Green Chemistry最新文献_第4页

A mesoporous TiO2/carbon dot heterojunction photocatalyst efficiently cleaves entire types of C–O bonds in lignin under visible light† 一种介孔TiO2/碳点异质结光催化剂在可见光下能有效地切割木质素中的C-O键

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-07-03 DOI: 10.1039/D5GC01918D

Song Han, Yun Zhao, Mina Liang, Xiangxiong Zhai, Qi Zhang, Na Sun, Rong Ma, Guoling Li, Zhubing Xiao and Zhonghai Ni

{"title":"A mesoporous TiO2/carbon dot heterojunction photocatalyst efficiently cleaves entire types of C–O bonds in lignin under visible light†","authors":"Song Han, Yun Zhao, Mina Liang, Xiangxiong Zhai, Qi Zhang, Na Sun, Rong Ma, Guoling Li, Zhubing Xiao and Zhonghai Ni","doi":"10.1039/D5GC01918D","DOIUrl":"https://doi.org/10.1039/D5GC01918D","url":null,"abstract":"The progress of photocatalytic biomass depolymerization under mild conditions for the production of high-value chemicals has great potential. Previous studies showed that commercial TiO2 effectively cleaved α-O-4 linkages, but 4-O-5 linkages were much harder to break due to higher bond energy. Here, we successfully synthesized mesoporous TiO2 with a high specific surface area, while oxygen vacancies enhanced its visible light absorption and regulated the position of the energy band. Additionally, the Z-scheme heterojunction Pt@CDs-2/TiO2-MP was successfully prepared by introducing carbon dots, thereby effectively promoting the separation and transfer of photogenerated hole–electron pairs. Pt@CDs-2/TiO2-MP was employed for the cleavage of 4-O-5 type lignin model diphenyl ether (DPE), with DPE being almost completely converted under 365 nm LED irradiation and achieving a 90.0% conversion rate under visible light. Besides, Pt@CDs-2/TiO2-MP effectively cleaved α-O-4 (benzyl phenyl ether, 77.8%) and β-O-4 (phenethoxybenzene, 99.6%) models. Even for the C–C bond with a high dissociation energy (biphenyl, 99.0%), it exhibited significant bond cleavage capability, achieving a cyclohexane yield of 10.0%. Furthermore, this photocatalytic method successfully converted different types of lignin into high-value aromatic monomers. This study presents a sustainable and efficient method for the conversion of lignin, thereby contributing significantly to the achievement of sustainable development goals.","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 29","pages":" 8883-8900"},"PeriodicalIF":9.3,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144671929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Selective C–O bond cleavage enhances aromatics production from lignin-derived platform molecules with ethanol as a hydrogen donor† 选择性C-O键裂解增强了以乙醇为氢供体的木质素衍生平台分子生成芳烃的能力

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-07-03 DOI: 10.1039/D5GC02104A

Hao Zhang, Qisong Yi, Huawei Geng, Zhifeng Liu, Wenhao Luo, Zichun Wang and Yuanshuai Liu

