RSC Mechanochemistry最新文献_第4页

Shedding water: using mechanochemistry to drive liquid assisted synthesis of the energetic complex glycine–magnesium tetrahydrate 脱水：利用机械化学驱动液体辅助合成高能配合物甘氨酸-四水镁

RSC Mechanochemistry Pub Date : 2025-12-11 DOI: 10.1039/D5MR00110B

Tristan W. Kenny and Lori J. Groven

引用次数: 0

Encapsulation of (pseudo)halogen metal complexes in zeolite Y cages by mechanochemistry （伪）卤素金属配合物在Y型沸石笼中的机械化学包封

RSC Mechanochemistry Pub Date : 2025-12-09 DOI: 10.1039/D5MR00053J

Damjan Šinjori, Emilija Petrović-Hađar, Nikola Jakupec and Ana Palčić

引用次数: 0

Flow-through mechanochemical synthesis by reactive extrusion 反应挤出流动机械化学合成

RSC Mechanochemistry Pub Date : 2025-12-09 DOI: 10.1039/D5MR00097A

Paolo Freisa, Luciano Lattuada, Alessandro Barge and Giancarlo Cravotto

{"title":"Flow-through mechanochemical synthesis by reactive extrusion","authors":"Paolo Freisa, Luciano Lattuada, Alessandro Barge and Giancarlo Cravotto","doi":"10.1039/D5MR00097A","DOIUrl":"https://doi.org/10.1039/D5MR00097A","url":null,"abstract":"Chemical reactions are conventionally carried out in solution, wherein solvents assume a pivotal role in facilitating the dissolution of reagents and thereby enabling molecular interactions. However, this conventional approach is associated with substantial solvent consumption, waste production, and environmental and safety concerns, while also necessitating protracted reaction times. In recent years, there has been an increase in the study of various mechanochemical methods, with the flow-through mechanochemical approach via reactive extrusion (REX) emerging as one of the most promising alternatives. This process employs screws (single, twin or multiple) to generate mechanical energy (shear, compression and friction) to drive chemical reactions, offering precise control over temperature, mixing and residence time. Typically, REX is performed with minimal or no solvents, which significantly reduces its environmental impact. Furthermore, it ensures shorter reaction times and higher yields. In this review, a comprehensive analysis is conducted on the role of screw configuration, temperature control, and residence time in optimising the outcomes of various reaction types.","PeriodicalId":101140,"journal":{"name":"RSC Mechanochemistry","volume":" 2","pages":" 144-160"},"PeriodicalIF":0.0,"publicationDate":"2025-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2026/mr/d5mr00097a?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147375083","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Shaping coordination polymers by ball milling 用球磨成形配位聚合物

RSC Mechanochemistry Pub Date : 2025-12-04 DOI: 10.1039/D5MR00106D

Giorgio Cagossi, Beatrice Piombo, Andrea Daolio, Paolo P. Mazzeo, Alessia Bacchi and Paolo Pelagatti

{"title":"Shaping coordination polymers by ball milling","authors":"Giorgio Cagossi, Beatrice Piombo, Andrea Daolio, Paolo P. Mazzeo, Alessia Bacchi and Paolo Pelagatti","doi":"10.1039/D5MR00106D","DOIUrl":"https://doi.org/10.1039/D5MR00106D","url":null,"abstract":"Selective syntheses of known 1D-coordination polymers derived from the combination of 4,4′-bipyridine (bipy) or 1,2-bis-(4-pyridyl)ethylene (dpe) with Zn(OAc)2·2H2O were achieved under mechanochemical conditions by carefully controlling the mechanochemical parameters, including reaction stoichiometry and the nature of the solvent used in liquid assisted grinding. Ligand exchange reactions performed under grinding conditions showed the conversion of the dpe-containing polymers into bipy-containing polymers, whereas the reverse reactions proved unfeasible. A computational rationale for the observed reactivity is provided. The dimensionality growth of the dpe-containing 1D-coordination polymers into a three-dimensional pillared metal–organic framework was achieved by reaction with terephthalic acid. The same 3D-MOF was also obtained by a one-pot procedure, involving dpe, Zn(OAc)2·2H2O and terephthalic acid simultaneously ground in the presence of a small aliquot of N,N-dimethylformamide. All the reactions occurred in high yields affording pure products with a favorable environmental profile, as evidenced by the environmental factor (EF) and reaction mass efficiency (RME) calculated for selective reactions. This work highlights how mechanochemistry not only allows the efficient synthesis of coordination polymers but also their post-synthetic modifications by environmentally benign protocols.","PeriodicalId":101140,"journal":{"name":"RSC Mechanochemistry","volume":" 2","pages":" 280-292"},"PeriodicalIF":0.0,"publicationDate":"2025-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2026/mr/d5mr00106d?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147375145","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Motion matters: the role of milling ball trajectories in mechanochemical reactions 运动问题：磨球轨迹在机械化学反应中的作用。

