Inorganic Chemistry Frontiers最新文献_第3页

Equatorial thiolate ligand effects in polynuclear dysprosium metallocene single-molecule magnets. 多核茂金属镝单分子磁体中的赤道硫酸盐配体效应。

IF 6.2 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-10-01 DOI: 10.1039/d6qi01594h

Dan Liu, Abdullah A Al-Kahtani, Liviu Chibotaru, Dinh Cao Huan Do, Fu-Sheng Guo, Richard A Layfield

{"title":"Equatorial thiolate ligand effects in polynuclear dysprosium metallocene single-molecule magnets.","authors":"Dan Liu, Abdullah A Al-Kahtani, Liviu Chibotaru, Dinh Cao Huan Do, Fu-Sheng Guo, Richard A Layfield","doi":"10.1039/d6qi01594h","DOIUrl":"10.1039/d6qi01594h","url":null,"abstract":"Thiolate ligands provide a valuable platform on which to study how soft, polarizable donor atoms affect local magnetic anisotropy and exchange coupling in polynuclear dysprosium single-molecule magnets (SMMs). Here, we report the synthesis of the naphthylthiolate-bridged dysprosium metallocene dimer [(CpMe)2Dy(μ-SNaph)]2 (Dy2S2) and trimer [(CpMe)2Dy(μ-SNaph)]3 (Dy3S3) (CpMe = C5H4Me), obtained selectively through temperature-dependent crystallization from the same reaction mixture. The two compounds enable direct comparison of the influence of nuclearity on magnetic behaviour while retaining closely related dysprosium coordination environments. Both compounds exhibit zero-field SMM behaviour with similar effective barriers to magnetic relaxation of 61 and 64 cm-1, respectively, together with significant Raman relaxation at lower temperatures. Ab initio calculations reveal strongly axial ground Kramers doublets with comparable crystal field splittings for all Dy3+ centres. The calculations accurately reproduce the experimental magnetic susceptibility and isothermal magnetization, revealing that increased nuclearity strengthens the antiferromagnetic exchange without significantly perturbing the local magnetic anisotropy.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":" ","pages":""},"PeriodicalIF":6.2,"publicationDate":"2026-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC13644314/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149134364","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Structure-Driven Single-Molecule Magnetism in Heterometallic Ln (III)-Cu (II) Double-Stranded Helicates 异质金属Ln (III)-Cu （II）双链螺旋结构驱动的单分子磁性

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-28 DOI: 10.1039/d6qi01416j

Sayan Saha,Kanta Miyake,Neeraj Dhauni,Riku Fukushima,Ryuto Tominaga,Hisui Kobayashi,Yoshihiro Sekine,Gopalan Rajaraman,Shinya Hayami

{"title":"Structure-Driven Single-Molecule Magnetism in Heterometallic Ln (III)-Cu (II) Double-Stranded Helicates","authors":"Sayan Saha,Kanta Miyake,Neeraj Dhauni,Riku Fukushima,Ryuto Tominaga,Hisui Kobayashi,Yoshihiro Sekine,Gopalan Rajaraman,Shinya Hayami","doi":"10.1039/d6qi01416j","DOIUrl":"https://doi.org/10.1039/d6qi01416j","url":null,"abstract":"By reacting a V-shaped ligand, 4,4’-oxydianiline, with 3-ethoxysalicylaldehyde through a condensation process, we successfully synthesised and characterised three mixed-metal double-stranded helicates involving 3d-4f (Gd-Cu, Dy-Cu and Tb-Cu) metal centres. In these complexes, the lanthanide ions adopt the same coordination environment and connect to the copper ions via a bridging oxygen atom. Comprehensive DC and AC magnetic susceptibility analyses revealed that the lanthanide centres displayed field-induced slow magnetic relaxation, characterised by axial magnetic anisotropy. Magnetic measurements revealed that Tb-Cu functions as an SMM under an applied field of 1000 Oe, with Ueff = 28.6 K. In contrast, Dy-Cu shows only Ueff = 12.5 K under a 3000 Oe field. The Gd-Cu complex, on the other hand, shows cryogenic magnetic refrigeration with an entropy change of 15.8 J kg–1 K–1 under a magnetic field of 5 T and at 2 K. There was a strong alignment between the experimental outcomes and theoretical models, underscoring the robustness of the findings, which is another important aspect of this study.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"20 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149067307","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Strong SHG, Piezoelectricity, and Fluorescence Coexisting in a Single-Component Organic Polar Crystal Enabled by -Hole Interactions 利用-空穴相互作用实现单组分有机极性晶体中强SHG、压电和荧光共存

