{"title":"Preparation and Catalytic Performance of Ti/CoO@ZIF-67 Composite Electrode","authors":"Xiaoze Liu, Yanan Gong, Khalil Md lbrahim, Hossain Md Azharul, Guowen Wang, Xinxin Zhang, Dedong Sun, Hongchao Ma","doi":"10.1007/s11270-024-07683-4","DOIUrl":"10.1007/s11270-024-07683-4","url":null,"abstract":"<div><p>While cobalt oxides (CoO, Co<sub>3</sub>O<sub>4</sub>) have attracted considerable interest in photoelectrocatalysis (PEC), supercapacitors, and lithium-ion batteries due to their inherent three-dimensional electronic structure. Herein, CoO nanowires were synthesized by one-step hydrothermal method, and then ZIF-67 was generated in situ on CoO nanowires by simple impregnation method. Finally, Ti/CoO@ZIF-67 composite electrode was synthesized. In order to find the PEC electrode with the best performance, we optimized the experimental system by adjusting the amount of organic ligand (0.01 mol, 0.015 mol, 0.02 mol, 0.025 mol). The PEC activity of Ti/CoO@ZIF-67 electrode was studied by electrochemical properties and degradation efficiency of Ti/CoO@ZIF-67 electrode for active brilliant blue (KN-R). The results show that the Ti/CoO@ZIF-67–0.02 electrode exhibits the largest specific surface area, the smallest charge radius, the fastest charge mass transfer rate and the highest PEC degradation efficiency for KN-R. The composite electrode with different amount of organic ligand showed higher degradation efficiency than the single component electrode. This is due to the staggered band structure of CoO and ZIF-67, which accelerates the effective separation of photogenerated electrons and holes on the surface of the electrode, and improves the mineralization effect of the composite electrode on organic polymer materials. This study provides an application strategy for the construction of composite heterojunction materials.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 2","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142976615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Alex Rodrigues Gomes, Letícia Paiva de Matos, Abner Marcelino Silva, Abraão Tiago Batista Guimarães, Thiarlen Marinho da Luz, Rafaela Ribeiro de Brito, Aline Sueli de Lima Rodrigues, Boniek Gontijo Vaz, Juraci Alves de Oliveira, Wesley Rodrigues Soares, Ivandilson Pessoa Pinto de Menezes, Guilherme Malafaia
{"title":"Complex Interactions and Ecotoxicological Consequences of Tannery Effluents on Aquatic Life: Differential Responses in Scinax Fuscovarius Tadpoles and Poecilia Reticulata Fish","authors":"Alex Rodrigues Gomes, Letícia Paiva de Matos, Abner Marcelino Silva, Abraão Tiago Batista Guimarães, Thiarlen Marinho da Luz, Rafaela Ribeiro de Brito, Aline Sueli de Lima Rodrigues, Boniek Gontijo Vaz, Juraci Alves de Oliveira, Wesley Rodrigues Soares, Ivandilson Pessoa Pinto de Menezes, Guilherme Malafaia","doi":"10.1007/s11270-024-07710-4","DOIUrl":"10.1007/s11270-024-07710-4","url":null,"abstract":"<div><p>Tannery industries contribute significantly to economic growth but generate highly toxic effluents, posing severe threats to aquatic ecosystems. This study assessed the ecotoxicological impacts of tannery effluents on <i>Scinax fuscovarius</i> tadpoles and <i>Poecilia reticulata</i> fish. Tadpoles and fish were exposed to environmentally relevant dilutions (0.3%) of raw tannery effluent (RTE) and effluent treated with mercerized microcrystalline cellulose particles (TTE) for 15 days. RTE exposure caused a 74.9% reduction in catalase (CAT) activity and a 50% increase in micronucleated erythrocytes in tadpoles, alongside heightened oxidative stress and inflammation. In fish, RTE exposure led to a 30% increase in superoxide dismutase (SOD) activity and moderate cytogenotoxic effects, reflecting their lower chromium (Cr) accumulation (0.5 mg/g in fish vs. 1.2 mg/g in tadpoles). TTE treatment significantly reduced Cr concentrations by 60% in tadpoles and 50% in fish, mitigating toxicity. However, residual sublethal effects persisted, including oxidative stress markers and nuclear abnormalities in both species. These findings highlight the differential sensitivity of aquatic species to tannery effluents and the partial efficacy of TTE in reducing toxicity. The results provide critical data for advancing remediation strategies, emphasizing the need for technologies capable of addressing residual toxicity. Furthermore, this study underscores the importance of multi-species ecotoxicological assessments and biomarker-based approaches in regulatory frameworks to ensure the ecological safety of treated industrial effluents. Future studies should explore long-term and transgenerational impacts to build a comprehensive understanding of these pollutants' ecological and evolutionary consequences.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 2","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142941270","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Blanca Yarely Bautista-García, Luis Antonio Castillo-Suárez, Elia Alejandra Teutli-Sequeira, Monserrat Castañeda-Juárez, Ivonne Linares-Hernández, Verónica Martínez-Miranda
