SiO2 as catalyst","authors":"Riaz Muhammad , Felizitas Schlederer , Ali Riaz","doi":"10.1016/j.wmb.2025.01.001","DOIUrl":"10.1016/j.wmb.2025.01.001","url":null,"abstract":"<div><div>Large quantities of used<!--> <!-->rubber<!--> <!-->material, mostly from vehicle scrap tires and tube rubbers, are discarded every year, causing environmental problems of great concern and representing a tough challenge for waste management bodies around the world. Various ways to remediate the issues have been proposed and applied from time to time. Pyrolysis offers a promising solution to convert waste tires into potential fuels and chemicals. Thermo-catalytic pyrolysis is a well-established process that aims for material, energy or chemical product recovery. The demand and need for the use of materials like scrap tubes and rubbers for producing useful products is a valuable consideration for this kind of waste that in turn may minimize the dependency on natural resources. Inner tube rubber, which is mainly made of isobutylene-isoprene, poses a hazard to the environment. However, there is also an opportunity to turn this waste product into a valuable energy source. In the current study optimization of parameters such as temperature, time and catalyst weight for catalytic pyrolysis of isobutylene-isoprene rubber into liquid fuel in the presence of Silicon Dioxide (SiO<sub>2</sub>) as catalyst is reported. A maximum rubber conversion into oils was obtained at optimized conditions of 350 °C temperature, 1.5 g of catalyst (SiO<sub>2</sub>) for an hour heating time. The obtained pyrolyzed products were subjected to several physical and chemical tests. Reported results confirm the presence of 30 % of aliphatic hydrocarbons, 25 % polar hydrocarbons and 40 % aromatic hydrocarbons. The distillation data indicates that oil obtained is a mixture of aromatic and olefinic hydrocarbons as that of diesel and may be used as an alternative fuel.</div></div>","PeriodicalId":101276,"journal":{"name":"Waste Management Bulletin","volume":"3 1","pages":"Pages 128-136"},"PeriodicalIF":0.0,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143153728","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Tailoring sustainable materials: Investigating nanoclay effects on citric acid crosslinked waste coconut fiber reinforced modified vegetable oil composites","authors":"Jurita Baishya , Tarun K. Maji","doi":"10.1016/j.wmb.2024.12.011","DOIUrl":"10.1016/j.wmb.2024.12.011","url":null,"abstract":"<div><div>Sustainability concerns are driving industries to focus on eco-friendly substitutes for polymers and plastics. Waste fibers and bio-based materials are increasingly becoming popular as renewable options. They help lower carbon footprints and reduce reliance on fossil fuels. These materials also tackle environmental problems and support resource conservation and waste reduction. The primary objective of this endeavor is to develop green composites from coconut fiber, an abundant and underutilized byproduct of the coconut industry. This study assesses the effect of incorporating nanoclay at varying weight percentages (1, 3, and 5 wt%) on the properties of Coconut Fiber (CF) reinforced composites. The composites are fabricated using a compression molding process, with Methacrylic Anhydride modified Epoxidized Linseed Soybean Oil (MAELSO) serving as the polymer matrix, and Citric Acid (CA), a naturally derived crosslinker obtained from citrus fruits, to enhance the bonding within the material. The interaction between MAELSO, CF, CA and nanoclay was determined by Fourier Transform Infrared (FTIR) spectroscopy. X-ray Diffraction (XRD) and Transmission Electron Microscopy techniques (TEM) were employed to investigate the delamination and dispersal of silicate layers. Evaluation of surface morphology was achieved by Scanning Electron Microscopy (SEM) technique. The nanoclay-filled composites exhibited better mechanical property, higher thermal stability and flame retardant property compared to the nanoclay-free composites. Among all the nanocomposites those loaded with 1 wt% of nanoclay, exhibited the least amount of water vapor absorption capacity, volumetric swelling, and highest chemical resistance. The significance of this study lies in that the resulting composites promote sustainability by utilizing waste, renewable resources and biodegradable materials. This approach minimizes environmental impact while maintaining performance. As an eco-friendly alternative, these composites provide a viable substitute for conventional, non-biodegradable synthetic materials, supporting both environmental conservation and advanced material performance. The developed green composites demonstrate potential for construction and household applications due to their improved mechanical strength, thermal stability, and flame retardancy. Their low water absorption and improved chemical resistance make them suitable for humid environments, supporting sustainable material innovation.