Journal of hazardous materials letters最新文献

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Understanding arsenic toxicity: Implications for environmental exposure and human health 了解砷毒性:对环境暴露和人类健康的影响
Journal of hazardous materials letters Pub Date : 2023-11-04 DOI: 10.1016/j.hazl.2023.100090
Ravidarshdeep kaur , Atul Garkal , Lopmudra Sarode , Priyanka Bangar , Tejal Mehta , Dhirendra Pratap Singh , Rakesh Rawal
{"title":"Understanding arsenic toxicity: Implications for environmental exposure and human health","authors":"Ravidarshdeep kaur ,&nbsp;Atul Garkal ,&nbsp;Lopmudra Sarode ,&nbsp;Priyanka Bangar ,&nbsp;Tejal Mehta ,&nbsp;Dhirendra Pratap Singh ,&nbsp;Rakesh Rawal","doi":"10.1016/j.hazl.2023.100090","DOIUrl":"10.1016/j.hazl.2023.100090","url":null,"abstract":"<div><p>Arsenic is a trace element and a metalloid which is prominently known as an environmental hazard. At present, rising health apprehensions are linked to emanating from a wide array of industrial, chemical, residential, agricultural, and technological sources, leading to extensive pollution of water, soil, and air ecosystems including flora, fauna and humans. It poses significant harm to biological organisms upon acute and chronic exposure. In this review, we delve into the reported experimental data that elaborates on arsenic as a toxicant, with particular emphasis on its occurrence, metabolism and diverse molecular mechanisms involved. It also includes the major molecular mechanisms leading to systemic toxicity with special emphasis on shedding light on the intricate ways it disrupts the nervous system.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"5 ","pages":"Article 100090"},"PeriodicalIF":0.0,"publicationDate":"2023-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911023000163/pdfft?md5=834a86ea1d64b7090a225e5b2f8fa1f7&pid=1-s2.0-S2666911023000163-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135455184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Burning questions: Current practices and critical gaps in evaluating removal of per- and polyfluoroalkyl substances (PFAS) during pyrolysis treatments of biosolids. 亟待解决的问题:评估生物固体热解处理过程中全氟烷基和多氟烷基物质(PFAS)去除率的现行做法和关键差距。
Journal of hazardous materials letters Pub Date : 2023-11-01 DOI: 10.2139/ssrn.4369128
J. S. Wallace, Dulan Edirisinghe, S. Seyedi, Haley Noteboom, Micah Blate, Derya Dursun Balci, Mohammad Abu-Orf, R. Sharp, Jeanette A. Brown, D. Aga
{"title":"Burning questions: Current practices and critical gaps in evaluating removal of per- and polyfluoroalkyl substances (PFAS) during pyrolysis treatments of biosolids.","authors":"J. S. Wallace, Dulan Edirisinghe, S. Seyedi, Haley Noteboom, Micah Blate, Derya Dursun Balci, Mohammad Abu-Orf, R. Sharp, Jeanette A. Brown, D. Aga","doi":"10.2139/ssrn.4369128","DOIUrl":"https://doi.org/10.2139/ssrn.4369128","url":null,"abstract":"Concerns surrounding potential health and environmental impacts of per- and polyfluoroalkyl substances (PFAS) are growing at tremendous rates because adverse health impacts are expected with trace-level exposures. Extreme measures are required to mitigate potential PFAS contamination and minimize exposures. Extensive PFAS use results in the release of diverse PFAS species from domestic, industrial, and municipal effluents to wastewater, which partition to biosolids throughout secondary treatment. Biosolids generated during municipal wastewater treatment are a major environmental source of PFAS due to prevailing disposal practices as fertilizers. Pyrolysis is emerging as a viable, scalable technology for PFAS removal from biosolids while retaining nutrients and generating renewable, raw materials for energy generation. Despite early successes of pyrolysis in PFAS removal, significant unknowns remain about PFAS and transformation product fates in pyrolysis products and emissions. Applicable PFAS sampling methods, analytical workflows, and removal assessments are currently limited to a subset of high-interest analytes and matrices. Further, analysis of exhaust gases, particulate matter, fly ashes, and other pyrolysis end-products remain largely unreported or limited due to cost and sampling limitations. This paper identifies critical knowledge gaps on the pyrolysis of biosolids that must be addressed to assess the effectiveness of PFAS removal during pyrolysis treatment.","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"4 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45304781","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Utilization of phosphogypsum in phenol removal from coking wastewater 磷石膏在焦化废水除酚中的应用
