电絮凝法去除废水中微塑料的机理及改进——现状与发展方向

IF 3 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES
Siao Zhang, Sen Wang, Zeng Liu, Xi He, Lifeng Shi, Yukuo Liu, Hao Wang
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引用次数: 0

摘要

与传统方法相比,电絮凝(EC)为去除废水中的微塑料(MPs)提供了一种高效、可持续的解决方案,具有操作简单、污泥产量最小、化学品使用量减少等优点。这篇综述批判性地分析了EC在MPs修复中的现状和机制,包括电荷中和、扫絮凝、电浮选和电化学生成的活性物质促进的氧化降解。评估了操作参数——电极材料(如铝、铁、复合材料)、结构、电流密度、pH值和电极间距——对去除效率的关键影响。至关重要的是,溶解有机物(DOM)在真实基质中的作用,通过吸附竞争或协同共去除影响MPs的去除,得到了解决。在反应器设计(如湍流/蛇形流)和电源(如脉冲电流减轻钝化)的进展是详细的。混合EC系统(如EC-电氧化,EC-膜过滤)表现出优异的MPs去除率(95%)。虽然非常有效(优化了90%),但MPs属性(类型、大小、形状)、DOM复杂性和扩展需求方面存在挑战。未来的研究重点包括优化配置,阐明降解途径,开发具有成本效益的电极,以及工业实施的中试规模验证。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Mechanism and Improvement of Electrocoagulation Technology for Removing Microplastics from Wastewater-Current Status and Future Directions

Electrocoagulation (EC) presents a highly efficient and sustainable solution for microplastic (MPs) removal from wastewater, offering advantages of operational simplicity, minimal sludge production, and reduced chemical usage compared to conventional methods. This review critically analyzes the current state and mechanisms of EC for MPs remediation, encompassing charge neutralization, sweep flocculation, electro-flotation, and oxidative degradation facilitated by electrochemically generated reactive species. The critical influence of operational parameters—electrode material (e.g., Al, Fe, composites), configuration, current density, pH, and inter-electrode spacing—on removal efficiency is evaluated. Crucially, the role of dissolved organic matter (DOM) in real matrices, impacting MPs removal via adsorption competition or synergistic co-removal, is addressed. Advancements in reactor design (e.g., turbulent/serpentine flow) and power supply (e.g., pulsed current mitigating passivation) are detailed. Hybrid EC systems (e.g., EC-electrooxidation, EC-membrane filtration) demonstrate superior MPs removal (> 95%). While highly effective (> 90% optimized), challenges regarding MPs properties (type, size, shape), DOM complexity, and scale-up requirements are identified. Future research priorities include optimizing configurations, elucidating degradation pathways, developing cost-effective electrodes, and pilot-scale validation for industrial implementation.

Graphical Abstract

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来源期刊
Water, Air, & Soil Pollution
Water, Air, & Soil Pollution 环境科学-环境科学
CiteScore
4.50
自引率
6.90%
发文量
448
审稿时长
2.6 months
期刊介绍: Water, Air, & Soil Pollution is an international, interdisciplinary journal on all aspects of pollution and solutions to pollution in the biosphere. This includes chemical, physical and biological processes affecting flora, fauna, water, air and soil in relation to environmental pollution. Because of its scope, the subject areas are diverse and include all aspects of pollution sources, transport, deposition, accumulation, acid precipitation, atmospheric pollution, metals, aquatic pollution including marine pollution and ground water, waste water, pesticides, soil pollution, sewage, sediment pollution, forestry pollution, effects of pollutants on humans, vegetation, fish, aquatic species, micro-organisms, and animals, environmental and molecular toxicology applied to pollution research, biosensors, global and climate change, ecological implications of pollution and pollution models. Water, Air, & Soil Pollution also publishes manuscripts on novel methods used in the study of environmental pollutants, environmental toxicology, environmental biology, novel environmental engineering related to pollution, biodiversity as influenced by pollution, novel environmental biotechnology as applied to pollution (e.g. bioremediation), environmental modelling and biorestoration of polluted environments. Articles should not be submitted that are of local interest only and do not advance international knowledge in environmental pollution and solutions to pollution. Articles that simply replicate known knowledge or techniques while researching a local pollution problem will normally be rejected without review. Submitted articles must have up-to-date references, employ the correct experimental replication and statistical analysis, where needed and contain a significant contribution to new knowledge. The publishing and editorial team sincerely appreciate your cooperation. Water, Air, & Soil Pollution publishes research papers; review articles; mini-reviews; and book reviews.
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