ACS Sustainable Resource Management最新文献

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Fabrication of Rice-Husk-Derived Silica Mediated Bioactive Glass for Antibacterial and Wound Healing Applications
ACS Sustainable Resource Management Pub Date : 2025-02-13 DOI: 10.1021/acssusresmgt.5c0003210.1021/acssusresmgt.5c00032
Mukta Rajotia, Pragya Pragya, Prakhar Bajpai, Anjali Upadhyay, Sudip Mukherjee* and Subrata Panda*, 
{"title":"Fabrication of Rice-Husk-Derived Silica Mediated Bioactive Glass for Antibacterial and Wound Healing Applications","authors":"Mukta Rajotia,&nbsp;Pragya Pragya,&nbsp;Prakhar Bajpai,&nbsp;Anjali Upadhyay,&nbsp;Sudip Mukherjee* and Subrata Panda*,&nbsp;","doi":"10.1021/acssusresmgt.5c0003210.1021/acssusresmgt.5c00032","DOIUrl":"https://doi.org/10.1021/acssusresmgt.5c00032https://doi.org/10.1021/acssusresmgt.5c00032","url":null,"abstract":"<p >Bioactive glass is a promising material for biomedical applications due to the presence of biologically active ions. In this article, we explored sustainable and cost-effective substitutes for pure quartz glass by utilizing rice-husk-extracted silica for wound healing applications. Two new bioglasses (rice-husk silica glass (RSG) and quartz silica glass (QSG)) were synthesized by using rice-husk extracted silica and pure quartz silica, respectively, and their physiochemical and biological properties were compared with the conventional 45S5 bioglass. Different biological assays like zone of inhibition, colony counting, and morphology analysis by electron microscopy confirmed the potent antibacterial activities of the newly developed bioglasses. Antioxidant assays and cytotoxicity assays proved that these bioglasses are biocompatible and promote normal cell proliferation. Finally, <i>in vivo</i> wound healing studies carried out in the rat model demonstrated rapid wound healing properties of the RSG bioglass. This study explores sustainable approaches of utilizing biomass derived silica for synthesizing bioactive glasses for biomedical applications.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"2 2","pages":"362–373 362–373"},"PeriodicalIF":0.0,"publicationDate":"2025-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143496377","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bioplastics from Shellfish Waste: Tuning the Tensile and Solubility Properties of Chitosan Films
ACS Sustainable Resource Management Pub Date : 2025-02-11 DOI: 10.1021/acssusresmgt.4c0033010.1021/acssusresmgt.4c00330
Kaydren Orcutt*, Zach McCaffrey, Lennard F. Torres, Delilah F. Wood, Tina G. Williams, Artur P. Klamczynski, Jong H. Kim, Gregory M. Glenn, William J. Orts and William M. Hart-Cooper*, 
{"title":"Bioplastics from Shellfish Waste: Tuning the Tensile and Solubility Properties of Chitosan Films","authors":"Kaydren Orcutt*,&nbsp;Zach McCaffrey,&nbsp;Lennard F. Torres,&nbsp;Delilah F. Wood,&nbsp;Tina G. Williams,&nbsp;Artur P. Klamczynski,&nbsp;Jong H. Kim,&nbsp;Gregory M. Glenn,&nbsp;William J. Orts and William M. Hart-Cooper*,&nbsp;","doi":"10.1021/acssusresmgt.4c0033010.1021/acssusresmgt.4c00330","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00330https://doi.org/10.1021/acssusresmgt.4c00330","url":null,"abstract":"<p >Chitosans of varying molecular weights were solubilized with acids (lactic, acetic, and malic) and formed into films with glycerin added as a plasticizer, with additional treatments applied to tune the solubility and tensile properties of the films. Lactic acid solubilized chitosan made films that had a wider range of tensile properties when tuned by the glycerin concentration. Neutralizing the films led to tensile strength increasing from 16.48 to 58.95 MPa, with a loss in strain at break percent decreasing from 47.95% to 28.19%. A plasticizer bath after neutralization of a glycerin-containing film leads to an increase in tensile stress from 17.97 to 26.44 MPa. The neutralized films without a plasticizer bath show a loss from 54.94 to 42.42 MPa in 98% humidity, while the neutralized sample with plasticizer decreases from 41.10 to 8.11 MPa. Having mechanisms for tunability of the properties increases the applicability of chitosan films as sustainably produced replacements for petroleum-derived plastics in single-use packaging, textiles, and many other applications.