Journal of hazardous materials letters Pub Date : 2023-11-01 DOI: 10.1016/j.hazl.2023.100089
Dmytro Yelatontsev
{"title":"Utilization of phosphogypsum in phenol removal from coking wastewater","authors":"Dmytro Yelatontsev","doi":"10.1016/j.hazl.2023.100089","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100089","url":null,"abstract":"<div><p>The paper presents the results of the application of raw phosphogypsum as an adsorbent for the preliminary treatment of coke-chemical wastewater with an initial concentration of phenol 395 mg/L. Studies in batch mode have proved that phenol removal is promoted by increasing the adsorbent dose and effluent temperature, the optimal phosphogypsum dose was found to be 5 g/L. The adsorption kinetics follows a pseudo-first-order model, the maximum adsorption capacity of phosphogypsum reaches 85 mg/g, which provides purification from phenol at the level of 85–90%. The process is spontaneous and endothermic. In column mode, at an effluent flow rate of 3 mL/min and the height of the fixed bed of 15 mm adsorbent dynamic capacity reached 124 mg/g. The obtained data indicate that raw phosphogypsum, available in huge quantities in the dumps of phosphoric acid plants, can be effectively used for the pretreatment of phenolic wastewater before biological treatment.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"4 ","pages":"Article 100089"},"PeriodicalIF":0.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911023000151/pdfft?md5=1cff6d96123d0f2dd933115837d7dd63&pid=1-s2.0-S2666911023000151-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91986616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characteristics and risk assessment of microplastic mediated heavy metal transport in black clam Villorita cyprinoides from a Ramsar wetland of South India 南印度拉姆萨尔湿地黑蛤(Villorita cyprinoides)微塑料介导的重金属迁移特征及风险评估
Journal of hazardous materials letters Pub Date : 2023-11-01 DOI: 10.1016/j.hazl.2023.100092
Prachi Siddharth Bagde , Rini Mathew , Roshna Jose , K. Ranjeet , V.G. Nikhil
{"title":"Characteristics and risk assessment of microplastic mediated heavy metal transport in black clam Villorita cyprinoides from a Ramsar wetland of South India","authors":"Prachi Siddharth Bagde ,&nbsp;Rini Mathew ,&nbsp;Roshna Jose ,&nbsp;K. Ranjeet ,&nbsp;V.G. Nikhil","doi":"10.1016/j.hazl.2023.100092","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100092","url":null,"abstract":"<div><p>The synergetic and interactive effects of microplastics (MPs) as potential carriers of pollutants and pathogens have a manifold impact on human health and aquatic biota. The present study delineates the role of MPs in transporting heavy metals to the black clam, <em>Villorita cyrpinoides</em> of Vembanad Lake in South India. MPs in water (3.41 ± 1.87 items/L), sediment (154.6 ± 45.4 items/kg) and within clams (0.87 ± 0.34 items/g tissue) showed considerable variation based on their physical and chemical characteristics, which in turn reflected its differential potential to carry heavy metals. Though the levels of heavy metals (Al, Fe, Mn, Zn, Cr, Pb) within the clam and those carried by MPs were less than the hazardous limits, the concentration of Cd within the clam and MP was found to have a positive correlation. Though the present levels of heavy metal pollution in the lake do not pose a direct threat to humans, anthropogenic interventions and reduced water flow have turned the lower reaches of the lake into a sink of heavy metals. Hence with MP concentration increasing it is worth investigating how their future interactions with heavy metals and other pollutants would pose a risk to living organisms.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"4 ","pages":"Article 100092"},"PeriodicalIF":0.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911023000187/pdfft?md5=d23d499b9715fbdbda2652daad3f8eeb&pid=1-s2.0-S2666911023000187-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91985831","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Revising the EPA Dilution-Attenuation Soil Screening Model for PFAS. PFAS中EPA稀释衰减筛分模型的修正。
Journal of hazardous materials letters Pub Date : 2023-11-01 Epub Date: 2023-03-20 DOI: 10.1016/j.hazl.2023.100077
Mark L Brusseau, Bo Guo
