Smart Materials in Manufacturing最新文献

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Study on mechanical and tribological properties of polytetrafluoroethylene and graphene oxide reinforced epoxy coatings based on MD simulation 基于MD模拟的聚四氟乙烯和氧化石墨烯增强环氧涂层力学和摩擦学性能研究
Smart Materials in Manufacturing Pub Date : 2026-01-01 Epub Date: 2025-11-25 DOI: 10.1016/j.smmf.2025.100116
Jinxu Hu , Jun Cao , Hulin Li , Yunfeng Chen , Yong Hu , Qiang Zhao , Xiuli Zhang
{"title":"Study on mechanical and tribological properties of polytetrafluoroethylene and graphene oxide reinforced epoxy coatings based on MD simulation","authors":"Jinxu Hu ,&nbsp;Jun Cao ,&nbsp;Hulin Li ,&nbsp;Yunfeng Chen ,&nbsp;Yong Hu ,&nbsp;Qiang Zhao ,&nbsp;Xiuli Zhang","doi":"10.1016/j.smmf.2025.100116","DOIUrl":"10.1016/j.smmf.2025.100116","url":null,"abstract":"<div><div>There are significant differences between the mechanical and tribological data of polymer coatings obtained from molecular dynamics(MD) calculations and those from actual experiments. To reduce the gap between MD calculations and experimental results, five types of EP/PTFE coatings with different GO contents were prepared. The tribological properties of these five coatings were calculated, and real experiments were conducted. By analyzing the microscopic morphological characteristics and mechanical properties of the coatings, the reasons for the differences between MD data and actual experimental results were discussed. An empirical predictive model was innovatively developed. This model incorporates a nonlinear correction term for GO content. The model successfully established a quantitative mapping relationship between the microscopic simulated wear rate and the macroscopic experimental wear rate. The highest error between its predicted values and the experimental data of all samples in this study was only 2.85 %, with a coefficient of determination as high as 0.9978. Blind testing was performed using an independently prepared 3 wt% GO sample, and the prediction error of the model was only 3. 05 %. Compared to simple MD calculations, the quantitative predictive mathematical formula established in this study provides a more accurate research method for coating design and screening.</div></div>","PeriodicalId":101164,"journal":{"name":"Smart Materials in Manufacturing","volume":"4 ","pages":"Article 100116"},"PeriodicalIF":0.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145623665","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Achieving Inconel 718-level tensile properties at room temperature with 23% less niobium: ICME-enabled design via controlled powder blending of Inconel 718 and stainless steel 316L in additive manufacturing 通过在增材制造中控制Inconel 718和不锈钢316L的粉末混合,在室温下减少23%的铌,实现Inconel 718级的拉伸性能
Smart Materials in Manufacturing Pub Date : 2026-01-01 Epub Date: 2026-06-10 DOI: 10.1016/j.smmf.2026.100140
Daozheng Li, Luis Fernando Ladinos Pizano, Liyi Wang, Wei Xiong
{"title":"Achieving Inconel 718-level tensile properties at room temperature with 23% less niobium: ICME-enabled design via controlled powder blending of Inconel 718 and stainless steel 316L in additive manufacturing","authors":"Daozheng Li,&nbsp;Luis Fernando Ladinos Pizano,&nbsp;Liyi Wang,&nbsp;Wei Xiong","doi":"10.1016/j.smmf.2026.100140","DOIUrl":"10.1016/j.smmf.2026.100140","url":null,"abstract":"<div><div>Mixing commercially available alloy powders in Additive Manufacturing (AM) provides a versatile route for composition exploration, yet tailoring post-heat treatments for such mixtures remains challenging. In this study, we developed an efficient ICME-based high-throughput model framework to screen aging choice as a part of post-heat treatment design for a novel alloy blend between Stainless Steel 316L (SS316L) and Inconel 718 (IN718). The framework centers on a modified yield strength model that explicitly accounts for the non-spherical morphology of <span><math><msup><mrow><mi>γ</mi></mrow><mrow><mo>′</mo><mo>′</mo></mrow></msup></math></span> precipitates and their multi-modal size distributions during multi-step isothermal aging. We