Sustainable Chemistry One World最新文献

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Microplastic particles as a vector for toxic-heavy metals: A study on selective aquatic and terrestrial ecosystems 微塑料颗粒作为有毒重金属的载体:选择性水生和陆地生态系统的研究
Sustainable Chemistry One World Pub Date : 2025-08-15 DOI: 10.1016/j.scowo.2025.100097
Haritha Thulaseedharan Nair , Roopika Sivaraman , Santhanakumari Ponnusamy , Renugapriya Palanisamy , Siddhuraju Perumal
{"title":"Microplastic particles as a vector for toxic-heavy metals: A study on selective aquatic and terrestrial ecosystems","authors":"Haritha Thulaseedharan Nair ,&nbsp;Roopika Sivaraman ,&nbsp;Santhanakumari Ponnusamy ,&nbsp;Renugapriya Palanisamy ,&nbsp;Siddhuraju Perumal","doi":"10.1016/j.scowo.2025.100097","DOIUrl":"10.1016/j.scowo.2025.100097","url":null,"abstract":"<div><div>This study examines the prevalence, characteristics, and potential sources of microplastics (MPs) in terrestrial and aquatic ecosystems. Microplastics were extracted from soil and sediment samples and characterized by shape, color, and polymer type using visual analysis and ATR-FTIR spectroscopy. The most abundant MP shapes identified were fragments (45.5 % in soil, 57.7 % in aquatic sediments), with polypropylene and polyurethane being the predominant polymer types. Blue and red were the most common colours observed. Potential MP sources include plastic waste, agricultural films, and sewage sludge. The study also examined the concentration of heavy metals (Cd, Cr, Zn) in MPs and compared them to the surrounding soil and sediment. Results indicated that MPs can act as vectors for heavy metals, potentially increasing their toxicity and environmental impact, with higher concentrations of Zn observed in MPs compared to sediments. When compared to terrestrial sediments, the aquatic sediments are found to have a higher concentration of MP contamination. Microplastics and sediment samples both occasionally showed detectable levels of Cd, Cr, and Zn, but Pb and Cu were below the detection limit in all cases. Cd concentrations reached up to 0.146 mg/g and Zn up to 15.31 mg/g in microplastic samples from the study area. These MPs can enter food chains through flora and fauna, affecting soil biophysics and potentially contaminating groundwater. Direct field observations suggest that human daily plastic usage is a significant source of microplastics in aquatic environments, while agricultural practices and waste management contribute to terrestrial microplastic pollution. This research highlights the widespread contamination of MPs and the associated risks of heavy metal pollution, emphasizing the need for effective waste management and mitigation strategies to protect ecosystem health. This research is the first to provide baseline data on trace metal concentrations in aquatic microplastics from the Coimbatore area.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"7 ","pages":"Article 100097"},"PeriodicalIF":0.0,"publicationDate":"2025-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144861222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Valorisation of Waste kapok leaves in Functional dyeing of nylon fabric 废木棉叶在尼龙布功能性染色中的价值评价
Sustainable Chemistry One World Pub Date : 2025-08-05 DOI: 10.1016/j.scowo.2025.100095
Mohammad Azeem, Nikhil Shaiwale, Javed Sheikh
{"title":"Valorisation of Waste kapok leaves in Functional dyeing of nylon fabric","authors":"Mohammad Azeem,&nbsp;Nikhil Shaiwale,&nbsp;Javed Sheikh","doi":"10.1016/j.scowo.2025.100095","DOIUrl":"10.1016/j.scowo.2025.100095","url":null,"abstract":"<div><div>Natural dyes are sustainable, biodegradable, and largely devoid of harmful chemicals. This research explored dyeing nylon fabric with waste kapok leaf extract (KLE) using various metallic mordants, such as aluminium sulfate, copper (II) sulfate, and ferrous sulfate. The dyed nylon fabrics were analyzed for their color properties, fastness, and functional features, such as antioxidant