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-28 DOI: 10.1039/d6qi01921h

Jun-Chao Liu,Xin-Yi Yang,Shuqi Han,Lei Ren,Ruru Wang,Wan-ying Zhang,Pingping Shi

{"title":"Strong SHG, Piezoelectricity, and Fluorescence Coexisting in a Single-Component Organic Polar Crystal Enabled by -Hole Interactions","authors":"Jun-Chao Liu,Xin-Yi Yang,Shuqi Han,Lei Ren,Ruru Wang,Wan-ying Zhang,Pingping Shi","doi":"10.1039/d6qi01921h","DOIUrl":"https://doi.org/10.1039/d6qi01921h","url":null,"abstract":"Single-component organic crystals that simultaneously exhibit strong second-harmonic generation (SHG) and measurable piezoelectricity are highly attractive for multifunctional applications such as flexible optoelectronics, wearable sensors, electromechanical transducers, and on-chip frequency converters, yet achieving such crystals remains a significant challenge because dipolar molecules inherently tend to adopt centrosymmetric packing. Herein, we synthesized a single-component organic small molecule, methyl 4-((5-(thiophen-2-yl)-2H-tetrazol-2-yl)methyl)benzoate (MTTB), a thiophene-tetrazole derivative designed to exploit S•••N σ-hole interactions for directing polar assembly. Single-crystal X-ray diffraction reveals that MTTB crystallizes in the polar space group Pn, with directional S•••N contacts that template the non-centrosymmetric arrangement. The crystal delivers an SHG intensity 7.7-times that of KDP and a piezoelectric coefficient (d33) of 9 pC/N, while also retaining solid-state fluorescence. Density functional theory calculations reveal a HOMO-LUMO gap of 4.55 eV, along with the dipole moment and elastic moduli, providing insight into the electronic and mechanical origins of the observed SHG and piezoelectric responses. This work demonstrates that σ-hole engineering offers a viable strategy for integrating strong SHG, piezoelectricity, and fluorescence within a single-component organic crystal, suggesting a promising direction for the design of multifunctional polar organic materials.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"20 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149067375","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Radical-Driven Reduction Coupled with Protonation for Constructing Cu(I)-Based Hierarchical Metal Organic Frameworks 自由基驱动还原与质子化耦合构建Cu(I)基层次化金属有机骨架

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-28 DOI: 10.1039/d6qi01666a

Xing Gao,Aoxiang Zhang,Xiao Jiao Hou,Xinyi Luo,Xu Zhai,Xinyu Xiao,Xiaotong Lu,Zhicheng Pan,Fanbao Meng,Sha Wang,Wenxiu He,Junyi Chen,Yu Fu