</p><p >Chitosan films made from shellfish food waste have tunable mechanical and solubility properties, leading to a wide breadth of applications.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"2 2","pages":"294–302 294–302"},"PeriodicalIF":0.0,"publicationDate":"2025-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acssusresmgt.4c00330","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143496206","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correction to “Equilibrium Studies of Biodiesel Ethyl Esters Prepared with a Potassium Glyceroxide Catalyst”
ACS Sustainable Resource Management Pub Date : 2025-02-06 DOI: 10.1021/acssusresmgt.5c0005910.1021/acssusresmgt.5c00059
Aaron M. Socha*, 
{"title":"Correction to “Equilibrium Studies of Biodiesel Ethyl Esters Prepared with a Potassium Glyceroxide Catalyst”","authors":"Aaron M. Socha*,&nbsp;","doi":"10.1021/acssusresmgt.5c0005910.1021/acssusresmgt.5c00059","DOIUrl":"https://doi.org/10.1021/acssusresmgt.5c00059https://doi.org/10.1021/acssusresmgt.5c00059","url":null,"abstract":"","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"2 2","pages":"374 374"},"PeriodicalIF":0.0,"publicationDate":"2025-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143496298","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient Water Evaporation Using Black Silicon
ACS Sustainable Resource Management Pub Date : 2025-02-04 DOI: 10.1021/acssusresmgt.4c0041810.1021/acssusresmgt.4c00418
Yoshiaki Nishijima*, Hiroyoshi Nishijima, Makoto Ohashi, Tomas Katkus and Saulius Juodkazis, 
{"title":"Efficient Water Evaporation Using Black Silicon","authors":"Yoshiaki Nishijima*,&nbsp;Hiroyoshi Nishijima,&nbsp;Makoto Ohashi,&nbsp;Tomas Katkus and Saulius Juodkazis,&nbsp;","doi":"10.1021/acssusresmgt.4c0041810.1021/acssusresmgt.4c00418","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00418https://doi.org/10.1021/acssusresmgt.4c00418","url":null,"abstract":"<p >The black silicon (b-Si)─plasma-etched nanostructured surface of crystalline Si─was used as a light absorber due to its extremely low reflectivity (&lt;1%) at the visible-to-near-IR spectral range. Flat Fresnel lenses of 1.47 and 0.36 m<sup>2</sup> were used to focus light onto b-Si, which was a photothermal absorber. Experiments to distill water were carried out from October 2021 to April 2022 in Obihiro (42°55′N 143°12′E), Hokkaido, Northern Japan. The same b-Si has biocidal properties (antibactericidal, antiviral, and antifungal) due to mechanical nanoscale needles, which complement the water purification when gray water sources are used in applications.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"2 2","pages":"316–321 316–321"},"PeriodicalIF":0.0,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143496285","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Use of Recovered Carbon Black from Waste Tires in Triple Mesoscopic Stack Perovskite Solar Cells
ACS Sustainable Resource Management Pub Date : 2025-02-03 DOI: 10.1021/acssusresmgt.4c0042210.1021/acssusresmgt.4c00422
Susana Iglesias-Porras*, Amy Neild, Lee Stevens, Wei Li, Colin Snape, Owen Woodford, Niall Straughan and Elizabeth A. Gibson*, 
{"title":"Use of Recovered Carbon Black from Waste Tires in Triple Mesoscopic Stack Perovskite Solar Cells","authors":"Susana Iglesias-Porras*,&nbsp;Amy Neild,&nbsp;Lee Stevens,&nbsp;Wei Li,&nbsp;Colin Snape,&nbsp;Owen Woodford,&nbsp;Niall Straughan and Elizabeth A. Gibson*,&nbsp;","doi":"10.1021/acssusresmgt.4c0042210.1021/acssusresmgt.4c00422","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00422https://doi.org/10.1021/acssusresmgt.4c00422","url":null,"abstract":"<p >This research addresses critical challenges in the photovoltaic (PV) industry to achieve net-zero greenhouse gas emissions by 2050, amidst geopolitical semiconductor supply risks and escalating volumes of PV waste. We demonstrate the opportunity