{"title":"Degradation of the commercial Paraquat herbicide by UVA-LED Photo-Electrooxidation utilizing a BDD-Fe system: Multiple response optimization","authors":"Blanca Yarely Bautista-García, Luis Antonio Castillo-Suárez, Elia Alejandra Teutli-Sequeira, Monserrat Castañeda-Juárez, Ivonne Linares-Hernández, Verónica Martínez-Miranda","doi":"10.1007/s11270-024-07715-z","DOIUrl":"10.1007/s11270-024-07715-z","url":null,"abstract":"<div><p>The UVA-LED photo-electrooxidation process was studied using Fe and boron-doped diamond electrodes and a UVA LED lamp for the degradation of gramoxone (paraquat, PQ), a highly toxic herbicide widely used in agriculture. The factors of hydraulic retention time (HRT), electric current (j) and the concentration of MgSO<sub>4</sub> as a supporting electrolyte were evaluated regarding the response variables percentage removal of chemical oxygen demand (COD) and PQ concentration using the desirability function through a Box‒Behnken experimental design for maximum response of both variables. A degradation efficiency of 47.8% of PQ was achieved, as well as a removal of 78.1% of COD and 71.6% of total organic carbon (TOC) for a commercial herbicide concentration of 60.4 mg/L PQ, electric current of 0.84 A, and electrolytic support of 6.3 g/L. After 172.3 min of hydraulic retention time, the electrical consumption was 42.5 kW/m<sup>3</sup>. To calculate the kinetic constants, the first order, second order and Behnajady-Modirshahla-Ghanbery (BMG) kinetic models were evaluated. In the two response variables (PQ and COD), the model that showed the best fit was the BMG. The HRT/electrical current interaction had a significant effect on PQ removal, and this interaction improved the herbicide removal to 77% after 300 min of HRT, and 0.9 A and 6.3 g/L MgSO<sub>4</sub> generated a consumption of 114.7 kW/m<sup>3</sup>. Excess electrical consumption is related to the complexity of the water, and the UVA-LED photoelectrooxidation reactor<b> (</b>LPEr) process (BDD-Fe/UVA-LED) may be suitable for the removal of contaminants in waters with low complexity or as a polishing stage in wastewater treatment.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 2","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142963148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Mango Peel Bio-actives for the Fabrication of Inorganic Metal Nanoparticles and their Potential for Wastewater treatment","authors":"Khalida Naseem, Kiran Mir, Kiky Corneliasari Sembiring, Awais Khalid, Mohmmad Ehtisham Khan, Anil Kumar Deepati","doi":"10.1007/s11270-024-07728-8","DOIUrl":"10.1007/s11270-024-07728-8","url":null,"abstract":"<div><p>Mango peel is mango fruit waste, discarded without any use. These peels can be utilized to prepare an extract that exhibits many phytochemicals and phenolic compounds such as polyphenols, flavonoids, carotenoids, and vitamins. These compounds are utilized as a cost-effective stabilizer and reducing agent for the fabrication of different types of metal nanoparticles (MNPs). The hydroxyl groups present as part of different functional group in these compounds reduce the metal ions and alternatively synthesize MNPs of different size and shape. Many researchers reported the preparation of MNPs by using mango peel extract (MPE) as a source of bioactive compounds that reduce metal ions into metal atoms and cage them. These MNPs are utilized as effective antimicrobial agents to prepare effective food packaging, for killing mosquito larvae, and as an adsorbent for the removal of heavy metal ions and toxic dyes from the water medium. Here we covered the overview of the preparation of mango peel extract-induced MNPs, their characterization by various techniques and their use in different fields from the previously reported literature. In the future, these MNPs can be used as potential catalysts for various organic reactions, sensing, and in the biomedical field due to the easy availability of sources such as peel and precursor salts.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 2","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142941266","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mehmet Akif Omeroglu, Buket Bakan, Mustafa Ozkan Baltaci, Nazli Pinar Arslan, Sefa Ucar, Seydanur Elmas, Ahmet Adiguzel, Mesut Taskin
