eScience最新文献_第2页

PdO-resisted oxidation and enhanced hydration promotion of nitrogen electrooxidation to nitrate pdo抗氧化和增强水化促进氮电氧化成硝酸盐

IF 36.6

eScience Pub Date : 2026-03-01 Epub Date: 2025-09-12 DOI: 10.1016/j.esci.2025.100473

Tieliang Li , Chuanqi Cheng , Shuhe Han , Ying Gao , Kaiwen Yang , Bin Zhang , Yifu Yu

{"title":"PdO-resisted oxidation and enhanced hydration promotion of nitrogen electrooxidation to nitrate","authors":"Tieliang Li , Chuanqi Cheng , Shuhe Han , Ying Gao , Kaiwen Yang , Bin Zhang , Yifu Yu","doi":"10.1016/j.esci.2025.100473","DOIUrl":"10.1016/j.esci.2025.100473","url":null,"abstract":"<div><div>The electrocatalytic nitrogen oxidation reaction (NOR) provides a sustainable strategy for nitrate production. However, the challenges of inert nitrogen and competing oxygen evolution reaction severely limit NOR performance. To overcome these challenges, we propose a cooperative system of a superficially armed Pd@PdO electrocatalyst for NOR in a water-in-salt electrolyte. The thin PdO layer efficiently prevents the deep oxidation of Pd to PdO<sub>2</sub>, maintaining the high activity of NOR. Moreover, the water-in-salt electrolyte with a strengthened hydration effect weakens water activity and interrupts hydrogen-bond networks, thus retarding competitive oxygen evolution and accelerating the mass transfer of nitrogen. Therefore, the nitrate yield rate and Faradaic efficiency increase 2.3 and 14.4 times, respectively. Electrochemical <em>in situ</em> spectroscopies unveil the reaction mechanism of nitrogen electrooxidation over the Pd@PdO catalyst. This work provides a foundational strategy for the rational design of electrocatalysts and electrolytes aimed at efficient nitrate electrosynthesis.</div></div>","PeriodicalId":100489,"journal":{"name":"eScience","volume":"6 2","pages":"Article 100473"},"PeriodicalIF":36.6,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146039156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

30 years of AI for electrocatalysis: Where we are and what’s next? 人工智能电催化30年：我们在哪里，下一步是什么？

IF 36.6

eScience Pub Date : 2026-03-01 Epub Date: 2025-12-17 DOI: 10.1016/j.esci.2025.100515

Haotian Chen , Enno Kätelhön , Yuanyuan Lu , Jun Cheng , Zhong-Qun Tian , Richard G. Compton

{"title":"30 years of AI for electrocatalysis: Where we are and what’s next?","authors":"Haotian Chen , Enno Kätelhön , Yuanyuan Lu , Jun Cheng , Zhong-Qun Tian , Richard G. Compton","doi":"10.1016/j.esci.2025.100515","DOIUrl":"10.1016/j.esci.2025.100515","url":null,"abstract":"<div><div>Artificial Intelligence (AI) has evolved over the past three decades from the initial pioneering stage to become a transformative force in electrocatalytic research yet is far from realizing its full potential. This review traces foundational applications of AI to electrocatalysis in the 1990s to highlight the integration of AI into the full catalyst development workflow in the last five years, from material design and synthesis to characterization and performance evaluation, and ultimately to knowledge extraction. Emphasis is placed on critical but often partially recognized or neglected bottlenecks: the scale gap between atomistic simulations and macroscopic performance, inverse electrocatalyst design, physical consistency and interpretability of machine learning models, automated experiments, and the scarcity of high-quality, well validated experimental data. Cutting edge solutions such as exascale computing, machine learning interatomic potentials (MLIPs), physics-informed machine learning (PIML), generative models (variational autoencoders, diffusion models, and large language models), and FAIR-compliant data are discussed. This review highlights that the progress of AI for electrocatalysis is inherently data-centric, driven by advances in data-quality, FAIR-compliant infrastructure, and data-driven workflows that connect experiment, simulations, and machine learning. Beyond technical perspectives, this review also emphasizes the importance of interdisciplinary collaboration, industrial relevance, and cautions in respect of hyping. By identifying challenges and highlighting emerging breakthroughs, this work offers a roadmap for advancing AI-driven electrocatalysis towards more predictive, interpretable, and scalable discovery.</div></div>","PeriodicalId":100489,"journal":{"name":"eScience","volume":"6 2","pages":"Article 100515"},"PeriodicalIF":36.6,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145957650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Grain boundary hinge structure design for upcycling of cathode materials from spent lithium-ion batteries 废锂离子电池正极材料升级回收的晶界铰链结构设计

