Biochar最新文献

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Synergistically enhancing nitrate reduction into N2 in water by N-doped Pd–Cu biochar bimetallic single-atom electrocatalysis 掺杂 N 的 Pd-Cu 生物炭双金属单原子电催化协同提高水中硝酸盐还原成 N2 的能力
IF 12.7 2区 环境科学与生态学
Biochar Pub Date : 2024-01-15 DOI: 10.1007/s42773-023-00298-8
Lihao Zhang, Yuqing Wu, Zongqiang Zhu, Yinian Zhu, Yi Dong, Meina Liang, Huan Deng
{"title":"Synergistically enhancing nitrate reduction into N2 in water by N-doped Pd–Cu biochar bimetallic single-atom electrocatalysis","authors":"Lihao Zhang, Yuqing Wu, Zongqiang Zhu, Yinian Zhu, Yi Dong, Meina Liang, Huan Deng","doi":"10.1007/s42773-023-00298-8","DOIUrl":"https://doi.org/10.1007/s42773-023-00298-8","url":null,"abstract":"<p>Noble metal materials have been identified as high efficiency catalysts for electrocatalytic reduction of nitrate, and the synthesis and manufacture of high catalytic activity and environmentally friendly catalysts of activating hydrogen for water purification applications is extremely attractive. In this work, the Pd–Cu single-atom catalysts (Pd–Cu-N-BC) were first prepared by direct growth of Pd–Cu single-atom on bamboo biochar by regulating the concentration of precursors and doping method, and then enhanced electrocatalytic reduction nitrate performance and N<sub>2</sub> generation. The results showed that Pd–Cu-N-BC displayed excellent catalytic activity and reusability in electrocatalytic reduction nitrate with a low potential of 0.47 V vs. RHE (@10 mA cm<sup>−2</sup>). The maximum nitrate removal efficiency and N<sub>2</sub> generation could reach about 100% and 72.32% within 180 min, respectively. The density functional theory (DFT) calculations confirmed that Cu atoms could catalyze the electrochemical reduction of nitrate to nitrite, and Pd atoms anchored in the nitrogen-doped biochar (N-BC) lattice could catalyze electrochemical reduction of nitrite to N<sub>2</sub> involving the formation of hydrogen radical (H*). The characterization results of XANES showed that electronic synergistic effect between Pd and Cu single atoms significantly promotes the N<sub>2</sub> production through hydrogenation while inhibiting the generation of byproducts, leading to significantly enhanced electrocatalytic reduction of nitrate to N<sub>2</sub>. Finally, Pd–Cu-N-BC was designed as a 3D particle electrode for enhanced electrocatalytic reduction of nitrate, exhibiting excellent stability and reusability, which could be considered as a suitable candidate for applications in the remediation of nitrate contamination.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>\u0000","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"19 1","pages":""},"PeriodicalIF":12.7,"publicationDate":"2024-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139476970","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biochar reduced the mineralization of native and added soil organic carbon: evidence of negative priming and enhanced microbial carbon use efficiency 生物炭降低了原生和添加的土壤有机碳的矿化度:负引力和微生物碳利用效率提高的证据
IF 12.7 2区 环境科学与生态学
Biochar Pub Date : 2024-01-15 DOI: 10.1007/s42773-023-00294-y
Subin Kalu, Aino Seppänen, Kevin Z. Mganga, Outi-Maaria Sietiö, Bruno Glaser, Kristiina Karhu
{"title":"Biochar reduced the mineralization of native and added soil organic carbon: evidence of negative priming and enhanced microbial carbon use efficiency","authors":"Subin Kalu, Aino Seppänen, Kevin Z. Mganga, Outi-Maaria Sietiö, Bruno Glaser, Kristiina Karhu","doi":"10.1007/s42773-023-00294-y","DOIUrl":"https://doi.org/10.1007/s42773-023-00294-y","url":null,"abstract":"<p>Biochar has been widely recognized for its potential to increase carbon (C) sequestration and mitigate climate change. This potential is affected by how biochar interacts with native soil organic carbon (SOC) and fresh organic substrates added to soil. However, only a few studies have been conducted to understand this interaction. To fill this knowledge gap, we conducted a <sup>13</sup>C-glucose labelling soil incubation for 6 months using fine-textured agricultural soil (Stagnosol) with two different biochar amounts. Biochar addition reduced the mineralization of SOC and <sup>13</sup>C-glucose and increased soil microbial biomass carbon (MBC) and microbial carbon use efficiency (CUE). The effects were found to be additive i.e., higher biochar application rate resulted in lower mineralization of SOC and <sup>13</sup>C-glucose. Additionally, soil density fractionation after 6 months revealed that most of the added biochar particles were recovered in free particulate organic matter (POM) fraction. Biochar also increased the retention of <sup>13</sup>C in free POM fraction, indicating that added <sup>13</sup>C-glucose was preserved within the biochar particles. The measurement of <sup>13</sup>C from the total amino sugar fraction extracted from the biochar particles suggested that biochar increased the microbial uptake of added <sup>13</sup>C-glucose and after they died, the dead microbial residues (necromass) accumulated inside biochar pores. Biochar also increased the proportion of occluded POM, demonstrating that increased soil occlusion following biochar addition reduced SOC mineralization. Overall, the study demonstrates the additional C sequestering potential of biochar by inducing negative priming of native SOC as well as increasing CUE, resulting in the formation and stabilization of microbial necromass.