Canadian Journal of Chemical Engineering最新文献

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IF 1.6 4区 工程技术
Canadian Journal of Chemical Engineering Pub Date : 2025-04-15 DOI: 10.1002/cjce.25327
{"title":"Issue Highlights","authors":"","doi":"10.1002/cjce.25327","DOIUrl":"https://doi.org/10.1002/cjce.25327","url":null,"abstract":"","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 5","pages":"1939"},"PeriodicalIF":1.6,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143836274","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Issue Highlights 问题突出
IF 1.6 4区 工程技术
Canadian Journal of Chemical Engineering Pub Date : 2025-03-09 DOI: 10.1002/cjce.25325
{"title":"Issue Highlights","authors":"","doi":"10.1002/cjce.25325","DOIUrl":"https://doi.org/10.1002/cjce.25325","url":null,"abstract":"","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 4","pages":"1463"},"PeriodicalIF":1.6,"publicationDate":"2025-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143581780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of nozzle shape on bubble column reactor with constant flow rate 喷嘴形状对恒流量气泡塔反应器的影响
IF 1.6 4区 工程技术
Canadian Journal of Chemical Engineering Pub Date : 2025-02-24 DOI: 10.1002/cjce.25624
Sachin Kumar, Raj Kumar Singh, Bahni Ray
{"title":"Effect of nozzle shape on bubble column reactor with constant flow rate","authors":"Sachin Kumar,&nbsp;Raj Kumar Singh,&nbsp;Bahni Ray","doi":"10.1002/cjce.25624","DOIUrl":"https://doi.org/10.1002/cjce.25624","url":null,"abstract":"<p>The present investigation is focused on the bubble formation from different shaped nozzles: straight nozzle, straight converging nozzle, straight diverging nozzle, converging nozzle, and submerged nozzle, with a constant flow rate of 0.008 m/s and static contact angle of 45°, respectively. The effective dimension of the nozzle has been taken as 2 mm radius and 3 mm height. The impact of varying nozzle shapes on changes in bubble volume and the occurrence of different pinch-off times have been observed. A maximum pinch-off time of 1.854 s on straight nozzle and minimum of 0.078 s on converge nozzle with bubble volumes 111.36 mm<sup>3</sup> and 62.12 mm<sup>3</sup> was obtained. Maximum bubble volume attained from diverging nozzle was 123.21 mm<sup>3</sup> with optimum pinch-off time, which is highly useful for bioreactor application.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 8","pages":"4051-4064"},"PeriodicalIF":1.6,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144551336","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental investigation of spreading dynamics of glycerol droplets on a heated surface 甘油液滴在受热表面扩散动力学的实验研究
IF 1.6 4区 工程技术
Canadian Journal of Chemical Engineering Pub Date : 2025-02-18 DOI: 10.1002/cjce.25652
Merve Durubal, Martijn Munck, Kay Buist, J. A. M. (Hans) Kuipers, Maike Baltussen
{"title":"Experimental investigation of spreading dynamics of glycerol droplets on a heated surface","authors":"Merve Durubal,&nbsp;Martijn Munck,&nbsp;Kay Buist,&nbsp;J. A. M. (Hans) Kuipers,&nbsp;Maike Baltussen","doi":"10.1002/cjce.25652","DOIUrl":"https://doi.org/10.1002/cjce.25652","url":null,"abstract":"<p>The dynamics of droplets impacting on solid surfaces are widely encountered in industrial applications. This paper presents an experimental study of the spreading dynamics of droplets of liquids with a temperature-dependent viscosity on a heated horizontal sapphire surface. This surface can be heated between 40 and 90°C and allows for usual observation from different directions. The used liquids are glycerol water solutions with a volume percentage of 80%, 85.2%, and 92.8% glycerol, which feature a large dependency of the viscosity on the temperature. Using high-speed imaging and infrared thermography, the shape of the droplet and the temperature of the droplet surface in contact with the surface are measured, respectively. Our experiments reveal that the spreading of the droplets increases with an increase in the surface temperature, which is also expected as the effective viscosity of the liquid will decrease with an increase in the droplet temperature. However, the heating of the droplets ensures that these effects only are apparent after sufficient time to heat the droplet. In addition, the amplitude of the oscillations in the spreading of the surface will increase when the temperature of the surface is increased, which is also related to the decreased viscosity. Finally, the effects on the local spreading cannot be directly correlated to the temperature of the droplet in contact with the surface, which indicates that the viscosity in the droplet is not homogeneous during the experiment and local gradients in the viscosity are important in the overall spreading behaviour of the droplet.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 8","pages":"3971-3982"},"PeriodicalIF":1.6,"publicationDate":"2025-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cjce.25652","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144551342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Data-driven deep learning prediction of full molecular weight distribution in polymerization processes 聚合过程中全分子量分布的数据驱动深度学习预测
IF 1.6 4区 工程技术
Canadian Journal of Chemical Engineering Pub Date : 2025-02-18 DOI: 10.1002/cjce.25635
Dante Mora-Mariano, Antonio Flores-Tlacuahuac, Iván Zapata-González, Enrique Saldívar-Guerra