IF 36.6

eScience Pub Date : 2026-03-01 Epub Date: 2025-09-16 DOI: 10.1016/j.esci.2025.100476

Zitong Fei , Haocheng Ji , Enhua Dong , Liang Luo , Guanghui Jiang , Pengfei Yan , Qi Meng , Peng Dong , Guangmin Zhou , Yingjie Zhang

{"title":"Grain boundary hinge structure design for upcycling of cathode materials from spent lithium-ion batteries","authors":"Zitong Fei , Haocheng Ji , Enhua Dong , Liang Luo , Guanghui Jiang , Pengfei Yan , Qi Meng , Peng Dong , Guangmin Zhou , Yingjie Zhang","doi":"10.1016/j.esci.2025.100476","DOIUrl":"10.1016/j.esci.2025.100476","url":null,"abstract":"<div><div>The recycling of spent lithium-ion batteries in a scientific and efficient manner is expected to address resource scarcity and reduce environmental pollution. Currently, conventional direct regeneration methods are difficult to simultaneously repair the particles, crystal structure, and interface of spent Lithium cobalt oxide (LCO) in three dimensions. This work adopts a \"disintegrate-mend\" reshaping approach to construct a localized heterogeneous hinge structure, grain boundary gradient crystal phases, and uniform polycrystalline particles, thereby achieving a unique structure for regenerated LCO materials. This design overcomes the limitations of uneven degradation in spent LCO, enhances the three-dimensional electron shuttle behaviour of the regenerated material, suppresses the redox activity of lattice oxygen, and optimizes spin-orbital coupling effects. Consequently, the regenerated LCO material demonstrates exceptionally high discharge capacity, with an initial discharge specific capacity of 228.94 mAh g<sup>−1</sup>. Moreover, the soft-packed batteries demonstrate outstanding cycle stability, with capacity retentions of 95.94% after 500 cycles.</div></div>","PeriodicalId":100489,"journal":{"name":"eScience","volume":"6 2","pages":"Article 100476"},"PeriodicalIF":36.6,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146039219","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Bioinspired triboelectric-driven multisensory framework with autonomous cross-modal adaptation 具有自主跨模态适应的仿生摩擦电驱动多感官框架

IF 36.6

eScience Pub Date : 2026-03-01 Epub Date: 2025-10-09 DOI: 10.1016/j.esci.2025.100482

