Sustainable Chemistry One World最新文献

{"title":"Concise review on the development of anionic cellulose materials and their applications in the removal of heavy metals and dyes from water","authors":"Ayodele Akinterinwa ,&nbsp;Elizabeth T. Akinterinwa ,&nbsp;Lee D. Wilson","doi":"10.1016/j.scowo.2025.100065","DOIUrl":"10.1016/j.scowo.2025.100065","url":null,"abstract":"<div><div>Pollution threats and the economic loss of valuable minerals in water systems pose significant risks to health, environmental well-being, resource conservation, and sustainability. Adsorption-based techniques are advancing in water treatment and monitoring processes, integrating sustainable bioproducts such as cellulose and its derivatives into the development of adsorbent materials. Cellulose derivatives modified with anionic (electron-rich) functionalities provide versatile platforms for (1) the electrostatic adsorption of cationic pollutants (CPs) and (2) chemical interaction sites for secondary functionalization. This review succinctly explores the development of anionic cellulose (AiC) derivatives, focusing on the substitution and/or grafting of one or more negatively charged functionalities onto the cellulose platform. Additionally, it highlights tailored syntheses, mechanisms, material characterizations, and the resultant adsorption properties for CP removal from water. This review aims to serve as a comprehensive and complementary reference for future conceptualization and development of anionic cellulose-based materials for water treatment.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"6 ","pages":"Article 100065"},"PeriodicalIF":0.0,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144071312","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Valorization of argan fruit residues to produce thermal energy by combustion","authors":"Mohammed Benchrifa ,&nbsp;Khaoula Benchrifa ,&nbsp;Ibrahim Alsayer ,&nbsp;Driss Azdem ,&nbsp;Jamal Mabrouki ,&nbsp;Driss Hmouni","doi":"10.1016/j.scowo.2025.100066","DOIUrl":"10.1016/j.scowo.2025.100066","url":null,"abstract":"<div><div>This study investigates the valorization of argan fruit residues into compressed biofuel logs as a sustainable energy solution for Morocco. With annual argan oil production exceeding 4000 tonnes and generating over 80,000 tonnes of waste, we developed an optimized process involving solar drying (reducing moisture to ≤10 % in 3 days, 50 % faster than open-air drying), grinding, and mixing with 20 % beeswax before hydraulic pressing. Experimental combustion tests revealed that the argan logs achieved a peak temperature of 460 °C within 45 min significantly outperforming wood (400 °C) and olive pomace (420 °C). The combustion process exhibited three distinct phases: rapid temperature increase (0–45 min), stable high-temperature maintenance (45–150 min at 460 ± 2 °C), and gradual cooling (150–420 min). Notably, the logs demonstrated a 250-minute sustained burn duration, 39 % longer than conventional wood fuels, attributed to the beeswax's calorific contribution (628 kcal/kg). These results demonstrate that argan waste logs offer superior thermal performance while addressing environmental concerns through waste valorization. The study provides a complete circular economy model from agricultural byproduct to value-added bioenergy source, with particular relevance for Mediterranean regions seeking sustainable alternatives to fossil fuels and traditional biofuels.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"6 ","pages":"Article 100066"},"PeriodicalIF":0.0,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144107074","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent advances in zinc oxide nanoparticles for dye removal: Challenges and future directions – A review","authors":"Segun Michael Abegunde ,&nbsp;Matthew Ayorinde Adebayo ,&nbsp;Emmanuel Folorunso Olasehinde ,&nbsp;Kamaldeen Tunde Jimoh","doi":"10.1016/j.scowo.2025.100064","DOIUrl":"10.1016/j.scowo.2025.100064","url":null,"abstract":"<div><div>The removal of hazardous dye molecules from industrial wastewater remains a significant environmental challenge, driving the search for cost-effective and efficient treatment methods. Though many techniques for removing dye from aqueous solutions have been developed and used with varying degrees of success, adsorption has gained recognition due to its simplicity, low cost, and high efficiency. Zinc oxide nanoparticles (ZnO NPs) have recently emerged as promising adsorbents owing to their high surface area, controllable surface properties, and strong dye–adsorbent interactions. This review presents a comprehensive analysis of recent advancements in the application of ZnO NPs for dye adsorption, critically evaluating their performance and addressing the challenges associated with their use. Particular emphasis is placed on the underlying adsorption mechanisms and the role of ZnO NPs in enhancing wastewater treatment efficacy. By identifying existing knowledge gaps and proposing targeted research directions, this review provides critical insights to guide the development of more effective ZnO NP-based adsorption systems in real-world wastewater treatment applications.