V. Zazhigalov, O. Sachuk, O. Kiziun, O. Diyuk, I. Bacherikova
{"title":"Mechanochemical and Sonochemical Obtaining of Nanosized Oxides Materials and Catalysts: A Review","authors":"V. Zazhigalov, O. Sachuk, O. Kiziun, O. Diyuk, I. Bacherikova","doi":"10.1007/s11237-024-09797-6","DOIUrl":"https://doi.org/10.1007/s11237-024-09797-6","url":null,"abstract":"","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141377356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sh.F. Tagiyeva, S. N. Osmanova, A. I. Rustamova, D. B. Tagiyev, E. H. Ismailov
{"title":"Methanation of Carbon Dioxide on Co-Containing Aluminosilicate Catalysts","authors":"Sh.F. Tagiyeva, S. N. Osmanova, A. I. Rustamova, D. B. Tagiyev, E. H. Ismailov","doi":"10.1007/s11237-024-09803-x","DOIUrl":"https://doi.org/10.1007/s11237-024-09803-x","url":null,"abstract":"<p>Results of the study of CO<sub>2</sub> methanation on Co-containing catalysts based on Siral aluminosilicates with different SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> ratios (1, 10, and 40) are presented. It is shown that methane is the main product at temperatures up to 573 K, its yield varies depending on the SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> ratio of aluminosilicate. Carbon monoxide is formed along with methane at temperatures above 573 K. Maximum methane yields of 55% and 41% (at 573 K) are achieved on Co/Siral-1 and Co/Siral-10 catalysts. It is shown that catalysts reduced in a hydrogen flow are characterized by the presence of superpara/ferromagnetic particles and magnetic resonance parameters of their EMR spectra significantly depends on the SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> ratio of the aluminosilicate. It is assumed that the superpara/ferromagnetic particles formed during high-temperature hydrogen treatment of Co-containing aluminosilicates are catalytically active particles in the methanation of carbon dioxide.</p>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141259180","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. S. Saberov, N. Korotkikh, A. Avksentiev, V. Yenya, G. Rayenko
{"title":"Catalytic Properties of Sterically Shielded Carbene Complexes of Palladium in C–C and C–N Coupling Reactions of Haloarenes","authors":"V. S. Saberov, N. Korotkikh, A. Avksentiev, V. Yenya, G. Rayenko","doi":"10.1007/s11237-024-09801-z","DOIUrl":"https://doi.org/10.1007/s11237-024-09801-z","url":null,"abstract":"","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141271287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. S. Avksentiev, V. Sh. Saberov, G. F. Rayenko, A. B. Ryabitsky, E. V. Polunkin, S. M. Pleskun, N. I. Korotkikh
{"title":"Catalysis of the Transesterification Reaction of Alkyl Benzoates and Vegetable Oils by Carbonates, Carbene, and Anionite","authors":"A. S. Avksentiev, V. Sh. Saberov, G. F. Rayenko, A. B. Ryabitsky, E. V. Polunkin, S. M. Pleskun, N. I. Korotkikh","doi":"10.1007/s11237-024-09802-y","DOIUrl":"https://doi.org/10.1007/s11237-024-09802-y","url":null,"abstract":"<p>The catalytic effect of alkali metal carbonates, in situ generated carbene, and anionite in the transesterification reaction of alkyl benzoates with methanol, ethanol, benzyl alcohol, and cyclohexanol, as well as vegetable oils with methanol and ethanol was studied. Catalytic reactions with methanol occur at room temperature with yields close to quantitative. The reactions of the vegetable oils in the presence of potassium carbonate with small amounts of methanol or ethanol (3.2 eq) at room temperature lead to high yields of biodiesel fuel and are suitable for industrial use.</p>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141258924","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. L. Ovcharov, P. I. Glukhova, G. V. Korzhak, O. S. Kutsenko, T. R. Stara, S. Ya. Kuchmiy
{"title":"Influence of Sulfur Doping of Crystalline Carbon Nitride on Photocatalytic Hydrogen Evolution from Alcohol–Aqueous Solutions Under Visible Light","authors":"M. L. Ovcharov, P. I. Glukhova, G. V. Korzhak, O. S. Kutsenko, T. R. Stara, S. Ya. Kuchmiy","doi":"10.1007/s11237-024-09798-5","DOIUrl":"https://doi.org/10.1007/s11237-024-09798-5","url":null,"abstract":"<p>The influence of sulfur on the morphology, spectral, and photocatalytic properties of bulk (S-g-C<sub>3</sub>N<sub>4</sub>) and crystalline carbon nitride (S-CGCN), obtained by the pyrolysis of melamine–S<sub>8</sub> mixtures and additional thermal treatment of S-g-C<sub>3</sub>N<sub>4</sub> in the eutectic melt of KCl and LiCl salts, has been investigated. It is shown that crystalline carbon nitride obtained in the presence of 5 wt.% of S<sub>8</sub> (5S-CGCN) demonstrate the highest photocatalytic activity in the hydrogen evolution process from water–ethanol solutions under the effect of visible light. The effective quantum yield of H<sub>2</sub> formation with the participation of 5S-CGCN and metal co-catalysts (palladium and gold) is Φ ≈ 100% at λ = 405 nm, which is almost twice as much as with the participation of unmodified CGCN. The high activity of 5S-CGCN can be associated with more intensive absorption of light, better separation of photogenerated charges, and suppression of their recombination.</p>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141259946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. S. Davtian, D. G. Chikhichin, O. O. Levchenko, G. L. Kamalov