Yao Xiong , Yang Liu , Jiahong Yang , Mingxia Chen , Zhong Lin Wang , Qijun Sun

{"title":"Bioinspired triboelectric-driven multisensory framework with autonomous cross-modal adaptation","authors":"Yao Xiong , Yang Liu , Jiahong Yang , Mingxia Chen , Zhong Lin Wang , Qijun Sun","doi":"10.1016/j.esci.2025.100482","DOIUrl":"10.1016/j.esci.2025.100482","url":null,"abstract":"<div><div>The human multisensory neural network supports advanced cognitive functions through cross-modal integration, recognition, and imagination by synergistically processing visual, tactile, auditory, olfactory, and gustatory stimuli. This biological mechanism generates comprehensive environmental representations through dynamic sensory interactions rather than isolated processing. In this study, a bioinspired multisensory framework is developed, integrating triboelectric sensors with artificial vision, tactile receptors, auditory interfaces, and simulated olfactory/gustatory modules. The system employs a distributed multisensory framework for biomimetic hierarchical processing of multimodal data perception, storage, and fusion. Through cross-modal learning, the system establishes effective associations among different sensory inputs, achieving 97.12% accuracy in tactile-visual recognition and 94.62% accuracy in auditory-visual-olfactory-gustatory reconfiguration. Beyond empirical learning, the framework also demonstrates non-empirical human-like cognitive functions, such as association, inference, and creative pattern generation. The proposed multisensory cross-modal system establishes a versatile framework with significant technological advantages of energy-efficient cognition, adaptive processing, and cognitive scalability. The bioinspired cross-modal reconfiguration combining with triboelectric sensing provides technical innovation and methodological impact to establishing new paradigm for energy-autonomy robotic perception.</div></div>","PeriodicalId":100489,"journal":{"name":"eScience","volume":"6 2","pages":"Article 100482"},"PeriodicalIF":36.6,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146039155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Relay orbital hybridization on MnMoO4 catalysts for durable lithium–oxygen batteries 耐用锂氧电池用MnMoO4催化剂的中继轨道杂化

IF 36.6

eScience Pub Date : 2026-03-01 Epub Date: 2025-06-18 DOI: 10.1016/j.esci.2025.100434

Yichuan Dou , Lanling Zhao , Jun Wang , Songze Li , Yiming Zhang , Ruifeng Li , Mingzhu Gao , Ce Zhang , Zaiping Guo

{"title":"Relay orbital hybridization on MnMoO4 catalysts for durable lithium–oxygen batteries","authors":"Yichuan Dou , Lanling Zhao , Jun Wang , Songze Li , Yiming Zhang , Ruifeng Li , Mingzhu Gao , Ce Zhang , Zaiping Guo","doi":"10.1016/j.esci.2025.100434","DOIUrl":"10.1016/j.esci.2025.100434","url":null,"abstract":"<div><div>MnMoO<sub>4</sub> holds great promise as a cathode material for lithium–oxygen batteries (LOBs), but its poor conductivity and weak interaction with oxygenated intermediates substantially impede its electrocatalytic properties. Herein, electron-deficient P atoms were incorporated with MnMoO<sub>4</sub> hollow nanospheres (P-doped MnMoO<sub>4</sub>) to realize internal orbital interactions between Mo 4d and P 3p, activating external orbital hybridization between catalysts and LiO<sub>2</sub> during cycling. This relay orbital hybridization not only promoted charge transfer but also optimized the adsorption and desorption abilities of catalysts toward LiO<sub>2</sub>, thereby reducing the reaction energy barriers. Consequently, LOBs with P-doped MnMoO<sub>4</sub> cathode catalysts sustained steady operation for 380 cycles under 1000 mA g<sup>−1</sup>, which is even better than some of their noble metal counterparts and points to their commercial promise for use in future large-scale applications. This work provides general guidance for constructing relay orbital hybridization through P doping on catalysts for LOBs and other electrocatalytic systems.</div></div>","PeriodicalId":100489,"journal":{"name":"eScience","volume":"6 2","pages":"Article 100434"},"PeriodicalIF":36.6,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146039159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Regulating lower hubbard band for tandem electrocatalytic lithium polysulfides conversion 串联电催化锂多硫化物转化的调节下轨带

IF 36.6

eScience Pub Date : 2026-01-01 Epub Date: 2025-11-11 DOI: 10.1016/j.esci.2025.100497

Pan Zeng , Wanhai Zhou , Bin Su , Yinqi Hu , ChengWei Du , Xiaoqin Li , Cheng Yuan , Genlin Liu , Xiaofeng Zhao , Wei Luo , Rajeev Ahuja , Qingyuan Wang , Dongliang Chao , Liang Zhang