{"title":"Radical-Driven Reduction Coupled with Protonation for Constructing Cu(I)-Based Hierarchical Metal Organic Frameworks","authors":"Xing Gao,Aoxiang Zhang,Xiao Jiao Hou,Xinyi Luo,Xu Zhai,Xinyu Xiao,Xiaotong Lu,Zhicheng Pan,Fanbao Meng,Sha Wang,Wenxiu He,Junyi Chen,Yu Fu","doi":"10.1039/d6qi01666a","DOIUrl":"https://doi.org/10.1039/d6qi01666a","url":null,"abstract":"The distinctive microporous architecture of metal organic frameworks (MOFs) endows them with exceptional performance in gas storage and heterogeneous catalysis. However, the intrinsic microporosity of conventional bulk MOFs significantly restricts molecular diffusion pathways and limits accessibility to active sites. Therefore, converting bulk MOFs into hierarchical nanostructures has emerged as an effective strategy to address this issue. Herein, we propose a radical-driven reduction and protonation (RDRP) strategy. This approach employs photogenerated cyclohexyl radicals from 1-hydroxycyclohexyl phenyl ketone (UV-184) to treat two Cu(II)-based MOFs, successfully constructing hierarchical Cu(I)-MOFs with cubic (PC-I-R) and tubular (PC-II-R) architectures through radical-driven reduction and H⁺-dominated protonation. Notably, this transformation not only preserves the initial crystal morphology, but also maintains the monodentate coordination structure between copper ions and carboxylate groups. Density functional theory (DFT) calculations reveal that the uncoordinated carboxyl oxygen atoms act as Lewis basic sites, capable of accepting protons from the substrate's amino group. This enables PC-II-R to exhibit excellent catalytic performance in the reaction between propargylic amines and CO 2 under solvent-free and cocatalyst-free conditions. A turnover frequency (TOF) as high as 186 h -1 surpasses nearly all noble metal catalysts. The proposed RDRP strategy not only provides an innovative approach for nanostructuring of bulk MOFs but also sets a precedent for catalytic structures with multiple active sites.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"53 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149067440","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Interfacial Electronic Reconstruction in a 3D/2D PCN-222/Bi2MoO6 Heterojunction Enables Efficient CO2 Photoreduction in Pure Water 3D/2D PCN-222/Bi2MoO6异质结的界面电子重建实现纯水中高效的CO2光还原

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-23 DOI: 10.1039/d6qi01784c

Zongqin Zhang,Min Huang,Yanan Wang,Man Zhou,Song Xu,Han Li,Zhongyu Li

{"title":"Interfacial Electronic Reconstruction in a 3D/2D PCN-222/Bi2MoO6 Heterojunction Enables Efficient CO2 Photoreduction in Pure Water","authors":"Zongqin Zhang,Min Huang,Yanan Wang,Man Zhou,Song Xu,Han Li,Zhongyu Li","doi":"10.1039/d6qi01784c","DOIUrl":"https://doi.org/10.1039/d6qi01784c","url":null,"abstract":"Photocatalytic CO2 reduction in pure water represents a promising strategy for sustainable carbon recycling, yet its efficiency is often restricted by inefficient interfacial charge migration and uncontrolled reaction pathways. Herein, a 3D/2D PCN-222/Bi2MoO6 heterojunction was rationally constructed via an in situ growth approach in which porphyrin-based PCN-222 metal-organic frameworks were directly integrated with an Aurivillius-type Bi2MoO6 semiconductor. The optimized PB-2 heterostructure achieves a CO evolution rate of 55.3 μmol g -1 h -1 with nearly 100% selectivity in pure water and retains excellent structural stability over 30 h. Combined spectroscopic investigations and theoretical calculations reveal that interfacial electronic reconstruction induces an S-scheme charge-transfer pathway, enabling efficient separation of photogenerated carriers while preserving strong redox potentials. Furthermore, in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) coupled with density functional theory (DFT) calculations elucidates the CO2 reduction mechanism via a sequential *CO2 → *COOH → *CO pathway, with *COOH formation identified as the rate-determining step. This work elucidates the interplay between heterointerface electronic structure, charge-transfer pathways, and CO2 activation chemistry, providing mechanistic insights into the rational design of MOF-based hybrid photocatalysts for efficient solar-driven CO2 reduction.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"16 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149019699","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Tethered η 2 -B,C Borataalkene Cerium Complexes 系留η 2 -B，C硼烷铈配合物