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"11 1","pages":""},"PeriodicalIF":12.7,"publicationDate":"2024-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139476966","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biochar: a high performance and renewable basic carbocatalyst for facilitating room temperature synthesis of 4H-benzo[h]chromene and pyranopyrazoles in water 生物炭:促进水中 4H-苯并[h]色烯和吡喃吡唑室温合成的高性能可再生碱性碳催化剂
IF 12.7 2区 环境科学与生态学
Biochar Pub Date : 2024-01-11 DOI: 10.1007/s42773-023-00286-y
{"title":"Biochar: a high performance and renewable basic carbocatalyst for facilitating room temperature synthesis of 4H-benzo[h]chromene and pyranopyrazoles in water","authors":"","doi":"10.1007/s42773-023-00286-y","DOIUrl":"https://doi.org/10.1007/s42773-023-00286-y","url":null,"abstract":"<h3>Abstract</h3> <p>This study has introduced a pioneering methodology by employing biochars as a basic carbocatalyst in the context of multicomponent reactions. Biochars were produced from different manures and organic wastes using the pyrolysis-carbonization process under limited oxygen conditions. The prepared biochars were well characterized using Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), Brunauer–Emmett–Teller (BET) analysis, and powder X-ray diffraction (XRD). The chemical characteristics and potentiometric titration analysis provide compelling evidence of the intriguing basicity properties exhibited by the prepared biochars. The pH values, ash content, and potentiometric titration results confirmed the exceptional basicity characteristics of cow manure biochar formed at 600 <sup>o</sup>C (CB600), establishing it as the most basic carbocatalyst in this study. Encouraged by these initial results, the activity of the biochars as basic carbocatalysts was evaluated in multicomponent synthesis of 4<em>H</em>-benzo[h]chromene and pyranopyrazoles and 600 °C exhibited the most pronounced catalytic performance owing to its superior total basicity. By these findings, it can be asserted that this work introduces the groundbreaking application of biochars as potent basic carbocatalysts for the multicomponent synthesis of structurally diverse heterocycles. Unveiling the vital basic role of biochars will definitely open up new opportunities in organic chemistry and provide salient features for environmentally-friendly chemistry, including easy retrieval, non-toxicity, and widespread accessibility.</p> <span> <h3>Graphical Abstract</h3> <p><span> <span> <img alt=\"\" src=\"https://static-content.springer.com/image/MediaObjects/42773_2023_286_Figa_HTML.png\"/> </span> </span></p> </span>","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"109 1","pages":""},"PeriodicalIF":12.7,"publicationDate":"2024-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139423514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced denitrification driven by a novel iron-carbon coupled primary cell: chemical and mixotrophic denitrification 新型铁碳耦合原电池驱动的强化反硝化作用:化学和混养反硝化作用
IF 12.7 2区 环境科学与生态学
Biochar Pub Date : 2024-01-10 DOI: 10.1007/s42773-023-00274-2
Ruofan Wu, Paramsothy Jeyakumar, Nanthi Bolan, Xu Zhai, Hailong Wang, Minghui Pan, Jiapan Lian, Liping Cheng, Jiangzhou Li, Minghei Hou, Yonghe Cui, Xiaoe Yang, Kuai Dai
{"title":"Enhanced denitrification driven by a novel iron-carbon coupled primary cell: chemical and mixotrophic denitrification","authors":"Ruofan Wu, Paramsothy Jeyakumar, Nanthi Bolan, Xu Zhai, Hailong Wang, Minghui Pan, Jiapan Lian, Liping Cheng, Jiangzhou Li, Minghei Hou, Yonghe Cui, Xiaoe Yang, Kuai Dai","doi":"10.1007/s42773-023-00274-2","DOIUrl":"https://doi.org/10.1007/s42773-023-00274-2","url":null,"abstract":"<p>Iron-carbon micro-electrolysis system is a promising method for promoting electron transfer in nitrate removal. However, many traditional approaches involving simple physical mixing inevitably suffered from the confined iron-carbon contact area and short validity period, leading to the overuse of iron. Here, a ceramsite-loaded microscale zero-valent iron (mZVI) and acidified carbon (AC) coupled-galvanic cell (CMC) was designed to support chemical, autotrophic and heterotrophic denitrification. Long-term experiments were conducted to monitor the nitrogen removal performance