{"title":"Regulating lower hubbard band for tandem electrocatalytic lithium polysulfides conversion","authors":"Pan Zeng , Wanhai Zhou , Bin Su , Yinqi Hu , ChengWei Du , Xiaoqin Li , Cheng Yuan , Genlin Liu , Xiaofeng Zhao , Wei Luo , Rajeev Ahuja , Qingyuan Wang , Dongliang Chao , Liang Zhang","doi":"10.1016/j.esci.2025.100497","DOIUrl":"10.1016/j.esci.2025.100497","url":null,"abstract":"<div><div>Catalytic conversion of lithium polysulfides (LiPSs) is a promising avenue to suppress the shuttle effect and enhance the redox kinetics of lithium–sulfur (Li–S) batteries. However, the consecutive multiple LiPSs redox reactions make the activity prediction of electrocatalysts elusive. Herein, we propose a lower Hubbard band (LHB) descriptor to regulate tandem electrocatalytic LiPSs conversion for fast and robust Li–S batteries. Combined with theoretical calculations, the catalytic activity is jointly determined by the balance between LHB center position (Ɛ<sub>LHB</sub>) and LHB width (ꞷ<sub>LHB</sub>). As a proof of concept, Fe<sub>3</sub>O<sub>4</sub>@FeP shows a balance of possessing a close Ɛ<sub>LHB</sub> to the Fermi level and a wide ꞷ<sub>LHB</sub> simultaneously. An accelerated tandem electrocatalytic LiPSs conversion is achieved, where a close Ɛ<sub>LHB</sub> to Fermi level (with Fe<sub>3</sub>O<sub>4</sub> as the active center) benefits the adsorption of long-chain LiPSs and catalyzes S<sub>8</sub>-to-Li<sub>2</sub>S<sub>4</sub> process, while a wide ꞷ<sub>LHB</sub> (with FeP as the active center) subsequently contributes to catalyze the Li<sub>2</sub>S<sub>4</sub>-to-Li<sub>2</sub>S reaction. Consequently, the elaborate Li–S batteries deliver outstanding cycle stability over 1000 cycles and superior rate performance over 10C. Further, the constructed Ah-scale pouch cell delivers notable energy density of 360.6 Wh kg<sup>−1</sup>. This work demonstrates the great promise of LHB regulation strategy for designing high-efficient electrocatalysts for Li–S batteries and beyond.</div></div>","PeriodicalId":100489,"journal":{"name":"eScience","volume":"6 1","pages":"Article 100497"},"PeriodicalIF":36.6,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145842606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Heartbeat electro-language: Exploring piezoelectric technologies for cardiovascular health monitoring 心跳电语言：探索压电技术用于心血管健康监测

IF 36.6

eScience Pub Date : 2026-01-01 Epub Date: 2025-06-05 DOI: 10.1016/j.esci.2025.100436

Yun Ke , Tong Li , Jun Li , Mingliang Pei , Xinming Wang , Weichang Xie , Shuting Zhuang , Xiaofeng Ye , Zhou Li , Zuankai Wang , Fan Yang

{"title":"Heartbeat electro-language: Exploring piezoelectric technologies for cardiovascular health monitoring","authors":"Yun Ke , Tong Li , Jun Li , Mingliang Pei , Xinming Wang , Weichang Xie , Shuting Zhuang , Xiaofeng Ye , Zhou Li , Zuankai Wang , Fan Yang","doi":"10.1016/j.esci.2025.100436","DOIUrl":"10.1016/j.esci.2025.100436","url":null,"abstract":"<div><div>Cardiovascular diseases remain the leading cause of global morbidity and mortality, underscoring the urgent need for advanced technologies capable of continuous, noninvasive, and intelligent monitoring. Piezoelectric sensors, owing to their inherent electromechanical transduction, high sensitivity, and self-powered operation, offer a compelling pathway for next-generation cardiovascular health monitoring. In this review, we summarize recent advances in piezoelectric materials, from zero-to three-dimensional architectures, and their integration into wearable and implantable platforms. Key applications include the assessment of arterial health via pulse wave velocity and vascular stiffness, cuffless blood pressure estimation, and the monitoring of cardiopulmonary functions such as heart rate, respiratory rhythm, and cardiac acoustics. We also highlight emerging strategies such as passive wireless communication enabled by surface acoustic wave principles, and the development of multimodal systems that concurrently capture mechanical, optical, and chemical signals. The convergence of piezoelectric technologies with artificial intelligence and Internet of Things frameworks enables real-time signal processing, remote access, and personalized medical interventions. Finally, we discuss current challenges in material biocompatibility, encapsulation, signal fidelity, and clinical translation, and outline future directions for advancing high-performance piezoelectric systems for intelligent cardiovascular diagnostics and connected healthcare.</div></div>","PeriodicalId":100489,"journal":{"name":"eScience","volume":"6 1","pages":"Article 100436"},"PeriodicalIF":36.6,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145842682","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Achieving high-voltage polymer-based all-solid-state batteries based on thermodynamic and kinetic degradation insights 实现基于热力学和动力学降解的高压聚合物全固态电池