{"title":"Biodegradation of Benzophenone-3 in Non-Sterile Culture Process Using Klebsiella huaxiensis W2","authors":"Mehmet Akif Omeroglu, Buket Bakan, Mustafa Ozkan Baltaci, Nazli Pinar Arslan, Sefa Ucar, Seydanur Elmas, Ahmet Adiguzel, Mesut Taskin","doi":"10.1007/s11270-025-07744-2","DOIUrl":"10.1007/s11270-025-07744-2","url":null,"abstract":"<div><p>Benzophenone-3 (BP3) is an organic pollutant widely detected in soil and aquatic environments. The aims of this study were to isolate a bacterium which is capable of degrading BP3 and converting it into non-toxic products, and to design a non-sterile culture process which may be applied to the real biological treatment systems for the bioremediation of BP3. <i>Klebsiella huaxiensis</i> W2 (GenBank accession number: PQ143284) isolated from a wastewater treatment system was found to have high potency to degrade BP3. This bacterium degraded BP3 into two byproducts: phenol, 2,4-bis-(1,1-dimethylethyl) and benzyl benzoate. Oxygenases (P450 monooxygenases, dioxygenases etc.) were predicted to be effective in BP3 degradation. BP3-degradation products did not cause a toxicity on fibroblast cell line. Optimizing inoculum size, that is, inoculating the high size (1–2%) of the bacterial preculture into the wastewater-based medium, make the bacterium more dominant in this medium, thus enabling the bacterial cells to degrade BP3 under non-sterile culture conditions. In this process, biodegradation efficiency was not affected notably from temperature variations, and the bacterium was able to hydrolyze about 99.33% of 1 g/L BP3 within 120 h. Overall, <i>K. huaxiensis</i> W2 was deduced to possess the potency for being used as a bioremediation agent in non-sterile biological treatment systems, in which sterilization process, temperature control, and nutrient supplementation were not needed. The designed process may find applications in the bioremediation of wastewater and sewage effluents. This is the first study using <i>K. huaxiensis</i> in a non-sterile environment for BP3 degradation.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 2","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11270-025-07744-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142941267","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Min-oh Park, Gayatri Panthi, Joung-Ho Park, Rishikesh Bajagain, Keum Young Lee, Yongseok Hong
{"title":"Molecular Weight-Dependent Desorption of Alkanes in Low Temperature Thermal Treatment of Total Petroleum Hydrocarbon-Contaminated Soils","authors":"Min-oh Park, Gayatri Panthi, Joung-Ho Park, Rishikesh Bajagain, Keum Young Lee, Yongseok Hong","doi":"10.1007/s11270-025-07738-0","DOIUrl":"10.1007/s11270-025-07738-0","url":null,"abstract":"<div><p>Thermal treatment technology is one way of remediating oil-contaminated soil using elevated temperatures and collecting contaminants using a vapor treatment system. In this study, we aimed to investigate the dynamics of hydrocarbons (C<sub>6</sub>–C<sub>26</sub>) in oil-based contaminated soils and develop a model that can eventually be used to predict the application and hydrocarbon dynamics when thermal treatment is applied to the field. The thermal desorption (TD) efficiencies for all compounds increased with temperature and treatment time. The results showed that low-molecular weight hydrocarbons (≤ C<sub>12</sub>) were completely removed at 50°C while a similar removal efficiency was achieved for high molecular weight hydrocarbons (≥ C<sub>18</sub>) only at higher temperature studied (200°C). Notably, the total petroleum hydrocarbon (TPH) in diesel-contaminated soil decreased below Korean residential site limit (500 mg/kg) from an initial concentration of 14,300 mg/kg within 10 min at 150‒200°C (overall > 95% efficiency), indicating a good potential of low-temperature TD technology. However, the TPH concentration remained above 2000 mg/kg when the diesel contaminated soil was treated at ≤ 100°C, suggesting insufficient efficiency at very low temperatures. The TD efficiency decreased with increasing molecular weight of hydrocarbons. The fine particles have shown less tendency to desorb the contaminants, while the presence of organic matter had minimal impact. Furthermore, the developed model accurately estimated residual contaminant concentrations based on carbon number of compounds and temperature. The findings highlight the potential of low-temperature TD (≤ 200°C) for efficient and rapid remediation, offering cost-effective and energy-saving alternative to processes requiring higher temperatures or longer timeframes.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 2","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142940694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Evelyn Flores Alberto, Julia Liliana Rodríguez Santillán, Tatyana Poznyak, Itzany Janet De la Cruz Salazar, Daniela Sánchez Vargas, Iliana Fuentes Camargo, Jesús I. Guzmán Castañeda