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-23 DOI: 10.1039/d6qi01313a

Wei Su,Laurent Maron,Qing Ye,Ganping Wang,Na Sun

{"title":"Tethered η 2 -B,C Borataalkene Cerium Complexes","authors":"Wei Su,Laurent Maron,Qing Ye,Ganping Wang,Na Sun","doi":"10.1039/d6qi01313a","DOIUrl":"https://doi.org/10.1039/d6qi01313a","url":null,"abstract":"Abstract: The synthesis and complexation of borataalkenes are of burgeoning interests, owing to their isoelectronic structures to alkenes and potential applications in catalysis. Nevertheless, borataalkene lanthanide complexes are significantly underdeveloped to date, which presumably can be attributed to the mismatch between soft π(B=C) donor and hard lanthanide ions. We herein illustrate several tethered borataalkene cerium complexes. Treatment of cerium diylide 1 with excess BEt3 generated complex 2, featuring a 6-membered NBCPCSi ring. Subsequent reactions between 2 and excess KC8 lead to dearylation and ortho-metalation, affording complex [3•K2(Et2O)3]2. Control experiments imply that dearylation likely happened prior to ortho-metalation in the formation of complex [3•K2(Et2O)3]2, as suggested by the isolation of complex 4•K(Et2O)2. In these complexes, the atomic distances between B and C range from 1.461(14)-1.517(16) Å, demonstrating the presence of borataalkene moieties. Quantum chemical calculations elucidate their electronic structures, revealing the η2-B,C-cerium interactions are predominately electrostatic in nature with distinct ligand-to-metal π donations and without significant π backbonding contributions. These findings may open an avenue to other borataalkene f-block complexes and novel catalytic transformations mediated by them.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"221 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149019754","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Topology-Symmetry Analysis and Design of Nonlinear Optical Borate-Halide Polytypes 非线性光学卤化硼多型的拓扑对称性分析与设计

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-23 DOI: 10.1039/d6qi01900e

Olga Reutova,Wenqi Jin,Zhihua Yang,Shilie Pan

{"title":"Topology-Symmetry Analysis and Design of Nonlinear Optical Borate-Halide Polytypes","authors":"Olga Reutova,Wenqi Jin,Zhihua Yang,Shilie Pan","doi":"10.1039/d6qi01900e","DOIUrl":"https://doi.org/10.1039/d6qi01900e","url":null,"abstract":"Symmetry and topological features are crucial for understanding the nonlinear optical (NLO) effects of functional crystals. Here, we apply the topology-symmetry approach of Dornberger-Schiff's order-disorder (OD) theory, combined with topological analysis of underlying nets, to systematically investigate the only practically used deep-ultraviolet (DUV) NLO crystal KBe2BO3F2 (KBBF) and related compounds. The local symmetry of KBBF-type layers and interlayer spaces is characterized, and the maximum degree of order (MDO) polytypes for KBBF, as well as for KBBF-like family Pb2BO3X (X = Cl, Br, I), are described using symmetry groupoids. Topological analysis shows that KBBF and Pb2BO3X structures possess different topological types, despite identical local layer symmetries. Guided by these results, we designed two novel KBBF polytypes with the Pb2BO3X topology of underlying net, and confirmed their thermodynamic stability by first-principles calculations. The designed KBBF-P321 phase exhibits significantly enhanced second harmonic generation (d22 = 0.58 pm/V compared to 0.47 pm/V for KBBF-R32) due to optimal alignment of [BO3] anionic groups in adjacent layers. This work demonstrates that the integration of symmetry-based OD analysis, topological analysis, and first-principles calculations provides a powerful framework for the rational design of advanced nonlinear optical materials with tailored properties.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"221 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149019662","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Reversible On/Off Switching of Altermagnetism in Two-dimensional Metal-Organic-Frameworks via Molecular Tautomerism 二维金属-有机骨架中通过分子互变异构的可逆电磁开关