IF 36.6

eScience Pub Date : 2026-01-01 Epub Date: 2025-05-26 DOI: 10.1016/j.esci.2025.100433

Xiaoyan Yu , Yun Su , Hang Su , Ruizhi Liu , Jingyi Qiu , Xiayu Zhu , Rui Wen , Hao Zhang , Xiaohui Rong , Yong-Sheng Hu , Gaoping Cao

{"title":"Achieving high-voltage polymer-based all-solid-state batteries based on thermodynamic and kinetic degradation insights","authors":"Xiaoyan Yu , Yun Su , Hang Su , Ruizhi Liu , Jingyi Qiu , Xiayu Zhu , Rui Wen , Hao Zhang , Xiaohui Rong , Yong-Sheng Hu , Gaoping Cao","doi":"10.1016/j.esci.2025.100433","DOIUrl":"10.1016/j.esci.2025.100433","url":null,"abstract":"<div><div>Understanding the mechanisms behind the degradation in cyclic stability of polymer-based all-solid-state batteries (ASSBs) at high voltages is important for facilitating their commercial application. Beyond the examination of specific material properties, from the perspectives of thermodynamic and kinetic factors, we find that the operating temperature critically influences the stability of the electrodes, electrolytes and electrode/electrolyte interfaces within the ASSBs. In this study, we constructed polymer-based ASSBs and comprehensively investigated the cyclic stability and changes in failure mechanisms with different operating temperatures at high voltages. Notably, a lower operating temperature enhanced the cyclic stability by suppressing structural collapse of the cathode and decomposition of the electrolytes while inhibiting lithium dendrites growth. The assembled lithium coin cells exhibited a superior capacity retention of 81.8% after 400 cycles at a voltage of 3.0–4.45 V and operating temperature of 40 °C. In addition, both lithium pouch cells and sodium coin cells were prepared and demonstrated excellent performances. This work provides a rational guide for the development of advanced polymer-based ASSBs.</div></div>","PeriodicalId":100489,"journal":{"name":"eScience","volume":"6 1","pages":"Article 100433"},"PeriodicalIF":36.6,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145842685","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Mutual stabilization of hybrid and inorganic perovskites for photovoltaics 光伏用杂化钙钛矿和无机钙钛矿的相互稳定

IF 36.6

eScience Pub Date : 2026-01-01 Epub Date: 2025-07-18 DOI: 10.1016/j.esci.2025.100449

Yuheng Li , Ziwei Zheng , Xin Zheng , Xiaoyuan Liu , Yingguo Yang , Yongcheng Zhu , Zaiwei Wang , Xingyu Ren , Mimi Fu , Rui Guo , Jing Guo , Zewen Xiao , Yaoguang Rong , Xiong Li

