Inorganic Chemistry Frontiers最新文献

{"title":"Photoisomerisable zero-field Co(II) single-ion magnets with azo-functionalized sulfonamide ligands: synthesis, crystal structure, magnetism and light-induced switching","authors":"Petr Halaš,Ivan Nemec,Erik Čižmár,Lucie Routaboul,Laure Vendier,Radovan Herchel","doi":"10.1039/d6qi01825d","DOIUrl":"https://doi.org/10.1039/d6qi01825d","url":null,"abstract":"Three new zero-field Co(II) single ion magnets (SIMs) [Co(L1)2]·1.3MeOH (1), [Co(L2)2]·0.25MeOH (2), [Co(L3)2] (3) and one Zn(II) analogue [Zn(L3)2] (Zn3) were synthesized using azo-derivatized N-sulfonylated amine ligands HL1, HL2 and HL3. All Co(II) complexes possess large axial magnetic anisotropy (Dexp = -61.2, -58.5, and -94.8 cm-1 for 1-3, respectively) with near-zero rhombicity stemming from axially elongated tetrahedral symmetry. Dynamic magnetic measurements revealed slow relaxation of magnetization up to 15 K for 1 and 2, and up to 18 K for 3 under zero applied DC field, dominated by Raman and quantum tunneling processes. For complex 2, Orbach process was additionally observed with Ueff = 164.0 K (114.0 cm-1). Photoisomerisation experiments in solution and PMMA films demonstrated reversible light-induced switching for 1, 2, and Zn3 upon blue/UV irradiation, with no detectable degradation after ten cycles. These findings are further supported by DFT/TD-DFT calculations. Special attention is given to the study of non-covalent interactions in the vicinity of metal centres. To our knowledge, this represents the first report of light-switchable azo-functionalized zero-field Co(II) SIMs.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"4 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148853730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Guest-controlled charge transfer strategy for developing MOF-based triboelectric materials to enhance self-powered corrosion protection","authors":"Dongqing Wu,Weibing Liu,Yangshuang Yan,Xinyu Zhao,Yuchen Liu,Keru Li,Ji Chen,Yahui Ma,Bin Zhai,Zhichao Shao","doi":"10.1039/d6qi01500j","DOIUrl":"https://doi.org/10.1039/d6qi01500j","url":null,"abstract":"The development of triboelectric materials with efficient charge transfer capabilities is critically important for advancing self-powered systems. In this study, two isostructural Cd-MOFs were rationally designed and synthesized via a guest molecule-mediated charge transfer strategy. Their triboelectric performance results demonstrate that Cd-MOF-DMF delivers superior electrical output: under 5 Hz mechanical excitation, it achieves an open-circuit voltage of 495.48 V, a short-circuit current of 51.05 μA, and a peak power density of 1211.28 mW m-2. Moreover, Cd-MOF-DMF exhibits excellent chemical stability, structural robustness, and tunable functionality — outperforming conventional polymeric triboelectric materials. Furthermore, Cd-MOF-DMF was successfully integrated into an active cathodic protection system, effectively suppressing electrochemical corrosion of metallic substrates. DFT calculations further reveal that guest molecule incorporation elevates the HOMO energy level and narrows the band gap of the Cd-MOF framework, thereby enhancing electron delocalization and facilitating interfacial charge transfer during triboelectrification. This work establishes a promising pathway toward high-efficiency, stable, and designable triboelectric materials.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"3 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148853695","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Constructing bifunctional Pd@CoAl-LDHs catalysts via metal cation confined in-situ reduction for highly efficient reductive amination of biomass-derived cyclohexanone","authors":"Jun Wu,Jiahao Bai,Yuhang Xie,Tailong Shi,Gang Pan,Yong Li","doi":"10.1039/d6qi01381c","DOIUrl":"https://doi.org/10.1039/d6qi01381c","url":null,"abstract":"Developing efficient and stable metal catalysts for the highly selective reductive amination of biomass-derived model compound of cyclohexanone (CyO) under mild conditions remains a significant challenge. Herein, a thermodynamic-driven metal cation confined in-situ reduction strategy was used to construct highly dispersed Pd nanoparticles on CoAl-LDHs (Pdx@CoyAl-LDHs, x = 0.5-2.5 wt%, y = 2-4) without employing external reductants. Driven by the intrinsic low oxidation potential of atomically distributed Co2+ within the LDHs laminates, the adsorbed Pd2+ species are in-situ reduced and anchored, producing small-sized and uniformly dispersed Pd nanoparticles supported on the CoAl-LDHs. Moreover, the electronic metal-support interaction (EMSI) between active Pd and CoAl-LDHs support promoted the formation of bifunctional metal-acid active sites within the Pdx@CoyAl-LDHs catalysts. The catalytic reaction kinetic study revealed that the optimal Pd2@Co3Al-LDHs presented excellent catalytic performance toward CyO reductive amination, affording a 95.1% cyclohexylamine selectivity and a high reaction rate of 469 mmol·gPd-1·h-1. Such superior catalytic performance was attributed to the synergistic catalysis of bifunctional metal-acid sites based on the structure-performance relationship analysis, which promoted the adsorption and activation of CyO, H2, NH3 and Schiff base intermediate, and effectively suppressed the side reactions such as over-hydrogenation. The corresponding reaction pathway and catalytic mechanism for CyO reductive amination were elucidated. Furthermore, the catalyst exhibited robust cycling stability and broad substrate generality for the reductive amination of various carbonyl compounds, providing a facile and green paradigm for designing bifunctional catalysts for sustainable biomass upgrading to valuable primary amines.