{"title":"Data-driven deep learning prediction of full molecular weight distribution in polymerization processes","authors":"Dante Mora-Mariano,&nbsp;Antonio Flores-Tlacuahuac,&nbsp;Iván Zapata-González,&nbsp;Enrique Saldívar-Guerra","doi":"10.1002/cjce.25635","DOIUrl":"https://doi.org/10.1002/cjce.25635","url":null,"abstract":"<p>The mathematical modelling of the full molecular weight distribution (MWD) results in a large set of ordinary differential equations (ODEs), which usually requires considerable computation time because of stiffness behaviour. This study applies state-of-the-art deep learning (DL) methods to model three academically and industrially relevant polymerization processes: free radical polymerization (FRP), reversible addition–fragmentation (RAFT), and coordination catalyst polymerization (CCP). The DL models were trained with datasets generated from the numerical solution of the first principles kinetic model of each polymerization process. Then, the applied DL models were used to predict the conversion rate, average molar weights, and molecular weight distributions with minimum deviations and reduced computational load. Therefore, by reducing the large computational load, this type of DL models can make feasible the application of on-line optimal control strategies to complex and economically important polymerization processes.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 8","pages":"3713-3725"},"PeriodicalIF":1.6,"publicationDate":"2025-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144551341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Challenges and influencing factors in microalgae harvesting using crossflow membrane technology 交叉流膜技术收获微藻的挑战及影响因素
IF 1.6 4区 工程技术
Canadian Journal of Chemical Engineering Pub Date : 2025-02-16 DOI: 10.1002/cjce.25628
Jie Bao, John Ashley Scott, Corey Alfred Laamanen
{"title":"Challenges and influencing factors in microalgae harvesting using crossflow membrane technology","authors":"Jie Bao,&nbsp;John Ashley Scott,&nbsp;Corey Alfred Laamanen","doi":"10.1002/cjce.25628","DOIUrl":"https://doi.org/10.1002/cjce.25628","url":null,"abstract":"<p>As a result of the renewable nature of microalgae, combined with significant potential for application in various industries (such as bioenergy and nutrition), there is increasing interest in their commercial production. A key processing step is harvesting the microalgae and utilization of crossflow membrane technology is gaining interest. Published research shows biomass recoveries of 93%–100%, relatively low energy consumption, and the option to avoid chemical additives. This review discusses membrane harvesting performance, by examining the effect of microalgal physical characteristics, membrane and module types, and operational conditions. As membrane fouling is a major challenge to maintaining good performance, different strategies to control and mitigate fouling are also discussed.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 8","pages":"3911-3922"},"PeriodicalIF":1.6,"publicationDate":"2025-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cjce.25628","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144551274","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of a bio-xerogel from Kraft black liquor and tannin: Crosslinker analysis and property assessment 以牛皮纸黑液和单宁为原料制备生物干凝胶的交联分析及性能评价
IF 1.6 4区 工程技术
Canadian Journal of Chemical Engineering Pub Date : 2025-02-14 DOI: 10.1002/cjce.25619
Wardleison Martins Moreira, Paula Valéria Viotti, Sirlei Marques Paschoal, Cristina Maria dos Santos Gaudêncio Baptista, Marcelino Luiz Gimenes
{"title":"Development of a bio-xerogel from Kraft black liquor and tannin: Crosslinker analysis and property assessment","authors":"Wardleison Martins Moreira,&nbsp;Paula Valéria Viotti,&nbsp;Sirlei Marques Paschoal,&nbsp;Cristina Maria dos Santos Gaudêncio Baptista,&nbsp;Marcelino Luiz Gimenes","doi":"10.1002/cjce.25619","DOIUrl":"https://doi.org/10.1002/cjce.25619","url":null,"abstract":"<p>The increasing environmental impact of industrial waste has driven the search for new synthesis routes utilizing natural precursors. This study explores the production of a biobased polymer from crude Kraft black liquor and condensed tannin, crosslinked with less toxic aldehydes such as furfural and glyoxal, as alternatives to formaldehyde. The synthesized bio-xerogels demonstrated varying viscosities and physical properties depending on the tannin content and type of crosslinker used. Results indicated that furfural-based formulations successfully gelled and exhibited superior mechanical strength and stability compared to formaldehyde ones. The study highlights the feasibility of using lignin-rich industrial by-products and natural phenolic compounds to develop sustainable, high-performance materials. This contributes to achieving sustainable development goals (SDGs) and offers potential applications in various environmental, medical, and industrial sectors.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 8","pages":"3589-3610"},"PeriodicalIF":1.6,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144551305","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis of biomass as a feedstock in a chemical looping-based polygeneration process for CO2 valorization 生物质作为原料在基于化学环的多代过程中的CO2增值分析
IF 1.6 4区 工程技术
Canadian Journal of Chemical Engineering Pub Date : 2025-02-10 DOI: 10.1002/cjce.25615
Nimish Pankhedkar, Sushma Sunkara, Abhishek Dwivedi, Ravindra Gudi, Pratim Biswas, Suresh Bhargava
