{"title":"Exploring the untapped potentials of oily sludge ash blended with fly ash for geopolymer binder via waste valorisation approach","authors":"Vicky Kumar , Shamsul Rahman Mohamed Kutty , Siti Nooriza Abd Razak , Nasir Shafiq , Abiola Adebanjo , Lavania Baloo , Ahmed-Aberkan Azougagh , Rilind Iseni","doi":"10.1016/j.hazl.2023.100076","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100076","url":null,"abstract":"<div><p>Globally, large quantities of oily sludge are produced in petroleum refineries as wastes from petroleum refining processes. Petroleum refinery oily sludge (PROS) is a major by-product of the processes and a major contributor to pollution in the oil and gas industry. In this study, Response Surface Methodology (RSM) was used for optimising and modelling experimental work. Thermally treated PROS replaced fly ash (FA) at 5–20 % in geopolymer mortar mixes at a fixed combination of sodium silicate (Na<sub>2</sub>SiO<sub>3</sub>) and sodium hydroxide (NaOH). The visual observations and effects of PROS on the density and compressive strength of PROS geopolymer mortar (PGM) were studied. PGM with 10 % replacement of PROS had the maximum compressive strength of 38.17 MPa after 28 days. P-values obtained from the quadratic models developed for the synergistic effect of FA-PROS on density and compressive strength were less than 0.005. Optimisation of the synergistic effect of FA-PROS binder produced an optimal combination of both materials for maximum compressive strength and density of 2200 kg/m<sup>3</sup> with desirability factor of 0.981. This investigation shows that replacing PROS with FA in geopolymer mortar can result in a new supply chain for greener binder materials in geopolymer mortar.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"4 ","pages":"Article 100076"},"PeriodicalIF":0.0,"publicationDate":"2023-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49858971","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Vicky Kumar, S. Kutty, S. N. A. Razak, N. Shafiq, A. Adebanjo, L. Baloo, Ahmed Azougagh, Rilind Iseni
{"title":"Exploring the Untapped Potentials of Oily Sludge Ash Blended With Fly Ash for Geopolymer Binder Via Waste Valorization Approach","authors":"Vicky Kumar, S. Kutty, S. N. A. Razak, N. Shafiq, A. Adebanjo, L. Baloo, Ahmed Azougagh, Rilind Iseni","doi":"10.1016/j.hazl.2023.100076","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100076","url":null,"abstract":"","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44052201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Seeing beyond the smoke: Selecting waterpipe wastewater chemicals for risk assessments","authors":"Yasmin Termeh-Zonoozi , P. Dilip Venugopal , Vyomesh Patel, Gregory Gagliano","doi":"10.1016/j.hazl.2022.100074","DOIUrl":"https://doi.org/10.1016/j.hazl.2022.100074","url":null,"abstract":"<div><h3>Background</h3><p>Increasing use prevalence of waterpipe tobacco products raises concerns about environmental impacts from waterpipe waste disposal. The U.S. Food and Drug Administration (FDA) is required to assess the environmental impact of its tobacco regulatory actions per the National Environmental Policy Act. This study builds on FDA’s efforts characterizing the aquatic toxicity of waterpipe wastewater chemicals.</p></div><div><h3>Methods</h3><p>We compiled a comprehensive list of waterpipe wastewater chemical concentrations from literature. We then selected chemicals for risk assessment by estimating persistence, bioaccumulation, and aquatic toxicity (PBT) characteristics (U.S. Environmental Protection Agency), and hazardous concentration values (concentration affecting specific proportion of species).</p></div><div><h3>Results</h3><p>Of 38 chemicals in waterpipe wastewater with concentration data, 20 are listed as harmful or potentially harmful constituents (HPHCs) in tobacco smoke and tobacco products by FDA, and 15 are hazardous waste per U. S. Environmental Protection Agency. Among metals, six (cadmium, chromium, lead, mercury, nickel and selenium) are included in both HPHC and hazardous waste lists and were selected for future risk assessments. Among non-metals, nicotine, and 4-methylnitrosamino-1-(3-pyridyl)− 1-butanone (NNK) were shortlisted, as they are classified as persistent and toxic. Further, N-nitrosonornicotine (NNN), with a low hazardous concentration value (<em>HC</em><sub><em>50</em></sub>; concentration affecting 50 % of aquatic species) for chronic aquatic toxicity, had high aquatic toxicity concern and is selected.