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"6 ","pages":"Article 100064"},"PeriodicalIF":0.0,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144084620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A comprehensive emphasis on graphene technology and its bioscience applications","authors":"Boddu Asha Jyothi,&nbsp;Alavalapati Sahasra Sri,&nbsp;Kella Bhuvaneshwari,&nbsp;Alapati Jyotsna Sravani,&nbsp;Vemula Madhavi","doi":"10.1016/j.scowo.2025.100063","DOIUrl":"10.1016/j.scowo.2025.100063","url":null,"abstract":"<div><div>The rapid translation of Graphene technology from laboratory discoveries to commercial products has been a remarkable phenomenon, with far-reaching implications for bioscience applications. Graphene is a two-dimensional nanomaterial comprising a single layer of carbon atoms arranged in a hexagonal crystal lattice structure, has captivated researchers and industries worldwide due to its extraordinary properties, making it ideal for applications in medical devices, biosensors, drug delivery systems and tissue engineering. The journey of graphene technologies, from ground breaking laboratory research to impactful integration into various industrial applications, is marked by challenges associated with scaling up graphene production, including the need for cost-effective methods and robust infrastructure to support large-scale commercialization. As graphene technology continues to evolve, its prospects in the bioscience sector are transforming from experimental successes in ongoing research to regulatory frameworks and tangible industrial contributions, with a focus on the versatile ability of graphene to enhance strength, durability, and tunability in various bioscience applications, ultimately holding the transformative potential to revolutionize the bioscience industry.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"6 ","pages":"Article 100063"},"PeriodicalIF":0.0,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143937811","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Evaluating the efficiency of cattle hair waste biochar fortified with alum on the treatment of vegetable oil refinery wastewater","authors":"Goufdour Alexis ,&nbsp;Cornelius Tsamo ,&nbsp;Wangmene Bagamla ,&nbsp;Abba Paltahe","doi":"10.1016/j.scowo.2025.100061","DOIUrl":"10.1016/j.scowo.2025.100061","url":null,"abstract":"<div><div>Vegetable oils wastewater is very coloured and rich in organic and inorganic contaminants with potential effects on humans, ecosystem and environment at large. Cattle hair biochar has good adsorbent properties which can be enhanced by alum but has not been tested before. Testing of used biochar/alum adsorbent as fertilizer is scarce despite the organic fertilizer role of biochar which can be enhanced by organics and inorganics like phosphate adsorbed from the effluent. This study is aimed at evaluating the efficiency of cattle hair waste biochar fortified with alum in removing colour and sulfate from vegetable oil refinery wastewater and investigating the effects of used adsorbents on the growth performance of maize. Biochar produced by pyrolysis at 465 °C gave a yield of 69.36 % and was characterized using FTIR, XRD, and SEM-EDX analysis. Colour and sulfate removal were studied using the parameters such as contact time without stirring, stirring time, concentration, pH dose of biochar and temperature were studied. Biochar/alum recovered after water treatment was tested as fertilizer on growth performance of maize for 34 days. This biochar is rich in carbon, very porous and contain C-O and OH^- groups. The percentage removal of colour removed was higher than that of sulfate for all the parameters. For example, colour removal attained a maximum of about 98 % in 40 mins without stirring, against 74 % in 10 mins for sulfate. When the process is stirred, equilibrium is attained in 20 mins for both colour and sulfate with respective removal efficiencies of 95 and 77 %. 100 % colour was removed at pH 4–10 against pH 6 for maximum sulfate removal. Maximum colour removal of 97 % occurred at 25 °C and 86 % for sulfate at 20 °C. Colour removal is more favourabele K_L = 478.468 ABS g⁻¹ compared to 0.619 L g⁻¹ for sulfate. Recycled adsorbent after treatment showed better maize growth performance than the control (the average leaf area index was 282.2 ± 36.7 on day 34 for recycled adsorbent treatment compared to 210.5 ± 13.5 for the control). Tested biochar fortified with alum is very efficient in improving the quality of studied wastewater, and the recycled adsorbents enhance maize growth.