</div></div>","PeriodicalId":101276,"journal":{"name":"Waste Management Bulletin","volume":"3 1","pages":"Pages 137-152"},"PeriodicalIF":0.0,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143153718","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A sustainable approach to dairy wastewater treatment through electrocoagulation: From beverage cans to clean water","authors":"Nosa Idusuyi , Marzouq Adeyemi Adebayo , Chinenye Adaobi Igwegbe , Orhadahwe Thomas Aghogho , Anina James , Rasaq Adebayo Kazeem","doi":"10.1016/j.wmb.2024.12.012","DOIUrl":"10.1016/j.wmb.2024.12.012","url":null,"abstract":"<div><div>Dairy industry wastewater, laden with high levels of biological oxygen demand (BOD), chemical oxygen demand (COD), and various pollutants, poses significant environmental concerns. This study introduces the innovative use of recycled aluminium cans as electrodes for electrocoagulation, presenting an eco-friendly and cost-effective approach to wastewater treatment that aligns with circular economy principles. This study explores the efficacy of electrocoagulation (EC) in treating dairy wastewater, focusing on the influence of treatment duration, voltage, and pH levels on BOD, COD, and turbidity reduction. Utilizing recycled aluminium electrodes derived from beverage cans, a Taguchi design of experiments with a 3-factor, 3-level orthogonal array was employed. Results from nine experiments reveal that higher voltages and alkaline pH levels notably enhanced COD and BOD removal efficiencies. For instance, high removal rates of 91.67 % for COD and 95.36 % for BOD were achieved at 20 V and pH 9 over a 15-minute treatment duration were obtained from experiments. Furthermore, optimal overall EC performance parameters were obtained using Taguchi and Multi-response optimization using TOPSIS. Analysis of turbidity removal efficiencies demonstrates the significant impact of voltage and treatment duration. The study provides valuable insights into optimizing electrocoagulation processes for efficient treatment of dairy wastewater, offering a sustainable solution for environmental preservation and resource recovery.</div></div>","PeriodicalId":101276,"journal":{"name":"Waste Management Bulletin","volume":"3 1","pages":"Pages 96-106"},"PeriodicalIF":0.0,"publicationDate":"2024-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143153715","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Asif Iqbal , Rafia Haider , Abdullah Yasar , Abdul-Sattar Nizami
{"title":"A governance model for sustainable municipal solid waste management: Aligning the sector with Pakistan’s economic goals","authors":"Asif Iqbal , Rafia Haider , Abdullah Yasar , Abdul-Sattar Nizami","doi":"10.1016/j.wmb.2024.12.010","DOIUrl":"10.1016/j.wmb.2024.12.010","url":null,"abstract":"<div><div>Pakistan’s economy is transitioning from crisis to stability, necessitating the alignment of public service sectors like Municipal Solid Waste (MSW) management with the country’s economic conditions. By leveraging discrete mathematics and logical frameworks, this study identifies the potential of the waste sector to reduce public expenditure and contribute to economic sustainability. The proposed Wasteism Hierarchy Approach (WHA) offers policy guidelines across waste hierarchy levels to aid decision-making for municipalities, waste management companies, and local governments. Key considerations include the interplay of waste collection modes, fleet management, infrastructure, and catchment areas. Additionally, a Multi-Criteria Decision-Making (MCDM) framework ranks and prioritizes feasible MSW treatment and disposal options. This research highlights the integration of the waste sector into the circular economy and its potential to address climate change, promote regenerative agriculture, and support local economic sustainability.</div></div>","PeriodicalId":101276,"journal":{"name":"Waste Management Bulletin","volume":"3 1","pages":"Pages 107-127"},"PeriodicalIF":0.0,"publicationDate":"2024-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143153716","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Extending the TPB of residential waste sorting with situational factors using a data-driven approach: The case of Gothenburg, Sweden","authors":"Jonathan Cohen, Jorge Gil, Leonardo Rosado","doi":"10.1016/j.wmb.2024.12.007","DOIUrl":"10.1016/j.wmb.2024.12.007","url":null,"abstract":"<div><div>Waste separation at source is perceived as an effective Municipal Waste Management strategy, and the success depends on understanding the drivers of proper waste sorting behaviour. The Theory of Planned Behaviour (TPB) has been extensively applied to determining the importance of different psychological constructs in waste sorting behaviour. Despite evidence of its validity in specific contexts, in urban contexts, one requires an understanding of how the built environment affects waste sorting behaviour. Furthermore, this study introduces the use of Exploratory Factor Analysis as a data-driven approach to define various TPB constructs from a collection of items, including situational factors such as distance to waste bins or the condition of recycling facilities. It shows how this technique outperforms the typical top-down approach of starting from pre-defined items assigned to its constructs. This study surveyed residents of Gothenburg, Sweden, to capture empirical data on factors that affect the planned behaviour of waste separation. Structural Equation Modelling (SEM) is used to evaluate the extended TPB model and extract the drivers of waste sorting behaviour. Results from the study can extend the application of TPB to inform urban planners about the location and maintenance of waste management infrastructure.</div></div>","PeriodicalId":101276,"journal":{"name":"Waste Management Bulletin","volume":"3 1","pages":"Pages 87-95"},"PeriodicalIF":0.0,"publicationDate":"2024-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143153714","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}