applied this approach to a 77 wt% IN718 and 23 wt% SS316L blend (77.IN718), selected for its potential for grain refinement during homogenization. After screening 1944 double-step aging profiles, the simulation identified an optimized treatment (725 °C/8 h + 600 °C/8 h) predicting a yield strength of 1070 MPa, which closely matches the experimental value. Despite a significant reduction in niobium and titanium content relative to standard Inconel 718, the new alloy 77.IN718 achieved performance (1055 MPa yield strength, 1285 MPa ultimate tensile strength, and 19.5% elongation) comparable to bulk IN718 processed by conventional manufacturing at room temperature. This work demonstrates a successful integration of ICME-enabled design and experimental validation, offering a sustainable and efficient pathway for developing high-performance alloys by blending existing commercial feedstocks. The methodology enables alloy development with reduced reliance on critical elements, enhancing supply chain resilience in resource-constrained environments.</div></div>","PeriodicalId":101164,"journal":{"name":"Smart Materials in Manufacturing","volume":"4 ","pages":"Article 100140"},"PeriodicalIF":0.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148241534","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanism-based comparison of Ti-6Al-4V lattice topologies with and without face sheets under quasi-static and dynamic loading 准静态和动态载荷下带和不带面片的Ti-6Al-4V晶格拓扑结构的机理比较
IF 13.3
Smart Materials in Manufacturing Pub Date : 2026-01-01 Epub Date: 2026-07-13 DOI: 10.1016/j.smmf.2026.100145
Muhammad Arslan Bin Riaz, Zoran Ren, Aleksej Rikic, Mustafa Guden
{"title":"Mechanism-based comparison of Ti-6Al-4V lattice topologies with and without face sheets under quasi-static and dynamic loading","authors":"Muhammad Arslan Bin Riaz,&nbsp;Zoran Ren,&nbsp;Aleksej Rikic,&nbsp;Mustafa Guden","doi":"10.1016/j.smmf.2026.100145","DOIUrl":"10.1016/j.smmf.2026.100145","url":null,"abstract":"<div><div>A constitutive model calibrated for an electron-beam-melted Ti-6Al-4V Body-Centred Cubic (BCC) lattice was modelled to evaluate nine strut-based lattice topologies different strain rates. For each topology, configurations with face sheets (WFS) and without face sheets (WOFS) were compared using the first-peak stress, ultimate compressive stress (UCS), plateau stress, and specific energy absorption (SEA) performance indicators. The model was initially validated against experiments for a WFS BCC lattice and then used to predict performance across the remaining designs. Face sheet efficiency factors <span><math><mrow><mi>η</mi></mrow></math></span> were introduced to quantify the mass-normalised benefit or penalty of face sheets for each topology, including peak stress, UCS, plateau stress, and SEA. The highest SEA under quasi-static loading was obtained for Face-Body-Centred-Cubic (FBCC)–WOFS, while under dynamic impact, the highest SEA was achieved by Face-Body-Centred-Cubic with stiffener in Z direction (FBCCz)–WOFS, closely followed by Octet–WOFS. Face-Body-Centred-Cubic stiffeners in x, y and z directions (FBCCxyz) exhibited the highest strength response. Collapse was classified into four dominant modes. Shear collapse encouraged load redistribution, mixed (shear–global) collapse rendered homogenous deformation, global failure showed the highest crushing force efficiency, and layer-wise collapse resulted in higher peak stresses.</div></div>","PeriodicalId":101164,"journal":{"name":"Smart Materials in Manufacturing","volume":"4 ","pages":"Article 100145"},"PeriodicalIF":13.3,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148523752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design and additive manufacturing of low-elastic-modulus β-titanium alloys for biomedical applications: from alloying theory to scaffold engineering 生物医学用低弹性模量β钛合金的设计和增材制造:从合金理论到支架工程
IF 13.3
Smart Materials in Manufacturing Pub Date : 2026-01-01 Epub Date: 2026-07-07 DOI: 10.1016/j.smmf.2026.100143
Jiewen Zeng, Weiwei Xu, Zhukun Zhou, Wencheng Pan, Guangxian Li