{"title":"Sequential Ozonation Processes for Enhanced Degradation of Aromatic Sulfonic Compounds in Water","authors":"Evelyn Flores Alberto, Julia Liliana Rodríguez Santillán, Tatyana Poznyak, Itzany Janet De la Cruz Salazar, Daniela Sánchez Vargas, Iliana Fuentes Camargo, Jesús I. Guzmán Castañeda","doi":"10.1007/s11270-025-07740-6","DOIUrl":"10.1007/s11270-025-07740-6","url":null,"abstract":"<div><p>Aromatic sulfonic compounds (ASCs), widely used in textile industry for synthesizing azo dyes, are commonly detected in aquatic environments, where they pose potential ecological risks. This study proposes a sequential ozonation system to degrade two ASCs: 4-phenol sulfonic acid (4-PSA) and 2-naphthalene sulfonic acid (2-NSA). The sequential treatment consists of two stages: first, conventional ozonation is applied to partially degrade the target compounds and produce intermediate byproducts, with ozonation time of 20 or 40 min. In the second stage, a commercial metal oxide (NiO or CuO) is used as catalyst with ozone to further degrade the intermediates generated in the first stage. The sequential approached achieved nearly complete mineralization of both ASCs, significantly surpassing the total organic carbon (TOC) removal (around 61%), when the catalyst was added at the start of ozonation and maintained for 2 h. The success of sequential system is attributed to the reactive oxygen species (ROS) generated by the catalyst, which mostly eliminate byproducts formed during conventional ozonation. Contrary to single catalytic ozonation, where ROS are generated since the beginning and act on both intermediates and target compounds, reducing the TOC removal around 33%. Additionally, sulphate ions are released during the ASCs elimination, which can inhibit the catalytic activity by blocking the active sites; the sequential process mitigates this effect by minimizing catalyst exposure to sulphate ions. FTIR and XPS analyses confirmed the presence of these ions on the catalyst surfaces. Therefore, sequential ozonation reduces the metal leaching and offers high ASCs mineralization efficiency compared to conventional ozonation processes, and thus, could have a potential use for treating ASCs contaminated effluents.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 2","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142939420","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Leipeng Ji, Haomiao Xu, Fubing Zhang, Xiaoming Sun, Wenjun Huang, Zan Qu, Naiqiang Yan
{"title":"Evaluation of As(III) Removal and Corresponding Species Regulation Mechanism from Sulfide-Abundant Arsenic Solution with Potential Application in Smelting Wastewater","authors":"Leipeng Ji, Haomiao Xu, Fubing Zhang, Xiaoming Sun, Wenjun Huang, Zan Qu, Naiqiang Yan","doi":"10.1007/s11270-024-07691-4","DOIUrl":"10.1007/s11270-024-07691-4","url":null,"abstract":"<div><p>H<sub>2</sub>S treatment is a potential method to remove As from smelting wastewater. However, it was difficult to achieve the high concentration As containing wastewater to standard through H<sub>2</sub>S one-step treatment. Meanwhile, the sulfide-abundant conditions after H<sub>2</sub>S treatment changed the As species and the pH condition, which put forward challenges for removing As deeply. In this study, we developed an H<sub>2</sub>S-modification method to prepare sulfide nanoscale zero-valent iron (S-nZVI) to improve the acid resistance and the adsorption performance of adsorbents for As in sulfide-abundant conditions. The results showed that the H<sub>2</sub>S-modification method expanded the pH windows with excellent As(III) removal efficiency from 3 to 7, and at pH value of 3, the As(III) removal efficiency reached 99%. Under pH = 3, the concentration of iron released from nanomaterials decreased from 200 to 20 mg/L, which is attributed to the protection of the surface by the FeS<sub>x</sub> layer. Moreover, through H<sub>2</sub>S-sulfidation, H<sub>3</sub>AsO<sub>3</sub> (As-O species) transformed to As-S species, which were more challenging to remove than As-O species. In As(III)-S(-II) solution, S-nZVI adsorbed 95% of As(III) in the range of pH 1–5, and the excessive S(-II) could react with Fe(III) to accelerate the cycle of Fe(III)/Fe(II). This improved the efficiency of the Fenton reaction to enhance the oxidation of As(III). Furthermore, consumption of the S(-II) could promote the transformation from As-S species to As-O species. Thus, excellent acid resistance and the synergy with S(-II) made S-nZVI holds great potential to be applied in As(III) removal.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 2","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142940968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nurul’ Ain Jamion, Khai Ern Lee, Mazlin Mokhtar, Thian Lai Goh
