Chalcogenide Letters最新文献

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Effect of annealing temperature on the structural and optical properties of vacuum evaporated Cu13Se52Bi35 thin films 退火温度对真空蒸发 Cu13Se52Bi35 薄膜结构和光学特性的影响
IF 1 4区 材料科学
Chalcogenide Letters Pub Date : 2024-01-31 DOI: 10.15251/cl.2024.211.99
A. Alwany, A. Alnakhlani, B. Hassan, M. Algradee, R. A. Fouad, A. A. Alfaqeer
{"title":"Effect of annealing temperature on the structural and optical properties of vacuum evaporated Cu13Se52Bi35 thin films","authors":"A. Alwany, A. Alnakhlani, B. Hassan, M. Algradee, R. A. Fouad, A. A. Alfaqeer","doi":"10.15251/cl.2024.211.99","DOIUrl":"https://doi.org/10.15251/cl.2024.211.99","url":null,"abstract":"Thermal evaporation technique was used to prepare Cu13Se52Bi35 thin films. The asdeposited and annealed samples were investigated by using the X-ray diffraction (XRD), scanning electron microscopy (SEM) and optical transmission and reflection. The XRD showed that the as-deposited film is crystalline in nature, and the crystalline size of samples increased with increasing the annealing temperature. SEM images showed that the morphology of the sample changes with the annealing temperature. The direct transition of the optical band gap (Eg) of Cu13Se52Bi35 films was observed and the values of Eg decreased with increasing the annealing temperature. Other optical parameters were also investigated.","PeriodicalId":9710,"journal":{"name":"Chalcogenide Letters","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140475551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Performance of high sensitive heterojunction CuS/porous silicon photodetector 高灵敏度异质结 CuS/多孔硅光电探测器的性能
IF 1 4区 材料科学
Chalcogenide Letters Pub Date : 2024-01-01 DOI: 10.15251/cl.2024.211.81
A. A. Ahmed, G. G. Ali, N. A. Daham
{"title":"Performance of high sensitive heterojunction CuS/porous silicon photodetector","authors":"A. A. Ahmed, G. G. Ali, N. A. Daham","doi":"10.15251/cl.2024.211.81","DOIUrl":"https://doi.org/10.15251/cl.2024.211.81","url":null,"abstract":"In this work, copper sulfide (CuS) nanostructure was deposited on a porous silicon wafer for the visible light by spray pyrolysis method. Through this, a series of devices were suggested as a part of the deposit concentration of CuS on n-type porous silicon. Simultaneously, the physical features of the attained film were illustrated. FESEM exhibited that the average nanoparticle diameter increased with the concentration of CuS at orientation (100) and was found to be 47.84 nm, 56.36nm and 71.32nm, while the average diameter at (111) orientation was found to be 37.64 nm, 41.46nm, 55.22 nm of 0.1, 0.3 and 0.5M respectively. In addition to the atomic force microscope (AFM) showed the roughness and uniformity of the CuS/PSi fabricated decreased with increasing concentration of CuS, In detail, the attained photo-responsivity and specific detectivity were observed to be 210 mW/A, 340 mW/A and 3×1010 Jones, 4.2×1010 Jones at orientation (100 )using concentration of 0.1M and 0.5M respectively . On the other hand, the photo-responsivity and specific detectivity were observed to be 260 mW/A, 380 mW/A and 1.8 ×1010 Jones, 4.5×1010 Jones at orientation (111) using concentrations of 0.1M and 0.5M respectively. The presented work shows a substitutional system for an economical and environmentally friendly optoelectronic scheme. The photo-responsive considered to be in a positive linear relationship with the used concentration.","PeriodicalId":9710,"journal":{"name":"Chalcogenide Letters","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139634120","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Theoretical study on the elastic and thermodynamic properties of CdS 关于 CdS 弹性和热力学性质的理论研究
IF 1 4区 材料科学
Chalcogenide Letters Pub Date : 2024-01-01 DOI: 10.15251/cl.2024.211.39
G. Hao, H. Hou, S. R. Zhang, L. Xie
{"title":"Theoretical study on the elastic and thermodynamic properties of CdS","authors":"G. Hao, H. Hou, S. R. Zhang, L. Xie","doi":"10.15251/cl.2024.211.39","DOIUrl":"https://doi.org/10.15251/cl.2024.211.39","url":null,"abstract":"The physical properties of CdS is calculated by using the first principles pseudopotential plane wave method based on density functional theory (DFT). The calculated lattice parameters and elastic constants agree well with other theoretical values, and the crystal is determined to be structurally stable by the Born mechanical stability condition. The Debye temperature, Grüneisen parameters, heat capacity and thermal expansion coefficient of CdS under high temperature and high pressure were studied successfully by using the quasi-harmonic Debye model. The influence of pressure on thermal expansion coefficient and Debye temperature is greater than that of temperature. The heat capacity decreases with the increase of pressure. At high temperature and high pressure, the heat capacity approaches the Dulong-Petit limit.","PeriodicalId":9710,"journal":{"name":"Chalcogenide Letters","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140525604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