{"title":"Design and additive manufacturing of low-elastic-modulus β-titanium alloys for biomedical applications: from alloying theory to scaffold engineering","authors":"Jiewen Zeng,&nbsp;Weiwei Xu,&nbsp;Zhukun Zhou,&nbsp;Wencheng Pan,&nbsp;Guangxian Li","doi":"10.1016/j.smmf.2026.100143","DOIUrl":"10.1016/j.smmf.2026.100143","url":null,"abstract":"<div><div>β-titanium (β-Ti) alloys are promising materials for biomedical implants due to their excellent biocompatibility and intrinsically low Young's modulus, which reduces stress shielding compared with conventional α- and α+β-Ti alloys. With advances in additive manufacturing (AM), laser powder bed fusion (LPBF) is increasingly used to fabricate near-net-shape implants and scaffold structures, which can further reduce the Young's modulus. This paper comprehensively reviews the design and fabrication of β-Ti alloys with low Young's modulus, focusing on the alloy design, manufacturing of products via LPBF, and their joint effects on the regulation of Young's modulus. Specifically, β-Ti alloy design principles are systematically reviewed, focusing on the optimization of chemical composition, microstructural control, and emerging methodologies for predicting and tailoring mechanical properties. Furthermore, the influence of LPBF processing parameters and strategies on microstructure, texture, and mechanical properties is introduced, highlighting current achievements in the modulation of Young's modulus from the aspects of alloy fabrication. As a key advantage of AM, particular attention is given to the manufacturing of complex scaffold structures, which enable the regulation of wide-range stiffness through structural design. Moreover, challenges and limitations of β-Ti alloys with low modulus in the aspects of alloy design, LPBF, and design of scaffold structures are discussed. Overall, this review demonstrates state-of-the-art achievements on the fabrication of low-modulus β-Ti alloy via LPBF, providing systematic insights on the manufacturing of next-generation orthopedic implants with high precision and outstanding properties.</div></div>","PeriodicalId":101164,"journal":{"name":"Smart Materials in Manufacturing","volume":"4 ","pages":"Article 100143"},"PeriodicalIF":13.3,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148523773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Powder metallurgical supersaturated Fe-Zn alloys with enhanced mechanical strength, degradability and cytocompatibility for esophageal stent application 粉末冶金过饱和铁锌合金具有增强的机械强度,可降解性和细胞相容性用于食管支架
Smart Materials in Manufacturing Pub Date : 2026-01-01 Epub Date: 2026-03-11 DOI: 10.1016/j.smmf.2026.100134
Jing Huang , Shengye Dong , Luxin Liang , Yilong Dai , Rongwei Tan , Qianli Huang
{"title":"Powder metallurgical supersaturated Fe-Zn alloys with enhanced mechanical strength, degradability and cytocompatibility for esophageal stent application","authors":"Jing Huang ,&nbsp;Shengye Dong ,&nbsp;Luxin Liang ,&nbsp;Yilong Dai ,&nbsp;Rongwei Tan ,&nbsp;Qianli Huang","doi":"10.1016/j.smmf.2026.100134","DOIUrl":"10.1016/j.smmf.2026.100134","url":null,"abstract":"<div><div>Current non-degradable esophageal stents frequently lead to long-term complications during the management of esophageal stricture, which drives a strong need for the development of novel degradable metallic materials with high strength, appropriate degradability and favorable biocompatibility. In this study, supersaturated Fe-<em>x</em>Zn alloys (x = 0, 1.25, 2.5, 5 and 10 at.%) were prepared via a powder metallurgy route combining mechanical alloying (MA) with subsequent fast hot-pressing sintering (FHP). The results reveal that a 40 h-milling duration is feasible for Fe-Zn alloys to achieve sufficient solid solubility and effective grain refinement. The synergy of solid solution strengthening and grain refinement (from 11.47 ± 3.19 μm in pure Fe to 5.24 ± 0.63 μm in Fe-5Zn alloy) mainly contributes to improved mechanical strength (from 681.9 ± 11.7 MPa for pure Fe to 787.9 ± 15.5 MPa for Fe-5Zn alloy) in Fe-<em>x</em>Zn alloys (x ≤ 5 at.