</p></div><div><h3>Conclusions</h3><p>The presence of multiple hazardous compounds in waterpipe wastewater highlights the importance of awareness on the proper disposal of waterpipe wastewater in residential and retail settings. Future studies can build on the hazard characterization provided in this study through fate and transport modeling, exposure characterization and risk assessments of waterpipe wastewater chemicals.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"4 ","pages":"Article 100074"},"PeriodicalIF":0.0,"publicationDate":"2023-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49858968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Liyan Wang , Jialuo Yu , Xiaoyan Wang , Jinhua Li , Lingxin Chen
{"title":"Molecular imprinting-based nanocomposite adsorbents for typical pollutants removal","authors":"Liyan Wang , Jialuo Yu , Xiaoyan Wang , Jinhua Li , Lingxin Chen","doi":"10.1016/j.hazl.2022.100073","DOIUrl":"https://doi.org/10.1016/j.hazl.2022.100073","url":null,"abstract":"","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"4 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49858967","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Influence of chain length on field-measured distributions of PFAS in soil and soil porewater","authors":"Mark L. Brusseau","doi":"10.1016/j.hazl.2023.100080","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100080","url":null,"abstract":"","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"4 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49858972","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Enhancing organic contaminant degradation through integrating advanced oxidation processes with microbial electrochemical systems","authors":"Kaichao Yang , Ibrahim M. Abu-Reesh , Zhen He","doi":"10.1016/j.hazl.2023.100075","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100075","url":null,"abstract":"","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"4 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49858969","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Comparative study on the microplastics abundance, characteristics, and possible sources in yellow clams of different demographic regions of the northwest coast of India","authors":"Bejawada Chanikya Naidu , K.A.Martin Xavier , Satya Prakash Shukla , Ashok Kumar Jaiswar , Binaya Bhusan Nayak","doi":"10.1016/j.hazl.2022.100051","DOIUrl":"https://doi.org/10.1016/j.hazl.2022.100051","url":null,"abstract":"<div><p>Microplastics have become ubiquitous on the planet and are considered one of the biggest threats to life on earth. Several recent studies have addressed the serious risks that microplastics can pose to human health. In this study, the microplastic content and spatial variations in number, size, colour, and polymers from a highly urbanized cosmopolitan, urban, and rural coastal locations of the northwest Indian coast were documented using yellow clams. The mean incidence of microplastics across all the stations among the clams is found to be one of the highest ever reported worldwide, which is 35.93 MPs items/g in soft tissue parts and 91.42 MPs items/individual. The clams were found to have a higher microplastic diversity integrated index (MDII) and Microplastic index (MPI). The majority of the microplastics observed were fibres and fragments, belonged to the size range of 1–100 µm (51.36%), and were identified as HDPE, polystyrene, polymethyl methacrylate, polyvinyl chloride, polyamide, and polypropylene. The clam condition index (CI) was recorded high at the rural coast with lower population and lowest at the megacity having greater population which may indicate the negative effect of MPs on clams growth.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"3 ","pages":"Article 100051"},"PeriodicalIF":0.0,"publicationDate":"2022-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911022000041/pdfft?md5=183dedd47f4b6a99b7a3019641add68b&pid=1-s2.0-S2666911022000041-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"137080941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gongde Chen , Sitao Liu , Qingyang Shi , Jay Gan , Bosen Jin , Yujie Men , Haizhou Liu
