含吡啶和对卤素取代苯甲酸盐的Zn和Cu配合物的机械化学和溶液合成比较

Giorgio Cagossi, Paolo P. Mazzeo, Alessia Bacchi and Paolo Pelagatti
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引用次数: 0

摘要

机械化学可以成为配位化学的重要工具,与溶液方案相比,它具有显著的优势,可以在研磨几分钟内实现高选择性、高效和快速的合成,并实现试剂的转化。机械化学合成含有非螯合配体如吡啶和对卤素取代苯甲酸盐的杂电性Zn(II)和Cu(II)配合物显示了该技术的潜力,并与基于溶液的合成方法进行了详细的比较。通过x射线衍射进行的结构分析证实,机械化学产生的结晶相与在溶液中获得的晶体相相同。在干燥的机械化学条件下也可以合成无水配合物,而不需要专门的设备,突出了这种方法的通用性,即使是对水分敏感的化合物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Comparison between mechanochemical and solution synthesis of Zn and Cu complexes containing pyridine and p-halogen substituted benzoates†

Comparison between mechanochemical and solution synthesis of Zn and Cu complexes containing pyridine and p-halogen substituted benzoates†

Mechanochemistry can be an essential tool for coordination chemistry, demonstrating significant advantages over solution protocols, enabling highly selective, efficient, and rapid syntheses with conversion of the reagents achieved within minutes of grinding. The mechanochemical synthesis of heteroleptic Zn(II) and Cu(II) complexes containing non-chelating ligands like pyridine and p-halogen-substituted benzoates showcased the potential of this technique, with a detailed comparison to solution-based synthetic methods. Structural analyses via X-ray diffraction confirm that the crystalline phases produced mechanochemically are identical to those obtained in solution. The synthesis of anhydrous complexes under dry mechanochemical conditions was also achieved without specialized equipment, highlighting the versatility of this approach even for moisture-sensitive compounds.

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