%), while Fe-10Zn alloy shows compromised mechanical strength due to excess precipitation of FHP-induced Fe<sub>3</sub>Zn<sub>10</sub> phase. With increased Zn content up to 5 at.%, the degradability and cytocompatibility of Fe-Zn alloys both increase, with Fe-5Zn alloy exhibiting a corrosion rate (0.130 ± 0.005 mm/year) over threefold higher than pure Fe (0.031 ± 0.004 mm/year) in a 56-day phosphate-buffered saline (PBS) immersion test. As a result, the supersaturated Fe-5Zn alloy with improved strength, enhanced degradability and favorable cytocompatibility is considered as a potential biodegradable metallic material for esophageal stent application.</div></div>","PeriodicalId":101164,"journal":{"name":"Smart Materials in Manufacturing","volume":"4 ","pages":"Article 100134"},"PeriodicalIF":0.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147419733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Physico-mechanical evaluation of benzoyl peroxide-treated water hyacinth reinforced polyvinyl alcohol composites and DFT studies of the reaction of the monomer of cellulose 过氧化苯甲酰处理水葫芦增强聚乙烯醇复合材料的物理力学性能评价及纤维素单体反应的DFT研究
Smart Materials in Manufacturing Pub Date : 2026-01-01 Epub Date: 2026-01-08 DOI: 10.1016/j.smmf.2025.100123
Kaniz Fatema , Taslima Akter , Shabiba Parvin Shandhi , Md Khabir Uddin Sarkar , Mohammad Amirul Hoque , Mohammad Shahriar Bashar , Shahin Sultana
{"title":"Physico-mechanical evaluation of benzoyl peroxide-treated water hyacinth reinforced polyvinyl alcohol composites and DFT studies of the reaction of the monomer of cellulose","authors":"Kaniz Fatema ,&nbsp;Taslima Akter ,&nbsp;Shabiba Parvin Shandhi ,&nbsp;Md Khabir Uddin Sarkar ,&nbsp;Mohammad Amirul Hoque ,&nbsp;Mohammad Shahriar Bashar ,&nbsp;Shahin Sultana","doi":"10.1016/j.smmf.2025.100123","DOIUrl":"10.1016/j.smmf.2025.100123","url":null,"abstract":"<div><div>The growing interest in natural fiber-reinforced polymer composites is driven by their sustainability and enhanced mechanical properties. In Bangladesh, the unchecked proliferation of water hyacinth has become a significant environmental issue, altering the pH and salinity of aquatic ecosystems. This study explores the potential of untreated and chemically treated water hyacinth fibers as reinforcement in polyvinyl alcohol (PVA) composites. The untreated water hyacinth (UWH) was subjected to alkali treatment to produce mercerized water hyacinth (MWH), then oxidation to produce oxidized water hyacinth (OWH). The structural modifications of UWH, MWH, and OWH were confirmed through ATR-FTIR spectroscopy. Composites were fabricated by embedding UWH and OWH fibers into PVA at varying concentrations (0.50, 1.00, 2.5, and 5.0 wt%) via compression molding. Composites with 1 % OWH exhibited the best performance, showing a 127 % increase in tensile strength, 162 % increase in elongation, and 28 % reduction in water absorption compared to UWH-PVA and pure PVA. The improved performance of OWH-PVA composites is attributed to enhanced fiber–matrix adhesion. Thermogravimetric analysis confirmed thermal stability, and Density Functional Theory (DFT) calculations supported the chemical modifications observed experimentally. These results highlight the potential of water hyacinth fibers as a sustainable reinforcement material for PVA-based composites.</div></div>","PeriodicalId":101164,"journal":{"name":"Smart Materials in Manufacturing","volume":"4 ","pages":"Article 100123"},"PeriodicalIF":0.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145924101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nonplanar rotary 3D printing framework for sustainable thin-walled structures manufacturing 用于可持续薄壁结构制造的非平面旋转3D打印框架
Smart Materials in Manufacturing Pub Date : 2026-01-01 Epub Date: 2026-01-20 DOI: 10.1016/j.smmf.2026.100125
Hesam Soleimanzadeh, Moslem Mohammadi, Bernard Rolfe, Ali Zolfagharian