DFT insights on the Be1-xCrxS alloys for optoelectronic and magnetic devices 关于用于光电和磁性器件的 Be1-xCrxS 合金的 DFT 见解
IF 1 4区 材料科学
Chalcogenide Letters Pub Date : 2024-01-01 DOI: 10.15251/cl.2024.211.53
N. Kanwal, M. Ishfaq, S. Aldaghfag, S. Saleem, M. Yaseen
{"title":"DFT insights on the Be1-xCrxS alloys for optoelectronic and magnetic devices","authors":"N. Kanwal, M. Ishfaq, S. Aldaghfag, S. Saleem, M. Yaseen","doi":"10.15251/cl.2024.211.53","DOIUrl":"https://doi.org/10.15251/cl.2024.211.53","url":null,"abstract":"In this work, the electro-optical and magnetic characteristics of Be1-xCrxS (x= 6.25%, 12.5% and 25%) are brought into investigation by employing full potential linearized augmented plane wave (FP-LAPW) scheme designed within density functional theory (DFT). The stability of the Be1-xCrxS alloy is justified by the negative values of formation energy. The band structures and density of states are examined by using GGA functional. Be1-xCrxS compound demonstrates the half-metallic (HM) ferromagnetic behavior for all doping concentrations; spin-up channel reveals the metallic character and other spin version displays the semiconductor (SC) behavior. The values of total magnetic moment (µB) are recorded as 4.0 8.0 and 16.0 µB for corresponding 6.25%, 12.5% and 25%, which mainly arises owing to Cr-3d state. Moreover, optical features including dielectric function ε(ꞷ), reflectivity, refraction, and absorption are explored within range of 0-10 eV. The maximum absorption of incident photons was found in ultraviolet (UV) span which implies their importance for optoelectronic applications. Results reveal that the studied alloy has potential applications in magnetic and optoelectronic gadgets.","PeriodicalId":9710,"journal":{"name":"Chalcogenide Letters","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139631261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Kinetics of thermally induced processes in Ag doped As40Se30Te30 chalcogenide glass 掺银 As40Se30Te30 卤化物玻璃中的热诱导过程动力学
IF 1 4区 材料科学
Chalcogenide Letters Pub Date : 2024-01-01 DOI: 10.15251/cl.2024.211.21
R. Vigi, G. Štrbac, D. Štrbac, O. Bošák, M. Kubliha
{"title":"Kinetics of thermally induced processes in Ag doped As40Se30Te30 chalcogenide glass","authors":"R. Vigi, G. Štrbac, D. Štrbac, O. Bošák, M. Kubliha","doi":"10.15251/cl.2024.211.21","DOIUrl":"https://doi.org/10.15251/cl.2024.211.21","url":null,"abstract":"The processes of glass-transition and crystallization of chalcogenide glass As40Se30Te30 with 5 at.% silver were analyzed using differential scanning calorimetry. The values of glass-transition temperatures and activation energy were determined. Two crystallization processes were also detected and three-dimensional growth. Using non-isoconversional models the activation energies for both processes amounted to 112(2) kJ/mol and 97(2) kJ/mol. Isoconversional models were used to track changes in activation energy. The presence of Te significantly affects the thermal parameters as well as the structure of the glass while the presence of Ag does not significantly change the degree of connectivity of the As40Se30Te30 glass matrix.","PeriodicalId":9710,"journal":{"name":"Chalcogenide Letters","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139637222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Er3+-doped SiO2-TeO2-ZnO-Na2O thin film fabricated by ultrafast laser plasma doping under different ambient atmospheres 在不同环境气氛下通过超快激光等离子体掺杂制备掺杂 Er3+ 的 SiO2-TeO2-ZnO-Na2O 薄膜
IF 1 4区 材料科学
Chalcogenide Letters Pub Date : 2024-01-01 DOI: 10.15251/cl.2024.211.11
S. A. Kamil, G. Jose