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"129 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148853805","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Size-controlled Pd clusters confined in zeolites for efficient and stable electrochemical nitrate reduction to ammonia","authors":"Shuting Du,Guizhen Gao,Jiayi Liu,Surong Zhang,Yihang Xia,Ziyu Wang,Hongming He,Chengpeng Li,Qiming Sun","doi":"10.1039/d6qi01413e","DOIUrl":"https://doi.org/10.1039/d6qi01413e","url":null,"abstract":"Electrochemical nitrate reduction to ammonia (NO3RR) represents an attractive strategy for coupling nitrate-containing wastewater treatment with sustainable ammonia synthesis under ambient conditions. However, its practical implementation is hindered by the competing hydrogen evolution reaction, insufficient nitrate adsorption at active interfaces, and poor long-term stability of noble metal catalysts. Herein, we present an ultra-stable Pd@S-1 electrocatalyst in which size-tunable Pd clusters are encapsulated within silicalite-1 (S-1) zeolite through a one-pot hydrothermal synthesis. The S-1 zeolite serves a dual role: it spatially confines Pd species to prevent aggregation and leaching, and establishes a microporous microenvironment that enriches nitrate near the active sites, thus promoting reaction kinetics and suppressing HER. The optimized Pdm@S-1 catalyst with an average Pd size of 2.08 nm exhibits superior NO3RR performance in neutral electrolyte, delivering an ammonia production rate of (133.38 ± 16.76) mg h−1 mgPd−1 at −1.1 V vs. RHE. Notably, Pdm@S-1 preserves nearly unchanged catalytic performance over 100 successive cycles, evidencing outstanding durability. These findings highlight the importance of coupling active metal sites with a confinement induced reactant-enrichment effect, and offer a viable design principle for durable and efficient electrocatalysts for nitrate reduction to ammonia.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"44 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148853761","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The formation of exfoliable zeolite nanosheets by addition of Al to the synthesis gel of unexfoliating 2D ferrierite precursor","authors":"Wieslaw J. Roth,Barbara K Gil,Wacław Makowski,Aleksandra Korzeniowska,Takayoshi Sasaki","doi":"10.1039/d6qi01199c","DOIUrl":"https://doi.org/10.1039/d6qi01199c","url":null,"abstract":"Zeolites are highly valued industrial catalysts and sorbents with discrete microporous framework structures that can produce two different forms with the same topology: a fixed 3D rigid framework and discrete 2D layers, less than a few nanometer thick. Layered zeolites have flexible structures that can be intercalated, expanded, delaminated and disorganized but proved difficult to exfoliate into monolayer dispersions in solution. Exfoliated zeolite layers can be used for the preparation of advanced materials that are not possible or difficult to obtain with the other 3D and 2D forms including intimate hybrids and composites, films, membranes and nano-devices. Direct exfoliation of several 2D zeolites has been achieved recently by treatments with suitable solutions, e.g. tetrabutylammonium hydroxide (TBAOH). However, 2D zeolite exfoliation is still a problem needing solving since the yields vary and depend on sample preparation, while some 2D zeolites do not exfoliate at all. The proposed likely reasons are crystal/layer intergrowths, which are difficult to control. The goal of this article is to report unexpected findings about exfoliation of siliceous 2D ferrierite precursor with 0.95 nm thick nanosheets, denoted ZSM-55. It does not exfoliate in TBAOH but adding Al to its synthesis gel generates new exfoliable layers, denoted bifer, with analogous planar unit cell but doubled thickness. This is a clear lead to extend the investigation to other 2D zeolites, to study the effect of adding Al to their synthesis mixture for the possibility of obtaining exfoliable layers. In the present case, increasing the amount of added Al produces more bifer in the mixture with ZSM-55, then pure bifer is obtained at Si/Al in the gel equal to 16/1, while for Si/Al = 10 3D ferrierite is produced. Similar transformations from multilayered precursor to exfoliable monolayers to 3D framework occur for MCM-22 (zeolite MWW) but without changing the layer thickness. Bifer materials separated from ZSM-55 by exfoliation and synthesized directly have comparable high Al content based on FTIR. ZSM-55 left after bifer removal by exfoliation has low Al content, emphasizing the primary role of Al in the bifer formation and probably its exfoliability. Sampling during synthesis of the mixture shows that ZSM-55 forms before bifer but is preceded by an unknown intermediate phase which disappears and is thermally unstable. Exfoliated and isolated bifer has high mesoporous surface area and strong acid activity. The reasons for Al promotion of zeolite monolayers and exfoliability are not well understood.