{"title":"Selective C–O bond cleavage enhances aromatics production from lignin-derived platform molecules with ethanol as a hydrogen donor†","authors":"Hao Zhang, Qisong Yi, Huawei Geng, Zhifeng Liu, Wenhao Luo, Zichun Wang and Yuanshuai Liu","doi":"10.1039/D5GC02104A","DOIUrl":"https://doi.org/10.1039/D5GC02104A","url":null,"abstract":"Selective catalytic cleavage of C–O bonds during the hydrodeoxygenation (HDO) of lignin-derived phenolics is essential for producing renewable aromatics from biomass. The HDO process typically involves the use of high-pressure molecular hydrogen, which poses safety concerns and lacks sustainability. Herein, we report an effective catalytic approach that integrates the aqueous-phase reforming (APR) of ethanol with the selective HDO of lignin-derived phenol to benzene over a well-defined Pt/Al2O3 catalyst. The effects of catalyst support, ethanol-to-water ratios, and reaction temperatures on in situ HDO processes were systematically explored and thoroughly discussed. The competitive routes of C–O bond hydrogenolysis and benzene ring hydrogenation during HDO of phenol were found to be significantly dependent on the H2 produced by the APR of ethanol and variations in reaction parameters. A lower H2 pressure, generated from an optimized Vethanol/Vwater of 3 : 5 and a high reaction temperature of 280 °C, favored the selective cleavage of C–O bonds rather than the hydrogenation of benzene rings, resulting in a relatively high phenol conversion of ca. 57% with a benzene selectivity of ca. 97% after 2 h of reaction. The proposed reaction pathways involved in the currently developed in situ HDO process provided a deep understanding of the pronounced selectivity towards benzene formation from phenol under optimized reaction conditions. The conversion of other representative lignin-derived phenolics and ethers further validated the superiority and versatility of the developed catalytic system in producing aromatic compounds from lignin biomass.","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 29","pages":" 8959-8971"},"PeriodicalIF":9.3,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144671955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

CO2-responsive membrane separation systems: a green solution for efficient separations† 二氧化碳响应膜分离系统：高效分离的绿色解决方案

IF 9.2 1区化学

Green Chemistry Pub Date : 2025-07-03 DOI: 10.1039/D5GC00220F

Ling Lei, Haohao Liu, Yunxiang Bai, Chunfang Zhang, Mingjie Yin, Wentao Wang and Liangliang Dong

{"title":"CO2-responsive membrane separation systems: a green solution for efficient separations†","authors":"Ling Lei, Haohao Liu, Yunxiang Bai, Chunfang Zhang, Mingjie Yin, Wentao Wang and Liangliang Dong","doi":"10.1039/D5GC00220F","DOIUrl":"https://doi.org/10.1039/D5GC00220F","url":null,"abstract":"Membrane separation technology, which is characterized by its green, environmentally friendly, efficient, and continuous operation, has become indispensable in modern separation processes. It has widespread applications in pharmaceuticals, mineral extraction, and water purification. Because efficient and stable separation processes often require the integration of components across isolated, functionally distinct regions and the synergistic achievement of separation outcomes, membrane systems have emerged as a prominent trend within the field of membrane separation. Among them, CO2-responsive materials are an important research hotspot because of their precise and efficient separation performance caused by their green driving mode, mild and green condition, non-accumulation, and excellent reversibility. This review comprehensively investigates the history of the development of CO2-responsive membrane separation systems, including their CO2-responsive mechanisms, fabrication methods, critical characterization techniques, and potential applications. The review culminates in a forward outlook, summarizing future research directions as well as highlighting challenges in CO2-responsive membrane separation systems and emerging potential applications.","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 31","pages":" 9313-9331"},"PeriodicalIF":9.2,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144767294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Dual functionalization of mesoporous organosilicon nanoflowers enhances heterogeneous chemoenzymatic conversion of alkynes toward enantiopure alcohols† 介孔有机硅纳米花的双功能化增强了炔烃向对映纯醇†的非均相化学酶转化

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-07-02 DOI: 10.1039/D5GC02373D

Chen Huang, Qian Zhang, Xiaoyang Yue, Aidang Lu, Guanhua Liu, Ying He, Li Ma, Liya Zhou, Yunting Liu and Yanjun Jiang