{"title":"Er3+-doped SiO2-TeO2-ZnO-Na2O thin film fabricated by ultrafast laser plasma doping under different ambient atmospheres","authors":"S. A. Kamil, G. Jose","doi":"10.15251/cl.2024.211.11","DOIUrl":"https://doi.org/10.15251/cl.2024.211.11","url":null,"abstract":"Er3+-ions doped SiO2-ZnO-Na2O thin films were fabricated using ultrafast laser plasma doping (ULPD) techniques under different ambient atmospheres; vacuum, nitrogen, oxygen and argon gas. The thickness of the layer produced depends on the ambient atmosphere during fabrication. The layer fabricated under a vacuum is the thinnest among all of the samples. In addition, the surface layer for the sample fabricated under a vacuum environment seems to be relatively smoother compared with those of the others. XRD patterns show that all samples are in a mixed amorphous-crystalline phase. All the Raman spectra exhibited a similar pattern, except for the intensity of the Si peak which depended on the thickness of the obtained layer. The PL intensity for each sample corresponds to the amount of Er3+ ions embedded in the doped layer. However, all samples still exhibited silicate-based characteristics, indicating nitrogen in Si3N4 was lost in the form of nitrogen gas during fabrication.","PeriodicalId":9710,"journal":{"name":"Chalcogenide Letters","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139638110","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermodynamic properties of chalcogenide and pnictide ternary tetrahedral semiconductors 瑀和锑三元四面体半导体的热力学性质
IF 1 4区 材料科学
Chalcogenide Letters Pub Date : 2024-01-01 DOI: 10.15251/cl.2024.211.1
S. Pal, D. Sharma, M. Chandra, M. Mittal, P. Singh, M. Lal, A. S. Verma
{"title":"Thermodynamic properties of chalcogenide and pnictide ternary tetrahedral semiconductors","authors":"S. Pal, D. Sharma, M. Chandra, M. Mittal, P. Singh, M. Lal, A. S. Verma","doi":"10.15251/cl.2024.211.1","DOIUrl":"https://doi.org/10.15251/cl.2024.211.1","url":null,"abstract":"In this paper, we present thermodynamic properties such as heat of formation, heat of fusion and entropy of fusion for chalcopyrite structured solids with the product of ionic charges and nearest neighbour distance d (Å). The heat of formation (∆Hf) of these compounds exhibit a linear relationship when plotted on a log-log scale against the nearest neighbour distance d (Å), but fall on different straight lines according to the ionic charge product of the compounds. On the basis of this result two simple heat of formation (∆Hf)heat of fusion (∆HF), and heat of formation (∆Hf)entropy of fusion (∆SF), relationship are proposed and used to estimate the heat of fusion (∆HF) and entropy of fusion (∆SF) of these semiconductors. We have applied the proposed relation to AIIBIVC2 V and AI BIIIC2 VI chalcopyrite semiconductor and found a better agreement with the experimental data than the values found by earlier researchers. The results for heat of formation differ from experimental values by the following amounts: 0.3% (CuGaSe2), 6.7% (CuInSe2), 5% (AgInSe2), 5% (ZnGeP2), 6% (ZnGeP2), 0.4% (ZnSnP2), 0.7% (ZnSiAs2), 2.6% (ZnGeAs2), 1.2% (ZnSnAs2), 3.8% (CdGeP2), 6.4% (CdGeAs2), the results for heat of fusion differ from experimental values by the following amounts: 2.6% (CuGaS2), 0.6% (CuInTe2), 6% (ZnGeAs2), 8.8% (ZnSiAs2) and the results for entropy of fusion differ from experimental values by the following amounts: 6% (CuInSe2), 8% (CdSiP2).","PeriodicalId":9710,"journal":{"name":"Chalcogenide Letters","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139638718","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermal stability and crystallization kinetic of Se-Te-Ag glassy alloys and thick films for electronic devices 用于电子设备的硒-碲-银玻璃合金和厚膜的热稳定性和结晶动力学
IF 1 4区 材料科学
Chalcogenide Letters Pub Date : 2024-01-01 DOI: 10.15251/cl.2024.211.65
K. I. Hussain, A. Ashour, E. S. Yousef, E. R. Shaaban
{"title":"Thermal stability and crystallization kinetic of Se-Te-Ag glassy alloys and thick films for electronic devices","authors":"K. I. Hussain, A. Ashour, E. S. Yousef, E. R. Shaaban","doi":"10.15251/cl.2024.211.65","DOIUrl":"https://doi.org/10.15251/cl.2024.211.65","url":null,"abstract":"The present work has examined the thermal features of glassy chacogenide materials Se0.75-xTe0.25Agx (x = 0, 2, 4, 6, 8, 10 at %). The thermal stability of these compositions has been assessed under non-isothermal conditions using Differential Scanning Calorimetry (DSC), which has been used to find the glass transition temperature (Tg), the initial crystallization temperature (Tin), the temperature corresponding to the top of the crystallization rate (Tp), and the melting temperature (Tm). In addition, the kinetic parameter Kr(T) was given as an additional sign of thermal stability. Among these compositions, it was discovered that Se0.71Te0.25Ag0.04 had the best glass-forming ability and glass-thermal stability. The average coordination numbers of the considered samples have been discussed in relation to these results. Additionally, we