of denitrification reactors filled with CMC and thus optimized the denitrification performance by improving fabrication parameters and various operating conditions. The denitrification contributions test showed that the chemical denitrification pathway contributed most to nitrate removal (57.3%), followed by autotrophic (24.6%) and heterotrophic denitrification pathways (18.1%). The microbial analysis confirmed the significant aggregation of related denitrifying bacteria in the reactors, while AC promoted the expression of relevant nitrogen metabolism genes because of accelerated uptake and utilization of iron complexes. Meanwhile, the electrochemical analysis revealed a significantly improved electron transfer capacity of AC compared to pristine carbon. Overall, our study demonstrated the application of a novel mZVI-AC coupled material for effective nitrate removal and revealed the potential impact of CMC in the multipathway denitrification process.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>\u0000","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"122 1","pages":""},"PeriodicalIF":12.7,"publicationDate":"2024-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139422360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fe/BC co-conditioners with environmental and economic benefits on composting: reduced NH3 emissions and improved fertilizer quality 对堆肥具有环境和经济效益的 Fe/BC 联合调节器:减少 NH3 排放,提高肥料质量
IF 12.7 2区 环境科学与生态学
Biochar Pub Date : 2024-01-09 DOI: 10.1007/s42773-023-00295-x
{"title":"Fe/BC co-conditioners with environmental and economic benefits on composting: reduced NH3 emissions and improved fertilizer quality","authors":"","doi":"10.1007/s42773-023-00295-x","DOIUrl":"https://doi.org/10.1007/s42773-023-00295-x","url":null,"abstract":"<h3>Abstract</h3> <p>The significant volatilization of NH<sub>3</sub> during aerobic composting causes nitrogen (N) losses and environmental risks. Both iron (Fe) and biochar (BC) can influence the N conversion process in composting. Fe application can delay the maturation of materials, while biochar can enhance the quality of organic fertilizer. The combination of these two conditioners may help decrease NH<sub>3</sub> emissions and improve organic fertilizer quality. Therefore, this study investigates the effects of different doses of FeCl<sub>3</sub> and BC on NH<sub>3</sub> emissions and organic fertilizer quality during composting. The results demonstrated that Fe/BC co-conditioners reduced the accumulation of NH<sub>3</sub> emissions during composting by 11.1–48.2%, increased the total nutrient content by 0.6–15.3%, and enhanced economic and environmental benefits by 0.1–23.6 $ t<sup>−1</sup>. At the high-temperature stage of composting, Fe/BC co-conditioners decreased the pH by 0.3–1.2, but there was no significant difference compared to the control at the end of composting, and they did not affect compost maturation. The structural equation model analysis suggested that the reduction in NH<sub>3</sub> emissions was related to ammonia-oxidizing bacteria (AOB), NH<sub>4</sub><sup>+</sup>–N, and total nitrogen (TN). As a result, the Fe/BC co-conditioners reduced NH<sub>3</sub> emissions by lowering the pH at the beginning of composting and increasing the content of NH<sub>4</sub><sup>+</sup>–N. This study concludes that Fe/BC co-conditioners could complement each other to significantly reduce NH<sub>3</sub> emissions and improve the quality of organic fertilizers.</p> <span> <h3>Graphical Abstract</h3> <p> <span> <span> <img alt=\"\" src=\"https://static-content.springer.com/image/MediaObjects/42773_2023_295_Figa_HTML.png\"/> </span> </span></p> </span>","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"16 1","pages":""},"PeriodicalIF":12.7,"publicationDate":"2024-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139410058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biochar and organic fertilizer applications enhance soil functional microbial abundance and agroecosystem multifunctionality 施用生物炭和有机肥可提高土壤功能微生物的丰度和农业生态系统的多功能性
IF 12.7 2区 环境科学与生态学
Biochar Pub Date : 2024-01-08 DOI: 10.1007/s42773-023-00296-w
Wang Hu, Yuping Zhang, Xiangmin Rong, Xuan Zhou, Jiangchi Fei, Jianwei Peng, Gongwen Luo