{"title":"Hydrogen-polarized vacuum ultraviolet photolysis system for enhanced destruction of perfluoroalkyl substances","authors":"Gongde Chen , Sitao Liu , Qingyang Shi , Jay Gan , Bosen Jin , Yujie Men , Haizhou Liu","doi":"10.1016/j.hazl.2022.100072","DOIUrl":"10.1016/j.hazl.2022.100072","url":null,"abstract":"<div><p>Reductive water treatment using hydrated electrons (<span><math><msubsup><mrow><mi>e</mi></mrow><mrow><mi>aq</mi></mrow><mrow><mo>−</mo></mrow></msubsup></math></span>) is a promising technology to destruct perfluoroalkyl substances; however, it faces challenges of slow reaction kinetics, undesirable chemical addition, and high energy consumption. Herein, we developed a hydrogen (H<sub>2</sub>)-polarized water photolysis system using vacuum UV (VUV) light at 185 nm for reductive destruction of perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS). The 185-nm photons directly photolyzed H<sub>2</sub>O and OH<sup>-</sup> into HO·, H·, and <span><math><msubsup><mrow><mi>e</mi></mrow><mrow><mi>aq</mi></mrow><mrow><mo>−</mo></mrow></msubsup></math></span>. H<sub>2</sub> elevated the <em>quasi</em> steady-state concentration of <span><math><msubsup><mrow><mi>e</mi></mrow><mrow><mi>aq</mi></mrow><mrow><mo>−</mo></mrow></msubsup></math></span> 18 times in untuned VUV systems through eliminating the scavenging effect of dissolved oxygen and converting hydroxyl radicals (HO·/O·<sup>-</sup>) into <span><math><msubsup><mrow><mi>e</mi></mrow><mrow><mi>aq</mi></mrow><mrow><mo>−</mo></mrow></msubsup></math></span>. The polarization effect of H<sub>2</sub> increased the degradation of PFOA from 10 % to 95 % and the defluorination from 17 % to 94 % and led to 87 % of defluorination for PFOS. The pH impacted VUV photon adsorption between H<sub>2</sub>O and OH<sup>-</sup> and shifted the equilibrium between H· and <span><math><msubsup><mrow><mi>e</mi></mrow><mrow><mi>aq</mi></mrow><mrow><mo>−</mo></mrow></msubsup></math></span>, which led to an optimal pH of 10.3 for PFOA destruction. The presence of chloride and sulfate enhanced the production of <span><math><msubsup><mrow><mi>e</mi></mrow><mrow><mi>aq</mi></mrow><mrow><mo>−</mo></mrow></msubsup></math></span> and promoted PFOA destruction. H<sub>2</sub>-polarized VUV water photolysis systems produced high levels of <span><math><msubsup><mrow><mi>e</mi></mrow><mrow><mi>aq</mi></mrow><mrow><mo>−</mo></mrow></msubsup></math></span> from clean water constituents and significantly reduced energy consumption for PFAS treatment under mild alkaline conditions.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"3 ","pages":"Article 100072"},"PeriodicalIF":0.0,"publicationDate":"2022-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911022000259/pdfft?md5=408d08ba5134e9573cbcd961eddba977&pid=1-s2.0-S2666911022000259-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46190258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sultana Afrin Jahan Rima , Gobindo Kumar Paul , Shirmin Islam , Md. Akhtar-E-Ekram , Shahriar Zaman , Md. Abu Saleh , Md. Salah Uddin
{"title":"Efficacy of Pseudomonas sp. and Bacillus sp. in textile dye degradation: A combined study on molecular identification, growth optimization, and comparative degradation","authors":"Sultana Afrin Jahan Rima , Gobindo Kumar Paul , Shirmin Islam , Md. Akhtar-E-Ekram , Shahriar Zaman , Md. Abu Saleh , Md. Salah Uddin","doi":"10.1016/j.hazl.2022.100068","DOIUrl":"10.1016/j.hazl.2022.100068","url":null,"abstract":"<div><p>One of the greatest environmental concerns in the world is thought to be the effluents from the textile industry. The use of synthetic dyes in textiles makes the traditional method of treating textile effluents more difficult. Microorganisms can be used