measured the sheet resistivity, ρ, whose thickness is equivalent to 1000 nm at heating rate 5 K/min, in this work to study the crystallization kinetics of thick films of Se0.75-xTe0.25Agx (x = 0, 2, 4, 6, 8, 10 at %) in the temperature range of 300 to 625 K. This range was sufficient to draw attention to two substantial areas in the resistivity versus temperature curve, and the derivation of resistivity as a function of temperature established that the films under study only had one crystallization region.","PeriodicalId":9710,"journal":{"name":"Chalcogenide Letters","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140518891","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancement efficiency of cadmium selenium solar cell by doping within silver 银内掺杂提高镉硒太阳能电池效率
4区 材料科学
Chalcogenide Letters Pub Date : 2023-11-10 DOI: 10.15251/cl.2023.2010.733
M. H. Mustafa, H. M. Ali, G. S. Ahmed, B. H. Hussein
{"title":"Enhancement efficiency of cadmium selenium solar cell by doping within silver","authors":"M. H. Mustafa, H. M. Ali, G. S. Ahmed, B. H. Hussein","doi":"10.15251/cl.2023.2010.733","DOIUrl":"https://doi.org/10.15251/cl.2023.2010.733","url":null,"abstract":"We studied at the morphology, structural setup, and optical characteristics of thin cadmium (CdSe) films a thickness of 250 nm that were created by thermal evaporation over glass, The films exhibited a hexagonal shape were crystalline, and tended to form grains in the (111) crystallographic direction, according to the X-ray diffraction examinations. These characteristics were established using the investigation's findings. Through the use of thin films of CdSe doped with Ag at a concentration of 1.5%, the crystal structure orientations for pure CdSe (25.32, 41.84) and CdSe:Ag (25.39, 41.01) that were both pure as well as those that were doped with silver were both determined. The band gap of the optical spectrum decreased by 1.93–1.81 eV (300–700 nm). This reduced the rate of absorption measuring the current-voltage properties of heterojunctions made from a range of clean and doped materials with an incident electrical power density of (100 mW/cm2 ). The films' hexagonal structure was revealed by the X-ray investigation, and grain development was driven by the (220,111) crystallographic direction.","PeriodicalId":9710,"journal":{"name":"Chalcogenide Letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135091780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of structural, morphological and optical properties of Mn+2 doped CdS nanoparticles synthesized at various doping concentration 不同掺杂浓度下Mn+2掺杂CdS纳米颗粒的结构、形态和光学性质研究
4区 材料科学
Chalcogenide Letters Pub Date : 2023-11-10 DOI: 10.15251/cl.2023.2010.709
R. Ranjan, C. M. S. Negi, S. K. Choubey, K. P. Tiwary
{"title":"Study of structural, morphological and optical properties of Mn+2 doped CdS nanoparticles synthesized at various doping concentration","authors":"R. Ranjan, C. M. S. Negi, S. K. Choubey, K. P. Tiwary","doi":"10.15251/cl.2023.2010.709","DOIUrl":"https://doi.org/10.15251/cl.2023.2010.709","url":null,"abstract":"Manganese-doped cadmium sulphide semiconductor nanoparticles (CdS: Mn) NPs have been created utilizing a microwave-assisted solvothermal technique at different Mn concentrations (0, 1%, 3%, and 5%). The chemicals utilized for the preparation of Mndoped CdS nanoparticles were sodium sulphide (Na2S.xH2O), manganese chloride (MnCl2.4H2O), and cadmium acetate (CH3COO)2Cd., H2O). To determine the structural dimensions of the generated nanoparticles, the Debye-Scherer equation was used to calculate the average crystallite size at the full-width half maximum (FWHM) of the diffraction peaks. FTIR spectra analysis was used to look at the various functional and vibrational groups present in the Mn-doped CdS nanoparticle sample. The structure features of the produced nanoparticles have been examined using X-ray diffraction patterns. Energy dispersive X-rays were employed to ascertain the chemical composition of the synthesized nanoparticles. The optical properties and quantification of the energy band gap of the nanoparticles have been done using UV-V spectroscopy. According to XRD calculations, the cubic zinc-blend structure of the generated NPs had a crystal size of between 4 and 7 nm. By using EDX spectroscopy, the incorporation of Mn at the CdS lattice was confirmed.","PeriodicalId":9710,"journal":{"name":"Chalcogenide Letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135091783","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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