{"title":"Biochar and organic fertilizer applications enhance soil functional microbial abundance and agroecosystem multifunctionality","authors":"Wang Hu, Yuping Zhang, Xiangmin Rong, Xuan Zhou, Jiangchi Fei, Jianwei Peng, Gongwen Luo","doi":"10.1007/s42773-023-00296-w","DOIUrl":"https://doi.org/10.1007/s42773-023-00296-w","url":null,"abstract":"<p>Biochar and organic fertilizer are widely supported to maintain crop production and sustainable development of agroecosystems. However, it is unclear how biochar and organic fertilizer alone or in combination regulate soil functional microbiomes and their relationships to ecosystem multifunctionality (EMF). Herein, a long-term (started in 2013) field experiment, containing five fertilization treatments, was employed to explore the effects of biochar and organic fertilizer applications on the EMF (based on 18 functional indicators of crop productivity, soil nutrient supply, element cycling, and microbial biomass) and the functional microbiomes of bulk soil and rhizosphere soil [normalizing the abundances of 64 genes related to carbon (C), nitrogen (N), phosphorus (P), and sulphur (S) cycles]. Compared with single-chemical fertilization, biochar and organic fertilizer inputs significantly enhanced most ecosystem-single functions and, in particular, the EMF significantly increased by 18.7–30.1%; biochar and organic fertilizer applications significantly increased the abundances of soil microbial functional taxa related to C-N-P-S cycles to varying degree. The combined application of biochar and organic fertilizer showed a better improvement in these indicators compared to using them individually. Most functional microbial populations in the soil, especially the taxa involved in C degradation, nitrification, nitrate-reduction, organic P mineralization, and S cycling showed significantly positive associations with the EMF at different threshold levels, which ultimately was regulated by soil pH and nutrient availability. These results highlight the strong links between soil microbiomes and agroecosystem functions, as well as providing scientific support for inclusion of biochar in agricultural production and services with organic amendments.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"57 1","pages":""},"PeriodicalIF":12.7,"publicationDate":"2024-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139410352","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Beyond the basics: a perspective on barriers and opportunities for scaling up biochar production from forest slash 超越基本原理:从一个角度看扩大利用森林砍伐物生产生物炭的障碍和机遇
IF 12.7 2区 环境科学与生态学
Biochar Pub Date : 2024-01-02 DOI: 10.1007/s42773-023-00290-2
{"title":"Beyond the basics: a perspective on barriers and opportunities for scaling up biochar production from forest slash","authors":"","doi":"10.1007/s42773-023-00290-2","DOIUrl":"https://doi.org/10.1007/s42773-023-00290-2","url":null,"abstract":"<h3>Abstract</h3> <p>Biochar production from woody biomass generated during forest management (slash) offers significant benefits for soil health and carbon emissions, yet its adoption remains limited in the western United States (U.S.). To address this challenge, the U.S. Department of Agriculture (U.S.D.A.) Forest Service Rocky Mountain Research Station organized two workshops focused on forest management-centric biochar production. These workshops convened a diverse group of stakeholders, including investors, land management practitioners, industry professionals, and research scientists, each with unique roles in slash-based biochar production. This article presents a synthesis of the insights and perspectives gathered from these workshops, aiming to identify barriers and propose viable pathways for overcoming them. The barriers encompass governance issues such as policy and permitting, economic challenges related to costs, funding, and market stability, technological hurdles concerning methods and equipment, and a need for further research and improved science dissemination. In response to these challenges, workshop attendees collaboratively outlined specific strategies to reduce these barriers. These strategies emphasize the expansion of operational initiatives, the development of proactive policies, the stabilization of biochar markets, and the generation of additional case studies showcasing the effects of biochar amendments across various soils and environments. Collectively, the insights gleaned from this workshop series provide a comprehensive roadmap outlining both the struggles and the necessary actions and investments required to enhance the scale of slash-based biochar production and application in the western U.S.</p> <span> <h3>Graphical Abstract</h3> <p> <span> <span> <img alt=\"\" src=\"https://static-content.springer.com/image/MediaObjects/42773_2023_290_Figa_HTML.png\"/> </span> </span></p> </span>","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"8 1","pages":""},"PeriodicalIF":12.7,"publicationDate":"2024-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139078166","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Current trends in antimicrobial activities of carbon nanostructures: potentiality and status of nanobiochar in comparison to carbon dots 碳纳米结构抗菌活性的当前趋势:与碳点相比,纳米生物炭的潜力和现状
IF 12.7 2区 环境科学与生态学
Biochar Pub Date : 2024-01-02 DOI: 10.1007/s42773-023-00282-2