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"643 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148853692","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Aromatic to Quinoid Structure Conversion Triggered by Two-Electron Reduction of B–N Lewis Pair Fused Anthracene","authors":"Yikun Zhu,Rajendra Prasad Nandi,Tara Phuyal,Wei Zheng,Frieder Jaekle,Marina A. Petrukhina","doi":"10.1039/d6qi01394e","DOIUrl":"https://doi.org/10.1039/d6qi01394e","url":null,"abstract":"Boron–nitrogen (BN) incorporation offers a versatile approach to modulate the electronic structure of polycyclic aromatic hydrocarbons by combining electron-deficient and electron-rich elements within a single π-framework. In this work, we examine the two-electron reduction of a BN-fused dipyridylanthracene (BDPA, 1), providing access to a family of alkali-metal dianion salts, M2-12– (M = Li, Na, K, and Rb). Single-crystal X-ray diffraction reveals cation-dependent ion-pairing motifs, with solvent-separated ion products for Li and K and contact ion products seen for Na and Rb. Computational analysis shows that product stabilization is governed by partial charge transfer from the reduced BDPA core to the metal centers. Structural analysis further reveals substantial bond-length reorganization and increased curvature of the π-framework upon reduction, consistent with the emergence of quinoidal electronic delocalization. This transformation is accompanied by a pronounced redistribution of aromaticity, involving a loss of aromatic character of the pyridyl groups and the central anthracene ring, and an enhancement of aromaticity in the terminal rings, as supported by HOMA and NICS analyses. A comparison of the electronic structure of the dianion 12– with those of isoelectronic dianionic all-carbon (M12–) and neutral BN-fused N,N-dihydrophenazine (M2) analogs demonstrates much more profound quinoidal character of 12–, signifying how the dearomatization and delocalization of charge is effectively supported by ‘B–N for C–C’ substitution. Together, these results demonstrate that two-electron reduction can be exploited to trigger dramatic changes in charge distribution and aromaticity, which directly impact the structural and spectroscopic properties of B–N Lewis pair functionalized PAHs.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"40 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148853691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mechanoresponsive Ir() acyclic-carbene luminophores exhibiting C,N ⇄ C,O coordination-mode switching","authors":"Shing-Lun Chan,Shun-Cheung Cheng,Shek-Man Yiu,Chi-Chiu Ko","doi":"10.1039/d6qi01474g","DOIUrl":"https://doi.org/10.1039/d6qi01474g","url":null,"abstract":"Mechanoresponsive luminophores are typically governed by mechanically induced changes in intermolecular packing, which is often difficult to control by molecular design. Herein, we report cyclometalated Ir(iii) complexes in which their solid-state phosphorescence mechanochromism originates instead from a discrete coordination-sphere transformation of a bidentate acyclic carbene ligand. Mechanical grinding triggers an unprecedented mechanochemical structural isomerization, converting a C,N-coordinated pyridyl-aminooxycarbene (NCN-type) into a C,O-coordinated diaminocarbene (OCN-type) via a reversible carbene ligand switching (NCN ⇄ OCN). IR difference spectroscopy, corroborated by DFT vibrational analysis, provides direct evidence for the NCN → OCN conversion in the solid state and reveals a characteristic C≡N stretch consistent with an isocyanide-containing intermediate. Solution NMR studies establish thermal interconversion and quantify the NCN ⇄ OCN equilibrium, while kinetic measurements across solvents with Eyring analysis afford positive ΔH‡ and ΔS‡ values, supporting an activated pathway involving C–O bond cleavage and recoordination. These results define a new mechanistic pathway for organometallic mechanochemical behavior, in which emission switching is driven by mechanically addressable structural isomerization of the ligand.