{"title":"Dual functionalization of mesoporous organosilicon nanoflowers enhances heterogeneous chemoenzymatic conversion of alkynes toward enantiopure alcohols†","authors":"Chen Huang, Qian Zhang, Xiaoyang Yue, Aidang Lu, Guanhua Liu, Ying He, Li Ma, Liya Zhou, Yunting Liu and Yanjun Jiang","doi":"10.1039/D5GC02373D","DOIUrl":"https://doi.org/10.1039/D5GC02373D","url":null,"abstract":"A tandem chemoenzymatic cascade for the direct synthesis of chiral alcohols from bulk alkynes is promising but challenging, as it couples the gold-catalysed alkyne hydration with an alcohol dehydrogenase-driven asymmetric reduction of the resulting ketones. Herewith two heterogeneous bifunctional catalysts are fabricated for chemocatalytic and biocatalytic steps, respectively. The bi-functionalized chemocatalyst (Au@HS/SO3H-DON), which possesses both Au NPs and Brønsted acid catalytic sites, exhibits superior catalytic performance and better reusability compared to those of homogeneous Au(III) catalysts. The bi-functionalized biocatalyst (ADH@QA-DON) exhibits enhanced reusability over free ADH and enriches NADH, enhancing the overall catalytic performance. Various chiral alcohols are directly obtained from alkynes with high yields (73%–92%) and enantioselectivity (>99% ee) via tandem cascade reactions catalyzed by bifunctional chemo- and biocatalysts. By fabricating a continuous-flow system, a space–time yield (STY) of 4.69 g L−1 h−1 for (S)-1-phenylethanol can be achieved, which is 6.7-fold higher than that obtained in batch.","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 29","pages":" 8858-8866"},"PeriodicalIF":9.3,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144671926","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sustainable approaches in vat photopolymerization: advancements, limitations, and future opportunities† 还原光聚合的可持续方法：进展、限制和未来机遇

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-07-02 DOI: 10.1039/D5GC02299A

Mirko Maturi, Erica Locatelli, Alberto Sanz de Leon, Mauro Comes Franchini and Sergio Ignacio Molina

{"title":"Sustainable approaches in vat photopolymerization: advancements, limitations, and future opportunities†","authors":"Mirko Maturi, Erica Locatelli, Alberto Sanz de Leon, Mauro Comes Franchini and Sergio Ignacio Molina","doi":"10.1039/D5GC02299A","DOIUrl":"https://doi.org/10.1039/D5GC02299A","url":null,"abstract":"Vat photopolymerization (VP) is reshaping advanced manufacturing, yet its dependence on petrochemical-derived resins poses significant sustainability challenges. This review critically evaluates conventional photocurable formulations, highlighting the limitations of standard metrics such as the biobased carbon content (BCC%), and introduces the sustainable formulation score (SFS) as a comprehensive alternative. By integrating factors like atom economy, hazardous reagent usage, solvent selection, and end-of-life considerations, SFS offers a more holistic measure of environmental impact. The analysis encompasses diverse resin systems, including (meth)acrylated vegetable oil derivatives, biobased small molecules from lignin and other renewable sources, non-isocyanate urethanes, and thiol–ene formulations. For vegetable oil-based systems, a key trade-off is observed between achieving high biobased content and maintaining optimal mechanical properties, driven by variations in the degree of acrylation and processing conditions. In contrast, the synthesis of small biobased molecules often involves toxic reagents and less favorable atom economies, reducing their overall green appeal. Moreover, non-isocyanate urethanes and thiol–ene systems emerge as promising routes for improving sustainability while preserving performance. Overall, this review underscores the need for unified green metrics and optimized synthesis strategies to bridge the gap between environmental sustainability and material performance in photopolymer formulations, paving the way for more responsible and efficient additive manufacturing technologies.","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 29","pages":" 8710-8754"},"PeriodicalIF":9.3,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/gc/d5gc02299a?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144671292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Chemical upcycling of biodegradable plastic waste: a critical review† 生物可降解塑料废物的化学升级回收：综述†

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-07-02 DOI: 10.1039/D5GC02078F

Ning Li, Zhixun Li, Yangli Cui, Lan Liang, Wenchao Peng, Zhanjun Cheng, Beibei Yan and Guanyi Chen