to remediate the damage that textile dyes do to the environment. In this investigation, two bacterial strains with the capacity of degrading dye were isolated from textile waste and identified as <em>Pseudomonas</em> sp. (Accession no. NR 117,678.1) and <em>Bacillus</em> sp. (Accession no: NR148248.1) through morphological, biochemical, and molecular test. The cytotoxicity of this wastewater on <em>Artemia salina</em> and phytotoxicity on <em>Triticum aestivum</em> were also investigated using brine shrimp lethality assay and plant growth analysis, respectively. Wheat seed germination was adversely affected by wastewater containing dyes, but subsequently germination was enhanced when the wastewater was treated by the isolated strains. <em>Pseudomonas</em> sp. degraded pink and green dyes more effectively than <em>Bacillus</em> sp., according to results of a comparison of the two bacteria's dye-degrading capacities using the spectrophotometric method. The dye degrading capacity of the bacteria was validated by the HPLC analysis. Therefore, both <em>Pseudomonas</em> species and <em>Bacillus</em> species could be used as efficient bacteria in the large-scale treatment of textile effluents.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"3 ","pages":"Article 100068"},"PeriodicalIF":0.0,"publicationDate":"2022-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911022000211/pdfft?md5=0e61940b10db0173dbeb04bdc9aa649f&pid=1-s2.0-S2666911022000211-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48410230","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nalok Dutta , Muhammad Usman , Muhammad Awais Ashraf , Gang Luo , Shicheng Zhang
{"title":"Efficacy of emerging technologies in addressing reductive dechlorination for environmental bioremediation: A review","authors":"Nalok Dutta , Muhammad Usman , Muhammad Awais Ashraf , Gang Luo , Shicheng Zhang","doi":"10.1016/j.hazl.2022.100065","DOIUrl":"10.1016/j.hazl.2022.100065","url":null,"abstract":"<div><p>Reductive dechlorination is a core pathway of chlorination in an anaerobic environment, which can be carried out by fermentative, methanogenic, iron and sulfate-reducing microorganisms. The present review showed the different metabolic ways of microbes with the emphasis on the anaerobic microbial dechlorination (including chemical, biological and nanotechnology-based strategies), that have been employed to mitigate the chlorinated pollutants. Chemical and nanomaterial science has made substantial advancement in several aspects of dechlorination over the past two decades, providing information about the process and the outcome of the reaction. However, these chemical processes are expensive to start with and pose ecological hazards. So, extensive research has been done to come up with eco-friendly biological alternatives). Under anaerobic conditions, dehalorespiring bacteria are capable of dechlorinating chloroethenes by mediating a stepwise replacement of chlorine with hydrogen resulting in the sequential conversion of perchloroethylene (PCE) to trichloroethylene (TCE), dichloroethylene (DCE) isomers, vinyl chloride (VC), and finally, ethane. Among many dehalorespiring bacterial isolates, only a few strains of the genus <em>Dehalococcoides</em> completely converted the chloroethenes to nontoxic ethane. In the paper we will, therefore, focus on this <em>Dehalococcoides spp.</em> Several factors influence the dechlorination activity between different dehalogenating bacteria. The vcrA and bvcA genes dechlorinate VC into ethene, which are essential for complete dechlorination. These pathways offer understanding of potential bioremediation of chlorinated aliphatic or aromatic compounds by <em>Dehalococcoides</em> with the likelihood of highly effective bioremediation.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":"3 ","pages":"Article 100065"},"PeriodicalIF":0.0,"publicationDate":"2022-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911022000181/pdfft?md5=56635a9ccc761f79d51985923ddd0596&pid=1-s2.0-S2666911022000181-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42478453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}