Influence of the Nature of Rare Earth Elements (Y, La, Ce) on Physicochemical and Catalytic Properties of Mg-Al Oxide System in the Vapor-Phase Conversion of Ethanol Into 1-Butanol

IF 0.7 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Theoretical and Experimental Chemistry Pub Date : 2025-04-02 DOI:10.1007/s11237-025-09827-x

K. V. Valihura, O. V. Larina, S. O. Soloviev

引用次数: 0

Abstract

The results of study on the influence of rare earth elements (Y, La, Ce) on physicochemical characteristics and catalytic properties of Mg-Al oxide system in the vapor phase condensation process of ethanol with the obtaining of 1-butanol are presented. The Mg-Al-Y-oxide catalyst is established to have the highest selectivity for the target product 1-butanol, as well as the stability of operation over time. The positive effect of yttrium consists in the formation of additional acidic and basic sites on the catalyst surface.

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稀土元素（Y、La、Ce）性质对Mg-Al氧化体系气相转化乙醇制1-丁醇理化及催化性能的影响

本文研究了稀土元素（Y、La、Ce）对Mg-Al氧化物体系在乙醇气相缩合制丁醇过程中理化特性和催化性能的影响。mg - al - y -氧化物催化剂对目标产物1-丁醇具有最高的选择性，并且随着时间的推移具有稳定性。钇的积极作用在于在催化剂表面形成额外的酸性和碱性位点。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Theoretical and Experimental Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

1.60

自引率

10.00%

发文量

审稿时长

6-12 weeks

期刊介绍： Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as: a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials; b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions; c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.