{"title":"Revising the EPA Dilution-Attenuation Soil Screening Model for PFAS.","authors":"Mark L Brusseau, Bo Guo","doi":"10.1016/j.hazl.2023.100077","DOIUrl":"10.1016/j.hazl.2023.100077","url":null,"abstract":"<p><p>Per and polyfluoroalkyl substances (PFAS) have been shown to be ubiquitous in the environment, and one issue of critical concern is the leaching of PFAS from soil to groundwater. The risk posed by contaminants present in soil is often assessed in terms of the anticipated impact to groundwater through the determination of soil screening levels (SSLs). The U.S. Environmental Protection Agency (EPA) established a soil screening model for determining SSLs. However, the model does not consider the unique retention properties of PFAS and, consequently, the SSLs established with the model may not represent the actual levels that are protective of groundwater quality. The objective of this work is to revise the standard EPA SSL model to reflect the unique properties and associated retention behavior of PFAS. Specifically, the distribution parameter used to convert soil porewater concentrations to soil concentrations is revised to account for adsorption at the air-water interface. Example calculations conducted for PFOS and PFOA illustrate the contrasting SSLs obtained with the revised and standard models. A comparison of distribution parameters calculated for a series of PFAS of different chain length shows that the significance of air-water interfacial adsorption can vary greatly as a function of the specific PFAS. Therefore, the difference between SSLs calculated with the revised versus standard models will vary as a function of the specific PFAS, with greater differences typically observed for longer-chain PFAS. It is anticipated that this revised model will be useful for developing improved SSLs that can be used to enhance site investigations and management for PFAS-impacted sites.</p>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10662647/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"54420984","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Improved microbial reduction of biogenic and abiogenic goethite by diesel soot 改进了柴油烟尘对生物和非生物针铁矿的微生物还原
Journal of hazardous materials letters Pub Date : 2023-11-01 DOI: 10.1016/j.hazl.2023.100091
Huali Yu , Zikang Guo , Guangfei Liu , Lianfeng Wang , Haiyan Guo , Ruofei Jin , Jiti Zhou
{"title":"Improved microbial reduction of biogenic and abiogenic goethite by diesel soot","authors":"Huali Yu ,&nbsp;Zikang Guo ,&nbsp;Guangfei Liu ,&nbsp;Lianfeng Wang ,&nbsp;Haiyan Guo ,&nbsp;Ruofei Jin ,&nbsp;Jiti Zhou","doi":"10.1016/j.hazl.2023.100091","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100091","url":null,"abstract":"<div><p>The biogeochemical cycling of iron is crucial to plenty of environmental processes, and is often influenced by black carbon with high electrical conductivity and abundant functional groups. This study for the first time revealed that diesel particulate matter (DPM), a typical black carbon material which often caused serious environmental effects, could significantly promote dissimilatory reduction of both abiogenic and biogenic goethite (CGt and BGt) by <em>Shewanella oneidensis</em> MR-1. In 7 days, Fe(II) production in CGt systems containing 0.5, 5, 10, 25, and 50 mg/L of DPM were 1.2, 1.3, 1.8, 1.9, and 2.7 folds higher than that in the system without DPM (0.12 mM), respectively. During the bioreduction of BGt, Fe(II) concentrations were 2.4–3.4 folds higher than those in the CGt systems, and were increased by 4.8%− 41.7% with the addition of 0.5–50 mg/L DPM. X-ray diffraction (XRD) analysis demonstrated that goethite was the sole mineralized product during the bioreduction of CGt, while vivianite appeared gradually during the microbial transformation of BGt. DPM enhanced electron transfer between cells and goethite via serving as electron shuttles. The results of this study would improve our understanding of interactions among microbes, natural minerals, and black carbon in the natural environments.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"4 ","pages":"Article 100091"},"PeriodicalIF":0.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911023000175/pdfft?md5=2f20c4689bc9dcd2dcef24986ca5a081&pid=1-s2.0-S2666911023000175-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91986615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Particle size matters: Discrepancies in the health risks posed by traditional cigarettes and e-cigarettes in mice and humans 颗粒大小很重要:传统香烟和电子烟对小鼠和人类健康风险的差异
Journal of hazardous materials letters Pub Date : 2023-10-15 DOI: 10.1016/j.hazl.2023.100088