to address these challenges through the design of PV cells which are compatible with a circular economy. In this proof-of-concept study, unpurified locally sourced recovered carbon black (rCB) from waste tires was integrated into the mesoporous carbon layer of triple mesoscopic perovskite solar cells as a sustainable alternative to virgin carbon sources, and comparable efficiencies (9.98%) to commercial carbon paste benchmarks (10.4%) were attained. Key findings reveal that the presence of sulfur, silica, and zinc oxide contaminants only affected performance and durability marginally. While sulfur enhanced perovskite crystallization, as evidenced by an increased fill factor, it potentially influenced the absorber’s valence band maximum, slightly dropping the open-circuit voltage. Silica and zinc oxide exacerbated moisture ingress under UK weather conditions, as revealed by outdoor testing, which accelerated degradation post-breaching of the encapsulant. Such degradation could be mitigated through effective encapsulation. Although further research is crucial to maximize performance and device longevity, the feasibility of using locally sourced rCB in PV technology has been demonstrated. This approach could support regional energy resilience and sustainability objectives within a circular economy framework.</p><p >This research explores integrating recycled carbon black from waste tires into solar cells to improve sustainability in the photovoltaic industry.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"2 2","pages":"322–333 322–333"},"PeriodicalIF":0.0,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acssusresmgt.4c00422","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143496284","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel Bio-inorganic Composite as a Sustainable Strength Additive and Potential Alternative to Inorganic Fillers for Papermaking
ACS Sustainable Resource Management Pub Date : 2025-02-03 DOI: 10.1021/acssusresmgt.4c0040510.1021/acssusresmgt.4c00405
Jitendra Kumar, Anuj Kumar, Indrasena Ghosh, Surendra Pal Singh and Chhaya Sharma*, 
{"title":"Novel Bio-inorganic Composite as a Sustainable Strength Additive and Potential Alternative to Inorganic Fillers for Papermaking","authors":"Jitendra Kumar,&nbsp;Anuj Kumar,&nbsp;Indrasena Ghosh,&nbsp;Surendra Pal Singh and Chhaya Sharma*,&nbsp;","doi":"10.1021/acssusresmgt.4c0040510.1021/acssusresmgt.4c00405","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00405https://doi.org/10.1021/acssusresmgt.4c00405","url":null,"abstract":"<p >This study explores the development and characterization of a novel bio-inorganic composite filler containing precipitated calcium carbonate (PCC) and regenerated cellulose (RC) derived from pineapple crown waste for papermaking. Hand sheets containing modified precipitated calcium carbonate (MdPCC) exhibited significant improvements in tensile strength (up to 68.21% increase at 15% of 20% MdPCC loading), burst index (up to 10.51 kg/cm<sup>2</sup>), burst factor (up to 95.50), and double fold (263–3383 at 25% of 20% MdPCC loading) compared to control paper. This exceptional improvement in double fold is attributed to MdPCC’s ability to facilitate stress transfer between paper fibers, leading to a more even distribution of stress and enhanced fold resistance. RC containing different dosages of PCC were characterized by different analytical techniques in order to evaluate the effective retention of the PCC into RC and paper matrix subsequently. PCC alone causes a decrease in the strength of the paper; hence, the proposed filler may overcome this drawback. This study provides the alternative pathway to replace the high dosage of inorganic filler along with no compromise in the strength properties of the paper.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"2 2","pages":"303–315 303–315"},"PeriodicalIF":0.0,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143496282","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Use of Recovered Carbon Black from Waste Tires in Triple Mesoscopic Stack Perovskite Solar Cells.