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"6 ","pages":"Article 100061"},"PeriodicalIF":0.0,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143881838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The annual variability of dry leaves and steviol glycosides production in Stevia rebaudiana (Bertoni) genotypes grown in two regions of Morocco","authors":"Abdelkarim Khiraoui ,&nbsp;Mohamed Bakha ,&nbsp;Kaoutar Aboukhalid ,&nbsp;Hassan Bouaik ,&nbsp;Aziz Hasib ,&nbsp;Abdelali Boulli ,&nbsp;Chaouki Al Faiz","doi":"10.1016/j.scowo.2025.100062","DOIUrl":"10.1016/j.scowo.2025.100062","url":null,"abstract":"<div><div><em>Stevia rebaudiana</em> is a perennial shrub native to Paraguay. Its leaves naturally accumulate steviol glycoside (SVglys) sweeteners. Currently, the demand for calorie-free sweeteners has prompted researchers to study other \"natural\" sweeteners that can replace sugar in the global market. Optimization of stevia perennial cultivation in Morocco is based upon breeding adapted high-value genotypes. The basis of a pre-breeding program is to evaluate in field conditions the performances of a large set of genotypes that could be used as genitors for new varieties. This study investigates the dry leaves production and the variability in total SVglys, rebaudioside A (RebA) and stevioside (STV) contents in stevia genotypes cultivated in two distinct regions of Morocco, Agadir and Marrakech, over four years. The analysis reveal significant year-to-year variability in dry leaf yields and SVglys content, with notable increases observed in the second year, indicating that specific climatic conditions were highly favorable during Y2. In addition, the results showed significant difference of SVglys, STV and RebA yields across the 4-harvest years. The STV represented the major SVglys in the both studied regions over the four harvest years with an amount reaching up to 12.63 %, followed by the RebA. In Agadir, the mean cumulative production per plant over four years was 518.57 g of dry leaves, 18.79 g of RebA, 51.37 g of STV and 80.87 g of SVglys. While in Marrakech, the cumulative dry leaves production was 529.9 g, 22.93 g of RebA, 41.99 g of STV and 77.95 g of SVglys. These findings highlight the influence of genotype and environment on SVglys production, emphasizing Morocco's potential as a competitive region for stevia cultivation.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"6 ","pages":"Article 100062"},"PeriodicalIF":0.0,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143881717","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Antioxidant activity, metal-chelation, and photoirradiation mediated enhanced green synthesis of silver nanoparticles by the aqueous extract of the bark of Xylocarpus granatum","authors":"Shafquat Perveen,&nbsp;Sourav Gurung,&nbsp;Monalisha Sarmin,&nbsp;Muddasarul Hoda","doi":"10.1016/j.scowo.2025.100059","DOIUrl":"10.1016/j.scowo.2025.100059","url":null,"abstract":"<div><div><em>Xylocarpus granatum</em> (XG) is a mangrove tree with potential therapeutic applications. The current study intends to demonstrate the photoirradiation-mediated green synthesis of silver nanoparticles, utilizing antioxidant and metal-chelating potential of the metabolites present in the aqueous extract of the bark of XG. The extract was produced by aqueous maceration of the bark for 24 h in dark conditions at room temperature. The GCMS analysis identified various proportions of primary and secondary metabolites. The total phenolic and flavonoid content of the extract was estimated to be 3.059 mmol and 2.119 mmol of gallic acid equivalents per gram of extract, respectively. Furthermore, 500 μg ml⁻¹ and 100 µg ml⁻¹ of extract demonstrated antioxidant activity and FRAP equivalent of 498.56 ± 0.156 µM of ascorbic acid and 195.93 ± 0.0035 µM of ascorbic acid, respectively. Likewise, 500 μg ml⁻¹ of extract demonstrated approximately 35 % iron- and copper-chelating potential against 0.1 mM FeSO₄ and 0.4 mM CuSO₄, respectively. The extract demonstrated silver nanoparticles synthesis in the dark which was significantly enhanced by photoirradiation under 825 lumens white LED light. The mean diameter of these nanoparticles was observed to be 36 ± 11.45 nm, with a poly-dispersive index of 0.276, indicating a homogenous nano-colloidal solution. The nanoparticles were predominantly spherical with approximately 17.5 % silver atoms and 37 % carbon atoms, indicating embedding of silver atoms in the extract nanocomposite that may lead to potential therapeutic application of the nanocomposite. Thus, the current study infers the antioxidant and metal-chelating potential of the extract may contribute to its nanotherapeutic applications.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"6 ","pages":"Article 100059"},"PeriodicalIF":0.0,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143868440","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhancing sustainability and quality: A comparative study of sunflower seed oil extraction methods and physico-chemical characterization","authors":"Sunil Kumar ,&nbsp;Amit Rai ,&nbsp;Kamlesh Prasad","doi":"10.1016/j.scowo.2025.100060","DOIUrl":"10.1016/j.scowo.2025.100060","url":null,"abstract":"<div><div>This study explores the potential of supercritical carbon dioxide (SC-CO₂) as a sustainable alternative to conventional solvent-based extraction for sunflower seed oil. SC-CO₂ extraction provides a safer, cleaner approach, yielding high-quality oil without using toxic solvents. This research compares the physico-chemical properties and fatty acid composition of sunflower seed oil extracted using SC-CO₂ and hexane. SC-CO₂ extraction achieved a higher oil recovery (44.580 ± 0.572 %) than hexane extraction (41.783 ± 0.377 %). Notable differences in oil properties were observed. SC-CO₂-extracted oil had a higher specific gravity (0.949 ± 0.001) than hexane-extracted oil (0.913 ± 0.003), indicating improved functional characteristics. It also demonstrated superior