Li-Ti Chou , Tsai-Ling Chen , Kai-Chien Yang , Hsiao-Chi Chuang , Ying-Jiun Chen , Ching-Huang Lai , Ta-Chih Hsiao
{"title":"Particle size matters: Discrepancies in the health risks posed by traditional cigarettes and e-cigarettes in mice and humans","authors":"Li-Ti Chou ,&nbsp;Tsai-Ling Chen ,&nbsp;Kai-Chien Yang ,&nbsp;Hsiao-Chi Chuang ,&nbsp;Ying-Jiun Chen ,&nbsp;Ching-Huang Lai ,&nbsp;Ta-Chih Hsiao","doi":"10.1016/j.hazl.2023.100088","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100088","url":null,"abstract":"<div><p>Electronic cigarettes (ECs), considered a healthier alternative to traditional cigarettes (TCs), vaporize e-liquid, which may produce harmful by-products due to thermal decomposition and metal transfer. These by-products' deposition in the respiratory tract is largely determined by particle size distribution (PSD). We employ the Multiple-Path Particle Dosimetry (MPPD) model to assess particle deposition within the human and mouse respiratory tracts. Leveraging the known connection between TC smoke inhalation and atherosclerosis, we used human aortic endothelial cells (HAECs) and ApoE<sup>-/-</sup> mice to explore the potential effects of EC aerosol inhalation on atherosclerosis. Our findings reveal that TCs exhibit a highly variable PSD, with mean diameters of approximately 300 nm for mainstream (MS) smoke and 120 nm for side stream (SS) smoke. Conversely, ECs demonstrate a more stable PSD. Combined with MPPD, the deposition fraction in the human respiratory system and mice is mainly deposited in the pulmonary region and head airway. For the Apoe<sup>-/-</sup> mice exposure experiment, preliminary findings suggest a potential impact on atherosclerosis, although not statistically significant, likely due to the limited sample size and exposure duration. This study highlights the importance of considering PSD, exposure dosage, and species-specific differences in risk assessments of EC aerosols.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"4 ","pages":"Article 100088"},"PeriodicalIF":0.0,"publicationDate":"2023-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49859225","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A critical review on In2S3-based nanomaterial for emerging contaminants elimination through integrated adsorption-degradation technique: Effect of reaction parameters and co-existing species 基于in2s3纳米材料的综合吸附-降解技术:反应参数和共存物质的影响
Journal of hazardous materials letters Pub Date : 2023-09-25 DOI: 10.1016/j.hazl.2023.100087
Soumya Ranjan Mishra, Vishal Gadore, Md. Ahmaruzzaman
{"title":"A critical review on In2S3-based nanomaterial for emerging contaminants elimination through integrated adsorption-degradation technique: Effect of reaction parameters and co-existing species","authors":"Soumya Ranjan Mishra,&nbsp;Vishal Gadore,&nbsp;Md. Ahmaruzzaman","doi":"10.1016/j.hazl.2023.100087","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100087","url":null,"abstract":"<div><p>The possibility of combined adsorption-degradation processes in wastewater treatment using nanomaterials based on indium sulfide (In<sub>2</sub>S<sub>3</sub>) is examined in this review paper. Regarding the synergistic adsorption and degradation of pollutants, In<sub>2</sub>S<sub>3</sub> performs exceptionally well, making it a suitable choice for wastewater remediation. Insights have been given to the pollutant removal mechanism through this integrated technique. The synergistic removal process is affected by several operational factors, including pH, catalyst dose, pollutant concentration, and contact duration. This analysis highlights the significance of optimizing these parameters for optimal contaminant removal efficiency. The influence of co-existing species, including cations, anions, and organic compounds, on the integrated elimination process is further highlighted by a discussion of their role. Future research directions are suggested, including a better comprehension of underlying processes, investigation of hybrid nanocomposites, and evaluation of long-term stability and recyclability to enhance the applicability of In<sub>2</sub>S<sub>3</sub>-based nanomaterials. This study aids in the creation of effective and long-lasting wastewater treatment methods by using the potential of In<sub>2</sub>S<sub>3</sub>-based nanomaterials.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"4 ","pages":"Article 100087"},"PeriodicalIF":0.0,"publicationDate":"2023-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49859226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Per- and polyfluoroalkyl substances (PFAS) in consumer products: Current knowledge and research gaps 消费品中的全氟烷基和多氟烷基物质:目前的知识和研究差距