and antibacterial activities. Fastness ratings ranged from “good” to “excellent”. Pre-mordanted fabrics exhibited enhanced color intensity and fastness, whereas non-mordanted samples showed relatively low color intensity . The dyed nylon fabrics showed antibacterial performance of varying degrees depending on the combination of mordant and dye; the best samples displayed a reduction of <em>E. coli</em> and <em>S. aureus</em> colonies by over 80 %. The antioxidant activity of the dyed fabrics ranged from 68.97 % to 94.42 %. GC-MS analysis revealed the presence of a variety of phytochemicals in the extract. The dyed nylon fabric pre-mordanted with ferrous sulphate (KL7) achieved a UPF of 82.98, indicating excellent UV protection, which was better than other dyed fabrics. The eco-friendly approach to functional dyeing of nylon has been validated.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"7 ","pages":"Article 100095"},"PeriodicalIF":0.0,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144813851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Integrative morpho-anatomical and phytochemical characterization of Alocasia longiloba for sustainable pharmaceutical and environmental applications 综合形态解剖和植物化学表征的药用和环境可持续应用的龙葵
Sustainable Chemistry One World Pub Date : 2025-07-30 DOI: 10.1016/j.scowo.2025.100094
Hong Quan Bui , Thu Trang Le Thi , Ngoc Thuan Nguyen , Huyen Trang Luu , Han Ngoc Bui
{"title":"Integrative morpho-anatomical and phytochemical characterization of Alocasia longiloba for sustainable pharmaceutical and environmental applications","authors":"Hong Quan Bui ,&nbsp;Thu Trang Le Thi ,&nbsp;Ngoc Thuan Nguyen ,&nbsp;Huyen Trang Luu ,&nbsp;Han Ngoc Bui","doi":"10.1016/j.scowo.2025.100094","DOIUrl":"10.1016/j.scowo.2025.100094","url":null,"abstract":"<div><div><em>Alocasia longiloba</em> Miq. (Araceae) is a Southeast Asian understory plant with limited anatomical and phytochemical studies. This work provides the first integrative characterization of its root, rhizome, petiole and lamina. Anatomical examination revealed a polyarch stele in roots, abundant calcium oxalate crystals in the rhizome and irregularly distributed vascular bundles in leaf tissues. Qualitative phytochemical screening of ethanolic extracts confirmed the presence of triterpenoids, flavonoids, phenolics, alkaloids, saponins, steroids and coumarins. Quantitative analysis showed higher total triterpenoid and polyphenol contents in the roots, while flavonoid content was greater in the rhizome. These findings offer foundational anatomical and chemical data, contributing to future taxonomic, ecological and pharmacognostic studies of <em>A. longiloba</em>. The species’ metabolite-rich tissues highlight its potential as a sustainable resource for natural product development and support ongoing biodiversity and health-related research efforts.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"7 ","pages":"Article 100094"},"PeriodicalIF":0.0,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144763795","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mitigation of magnesium corrosion in the presence and absence of KI using an ionic liquid in NaCl solutions 在NaCl溶液中使用离子液体减轻KI存在和不存在时镁的腐蚀
Sustainable Chemistry One World Pub Date : 2025-07-24 DOI: 10.1016/j.scowo.2025.100092
Alexander I. Ikeuba , William E. Azogor , Nnaemeka Ezenobi , Nelson Essiet , Anthony I. Obike , Fredrick C. Asogwa