thermal stability, with a higher flash point (320.224 ± 2.128 °C) and fire point (342.325 ± 2.248 °C) compared to hexane-extracted oil (flash point: 317.477 ± 0.467 °C; fire point: 340.786 ± 3.742 °C), making it suitable for food and industrial applications. Additionally, SC-CO₂ extraction preserved a higher total phenolic content (56.730 ± 0.904 mg GAE/100 g) than hexane extraction (49.532 ± 2.077 mg GAE/100 g), leading to greater antioxidant activity (39.140 % vs. 36.553 %). Gas Chromatography analysis confirmed a high unsaturated fatty acid content (89.679 ± 0.079 %), mainly linoleic and cis-oleic acids. SC-CO₂-extracted oil contained more cis-oleic and behenic acids, enhancing oxidative stability and nutritional value. The high cis-oleic acid content (57.713 ± 0.068 %) highlights its versatility in food, pharmaceuticals, and industrial formulations. These results establish SC-CO₂ extraction as a superior method for producing stable, bioactive-rich sunflower oil, reinforcing its role in sustainable processing.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"6 ","pages":"Article 100060"},"PeriodicalIF":0.0,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143868439","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Impact of financial development, technological innovation, green trade and institutional quality on sustainable development: Revelations from global evidence","authors":"Thanh Van Pho ,&nbsp;Dang-Khoa Phan ,&nbsp;Gia Quyen Phan ,&nbsp;Tran Thai Ha Nguyen","doi":"10.1016/j.scowo.2025.100058","DOIUrl":"10.1016/j.scowo.2025.100058","url":null,"abstract":"<div><div>Sustainable development is driven by a combination of economic growth, environmental protection and social development. Accordingly, this study examines sustainable development’s relationships with financial development, technological innovation and green trade with a particular focus on the moderating role played by institutional quality. Taking a two-step system generalised method of moments approach to the analysis of data from 151 countries in 2004 to 2021, this study finds that financial development and, more specifically, financial market development have positive and significant effects on sustainable development, while financial institutional development has significant negative effects. Institutional quality emerges as both a direct and moderating positive factor, diffusing the positive impact of institutions and financial development on sustainable development while mitigating the risks commonly associated with financial institutions. Technological innovation and green trade contribute significantly to sustainable development, while urbanisation detracts from it. These findings point to a clear need for a comprehensive approach that combines financial, technological, trade and institutional policies in pursuit of sustainable development.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"6 ","pages":"Article 100058"},"PeriodicalIF":0.0,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143855318","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Shea butter transesterification through clay-doped BaCl and ionic catalyst; process parameter impacts and kinetic evaluation","authors":"Kenechi Nwosu-Obieogu ,&nbsp;Ude Callistus Nonso ,&nbsp;Onukwuli Dominic Okechukwu ,&nbsp;Ezeugo Joseph","doi":"10.1016/j.scowo.2025.100057","DOIUrl":"10.1016/j.scowo.2025.100057","url":null,"abstract":"<div><div>In this work, Kinetic models were developed to evaluate shea butter (SB) transesterification with methanol using a novel developed clay impregnated with BaCl and ionic liquid (CD-BaCl-IL) catalyst to produce biodiesel and glycerol. To verify their suitability for the process, the synthesized catalyst was characterized using Scanning Electron Micrograph (SEM), X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), X-ray Fluorescence (XRF), and Braut Emmet Teller (BET). The biodiesel was characterized using GCMS (Gas Chromatography Mass Spectrometer) and FT-IR. Kinetic data using CD-BaCl-IL catalyst were obtained at 4 wt% catalyst, 2 hours reaction time, 300 rpm, 10:1 methanol/oil ratio, and 60 °C. Two elementary reaction mechanisms, Eley-Rideal (ER) and Langmuir-Hinshelwood-Hougen-Watson (LHHW) were employed to evaluate the kinetics. The kinetic analysis indicated that the LHHW model accurately represented the experimental data, exhibiting favorable parameters, an R² value of 0.999, and a variance of 2.61E-14 at 40°C. The rate-determining step (RDS) was the surface reaction that connected the adsorbed triglyceride and adsorbed alcohol. The rate rose as the temperature increased, suggesting an endothermic process. At a temperature less than the boiling point of alcohol, the frequency factor and activation energy for the reaction were 6.33E6h-1 and 45.3 kJ/mol, respectively. The feasibility of the CD-BaCl-IL catalyst was ascertained as the LHHW model determined that the RDS and the SB fuel properties complied with the ASTM D 6751 standards.</div></div>","PeriodicalId":101197,"journal":{"name":"Sustainable Chemistry One World","volume":"6 ","pages":"Article 100057"},"PeriodicalIF":0.0,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143855316","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}