Journal of hazardous materials letters Pub Date : 2023-09-22 DOI: 10.1016/j.hazl.2023.100086
Pradeep Dewapriya , Lachlan Chadwick , Sara Ghorbani Gorji , Bastian Schulze , Sara Valsecchi , Saer Samanipour , Kevin V. Thomas , Sarit L. Kaserzon
{"title":"Per- and polyfluoroalkyl substances (PFAS) in consumer products: Current knowledge and research gaps","authors":"Pradeep Dewapriya ,&nbsp;Lachlan Chadwick ,&nbsp;Sara Ghorbani Gorji ,&nbsp;Bastian Schulze ,&nbsp;Sara Valsecchi ,&nbsp;Saer Samanipour ,&nbsp;Kevin V. Thomas ,&nbsp;Sarit L. Kaserzon","doi":"10.1016/j.hazl.2023.100086","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100086","url":null,"abstract":"<div><p>While several sources of per- and polyfluoroalkyl substances (PFAS) are known, their use in consumer household products is far less explored. The aim of this study was to provide comprehensive bottom-up analysis of the types and concentrations of PFAS reported in the literature over the past decade. A total of 52 studies revealed 107 PFAS belonging to 15 different categories in 1040 consumer products. The highest number of products tested were from the USA (n = 389) followed by the Czech Republic (n = 111). Mean PFAS concentrations were highest in household firefighting products, followed by textile finishing agents and household chemicals. The highest diversity of PFAS was reported in textiles (72 PFAS). Fluorotelomer alcohol (FTOH), polyfluoroalkyl phosphate esters (PAPs), perfluorocarboxylic acid (PFCA) and perfluorosulfonic acid (PFSA) are the classes of PFAS of high interest. Eight out of 52 studies used High-Resolution Mass Spectrometry techniques. Highlighted knowledge gaps included (i) the development of analytical methods for detecting a range of PFAS in consumer products, (ii) method validation and QA/QC approaches, (iii) application of suspect and non-target analysis, and (iv) an understanding of human exposure risk. This review highlights that the presence of PFAS in consumer products is of concern and remains underexplored.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"4 ","pages":"Article 100086"},"PeriodicalIF":0.0,"publicationDate":"2023-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49858966","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
The influence of chain length on the sorption of C4-C10 perfluorocarboxylic acids during transport in a sand 链长对C4-C10全氟羧酸在砂中传输过程中吸附的影响
Journal of hazardous materials letters Pub Date : 2023-08-19 DOI: 10.1016/j.hazl.2023.100084
Ying Lyu , Baohua Wang , Mark L. Brusseau
{"title":"The influence of chain length on the sorption of C4-C10 perfluorocarboxylic acids during transport in a sand","authors":"Ying Lyu ,&nbsp;Baohua Wang ,&nbsp;Mark L. Brusseau","doi":"10.1016/j.hazl.2023.100084","DOIUrl":"10.1016/j.hazl.2023.100084","url":null,"abstract":"<div><p>The impact of chain length on the retention and transport of perfluorocarboxylic acids (PFCAs) in a quartz sand was investigated. Short-chain (C4–C7: PFBA, PFPeA, PFHxA, PFHpA) and long-chain (C8–C10: PFOA, PFNA, PFDA) PFCAs were selected as a representative homologous series. Miscible-displacement transport experiments were conducted under saturated conditions to characterize the magnitudes of sorption mediating retention and transport. Quantitative-structure/property-relationship (QSPR) analysis was applied to characterize the influence of molecular size on sorption. The transport of the long-chain PFCAs exhibited greater retardation than the short-chain PFCAs. The log of the equilibrium sorption coefficient (<em>K</em><sub><em>d</em></sub>) exhibited a biphasic relationship with carbon number and molar volume, with the magnitude of measured sorption for the short-chain PFCAs significantly greater than would be predicted using the QSPR regression developed for the long-chain PFCAs. This is consistent with batch-measured data reported in the literature, and likely reflects the relative influence of different sorption mechanisms for the short-chain vs long-chain PFCAs.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"4 ","pages":"Article 100084"},"PeriodicalIF":0.0,"publicationDate":"2023-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47627658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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