{"title":"Chemical upcycling of biodegradable plastic waste: a critical review†","authors":"Ning Li, Zhixun Li, Yangli Cui, Lan Liang, Wenchao Peng, Zhanjun Cheng, Beibei Yan and Guanyi Chen","doi":"10.1039/D5GC02078F","DOIUrl":"https://doi.org/10.1039/D5GC02078F","url":null,"abstract":"Biodegradable plastics (BPs) have emerged as a promising and sustainable alternative to traditional ones. It is essential to concentrate on BP waste recycling and upgrading. The chemical upcycling approach not only retains the intrinsic carbon value of the polymers, but also offers broad adaptability and high conversion efficiency across diverse types of BPs through precise reaction condition optimization. This review systematically summarizes the factors influencing BP conversion and the mechanisms of various chemical conversion techniques. The advantages and limitations of various conversion technologies, such as pyrolysis, hydrolysis, alcoholysis, electrocatalysis, and photocatalysis, were evaluated across five dimensions, including product value, selectivity, conversion rate, cost, and carbon emissions. Pyrolysis can produce high-value products, but it is limited by high energy consumption and low selectivity. Hydrolysis and alcoholysis, both mature and reliable technologies, offer high selectivity and conversion efficiency but require optimized conditions for effective implementation. Electrocatalysis and photocatalysis appear as promising technologies for waste-to-resource conversion, aligning well with green development goals. However, both require further advancements in catalyst design and reaction optimization. Future research should focus on integrating multiple technologies, enhancing catalyst efficiency, improving pretreatment processes, and refining reaction modeling to create more sustainable and cost-effective BP upcycling strategies. This work aims to provide theoretical support and guidance for waste plastic upcycling.","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 30","pages":" 9000-9015"},"PeriodicalIF":9.3,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144716385","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Two-dimensional materials for high-current-density seawater electrolysis 高电流密度海水电解用二维材料

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-07-02 DOI: 10.1039/D5GC01687H

Liyun Wei, Jiao Dai, Shutong Qin, Mingjie Wang, Ziyuan Zhu, Weilin Xu, Kaisi Liu and Jun Wan

{"title":"Two-dimensional materials for high-current-density seawater electrolysis","authors":"Liyun Wei, Jiao Dai, Shutong Qin, Mingjie Wang, Ziyuan Zhu, Weilin Xu, Kaisi Liu and Jun Wan","doi":"10.1039/D5GC01687H","DOIUrl":"https://doi.org/10.1039/D5GC01687H","url":null,"abstract":"Seawater electrolysis is a promising strategy for sustainable hydrogen production, using abundant water resources, while reducing freshwater depletion. However, achieving stable and efficient operation at industrially relevant current densities remains challenging, due to competition from the chlorine evolution reaction (CER), catalyst degradation, and mass transport limitations. Two-dimensional (2D) materials offer tunable electronic structures, high surface areas, and unique charge transport properties, yet their stability and catalytic mechanisms under high current densities remain insufficiently understood. While existing studies have focused on compositional tuning and surface modifications, a systematic understanding of how 2D architectures influence reaction kinetics, charge transfer, and long-term durability is still lacking. This review critically analyzes the role of 2D materials in high-current-density seawater electrolysis, focusing on structural and electronic properties, catalytic mechanisms, and stability. Unlike previous reviews that broadly discuss 2D materials for water electrolysis, this work highlights challenges and opportunities under industrial conditions. Materials are classified into metal oxides, hydroxides, sulfides, phosphides, carbides, nitrides, and other emerging compounds, with emphasis on their catalytic performance and electrochemical durability, while identifying key factors that optimize performance. These insights are essential for developing efficient, durable 2D catalysts for seawater electrolysis, contributing to sustainable hydrogen production and green chemistry.","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 29","pages":" 8755-8776"},"PeriodicalIF":9.3,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144671293","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Tuning the electron affinity of cobalt oxide catalysts for robust acidic oxygen evolution† 调节钴氧化物催化剂的电子亲和性以促进强酸性析氧†

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-07-02 DOI: 10.1039/D5GC02058A