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"27 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148853757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Study on the Mechanism of Ti Doping Inducing 1T-MoS 2 and Its Zinc Storage Performance","authors":"Changlian Wang,Yuning Cui,Yali Liang,Ye Xu,Meng Xing,Hailong Qiu,Di Jin","doi":"10.1039/d6qi01021k","DOIUrl":"https://doi.org/10.1039/d6qi01021k","url":null,"abstract":"Two-dimensional layered nanomaterials are promising cathodes for aqueous zinc-ion batteries (AZIBs) owing to their abundant ion transport channels. However, the narrow interlayer spacing of conventional MoS 2 limits Zn 2+ transport. In this study, Ti 4+ is introduced into the MoS 2 lattice to modulate its phase structure, thereby converting the conventional 2H-phase MoS 2 (interlayer spacing: 0.64 nm) to the 1T-phase with an expanded spacing of 0.98 nm. Density Functional Theory and molecular dynamics calculations based on a machine learning potential reveal that Ti 4+ intercalation reduce the 1T-2H energy difference, promotes 1T-phase formation, and increases the transition barrier for its stabilization. The resulting dual-phase nanoflower exhibits reduced particle size, abundant 1T content, and enhanced zinc ion transport, delivering a high reversible capacity of 274.4 mAh g -1 at 0.1 A g -1 and 120.8 mAh g -1 at 5 A g -1 with only 0.012% decay per cycle over 2500 cycles. The material also performs well under extreme temperatures and in flexible quasi-solid-state AZIBs, providing new insights into designing high-performance cathodes.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"489 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148853690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A dynamic stage for framework editing: harnessing late crystallization rearrangement in FAU zeolite","authors":"Tian Xia,Hongjuan Zhao,Rui Li,Peng Liu,Qiang Zhang,Jiujiang Wang,Huangfei Liu,Penghui Zeng,Honghai Liu,Xiaochun Zhu,Shenyong Ren,Xionghou Gao,Chunming Xu,Baojian Shen","doi":"10.1039/d6qi01072e","DOIUrl":"https://doi.org/10.1039/d6qi01072e","url":null,"abstract":"Zeolite properties are governed by their multi-scale structures, and precise control over these structures remains a central challenge. Conventional hydrothermal synthesis regards the plateau in macroscopic crystallinity, termed the “late stage of crystallization”, as the endpoint, overlooking atomic-scale evolution. This work reveals that the framework of NaY zeolite remains dynamic beyond this plateau, undergoing a directed rearrangement of the Si–Al distribution (decrease in Si(0Al) units and increase in Si(3Al) units). This “dynamic late stage of crystallization” provides a critical window for editing zeolite framework at the final synthetic step. Based on this, a “dynamic late-stage editing” strategy is proposed that introduces target elements during this stage to enable in situ framework modification. The editing outcome is inherently element-dependent. Silicon editing achieves framework optimization by altering the Si–Al redistribution pathway, synergistically increasing the framework Si/Al ratio and forming a silica-rich surface layer, thereby substantially enhancing thermal stability. Iron editing induces heterogeneous functionalization, with surface-enriched iron species forming a multiphase structure, reversing the decreasing trend of Si(0Al) units and tailoring a Lewis-acid-rich environment. This work uncovers the dynamic nature of the late stage of zeolite crystallization and establishes a general editing strategy that enables predictable tailoring of zeolite properties.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"19 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148805847","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ion rectification built-in electric field at ZnS/SnS heterojunction enables homogeneous epitaxial growth of Zn anodes","authors":"Maoyu Sun,Shiyu Zhang,Wanxing Zhang,Lu Li,Chungang Wang,Bingqiu Liu","doi":"10.1039/d6qi00627b","DOIUrl":"https://doi.org/10.1039/d6qi00627b","url":null,"abstract":"Aqueous zinc-ion batteries (AZIBs) show significant potential for grid-scale energy storage, yet their practical deployment is hindered by uncontrollable zinc dendrite growth and severe interfacial side reactions. Herein, we propose a multiscale interfacial regulation strategy that employs uniform carbon-encapsulated ZnS/SnS2 nanocube heterojunctions (CHZS) as a multifunctional protective layer for the Zn anode. The intimate coupling of ZnS and SnS2 induces a robust built-in electric field at the heterojunction interface. This field acts as an “ion rectifier”, thermodynamically lowering the nucleation overpotential and kinetically accelerating Zn2+ transfer. Furthermore, the tailored cubic architecture eliminates localized electric field hotspots and buffers mechanical stress during the plating and stripping processes. Owing to this synergistic regulation of both electronic structure and spatial morphology, CHZS@Zn symmetric cells exhibit highly stable cycling for over 1200 hours at 1 mA cm−2 with a low overpotential of 45 mV. When coupled with an α-MnO2 cathode, the resulting full cells demonstrate substantially enhanced rate capability and cycling stability. This heterojunction engineering strategy, centered on built-in electric fields and the “ion rectifier” concept, provides a highly effective approach for developing durable metal anodes in next-generation energy storage systems.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"20 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148805758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}