{"title":"Nonplanar rotary 3D printing framework for sustainable thin-walled structures manufacturing","authors":"Hesam Soleimanzadeh,&nbsp;Moslem Mohammadi,&nbsp;Bernard Rolfe,&nbsp;Ali Zolfagharian","doi":"10.1016/j.smmf.2026.100125","DOIUrl":"10.1016/j.smmf.2026.100125","url":null,"abstract":"<div><div>Rotary 3D printing offers an effective approach for fabricating cylindrical and curved-surface geometries without conventional supports, yet existing rotary slicing strategies remain unstandardized and difficult to reproduce across diverse platforms. This work introduces a unified, open-source rotary 3D printing framework integrating three complementary slicing pipelines, ranging from CAD-driven visual scripting to a fully automated Python–based user interface workflow. The framework incorporates a volume-preserving unwrapping formulation and a calibrated flow-ratio compensation factor that significantly improves extrusion continuity and seam-line closure. Multi-material dissolvable raft support strategies are implemented to enhance mandrel tolerance control, adhesion tuning, and sustainable detachment. The framework is validated through comprehensive quantitative experiments. Optical 3D metrology and roughness measurements demonstrate uniform radial and circumferential surface quality across cylindrical and auxetic structures. Annular-ring tests verify the effectiveness of correction in eliminating seam gaps. Scanning electron microscopy and optical cross-section imaging confirm interlayer fidelity and void-free dual-material bonding. Comparative studies further show notable reductions in material consumption and energy usage relative to planar printing with dense supports. Demonstrations across auxetic lattices, re-entrant structures, chiral shells, spiral geometries, and thin-walled cylinders highlight the robustness and versatility of the approach. Overall, this work establishes a general-purpose and open-source rotary manufacturing framework compatible with commercial 3D printers and suitable for programmable and 4D printing applications.</div></div>","PeriodicalId":101164,"journal":{"name":"Smart Materials in Manufacturing","volume":"4 ","pages":"Article 100125"},"PeriodicalIF":0.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146037545","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Metallic biomaterials in soft tissue fixation: Applications in wound closure, tendon repair, and vascular ligation 金属生物材料在软组织固定中的应用:伤口闭合、肌腱修复和血管结扎
Smart Materials in Manufacturing Pub Date : 2026-01-01 Epub Date: 2026-03-28 DOI: 10.1016/j.smmf.2026.100135
Delaram Balu , Alireza Nouri , Anahita Rohani Shirvan , Samin Yousefi
{"title":"Metallic biomaterials in soft tissue fixation: Applications in wound closure, tendon repair, and vascular ligation","authors":"Delaram Balu ,&nbsp;Alireza Nouri ,&nbsp;Anahita Rohani Shirvan ,&nbsp;Samin Yousefi","doi":"10.1016/j.smmf.2026.100135","DOIUrl":"10.1016/j.smmf.2026.100135","url":null,"abstract":"<div><div>Metallic surgical closure devices are widely used in wound closure, tendon repair, and vascular ligation due to their superior mechanical strength, stability, and durability compared to polymeric alternatives. Non-absorbable metals such as stainless steel, titanium, silver, and Nitinol provide reliable long-term fixation. In contrast, bioabsorbable metals, including magnesium, zinc, and iron, have emerged as promising alternatives that degrade after fulfilling their function, thereby reducing the need for secondary removal procedures. Despite their advantages, both permanent and bioabsorbable metallic devices require further optimization in biocompatibility, mechanical performance, and surface modifications to minimize foreign body reactions, reduce device-related complications, and improve integration with surrounding tissues. For bioabsorbable metals, key challenges include controlling degradation rates, avoiding excessive hydrogen release in magnesium-based devices, and enhancing structural integrity during the healing process. This review provides a comprehensive comparison of metallic surgical closure devices, with particular focus on sutures, staples, clips, screws, tags, and plugs, examining their applications, advantages, and limitations, as well as material selection and technological innovations that could improve clinical performance.</div></div>","PeriodicalId":101164,"journal":{"name":"Smart Materials in Manufacturing","volume":"4 ","pages":"Article 100135"},"PeriodicalIF":0.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147612247","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