{"title":"Mutual stabilization of hybrid and inorganic perovskites for photovoltaics","authors":"Yuheng Li , Ziwei Zheng , Xin Zheng , Xiaoyuan Liu , Yingguo Yang , Yongcheng Zhu , Zaiwei Wang , Xingyu Ren , Mimi Fu , Rui Guo , Jing Guo , Zewen Xiao , Yaoguang Rong , Xiong Li","doi":"10.1016/j.esci.2025.100449","DOIUrl":"10.1016/j.esci.2025.100449","url":null,"abstract":"<div><div>Stabilizing black-phase formamidinium lead triiodide (FAPbI<sub>3</sub>) is critical for high-performance perovskite solar cells (PSCs). We present a stabilization strategy utilizing co-evaporated cesium lead iodide (CsPbI<sub>3</sub>) capping layers. Enabled by favorable crystal lattice matching, cubic-phase CsPbI<sub>3</sub> spontaneously forms on FAPbI<sub>3</sub> surfaces, establishing mutual phase stabilization with the underlying black-phase FAPbI<sub>3</sub>. When combined with ammonium salt interface modification, the CsPbI<sub>3</sub> interlayer effectively suppresses the ion (FA<sup>+</sup> and F-PEA<sup>+</sup>) diffusion between the stacked perovskite layers. The FAPbI<sub>3</sub>/CsPbI<sub>3</sub> bilayer structured devices exhibited a certified record reverse-scanning power-conversion efficiency of 27.17% and maintained a stabilized power output efficiency of 26.62%. Remarkably, the cells retain 93.5% of the initial efficiency after 1500 h damp-heat test, and retaining over 94.2% of its maximum PCE after about 1185 h with a linear extrapolation to a <em>T</em><sub>90</sub> of 2352 h operation under continuous illumination at maximum power point tracking at 85 °C.</div></div>","PeriodicalId":100489,"journal":{"name":"eScience","volume":"6 1","pages":"Article 100449"},"PeriodicalIF":36.6,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145799745","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Longitudinal confinement engineering in phase change materials 相变材料的纵向约束工程

IF 36.6

eScience Pub Date : 2026-01-01 Epub Date: 2025-07-23 DOI: 10.1016/j.esci.2025.100454

Yuhao Feng , Keke Chen , Panpan Liu , Jindi Zhao , Yang Li , Xiao Chen

{"title":"Longitudinal confinement engineering in phase change materials","authors":"Yuhao Feng , Keke Chen , Panpan Liu , Jindi Zhao , Yang Li , Xiao Chen","doi":"10.1016/j.esci.2025.100454","DOIUrl":"10.1016/j.esci.2025.100454","url":null,"abstract":"<div><div>Amidst escalating energy demands and intensifying environmental pressures, advanced phase change materials (PCMs) have emerged as highly efficient and sustainable storage solutions, owing to their unique operational principles. However, pristine PCMs encounter a multitude of challenges, including susceptibility to leakage, inferior thermal/electrical conductivity, inadequate light responsiveness, intrinsic rigidity, and limited functionality, which impede their effectiveness in addressing the complex demands of real-world applications. Longitudinal confinement of PCMs using advanced multifunctional 1D materials is accepted as a cutting-edge solution to these limitations. A corresponding comprehensive review of longitudinally confined composite PCMs is thus imperative for subsequent studies and yet is missing from the literature, unlike reviews of 0D, 2D, and 3D materials for PCMs. Herein, this review systematically highlights the diverse roles of longitudinal materials in PCMs and analyzes the relationships between their architectures and thermophysical properties, with particular emphasis on design principles and advanced multifunctional interdisciplinary applications. Additionally, we provide an in-depth understanding of thermal transfer, energy conversion mechanisms, and rationalized routes to high-efficiency energy conversion PCMs. Finally, we introduce critical considerations for current challenges and future solutions to them, hoping to offer constructive guidance and facilitate significant breakthroughs for longitudinally confined composite PCMs in both fundamental interdisciplinary research and commercial applications.</div></div>","PeriodicalId":100489,"journal":{"name":"eScience","volume":"6 1","pages":"Article 100454"},"PeriodicalIF":36.6,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145842688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0