{"title":"Current trends in antimicrobial activities of carbon nanostructures: potentiality and status of nanobiochar in comparison to carbon dots","authors":"","doi":"10.1007/s42773-023-00282-2","DOIUrl":"https://doi.org/10.1007/s42773-023-00282-2","url":null,"abstract":"<h3>Abstract</h3> <p>The increase in antimicrobial resistance (AMR) poses a massive threat to world health, necessitating the urgent development of alternative antimicrobial growth control techniques. Due to their specific physical and chemical properties, nanomaterials, particularly carbon-based nanomaterials, have emerged as attractive candidates for antimicrobial applications, however, reviews are lacking. This comprehensive review aims to bridge the existing knowledge gaps surrounding the mechanism and significance of nanobiochar (NBC) and carbon nanostructures in the field of antimicrobial applications. Notably, NBC, which is derived from biochar, exhibits promising potential as an environmentally-friendly substance with antimicrobial properties. Its strong adsorption capabilities enable the removal and immobilization of pathogens and pollutants from soil and water and also exhibit antimicrobial properties to combat harmful pathogens. In addition to NBC, carbon dots (CDs) and graphene oxide (GO) have also shown excellent antimicrobial properties. These carbon-based nanomaterials find applications in agriculture for phytopathogen control and post-harvest disease management, as well as in medicine for nanotheranostics and in the food industry for extending shelf life as an eco-friendly alternative to chemicals and antibiotics. However, the long-term toxicity of these nanoparticles to humans and the environment needs further investigation, considering the influence of different physiochemical characteristics on antimicrobial properties and nanotoxicity. Therefore, continued exploration in this area will pave the way for future research and safe deployment strategies of carbon-based nanomaterials in combating microbial threats.</p> <span> <h3>Graphical Abstract</h3> <p> <span> <span> <img alt=\"\" src=\"https://static-content.springer.com/image/MediaObjects/42773_2023_282_Figa_HTML.png\"/> </span> </span></p> </span>","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"10 1","pages":""},"PeriodicalIF":12.7,"publicationDate":"2024-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139078336","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Waste bio-tar based N-doped porous carbon for supercapacitors under dual activation: performance, mechanism, and assessment 双重活化条件下用于超级电容器的废生物塔基掺杂氮的多孔碳:性能、机理和评估
IF 12.7 2区 环境科学与生态学
Biochar Pub Date : 2023-12-15 DOI: 10.1007/s42773-023-00293-z
{"title":"Waste bio-tar based N-doped porous carbon for supercapacitors under dual activation: performance, mechanism, and assessment","authors":"","doi":"10.1007/s42773-023-00293-z","DOIUrl":"https://doi.org/10.1007/s42773-023-00293-z","url":null,"abstract":"<h3>Abstract</h3> <p>Bio-tar extra-produced from biomass pyrolysis is prone to pose a threat to environment and human health. A novel N-doped porous electrode from bio-tar was produced under dual-activation of urea and KOH in this study. One-pot dual-activation played significant roles in N-functional group and micro-mesoporous structure, which resulted in the carbon material with the highest of nitrogen content (4.08%) and the special surface area (1298.26 m<sup>2</sup>·g<sup>−1</sup>). Specifically, the potential mechanisms of pore formation and N-doping in the one-pot dual-activation strategy were also proposed as a consequence, the one-pot dual-activated carbon material displayed excellent electrochemical performance with the highest capacitance of 309.5 F·g<sup>−1</sup> at 0.5 A·g<sup>−1</sup>, and the unipolar specific capacitance remained with cyclic characteristics of 80.1% after 10,000 cycles in two-electrode symmetric system. Furthermore, the one-pot dual-activation strategy could create a profit of $1.64–$2.38 per kilogram of bio-tar processed without considering the initial investment and labor costs, which provides new perspectives for the utilization of waste bio-tar.</p> <span> <h3>Graphical Abstract</h3> <p> <span> <span> <img alt=\"\" src=\"https://static-content.springer.com/image/MediaObjects/42773_2023_293_Figa_HTML.png\"/> </span> </span></p> </span>","PeriodicalId":8789,"journal":{"name":"Biochar","volume":"71 1","pages":""},"PeriodicalIF":12.7,"publicationDate":"2023-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138692782","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
N self‐doped multifunctional chitosan biochar-based microsphere with heterogeneous interfaces for self-powered supercapacitors to drive overall water splitting 具有异质界面的 N 自掺杂多功能壳聚糖生物炭基微球用于自供电超级电容器,以驱动整体水分离
IF 12.7 2区 环境科学与生态学
Biochar Pub Date : 2023-12-15 DOI: 10.1007/s42773-023-00266-2
Chunxia Yan, Yaqi Yang, Jie Wei, Jianhua Hou, Ziqiang Shao
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