ACS Sustainable Resource Management Pub Date : 2025-02-03 eCollection Date: 2025-02-27 DOI: 10.1021/acssusresmgt.4c00422
Susana Iglesias-Porras, Amy Neild, Lee Stevens, Wei Li, Colin Snape, Owen Woodford, Niall Straughan, Elizabeth A Gibson
{"title":"Use of Recovered Carbon Black from Waste Tires in Triple Mesoscopic Stack Perovskite Solar Cells.","authors":"Susana Iglesias-Porras, Amy Neild, Lee Stevens, Wei Li, Colin Snape, Owen Woodford, Niall Straughan, Elizabeth A Gibson","doi":"10.1021/acssusresmgt.4c00422","DOIUrl":"10.1021/acssusresmgt.4c00422","url":null,"abstract":"<p><p>This research addresses critical challenges in the photovoltaic (PV) industry to achieve net-zero greenhouse gas emissions by 2050, amidst geopolitical semiconductor supply risks and escalating volumes of PV waste. We demonstrate the opportunity to address these challenges through the design of PV cells which are compatible with a circular economy. In this proof-of-concept study, unpurified locally sourced recovered carbon black (rCB) from waste tires was integrated into the mesoporous carbon layer of triple mesoscopic perovskite solar cells as a sustainable alternative to virgin carbon sources, and comparable efficiencies (9.98%) to commercial carbon paste benchmarks (10.4%) were attained. Key findings reveal that the presence of sulfur, silica, and zinc oxide contaminants only affected performance and durability marginally. While sulfur enhanced perovskite crystallization, as evidenced by an increased fill factor, it potentially influenced the absorber's valence band maximum, slightly dropping the open-circuit voltage. Silica and zinc oxide exacerbated moisture ingress under UK weather conditions, as revealed by outdoor testing, which accelerated degradation post-breaching of the encapsulant. Such degradation could be mitigated through effective encapsulation. Although further research is crucial to maximize performance and device longevity, the feasibility of using locally sourced rCB in PV technology has been demonstrated. This approach could support regional energy resilience and sustainability objectives within a circular economy framework.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"2 2","pages":"322-333"},"PeriodicalIF":0.0,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11874465/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143560528","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Artificial Intelligence (AI) Can Advance Plastic Sustainability and Circular Economy
ACS Sustainable Resource Management Pub Date : 2025-01-27 DOI: 10.1021/acssusresmgt.4c0052610.1021/acssusresmgt.4c00526
Mehran Ghasemlou*, 
{"title":"Artificial Intelligence (AI) Can Advance Plastic Sustainability and Circular Economy","authors":"Mehran Ghasemlou*,&nbsp;","doi":"10.1021/acssusresmgt.4c0052610.1021/acssusresmgt.4c00526","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00526https://doi.org/10.1021/acssusresmgt.4c00526","url":null,"abstract":"","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"2 2","pages":"231–233 231–233"},"PeriodicalIF":0.0,"publicationDate":"2025-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143496240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Conversion of Non-biodegradable Super Absorbing Polymer (SAP) Waste into MnO-rich Functional Supercapacitor Carbon by a Sustainable, Low-Temperature Activation Process
ACS Sustainable Resource Management Pub Date : 2025-01-27 DOI: 10.1021/acssusresmgt.4c0025910.1021/acssusresmgt.4c00259
Aparna Deshpande*, Sarika Jadhav, Kiran Manohar, Shivam Rawat, Suresh Gosavi* and Sadhana Rayalu, 