{"title":"Water Quality Assessment of Ex-Mining Lakes Converted Man-made Wetlands in Paya Indah Wetlands, Selangor, Malaysia","authors":"Nurul’ Ain Jamion, Khai Ern Lee, Mazlin Mokhtar, Thian Lai Goh","doi":"10.1007/s11270-025-07741-5","DOIUrl":"10.1007/s11270-025-07741-5","url":null,"abstract":"<div><p>This study assessed the spatial variations of water quality and trophic state of the ex-mining lakes converted into man-made wetlands in Paya Indah Wetlands, Selangor, Malaysia. The variations of the parameters were referred to the National Water Quality Standard (NWQS) to determine the water quality index (WQI) and Carlson's Trophic State Index (CTSI), guided by the National Lake Water Quality Standard (NLWQS) to assess the quality and trophic state of lake water. Water sampling was carried out at 13 stations within the Main Lake, Sendayan Lake and Teratai Lake through the DotS sampling method. The potential pollution sources affecting water quality were quantified using a statistical approach, including Pearson's correlation and principal component analysis/factor analysis (PCA/FA). The results show that the water quality parameters in some stations exceeded the NLWQS. Pearson analysis shows that nutrients flow with the organic and inorganic matter in the lake. Average WQI values ranged from 62 to 77, indicating slightly polluted to clean water quality in Paya Indah Wetlands. Two factors were found to account for over 82% of the total variation in the dataset when PCA was used to compare the compositional patterns among the samples that were analysed. This suggests that the point source (open areas for development) and non-point source (agriculture-oil palm estate) as well as the natural processes are the main causes of fluctuations in the concentration of the water components. Organic matter and nutrient regimes mainly affect water quality. Even though the lakes at the studied stations are currently hypertrophic, the overall water quality assessment categorises Paya Indah Wetlands as Class III. Hence, Paya Indah Wetlands has great potential to be an alternative water source supplying water to surrounding areas which require extensive water treatment.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 2","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142939421","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Using a Citizen-installed Network of PM2.5 Sensors to Predict Hourly PM2.5 Airborne Concentration","authors":"Filip Nastić, Nebojša Jurišević, Davor Končalović","doi":"10.1007/s11270-024-07733-x","DOIUrl":"10.1007/s11270-024-07733-x","url":null,"abstract":"<div><p>A growing number of scientific studies have shown that particulate matter harms the environment and endangers human health. Thus, making timely predictions about airborne particulate matter (PM) concentrations could help the general public to be better organized and avoid excessive exposure to harmful pollutants. This study analyzes the possibility of making accurate predictions about PM<sub>2.5</sub> concentrations in ambient air. The proposed methodology is tested using the data from citizen-installed PM<sub>2.5</sub> sensors from three locations (Serbia, North Macedonia, and Pakistan) that are relatively different in size, population (density), geographic, economic, social, and other relevant means. The data (study sample) were collected through the NASA data access viewer online platform and citizen-installed devices that sample PM<sub>2.5</sub> concentrations (non-referent methods). Four predictive algorithms – Random Forest, XGBoost, CatBoost, and LightGBM – were employed to achieve this goal. The Sequential-Forward-Selection algorithm was used to simplify model building, contributing to the generalization of the methodology. Among the selected algorithms, CatBoost exhibited the best performance in Serbia and North Macedonia, while Random Forest performed best in Pakistan. The study conclusion is that here presented methodology is universally applicable for forecasting PM<sub>2.5</sub> airborne concentration in the areas that are covered by citizen-installed PM<sub>2.5</sub> sensors and are not necessarily covered by official referent sampling stations.</p></div>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":"236 2","pages":""},"PeriodicalIF":3.8,"publicationDate":"2025-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142941005","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}