{"title":"磷酸、膦基改性膨润土-聚丁二烯橡胶复合材料对罗丹明6G的多层吸附","authors":"S. Aliyeva, I. Buniyatzadeh, R. Alosmanov","doi":"10.1007/s11237-025-09838-8","DOIUrl":null,"url":null,"abstract":"<p>It is shown that the adsorption of Rhodamine 6G (Rh6G) onto a composite material obtained by oxidative chlorophosphorylation of polybutadiene rubber and bentonite with subsequent hydrolysis is satisfactory described with using the models containg at least three parameters. The need to use such multi –parametric models for description of Rh6G adsorption can be a sign of its multilayered adsorption on the adsorbent, as well as the cooperative effect. The high adsorption capacity of the composite towards Rh6G can be caused by its electrostatic binding with phosphate and phosphonate functional groups on the surface.</p>","PeriodicalId":796,"journal":{"name":"Theoretical and Experimental Chemistry","volume":"60 5","pages":"357 - 366"},"PeriodicalIF":0.9000,"publicationDate":"2025-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Multilayer Adsorption of Rhodamine 6G onto Composite of Bentonite and Polybutadiene Rubber Modified with Phosphate and Phosphonate Groups\",\"authors\":\"S. Aliyeva, I. Buniyatzadeh, R. Alosmanov\",\"doi\":\"10.1007/s11237-025-09838-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>It is shown that the adsorption of Rhodamine 6G (Rh6G) onto a composite material obtained by oxidative chlorophosphorylation of polybutadiene rubber and bentonite with subsequent hydrolysis is satisfactory described with using the models containg at least three parameters. The need to use such multi –parametric models for description of Rh6G adsorption can be a sign of its multilayered adsorption on the adsorbent, as well as the cooperative effect. The high adsorption capacity of the composite towards Rh6G can be caused by its electrostatic binding with phosphate and phosphonate functional groups on the surface.</p>\",\"PeriodicalId\":796,\"journal\":{\"name\":\"Theoretical and Experimental Chemistry\",\"volume\":\"60 5\",\"pages\":\"357 - 366\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2025-05-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Theoretical and Experimental Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11237-025-09838-8\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical and Experimental Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11237-025-09838-8","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Multilayer Adsorption of Rhodamine 6G onto Composite of Bentonite and Polybutadiene Rubber Modified with Phosphate and Phosphonate Groups
It is shown that the adsorption of Rhodamine 6G (Rh6G) onto a composite material obtained by oxidative chlorophosphorylation of polybutadiene rubber and bentonite with subsequent hydrolysis is satisfactory described with using the models containg at least three parameters. The need to use such multi –parametric models for description of Rh6G adsorption can be a sign of its multilayered adsorption on the adsorbent, as well as the cooperative effect. The high adsorption capacity of the composite towards Rh6G can be caused by its electrostatic binding with phosphate and phosphonate functional groups on the surface.
期刊介绍:
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.