{"title":"Mitigation of magnesium corrosion in the presence and absence of KI using an ionic liquid in NaCl solutions","authors":"Alexander I. Ikeuba ,&nbsp;William E. Azogor ,&nbsp;Nnaemeka Ezenobi ,&nbsp;Nelson Essiet ,&nbsp;Anthony I. Obike ,&nbsp;Fredrick C. Asogwa","doi":"10.1016/j.scowo.2025.100092","DOIUrl":"10.1016/j.scowo.2025.100092","url":null,"abstract":"<div><div>Hydrogen evolved from corroding magnesium surfaces was collected and used to evaluate the effect of ethyl dimethyl propylammonium bis (trifluoromethyl sulfonyl) imide (EDMPA-TFSI) on magnesium corrosion in 1.0 M NaCl solution in the presence and absence of potassium iodide (KI) at temperatures of 303 K and 333 K. The results showed that EDMPA-TFSI retarded magnesium corrosion rates, recording maximum inhibition efficiencies of 85.2 % and 86.6 % at 303 K and 333 K, respectively, in the absence of KI. However, in the presence of KI, the inhibition efficiency increased to 91.7 % at 303 K but decreased to 29.8 % at 333 K, respectively. This indicates an antagonistic effect of KI on the inhibition efficiency of EDMPA-TFSI at elevated temperatures and a synergistic effect of KI at ambient temperature. The corrosion kinetics in the presence of EDMPA-TFSI were consistent with first-order reaction kinetics. Thermodynamic parameters such as Activation energy (ranged from 40.77 to 134.33 kJ/mol) and Heat of adsorption Q<sub>ads</sub> (ranged from 6.05 to -67.19 kJ/mol) indicate that EDMPA-TFSI transitions from a mixed physisorption and chemisorption mechanism at lower concentration to predominant chemisorption at higher concentrations of EDMPA-TFSI. Results indicate that EDMPA-TFSI can be used as corrosion inhibitors for magnesium in aqueous salt environments.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"7 ","pages":"Article 100092"},"PeriodicalIF":0.0,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144722554","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of BaO-CeO2/TiO2 ternary nanocomposite: an efficient photocatalyst for removal of indigo carmine and rhodamine B BaO-CeO2/TiO2三元纳米复合材料的制备:一种去除靛胭脂红和罗丹明B的高效光催化剂
Sustainable Chemistry One World Pub Date : 2025-07-23 DOI: 10.1016/j.scowo.2025.100088
B.S. Ramya, G. Krishnamurthy
{"title":"Fabrication of BaO-CeO2/TiO2 ternary nanocomposite: an efficient photocatalyst for removal of indigo carmine and rhodamine B","authors":"B.S. Ramya,&nbsp;G. Krishnamurthy","doi":"10.1016/j.scowo.2025.100088","DOIUrl":"10.1016/j.scowo.2025.100088","url":null,"abstract":"<div><div>The current study investigates the photocatalytic degradation of organic dyes such as indigo carmine (IC) and Rhodamine B (RhB) using BaO-supported CeO<sub>2</sub>/TiO<sub>2</sub> as a photocatalyst. The produced nanocomposite was validated using XRD, XPS, UV-Visible, and SEM/EDAX techniques. The higher photocatalytic activity of BaO-CeO<sub>2</sub>/TiO<sub>2</sub> compared to CeO<sub>2</sub>/TiO<sub>2</sub> could be attributed to an increase in pore diameter, surface area, and oxygen vacancies, as determined by photoluminescence and BET studies. The energy band gap of the BCT composite, calculated using UV-Visible spectroscopy, decreased from 3.32 eV (for pure TiO₂) to 2.43 eV with BaO-CeO₂ incorporation, indicating enhanced visible light absorption. Additionally, the surface area increased from 81.40 m²/g for TiO₂ to 86.24 m²/g for CT and further to 92.98 m²/g for BCT, as determined by BET analysis. The percentage degradation is highest for IC (95.76 %) and RhB (95.70 %) dyes. After four cycles, IC and RhB dyes degraded by around 94.9 % and 93.9 %, respectively, which is comparable to the % degradation of the first cycle of around 96 %. pH analysis reveals that IC and RhB dyes degrade more effectively in alkaline (pH=9) and neutral (pH=7) conditions than in acidic environments. The BaO-CeO<sub>2</sub>/TiO<sub>2</sub> nanocomposite remains stable after four cycles of degradation. Kinetic investigations show that both BaO-CeO<sub>2</sub>/TiO<sub>2</sub> and CeO<sub>2</sub>/TiO<sub>2</sub> can fit with first-order (f.o) models (R<sup>2</sup>=1). BaO-CeO<sub>2</sub>/TiO<sub>2</sub> nanocomposite has a higher degradation rate constant <span><math><mrow><mo>(</mo><msub><mrow><mi>K</mi></mrow><mrow><mi>f</mi><mo>.</mo><mi>o</mi></mrow></msub><mo>=</mo><mn>34.38</mn><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mo>−</mo><mn>3</mn></mrow></msup><mspace></mspace></mrow></math></span>and <span><math><mrow><msub><mrow><mi>K</mi></mrow><mrow><mi>f</mi><mo>.