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-23 DOI: 10.1039/d6qi00848h

Hongjing Wang,Yixuan Che,Yujin Wang,Xiuling Li,Xiaojun Wu

{"title":"Reversible On/Off Switching of Altermagnetism in Two-dimensional Metal-Organic-Frameworks via Molecular Tautomerism","authors":"Hongjing Wang,Yixuan Che,Yujin Wang,Xiuling Li,Xiaojun Wu","doi":"10.1039/d6qi00848h","DOIUrl":"https://doi.org/10.1039/d6qi00848h","url":null,"abstract":"Altermagnets exhibit compensated magnetic moments in real space while retaining nonrelativistic spin splitting in momentum space, offering a platform for field-robust, ultrafast spin dynamics. Yet practical routes to reversibly manipulate altermagnetic states remain limited and are dominated by structural or external-field modulation. Here, we introduce a chemical molecular-switch strategy that leverages tautomerism in organic linkers to reversibly control spin states in two-dimensional metal-organic framework (2D MOF). Using a Ni-based 2D frameworks as a representative system, we demonstrate a reversible transition between a nonmagnetic phase (Ni-L1) and an altermagnetic phase (Ni-L2) driven by solvent-assisted lactim-lactam proton transfer, with computed barriers of 0.30 eV (forward) and 0.43 eV (reverse). The altermagnetic state exhibits ligand-centered moments of ~ 0.50 µB and a characteristic spin-split electronic structure with band splitting extending across nearly the entire Brillouin zone. Symmetry analysis attributes this unusually persistent splitting to the reduced local (molecular) symmetry of the lactam linker, which removes mirror-related spin-degeneracy constraints present in higher-symmetry analogues. These results establish tautomerization as a chemically reversible handle for altermagnetic phase control in reticular materials and highlight molecular-scale symmetry as a decisive design parameter for reconfigurable altermagnetic electronics.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"47 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149019679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Oxygen Vacancy-Rich 3D BiOBr Microtubes Promoting Exciton Dissociation for Efficient Photocatalytic H2O2 Production 富氧空位3D BiOBr微管促进激子解离，用于高效光催化H2O2生产

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-23 DOI: 10.1039/d6qi01964a

Ke Chen,Bo Lan,Zhishan Liang,Yucong Zou,Dongdong Qin,Bo Ding,Dongfang Han,Wen-Sheng Zhang,Li Niu,Dongxue Han

{"title":"Oxygen Vacancy-Rich 3D BiOBr Microtubes Promoting Exciton Dissociation for Efficient Photocatalytic H2O2 Production","authors":"Ke Chen,Bo Lan,Zhishan Liang,Yucong Zou,Dongdong Qin,Bo Ding,Dongfang Han,Wen-Sheng Zhang,Li Niu,Dongxue Han","doi":"10.1039/d6qi01964a","DOIUrl":"https://doi.org/10.1039/d6qi01964a","url":null,"abstract":"Rapid exciton dissociation into free charge carriers is essential for efficient semiconductor photocatalysis, yet high exciton binding energy often constrains photocarrier extraction. While defect creation and morphological tailoring are individually established strategies, their combined effect on exciton dynamics and carrier migration requires clarification. In this work, 3D mesoporous bismuth oxybromide microtubes with abundant oxygen vacancies were synthesized via a mannitolmediated hydrothermal route, effectively overcoming the intrinsic 2D anisotropic growth habit of BiOBr. Transient absorption spectroscopy, photoluminescence decay measurements, and density functional theory calculations demonstrate that the coupling of 3D tubular nanoconfinement and Ov defect states reduces exciton binding energy, accelerates exciton dissociation, and extends carrier lifetimes. Consequently, the optimized Ov-BiOBr microtubes display enhanced O2 adsorption capacity and superior photocatalytic H2O2 production, achieving an apparent quantum yield of 7.2% at 420 nm-a 14.4-fold increase over pristine BiOBr. This study demonstrates a practical defect-morphology co-engineering approach for modulating exciton dynamics in functional semiconductors.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"62 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149019718","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

From zero-dimensional square tetramers to one-dimensional screw chains: a structural evolution in V 3+ -based lead vanadium fluorides 从零维正方形四聚体到一维螺旋链：v3 +基氟化铅钒的结构演变

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-23 DOI: 10.1039/d6qi01376g

Tianyu Zhu,Wenbin Wei,Du Wang,Zhujing Zhang,Pengfei Zhou,Donger Cheng,Xiaoqin Min,Guang Wang,Junrong Zhang,Zhangzhen He,Xiao Wang,Myung-Hwan Whangbo,Hyun-Joo Koo,Erxi Feng

引用次数: 0