3D-printed bio-based polyurethane-acrylamide hydrogels from soybean oil polyols for efficient dye adsorption 3d打印生物基聚氨酯-丙烯酰胺水凝胶从大豆油多元醇高效染料吸附
IF 13.3
Smart Materials in Manufacturing Pub Date : 2026-01-01 Epub Date: 2026-07-22 DOI: 10.1016/j.smmf.2026.100150
Phanthanyaphon Tsupphayakorn-aek, Chompoonut Rungnim, Manit Nithitanakul, Lih-Sheng Turng, Chuanchom Aumnate
{"title":"3D-printed bio-based polyurethane-acrylamide hydrogels from soybean oil polyols for efficient dye adsorption","authors":"Phanthanyaphon Tsupphayakorn-aek,&nbsp;Chompoonut Rungnim,&nbsp;Manit Nithitanakul,&nbsp;Lih-Sheng Turng,&nbsp;Chuanchom Aumnate","doi":"10.1016/j.smmf.2026.100150","DOIUrl":"10.1016/j.smmf.2026.100150","url":null,"abstract":"<div><div>Sustainable waterborne polyurethane-acrylate (SWPUA)–acrylamide (AM) hydrogels were developed as 3D-printable adsorbents using Liquid Digital Display (LCD) 3D printing, enabling precise control over hydrogel architecture and geometry. Soybean oil-based polyols (SBOPs) were first synthesized through a one-pot epoxidation–hydroxylation process and subsequently used to prepare acrylate-functionalized waterborne polyurethane dispersions with enhanced colloidal stability and well-defined core–shell morphologies. The SWPUA dispersions were then combined with AM to fabricate photo-crosslinkable hydrogel resins suitable for high-resolution LCD printing. By varying the SWPUA:AM ratio and crosslinker content, the swelling behavior, gel content, mechanical properties, and adsorption performance of the 3D-printed hydrogels could be systematically tailored. Methylene blue (MB) was used as a model dye to evaluate adsorption performance. The 3D-printed SWPUA-AM hydrogels exhibited effective MB removal, with the highest Langmuir maximum adsorption capacity of 6.96 mg g<sup>−1</sup> obtained for the SWPUA:AM_75:25 formulation. Adsorption kinetics were best described by the pseudo-second-order model, while equilibrium data followed the Langmuir isotherm, suggesting surface-interaction-controlled adsorption and monolayer adsorption behavior. Density Functional Theory (DFT) calculations further supported the role of electrostatic interactions between MB molecules and functional groups within the hydrogel network. Although the adsorption capacity was moderate compared with highly functionalized adsorbents, the developed hydrogels offer key advantages in terms of renewable feedstock utilization, waterborne polyurethane chemistry, LCD printability, structural customizability, regeneration, and reusability. The developed SWPUA-AM hydrogel is better positioned as a sustainable and 3D-printable adsorbent platform for fabricating customized adsorption structures, such as reusable grids, filter inserts, or modular treatment components for low-to-moderate dye-contaminated wastewater.</div></div>","PeriodicalId":101164,"journal":{"name":"Smart Materials in Manufacturing","volume":"4 ","pages":"Article 100150"},"PeriodicalIF":13.3,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148634418","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Editorial: Insights into advances in additive manufacturing across materials systems 社论:洞察跨材料系统的增材制造进展
Smart Materials in Manufacturing Pub Date : 2026-01-01 Epub Date: 2025-12-01 DOI: 10.1016/j.smmf.2025.100102
Pan Wang , Antonella Sola , Cuie Wen
{"title":"Editorial: Insights into advances in additive manufacturing across materials systems","authors":"Pan Wang ,&nbsp;Antonella Sola ,&nbsp;Cuie Wen","doi":"10.1016/j.smmf.2025.100102","DOIUrl":"10.1016/j.smmf.2025.100102","url":null,"abstract":"","PeriodicalId":101164,"journal":{"name":"Smart Materials in Manufacturing","volume":"4 ","pages":"Article 100102"},"PeriodicalIF":0.0,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145693989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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