</mo><mi>o</mi></mrow></msub><mo>=</mo><mn>26.24</mn><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mo>−</mo><mn>3</mn></mrow></msup><mo>)</mo></mrow></math></span> is higher than that of CeO<sub>2</sub>/TiO<sub>2</sub> <span><math><mrow><mo>(</mo><msub><mrow><mi>K</mi></mrow><mrow><mi>f</mi><mo>.</mo><mi>o</mi></mrow></msub><mo>=</mo><mn>18.23</mn><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mo>−</mo><mn>3</mn></mrow></msup><mspace></mspace></mrow></math></span>and <span><math><mrow><msub><mrow><mi>K</mi></mrow><mrow><mi>f</mi><mo>.</mo><mi>o</mi></mrow></msub><mo>=</mo><mn>18.31</mn><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mo>−</mo><mn>3</mn></mrow></msup><mo>)</mo></mrow></math></span>. Thus, the above findings will assist technicians in designing and synthesising more effective photocatalytic degradation catalysts.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"7 ","pages":"Article 100088"},"PeriodicalIF":0.0,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144713545","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Engineered nanomaterials integrated water treatment processes for the public health and sustainable development: A mechanistic review 工程纳米材料集成水处理工艺的公共卫生和可持续发展:机制综述
Sustainable Chemistry One World Pub Date : 2025-07-22 DOI: 10.1016/j.scowo.2025.100090
Deepak Sharma , Sakshi Sharma , Komal Gupta , Nancy Dhiman , Chaitanayajit Singh , Vinay Kumar , Reena Sharma , Neha Luhakhra , Kanchan Kumari , Vishal Ahuja , Abhishek Chaudhary
{"title":"Engineered nanomaterials integrated water treatment processes for the public health and sustainable development: A mechanistic review","authors":"Deepak Sharma ,&nbsp;Sakshi Sharma ,&nbsp;Komal Gupta ,&nbsp;Nancy Dhiman ,&nbsp;Chaitanayajit Singh ,&nbsp;Vinay Kumar ,&nbsp;Reena Sharma ,&nbsp;Neha Luhakhra ,&nbsp;Kanchan Kumari ,&nbsp;Vishal Ahuja ,&nbsp;Abhishek Chaudhary","doi":"10.1016/j.scowo.2025.100090","DOIUrl":"10.1016/j.scowo.2025.100090","url":null,"abstract":"<div><div>Health related problems are increasing proportionally as industrialization, urbanization and population due to intake of polluted water. Infectious diseases such as cholera, diarrhoea, dysentery, hepatitis A, typhoid and polio are most prevailing due to contaminated water and poor sanitation practices. In addition, incidences of cancer, respiratory disorders, neural toxicities and digestive issues are becoming very common due ingestion of organic, inorganic and persistent pollutants with water. Undoubtedly, existing technologies to treat industrial, and municipal wastewater are in operation but are lagging in meeting the current requirements in terms of efficiencies and volume. The multifaceted characteristics of nanomaterials have led them to hold strong in the water treatment processes such as sorption, catalysis, filtrations, and antimicrobials. Current review article emphasizes on the nano-based processes and their derived advance technologies employed for wastewater treatment in recent years. The main objective of current review article is to provide insights about nanomaterials derived water treatment processes and the underlying mechanisms exhibited by nanomaterials in pollutant removal and degradation. Nanomaterials of metal, carbon, polymer, composites etc all have been reported for the water treatment efficiencies. Review paper provides a detailed information on the nanomaterials-driven degradation, transformation and elimination process for pollutants such as metals, dyes, pharmaceutical compounds, and microbes. Furthermore, main challenges and future perspectives has also been explained in this review article. Overall, present review paper highlights the nanomaterial’s contribution to water treatment technologies with simultaneous benefit in pollution control and public health.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"7 ","pages":"Article 100090"},"PeriodicalIF":0.0,"publicationDate":"2025-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144703418","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Size-directed preparation of chitosan-carrageenan nanoparticles using dynamic light scattering for sustainable materials development 利用动态光散射定向制备壳聚糖-卡拉胶纳米颗粒用于可持续材料的开发
