R. Faria, M. Houmard, V. A. M. D. Rosário, V. Lins, L. Heneine, T. Matencio
{"title":"TiO2 Sol-gel Coating as a Transducer Substrate for Impedimetric Immunosensors","authors":"R. Faria, M. Houmard, V. A. M. D. Rosário, V. Lins, L. Heneine, T. Matencio","doi":"10.15255/cabeq.2019.1699","DOIUrl":"https://doi.org/10.15255/cabeq.2019.1699","url":null,"abstract":"R. A. D. de Faria,a,* M. Houmard,b V. A. M. do Rosário,c V. de Freitas Cunha Lins,a L. G. D. Heneine,c and T. Matenciod aDepartment of Chemical Engineering, Universidade Federal de Minas Gerais, Belo Horizonte, MG 31270-90, Brazil bDepartment of Materials and Construction Engineering, Universidade Federal de Minas Gerais, Belo Horizonte, MG 31270-90, Brazil cDepartment of Applied Immunology, Fundação Ezequiel Dias, Belo Horizonte, MG 30510-010, Brazil dDepartment of Chemistry, Universidade Federal de Minas Gerais, Belo Horizonte, MG 31270-90, Brazil","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":"67 3 1","pages":"437-447"},"PeriodicalIF":1.5,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67063753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Nitrogen Removal by HN-AD Bacteria Immobilized on Modified Absorbent Stone","authors":"W. Zhang, Zhen Zhang, Sufeng Wang","doi":"10.15255/cabeq.2020.1823","DOIUrl":"https://doi.org/10.15255/cabeq.2020.1823","url":null,"abstract":"How to simplify the nitrogen removal process, reduce the cost and improve the efficiency has become an urgent problem to be solved. In this research, the isolated HNAD (heterotrophic nitrification and aerobic denitrification) bacteria were used to remove the nitrogen in wastewater. Modified absorbent stone was used as high-efficiency and low-cost immobilized material. The modification effect was determined by the changes in mechanical strength, Zeta potential, pore structure, micrographs and biomass. The practicability of the modified carrier was further proved by experiments of environmental effect and reuse. The modified carrier had excellent performance. By comparing the degradation effects of immobilized microorganism and free microorganism, it was proved that the immobilized microorganisms have broad application prospects and strong adaptability to environmental factors. Under the optimum conditions (temperature of 30 oC, pH of 7, dissolved oxygen of 3.5 mg L–1), the removal efficiency of ammonia nitrogen reached 100 % in 40 hours, the removal efficiency of total nitrogen reached 60.11 % in 50 hours, and the removal rate of total nitrogen was 2.404 mg-NL–1 h–1 by immobilized microorganisms with the treatment of simulated nitrogen-containing wastewater. This research provides new material for the immobilization of HN-AD bacteria and a new way for nitrogen removal.","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":"34 1","pages":"193-207"},"PeriodicalIF":1.5,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67063965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Integrated Treatment of Saline Oily Wastewater Using Sono-Electrokinetic Process, Degradation Mechanism, and Toxicity Assessment","authors":"B. Darabi, T. Tabatabaei, F. Amiri, S. Jorfi","doi":"10.15255/cabeq.2020.1843","DOIUrl":"https://doi.org/10.15255/cabeq.2020.1843","url":null,"abstract":"B. Darabi,a T. Tabatabaei,b,* F. Amiri,c and S. Jorfid,e,* aDepartment of Environmental Engineering, Bushehr Branch, Islamic Azad University, Bushehr, Iran bDepartment of Environmental Engineering, Bushehr Branch, Islamic Azad University, Bushehr, Iran cDepartment of Environmental Engineering, Bushehr Branch, Islamic Azad University, Bushehr, Iran dEnvironmental Technologies Research Center, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran eDepartment of Environmental Health Engineering, School of Health, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":"34 1","pages":"181-191"},"PeriodicalIF":1.5,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67064307","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Simulation and Optimization of Coal Gasification in a Moving-bed Reactor to Produce Synthesis Gas Suitable for Methanol Production Unit","authors":"M. Shamsi, H. A. Ebrahim, M. Azarhoosh","doi":"10.15255/cabeq.2019.1673","DOIUrl":"https://doi.org/10.15255/cabeq.2019.1673","url":null,"abstract":"This paper presents process simulation and optimization of coal gasification process in a moving-bed reactor using Pittsburgh No. 8 coal as feed. The system of differential equations for the mass and energy balances was solved using 4th-order Runge-Kutta method and optimized by non-dominated sorting genetic algorithm-II (NSGA-II) method. The simulation was used to predict solid and gas temperature profile and gas composition along the reactor. The simulation results were compared successfully with experimental data relevant to Westfield plant in Scotland. In addition, the effect of operating parameters such as coal-to-oxygen molar ratio, steam-to-oxygen molar ratio, inlet gas temperature, reactor pressure, and oxygen mole fraction in inlet air on amount of synthesis gas (syngas) production, hydrogen to carbon monoxide molar ratio (HCMR) in produced syngas, and coal conversion was investigated. Finally, the reactor performance was optimized to produce the highest syngas production with a HCMR of two using NSGA-II method.","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":"33 1","pages":"427-435"},"PeriodicalIF":1.5,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67063623","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. Buchmaier, C. Brunner, U. Griesbacher, A. Phan, A. Harvey, G. R. Krishna, B. Nidetzky, B. Muster
{"title":"Oscillatory Flow Bioreactor (OFB) Applied in Enzymatic Hydrolysis at High Solid Loadings","authors":"J. Buchmaier, C. Brunner, U. Griesbacher, A. Phan, A. Harvey, G. R. Krishna, B. Nidetzky, B. Muster","doi":"10.15255/cabeq.2018.1553","DOIUrl":"https://doi.org/10.15255/cabeq.2018.1553","url":null,"abstract":"J. Buchmaier,a,* C. Brunner,a U. Griesbacher,a A. N. Phan,b A. P. Harvey,b R. Krishna Gudiminchi,c B. Nidetzky,c and B. Mustera aIndustrial Processes and Energy Systems, AEE – Institute for Sustainable Technologies, 8200 Gleisdorf, Feldgasse 19, Austria bNewcastle University, Chemical Engineering and Advanced Materials, Newcastle upon Tyne NE1 7RU, United Kingdom cAustrian Center of Industrial Biotechnology, 14 Petersgasse, 8010 Graz, Austria","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":"33 1","pages":"459-470"},"PeriodicalIF":1.5,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67064055","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. Henrique, R. Sousa, A. Secchi, M. Ravagnani, Abdessamad Barbara, C. Costa
{"title":"Divided Wall Column Modeling and Simulation in an Open-Source Environment","authors":"J. Henrique, R. Sousa, A. Secchi, M. Ravagnani, Abdessamad Barbara, C. Costa","doi":"10.15255/cabeq.2020.1824","DOIUrl":"https://doi.org/10.15255/cabeq.2020.1824","url":null,"abstract":"J. P. Henrique,a R. de Sousa Jr.,a,b A. R. Secchi,c M. A. S. S. Ravagnani,d A. Barbara,e and C. B. B. Costad,* aChemical Engineering Graduate Program, Universidade Federal de São Carlos (UFSCar), Rodovia Washington Luís (SP-310), km 235, São Carlos, SP, CEP: 13565-905, Brazil bChemical Engineering Department/UFSCar, Universidade Federal de São Carlos (UFSCar), Rodovia Washington Luís (SP-310), km 235, São Carlos, SP, CEP: 13565-905, Brazil cInstituto Alberto Luiz de Coimbra de Pós-Graduação e Pesquisa de Engenharia, COPPE, Universidade Federal do Rio de Janeiro, UFRJ, Cidade Universitária, Rio de Janeiro, RJ, CEP: 21941-972, Brazil dChemical Engineering Department, Universidade Estadual de Maringá, Av. Colombo, 5790 Bloco D90, CEP 87020-290, Maringá, PR, Brazil eInstitut de Mathématiques de Bourgogne (IMB), Université de Bourgogne, 9 avenue Alain Savary, 21078 Dijon cedex, France","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":"34 1","pages":"149-167"},"PeriodicalIF":1.5,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67064081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of Helichrysum italicum on the Corrosion of Copper in Simulated Acid Rain Solution","authors":"Z. Pilić, Ivana Martinović","doi":"10.15255/cabeq.2019.1614","DOIUrl":"https://doi.org/10.15255/cabeq.2019.1614","url":null,"abstract":"The inhibition of copper corrosion by Helichrysum italicum extract (HI) in simulated acid rain was investigated using electrochemical techniques. Results indicate an increase in corrosion inhibition efficiency with the HI extract concentration. The inhibitive process was assumed to occur via adsorption of the extract on the metal surface. The thermodynamic data indicated physical adsorption and followed the Freundlich isotherm. The effect of temperature on the copper corrosion was studied. The value of the activation energy confirmed physisorption of extract molecules on the copper surface. The concentration of Cu ions released into solution, measured by atomic absorption spectrometry, was in accordance with the electrochemical results.","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":"33 1","pages":"449-457"},"PeriodicalIF":1.5,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67063613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