{"title":"Analysis of biomass as a feedstock in a chemical looping-based polygeneration process for CO2 valorization","authors":"Nimish Pankhedkar,&nbsp;Sushma Sunkara,&nbsp;Abhishek Dwivedi,&nbsp;Ravindra Gudi,&nbsp;Pratim Biswas,&nbsp;Suresh Bhargava","doi":"10.1002/cjce.25615","DOIUrl":"https://doi.org/10.1002/cjce.25615","url":null,"abstract":"<p>From the viewpoint of circular economy, the utilization of biomass as a preferred feedstock for power generation with carbon capture has become prevalent. Biomass utilization leads to a carbon-neutral balance by leveraging its inherent carbon that was absorbed from the atmosphere. While chemical looping combustion (CLC) is a promising carbon capture technology for solid fuels such as coal, this paper further explores the feasibility of using biomass in CLC along with valorization of CO<sub>2</sub> to valuable chemicals. A polygeneration approach utilizing biomass has been proposed to produce power and value-added chemicals (methanol and dimethyl ether [DME]), thus yielding an integrated CO<sub>2</sub> capture and utilization system. Biomass has a significant amount of oxygen and a higher H:C ratio than conventional fuels like coal. The effect of the same has been analyzed by assessing biomass as a feedstock in the proposed process and evaluating the effect of higher oxygen content towards the objective of CO<sub>2</sub> valorization relative to that of coal. Furthermore, a comparative discussion of the suitability of biomass compared to coal from a valorization perspective has been presented. Detailed techno-feasibility analysis on the schemes and optimization studies to maximize the performance of the system in terms of energetics, CO<sub>2</sub> mitigation, and profitability has been conducted. From the analysis, it has been identified that the utilization of biomass as a feedstock in CLC-based processes results in higher chemical production rates and higher profits with lesser CO<sub>2</sub> emissions than coal. The above analysis and evaluation has been carried out through simulations using Aspen Plus® software.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 8","pages":"3568-3588"},"PeriodicalIF":1.6,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144551101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption and the subsequent desorption of lactic acid molecules on zirconium metal-organic frameworks: An innovative and efficient approach for the recovery of the produced lactic acid from fermentation broth 乳酸分子在金属锆有机框架上的吸附和随后的解吸:一种从发酵液中回收产生的乳酸的创新和有效的方法
IF 1.6 4区 工程技术
Canadian Journal of Chemical Engineering Pub Date : 2025-02-06 DOI: 10.1002/cjce.25616
Mohammad Saeed Rahimi, Mehri Esfahanian
{"title":"Adsorption and the subsequent desorption of lactic acid molecules on zirconium metal-organic frameworks: An innovative and efficient approach for the recovery of the produced lactic acid from fermentation broth","authors":"Mohammad Saeed Rahimi,&nbsp;Mehri Esfahanian","doi":"10.1002/cjce.25616","DOIUrl":"https://doi.org/10.1002/cjce.25616","url":null,"abstract":"<p>Nowadays, biomass-derived lactic acid serves as a significant foundational chemical in the pursuit of sustainable production of various materials. Nevertheless, the current fermentation process faces limitations due to the challenging retrieval of the lactic acid product from the fermentation broth, resulting in the production of gypsum waste in stoichiometric quantities. In this work, we demonstrate the efficacy of Zr-UiO-66 metal–organic frameworks (MOFs) as effective adsorbents in the process of recovery of lactic acid from the fermentation broth. The MOF beads have been manufactured successfully and were applied to recover lactic acid from the solution and the experimental conditions were optimized. The results show that Zr-UiO-66 adsorbent has a good ability of up to 98.8% to adsorb the produced lactic acid from its fermentation broth at a pH value of 6.5, adsorbent (MOF) dosage of 0.625 g, an initial concentration of 15 mg/L, temperature of 298 K, within process time of 4 h. The data obtained from the adsorption process demonstrated a satisfactory fit with the Langmuir isotherm model (with a <i>R</i><sup>2</sup> of 0.958), kinetics (with a <i>R</i><sup>2</sup> of 0.970), and thermodynamic results, confirming the spontaneous and exothermic nature of the adsorption process. The regeneration experiment of the MOF beads showed that the adsorption efficiency of Zr-UiO-66 remained above 90% even after undergoing seven cycles.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 8","pages":"3940-3954"},"PeriodicalIF":1.6,"publicationDate":"2025-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144551097","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental methods in chemical engineering: Virtual issue II preface 化学工程中的实验方法:虚拟第II期前言
IF 1.6 4区 工程技术
Canadian Journal of Chemical Engineering Pub Date : 2025-02-06 DOI: 10.1002/cjce.25632
Gregory S. Patience
{"title":"Experimental methods in chemical engineering: Virtual issue II preface","authors":"Gregory S. Patience","doi":"10.1002/cjce.25632","DOIUrl":"https://doi.org/10.1002/cjce.25632","url":null,"abstract":"","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 5","pages":"1940-1944"},"PeriodicalIF":1.6,"publicationDate":"2025-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cjce.25632","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143835960","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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