{"title":"Effect of the Acidic Treatment on the Catalitic Properties of Natural Aluminosilicates in Glycerol Acetylation","authors":"A. S. Davtian, D. G. Chikhichin, O. O. Levchenko, G. L. Kamalov","doi":"10.1007/s11237-024-09800-0","DOIUrl":"https://doi.org/10.1007/s11237-024-09800-0","url":null,"abstract":"<p>The kinetics of the reaction of glycerol with acetic acid in the presence of natural aluminosilicates treated with nitric acid has been investigated. The influence of a molar ratio of the reagents, the reaction temperature and the catalyst mass fraction on glycerol conversion, as well as a rate of the accumulation of the products and their selectivities has been studied. It is established that in presence of clinoptilolite and trepel, monoacetin is the main product. In the case of bentonite, with the increase in the molar fraction of acetic acid and the catalyst mass fraction, the selectivity of monoacetin decreases due to a diacetin accumulation.</p>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141193038","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
I. B. Bychko, N. V. Vlasenko, G. R. Kosmambetova, L. B. Kharkova, O. G. Yanko, V. M. Ogenko, V. I. Grytsenko, P. E. Strizhak
{"title":"Catalytic Properties of Carbon Dots Based Rh-Containing Nanocomposites on Si, Al, Zr Oxides in the Water Shift Reaction","authors":"I. B. Bychko, N. V. Vlasenko, G. R. Kosmambetova, L. B. Kharkova, O. G. Yanko, V. M. Ogenko, V. I. Grytsenko, P. E. Strizhak","doi":"10.1007/s11237-024-09799-4","DOIUrl":"https://doi.org/10.1007/s11237-024-09799-4","url":null,"abstract":"<p>The catalytic activity of rhodium-containing nanocomposites with carbon nanodots and Si, Al and Zr oxides in high-temperature water shift reaction has been established. The role of support lies in regulation of the surface concentration of the active component (Rh) and its localization. The use of the support with a low specific surface promote the localization of the active component on the external surface that leads to the decrease of the distance between supported Rh particles, which is important for the surface migration of intermediate products of the reaction.</p>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141193039","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Y. I. Pyatnitsky, L. Yu. Dolgikh, I. L. Stolyarchuk
{"title":"Thermodynamic and Kinetic Analysis of Catalytic Processes of Bioethanol Conversion for Hydrogen and Propylene Obtaining","authors":"Y. I. Pyatnitsky, L. Yu. Dolgikh, I. L. Stolyarchuk","doi":"10.1007/s11237-024-09795-8","DOIUrl":"https://doi.org/10.1007/s11237-024-09795-8","url":null,"abstract":"<p>It is shown that the initial reaction pathways of the processes of steam reforming of ethanol (SRE) or ethanol to propylene (ETP) conversion can be the same and include dehydrogenation and condensation reactions with the formation of acetaldehyde and acetone. The equilibrium yields of propylene and hydrogen in the ETP process, in contrast to SRE, depend little on both temperature and ethanol concentration. An equation for the determination of hydrogen yield as the function of selectivity of carbon-containing compounds has been proposed, based on which the hydrogen concentration in products of the SRE and ETP processes can be calculated.</p>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140166808","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. M. Kurmach, D. V. Kyryliuk, A. O. Samotoi, S. O. Sotnik, P. S. Yaremov, O. V. Shvets, N. D. Shcherban
{"title":"Catalytic Properties of Hierarchical CsAlTi-BEA Zeolites in the Process of Conversion of Styrene with Co2 for Cyclic Carbonate Formation","authors":"M. M. Kurmach, D. V. Kyryliuk, A. O. Samotoi, S. O. Sotnik, P. S. Yaremov, O. V. Shvets, N. D. Shcherban","doi":"10.1007/s11237-024-09794-9","DOIUrl":"https://doi.org/10.1007/s11237-024-09794-9","url":null,"abstract":"<p>Hierarchical CsAlTi-BEA zeolites, due to the presence of a high concentration of Lewis acid sites formed by tetrahedrally coordinated Ti<sup>4+</sup> ions in the zeolite structure and the neutralization of Brønsted acid sites by Cs<sup>+</sup> cations, exhibit high catalytic activity in the tandem reaction of cyclic carbonate formation from styrene in the presence of tert-butyl hydroperoxide under CO<sub>2</sub> pressure. The conversion of styrene into epoxide and further into carbonate increases with the content of titanium in the samples, while the selectivity for the cyclic carbonate increases with the content of cesium.</p>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140166827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Prospects for the Development of Nanocomposite Catalysts for the Oxidative Conversion of C1-C4 Alkanes with Carbon Dioxide to Produce Hydrogen/Synthesis Gas and Organic Compounds: A Review","authors":"S. O. Soloviev","doi":"10.1007/s11237-024-09790-z","DOIUrl":"https://doi.org/10.1007/s11237-024-09790-z","url":null,"abstract":"<p>The ways of targeted design of effective nanocomposite catalysts based on metal oxide systems and zeolites, in particular BEA type, for the processes of dry/super-dry conversion of methane/biogas for the obtaining of hydrogen and syngas with adjustable H<sub>2</sub>/CO ratio as well as oxidative dehydrogenation of C<sub>3</sub>-C<sub>4</sub> alkanes with the participation of CO<sub>2</sub> producing valuable olefins and dienes are considered. Isolated metal cations/small clusters exhibit higher activity, selectivity, and stability when compared to bulk structures in alkane dehydrogenation reactions since their activation involves the participation of coordinatively unsaturated metal cations on anionic vacancies. This can serve as a scientific basis for the targeted development of highly active and stable catalysts for such processes.</p>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":null,"pages":null},"PeriodicalIF":1.0,"publicationDate":"2024-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140166758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}