Sustainable Chemistry One World Pub Date : 2025-07-22 DOI: 10.1016/j.scowo.2025.100091
Carlo S. Emolaga , Lumen C. Milo , Blessie A. Basilia
{"title":"Size-directed preparation of chitosan-carrageenan nanoparticles using dynamic light scattering for sustainable materials development","authors":"Carlo S. Emolaga ,&nbsp;Lumen C. Milo ,&nbsp;Blessie A. Basilia","doi":"10.1016/j.scowo.2025.100091","DOIUrl":"10.1016/j.scowo.2025.100091","url":null,"abstract":"<div><div>The sustainable development of biopolymer-based nanoparticles using marine wastes and algal polysaccharides can significantly push the advancement of green chemistry and nanotechnology by reducing waste and using safer chemicals. This study uses a dynamic light scattering (DLS)-guided sequential approach for optimizing chitosan-carrageenan nanoparticles to produce a sustainable nanocarrier while minimizing reliance on the traditional trial-and-error methods. By adopting a systematic approach, this study ensures that the nanoparticles achieve the desired properties while minimizing waste in the production process. Chitosan is a biopolymer derived from crustacean waste while carrageenan can be extracted from seaweeds, an abundant marine resource. These raw materials can be used as encapsulating materials to address the limitations of bioactive compounds in drug delivery and other applications. The process involves selecting the appropriate chitosan molecular weight, carrageenan type, chitosan: carrageenan ratio, crosslinker type, and crosslinker concentration. The four-step formulation process identified a 5:1:1:3 ratio of low molecular weight chitosan, κ-carrageenan, sodium tripolyphosphate (STPP), and calcium chloride (CaCl₂) as optimal, yielding nanoparticles with a hydrodynamic diameter of approximately 350 nm as measured by DLS. FTIR analysis confirmed successful chitosan–carrageenan nanoparticle formation, while AFM and TEM imaging revealed loosely aggregated particles with average sizes of ∼150 nm in AFM and below 100 nm in TEM. This biopolymer-based nanoparticle can have applications in drug delivery, active packaging, and other related industries while supporting multiple Sustainable Development Goals (SDGs 2, 3, 6, and 12) and contributes to waste reduction and the advancement of eco-friendly materials science.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"7 ","pages":"Article 100091"},"PeriodicalIF":0.0,"publicationDate":"2025-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144703417","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of microwave power, irradiation time, and ethanol concentration on phenolic extraction from ripe mango (Mangifera indica L.) peels using Box-Behnken design 采用Box-Behnken设计评价微波功率、辐照时间和乙醇浓度对成熟芒果果皮酚类物质提取的影响
Sustainable Chemistry One World Pub Date : 2025-07-18 DOI: 10.1016/j.scowo.2025.100089
Tristan Roy Panaligan, Danielle Raine Acantilado, Julian Cergio Gayagoy, Alainah Pearl Ramos, Jesuniño Aquino
{"title":"Evaluation of microwave power, irradiation time, and ethanol concentration on phenolic extraction from ripe mango (Mangifera indica L.) peels using Box-Behnken design","authors":"Tristan Roy Panaligan,&nbsp;Danielle Raine Acantilado,&nbsp;Julian Cergio Gayagoy,&nbsp;Alainah Pearl Ramos,&nbsp;Jesuniño Aquino","doi":"10.1016/j.scowo.2025.100089","DOIUrl":"10.1016/j.scowo.2025.100089","url":null,"abstract":"<div><div>This study investigates the influence of key parameters on the extraction of phenolic compounds (PC) from ripe mango (Mangifera indica L. var. Carabao) peels using Microwave-Assisted Extraction (MAE) combined with Response Surface Methodology (RSM) and a Box-Behnken Design (BBD). The parameters evaluated include ethanol concentration (50 %, 65 %, 80 %), microwave power (450 W, 630 W, 810 W), and irradiation time (30 s, 105 s, 180 s). Total phenolic content (TPC) was quantified using the Folin-Ciocalteu method, revealing that the extraction conditions—810 W microwave power, 105 s irradiation time, and 80 % ethanol—yielded the highest TPC of 235.245 mg GAE/g dry weight (DW) solely for the BBD runs. Conversely, the lowest TPC (53.095 mg GAE/g DW) was obtained with 50 % ethanol, 30 s irradiation time, and 450 W microwave power. The results suggest that higher microwave power facilitates cell wall disruption and enhances extraction efficiency, while prolonged exposure to heat can degrade phenolic compounds. Statistical analysis confirmed that all individual parameters significantly (p &lt; 0.05) affected TPC. However, the interaction between ethanol concentration and irradiation time was not statistically significant (p &gt; 0.05).</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"7 ","pages":"Article 100089"},"PeriodicalIF":0.0,"publicationDate":"2025-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144723153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Selective recovery of iron and aluminum from red mud wastewater using fluidized bed homogeneous crystallization 流化床均匀结晶法选择性回收赤泥废水中的铁和铝
Sustainable Chemistry One World Pub Date : 2025-07-16 DOI: 10.1016/j.scowo.2025.100087
Manh Tuan Truong , Gia Cuong Nguyen , Van Giang Le , Xuan Thanh Bui , The Anh Luu
{"title":"Selective recovery of iron and aluminum from red mud wastewater using fluidized bed homogeneous crystallization","authors":"Manh Tuan Truong ,&nbsp;Gia Cuong Nguyen ,&nbsp;Van Giang Le ,&nbsp;Xuan Thanh Bui ,&nbsp;The Anh Luu","doi":"10.1016/j.scowo.2025.100087","DOIUrl":"10.1016/j.scowo.2025.100087","url":null,"abstract":"<div><div>Red mud is a hazardous byproduct originating from the Bayer process during bauxite ore refining that contains substantial quantities of valuable metal ions including iron and aluminum. However, its high alkalinity and large volume pose considerable environmental concerns. In this present work, we developed a two-stage fluidized bed homogeneous crystallization (FBHC) technology for the selective and sequential recovery of ferric hydroxide (Fe(OH)<sub>3</sub>) and bayerite (Al(OH)<sub>3</sub>) from real red mud leachate, without the utilization of heterogeneous seed materials. The crystallization of Fe was optimized at pH 4.0 ± 0.2 and hydraulic retention time (HRT) of 30 min, while Al recovery via FBHC was most effective at pH 9.5 ± 0.3 and up-flow velocity (U) = 25.0 m/h. Iron and aluminum were correspondingly recovered as ferric hydroxide (Fe(OH)<sub>3</sub>) and bayerite (Al(OH)<sub>3</sub>) with total recovery efficiencies reached 99.89 % for Fe(III) and 99.6 % for Al(III). The FBHC technology developed in this study overcomes the limitations of conventional heterogeneous crystallization methods by producing pure products without the need for seed materials and generating less sludge. The resulting crystallized products exhibit uniform spherical shapes (0.5–1.0 nm) and well-defined crystal structures, as confirmed by SEM, EDS, XRD, and FTIR analyses. A preliminary cost-benefit analysis indicated that the proposed process has potential for upscaling and economic implementation in red mud valorization. Recovering metals from red mud helps reduce environmental risks whereas generating economic benefits.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"7 ","pages":"Article 100087"},"PeriodicalIF":0.0,"publicationDate":"2025-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144655270","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Conversion of biomass into useful adsorbents for oil spill remediation: A comprehensive review 生物质转化为有效的石油泄漏修复吸附剂:综述
Sustainable Chemistry One World Pub Date : 2025-07-15 DOI: 10.1016/j.scowo.2025.100086
Ayomipo M. Ojo , Matthew A. Adebayo , Isiaka A. Amoo
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