RSC Mechanochemistry Pub Date : 2025-12-02 DOI: 10.1039/D5MR00112A

Marisol Fabienne Rappen, Justus Mäder, Sven Grätz and Lars Borchardt

引用次数: 0

Smart mechanochemistry: optimizing amino acid acylation with one factor at a time, design of experiments and machine learning methods 智能机械化学：一次一个因素优化氨基酸酰化，设计实验和机器学习方法

RSC Mechanochemistry Pub Date : 2025-11-28 DOI: 10.1039/D5MR00096C

Adrien Gallego, Matthieu Lavayssiere, Xavier Bantreil, Nicolas Pétry, Julien Pinaud, Olivia Giani and Frédéric Lamaty

引用次数: 0

Mechanochemical α to β phase transition of U3O8 U3O8的机械化学α - β相变

RSC Mechanochemistry Pub Date : 2025-11-26 DOI: 10.1039/D5MR00046G

Jordan M. Roach, Tyler L. Spano and Andrew Miskowiec

{"title":"Mechanochemical α to β phase transition of U3O8","authors":"Jordan M. Roach, Tyler L. Spano and Andrew Miskowiec","doi":"10.1039/D5MR00046G","DOIUrl":"https://doi.org/10.1039/D5MR00046G","url":null,"abstract":"Recognized as the most stable phase of uranium oxide, α-U3O8 is widely used throughout the nuclear fuel cycle for safe storage and transportation. There is, however, a lack of understanding of the thermodynamic relationship between α-U3O8 and its polymorph, β-U3O8. This research contributes new knowledge regarding the kinetics and mechanism of a previously described mechanochemical phase transition between the α- and β-U3O8 polymorphs to improve the understanding of their thermodynamic relationship. In this work, tumble milling of α-U3O8 using different milling media shows an ingrowth of the β-phase over time, with an observed correlation between media density, percent conversion and lattice strain. Anisotropic peak broadening observed within collected X-ray diffraction powder patterns suggests the preservation of uranium polyhedral layered sheets throughout the milling process. Preservation of the sheets implies a shear-induced slip mechanism occurring through in-plane shifting of uranium polyhedra along lattice planes perpendicular to the polyhedral sheets.","PeriodicalId":101140,"journal":{"name":"RSC Mechanochemistry","volume":" 1","pages":" 56-66"},"PeriodicalIF":0.0,"publicationDate":"2025-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2026/mr/d5mr00046g?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145950619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Biasing mechanistically distinct reaction pathways by mechanochemistry 通过机械化学偏置不同的反应途径

RSC Mechanochemistry Pub Date : 2025-11-24 DOI: 10.1039/D5MR00104H

Hao Luo, Zhongye Huang, Yongning Lai, Yongjie Jiang, Taoyong Wang and KaKing Yan

引用次数: 0

Rapid, efficient and green solid-state mechanosynthesis of palladium complexes 快速、高效、绿色钯配合物的固态机械合成

RSC Mechanochemistry Pub Date : 2025-10-31 DOI: 10.1039/D5MR00107B

Leonardo Genesin, Eleonora Aneggi, Walter Baratta, Talha Munir, Fabio Trigatti and Daniele Zuccaccia

{"title":"Rapid, efficient and green solid-state mechanosynthesis of palladium complexes","authors":"Leonardo Genesin, Eleonora Aneggi, Walter Baratta, Talha Munir, Fabio Trigatti and Daniele Zuccaccia","doi":"10.1039/D5MR00107B","DOIUrl":"https://doi.org/10.1039/D5MR00107B","url":null,"abstract":"Mechanochemistry has emerged as a powerful and environmentally benign alternative to conventional solution synthesis. In this study, we present a comprehensive investigation into the solid-state mechanochemical synthesis of a diverse library of palladium(II) complexes. This investigation utilized five commercially available Pd(II) precursors and twelve diene, N- and P-donor ligands. Systematic investigations have revealed that high-yielding and clean reactions can be achieved by tuning the milling frequency, reaction time, and metal-to-ligand stoichiometry, affording more than forty Pd(II) complexes. A comparison with conventional solution-based protocols is therefore indicated to underscore the operational simplicity and ecological advantage of the mechanochemical approach, as demonstrated by favorable green chemistry metrics such as low E-factors and high effective mass yields (EMYs). The validity of the methodology was established through gram-scale syntheses, which demonstrated high yields and reproducibility. These findings contribute a robust and generalizable synthetic strategy for accessing widely used palladium precursors, thus supporting the integration of mechanochemistry into green organometallic synthesis.","PeriodicalId":101140,"journal":{"name":"RSC Mechanochemistry","volume":" 1","pages":" 115-130"},"PeriodicalIF":0.0,"publicationDate":"2025-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2026/mr/d5mr00107b?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145950572","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Mechanochemical synthesis of Ba-doped BiCuSeO oxyselenides: influence of processing conditions on phase formation 机械化学合成ba掺杂BiCuSeO氧化硒化物：工艺条件对相形成的影响

RSC Mechanochemistry Pub Date : 2025-10-29 DOI: 10.1039/D5MR00056D

Aleksandra Khanina, Tatyana Sviridova, Alexandra Ivanova, Andrey Voronin and Vladimir Khovaylo

引用次数: 0