{"title":"Conversion of Non-biodegradable Super Absorbing Polymer (SAP) Waste into MnO-rich Functional Supercapacitor Carbon by a Sustainable, Low-Temperature Activation Process","authors":"Aparna Deshpande*,&nbsp;Sarika Jadhav,&nbsp;Kiran Manohar,&nbsp;Shivam Rawat,&nbsp;Suresh Gosavi* and Sadhana Rayalu,&nbsp;","doi":"10.1021/acssusresmgt.4c0025910.1021/acssusresmgt.4c00259","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00259https://doi.org/10.1021/acssusresmgt.4c00259","url":null,"abstract":"<p >A non-biodegradable super absorbing polymer (SAP) is primarily used in biomedical devices and female menstrual sanitary waste pads. Its safe disposal is a massive problem that needs global strategic cognizance. The sanitary waste is mainly comprised of high molecular weight acrylate-based polymers having higher water-absorbent properties with a significant carbon atom-based cross-linked backbone. Here we have derived a workable energy storage material from menstrual sanitary waste with minimal energy input, making it environmentally viable. In this study, a rich carbon matrix was produced from pyrolysis of sanitary waste pads with KMnO<sub>4</sub> based activation at 300 °C. The obtained carbon showed the presence of MnO moieties having desirable properties as a supercapacitor electrode. The stored energy density in the synthesized carbons was found to be 11.23 Wh kg<sup>–1</sup> at a 0.275 kW kg<sup>–1</sup> power density. The derived carbon shows excellent capacity retention of 84% and electrochemical stability until 10,000 cycles. These porous functional carbons produced from non-biodegradable SAPs thus make a sustainable potential resource for energy storage applications.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"2 2","pages":"234–242 234–242"},"PeriodicalIF":0.0,"publicationDate":"2025-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143496241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Valorization of Corncob Acid Hydrolysis Residue to Glucose and Bio-Polyol by Enzymatic Hydrolysis of Cellulose and Etherification Modification of Lignin
ACS Sustainable Resource Management Pub Date : 2025-01-25 DOI: 10.1021/acssusresmgt.4c0045810.1021/acssusresmgt.4c00458
Chuanyuan Yang, Chuanmin Geng, Yujie Zhang, Xiaojing Jiang, Yingjuan Fu, Menghua Qin, Yongchao Zhang, Shuzhen Ni, Xiaoqian Chen, Guoyu Tian and Zhaojiang Wang*, 
{"title":"Valorization of Corncob Acid Hydrolysis Residue to Glucose and Bio-Polyol by Enzymatic Hydrolysis of Cellulose and Etherification Modification of Lignin","authors":"Chuanyuan Yang,&nbsp;Chuanmin Geng,&nbsp;Yujie Zhang,&nbsp;Xiaojing Jiang,&nbsp;Yingjuan Fu,&nbsp;Menghua Qin,&nbsp;Yongchao Zhang,&nbsp;Shuzhen Ni,&nbsp;Xiaoqian Chen,&nbsp;Guoyu Tian and Zhaojiang Wang*,&nbsp;","doi":"10.1021/acssusresmgt.4c0045810.1021/acssusresmgt.4c00458","DOIUrl":"https://doi.org/10.1021/acssusresmgt.4c00458https://doi.org/10.1021/acssusresmgt.4c00458","url":null,"abstract":"<p >Corncob acid hydrolysis residue (CAHR) is industrial waste and is mostly burned. This work used CAHR to produce sugars for biofuel fermentation, as well as polyols for polyurethane materials. By conditions optimization, cellulose conversion of 75% was attained at enzyme dosages of 10 FPU/g, 2 g/L sodium lignin sulfonate (SLS), 0.3% NaOH, and substrate consistency of 10 wt %. Residues from enzymatic hydrolysis (REH) enzyme dosages at 10, 20, and 30 FPU/g were chemically modified into lignin-based polyol (LP) through an etherification reaction with glycerol and polyethylene glycol. The LP was applied for the fabrication of polyurethane foam. Interestingly, polyurethane foam prepared using REH from 10 FPU/g of cellulase loading had a lower density of 57 kg/m<sup>3</sup>, and a higher compressive strength of 280 kPa. The enzymatic hydrolysis-etherification modification technology greatly enhances the utilization value of CAHR, enabling the full utilization of its components.</p>","PeriodicalId":100015,"journal":{"name":"ACS Sustainable Resource Management","volume":"2 2","pages":"354–361 354–361"},"PeriodicalIF":0.0,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143496238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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