G. Sangavi, Argho Bakshi, M. Ganapathy, N. Ganesan
{"title":"Adsorption of Reactive Dyes from Aqueous Solution Using Activated Carbon Prepared from Plantain Leaf Sheath Waste","authors":"G. Sangavi, Argho Bakshi, M. Ganapathy, N. Ganesan","doi":"10.15255/cabeq.2020.1826","DOIUrl":"https://doi.org/10.15255/cabeq.2020.1826","url":null,"abstract":"All parts of the plantain are widely used in India for various purposes. But plantain leaf sheath always ends up as waste material which accumulates as a biowaste. The present study focuses on the preparation of activated carbon using phosphoric acid as activating agent, and its efficacy as an adsorbent for the removal of reactive dyes, Reactive Green 19, and Reactive Red 141. Batch adsorption studies have been conducted and optimum adsorption conditions were determined as a function of contact time, initial dye concentration, adsorbent dosage, and pH. The experimental data were analyzed using Langmuir, Freundlich and Temkin isotherm models. The pseudo-first and second-order, intraparticle diffusion, and Elovich models were used to analyze the kinetic parameters of the adsorption system. Under the optimum conditions (initial dye concentration = 200 mg L–1, adsorbent dose = 1 g, pH = 2, contact time = 220 min for reactive green 19 and 180 min for reactive red 141), maximum percentage removal for reactive green 19 and reactive red 141 were obtained as 65.9 % and 72.7 %, respectively. The results demonstrate that activated carbon produced from chemical activation of the plantain waste has the potential of adsorbing reactive dyes from industrial effluents.","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":"34 1","pages":"169-180"},"PeriodicalIF":1.5,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67063674","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Enzymatic Kinetics of Solvent-free Esterification with Bio-imprinted Lipase","authors":"M. Matsumoto, Y. Matsumoto","doi":"10.15255/cabeq.2019.1692","DOIUrl":"https://doi.org/10.15255/cabeq.2019.1692","url":null,"abstract":"To avoid the use of compounds that burden the environment, a solvent-free enzymatic reaction was the focus of this study. Investigated were the catalytic activities and kinetics of lipases that were pretreated with carboxylic acids for the solvent-free esterification of propionic acid with isoamyl alcohol. The enhancements of the esterification yields and rates by the bio-imprinting effects of carboxylic acids were observed. We found no inhibition of isoamyl alcohol on the solvent-free enzymatic esterification, and obtained a large imprinting effect under a largely excessive amount of isoamyl alcohol to propionic acid. From the kinetic analysis, the imprinting of lipases mainly enhanced the catalytic reaction rate constant rather than the affinity between lipase and propionic acid compared with untreated lipase. The bio-imprinting treatment of lipase is found to be very effective for the yield and kinetics in solvent-free esterification.","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":"33 1","pages":"495-499"},"PeriodicalIF":1.5,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67063696","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Lipase-catalyzed Solvent-free Synthesis of Polyglycerol 10 (PG-10) Esters","authors":"Y. Satyawali, L. Cauwenberghs, W. Dejonghe","doi":"10.15255/cabeq.2019.1702","DOIUrl":"https://doi.org/10.15255/cabeq.2019.1702","url":null,"abstract":"Polyglycerol fatty acid esters, which have been widely used as emulsifiers in food, medicine and cosmetics industries, were the subject of solvent-free enzymatic synthesis in this study. There have been previous reports on enzymatic synthesis of various polyglycerol esters; however, this investigation extends the synthesis to PG-10 esters. The effects of substrate molar ratio, addition of emulsifiers to enhance mixing, and addition of molecular sieves or N2 flushing for water removal, was investigated. The solvent-free synthesis using N2 flushing leads to complete conversion of fatty acid, yielding a completely acid free product. The synthesis is validated for polyglycerol laurate and polyglycerol caprylate, both useful products in the cosmetic industry.","PeriodicalId":9765,"journal":{"name":"Chemical and Biochemical Engineering Quarterly","volume":"33 1","pages":"501-509"},"PeriodicalIF":1.5,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67063807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"生物学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}