Ruozi Fang, Xinyi Wan, Junsheng Chen, Youmin Hou and Bin Hua

{"title":"Tuning the electron affinity of cobalt oxide catalysts for robust acidic oxygen evolution†","authors":"Ruozi Fang, Xinyi Wan, Junsheng Chen, Youmin Hou and Bin Hua","doi":"10.1039/D5GC02058A","DOIUrl":"https://doi.org/10.1039/D5GC02058A","url":null,"abstract":"Developing acid-stable, active, and cost-effective oxygen evolution reaction (OER) electrocatalysts is essential for efficient hydrogen production via proton exchange membrane (PEM) water electrolysis. However, balancing activity and stability remains a persistent challenge for Co-based catalysts under acidic OER conditions. Here, we report an oxygen-defective Mo-substituted Co3O4 catalyst that delivers both enhanced activity and robust stability. The Mo–Co3O4 catalyst achieves a low overpotential of 348 mV at 10 mA cm−2 and maintains excellent durability for over 300 hours at 50 mA cm−2 in 0.5 M H2SO4. The enhanced performance arises from the incorporation of Mo, whose higher electron affinity promotes *OH adsorption and steers the OER through the adsorbate evolution mechanism pathway while suppressing the lattice oxygen-mediated pathway. Theoretical calculations further reveal that the nonbonding Mo–O state effectively stabilizes isolated hole formation under polarization, thereby favoring cation redox over oxygen loss. This work highlights a strategic approach for regulating catalytic pathways and opens new avenues for designing cost-effective, durable OER electrocatalysts for PEM water electrolysis.","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 30","pages":" 9243-9253"},"PeriodicalIF":9.3,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144716429","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electrochemical C–O bond cleavage of diaryl ethers: upcycling of lignin 4-O-5 models and polyphenylene oxide† 二芳醚的电化学C-O键裂解：木质素4-O-5模型和聚苯氧乙烯的升级循环

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-07-01 DOI: 10.1039/D5GC02174J

Fangfang He, Yifan Wang, Xianshuai Huang, Shuanglin Qu and Jie Liu

引用次数: 0

Atom-efficient aldol condensation via magnetically recyclable nanoreactors: sol–gel imprinting enables template-switchable triple selectivity† 原子高效醛缩通过磁性可回收的纳米反应器：溶胶-凝胶印迹使模板可切换三重选择性†

IF 9.3 1区化学

Green Chemistry Pub Date : 2025-07-01 DOI: 10.1039/D5GC02933C

Ya Liu, Jinghai Yan, Yi Hao, Xuemeng Tian, Yue Wang, Xueyi Liu and Ruixia Gao

{"title":"Atom-efficient aldol condensation via magnetically recyclable nanoreactors: sol–gel imprinting enables template-switchable triple selectivity†","authors":"Ya Liu, Jinghai Yan, Yi Hao, Xuemeng Tian, Yue Wang, Xueyi Liu and Ruixia Gao","doi":"10.1039/D5GC02933C","DOIUrl":"https://doi.org/10.1039/D5GC02933C","url":null,"abstract":"Substrate-selective catalysis is essential for sustainable synthesis, but has long been constrained by the inherent trade-off between precision and versatility in competitive environments. To address this challenge, we developed an eco-friendly magnetic nanoreactor that integrates layer-by-layer covalent active-site engineering with sol–gel imprinting to achieve adaptive molecular recognition. These molecularly imprinted nanoreactors (MMIPs), constructed using target products as templates, exhibit triple selectivity – positional (para/meta-isomer discrimination >8-fold), electronic (nitro/cyano differentiation 2-fold) and spatial (isopropyl exclusion) – in aldol catalysis. The nanoreactors operate effectively in both single and mixed substrate systems, bypassing the need for energy-intensive purification. A key innovation is the template-switching strategy that enables substrate reorientation, expanding recognition scope without structural redesign. For instance, m-MMIP exhibits high selectivity (coefficient >1.7) for the low-reactivity m-nitrobenzaldehyde, using its cyclohexanone adduct as a template. The platform minimizes environmental impact by enabling energy-efficient substrate-selective catalysis, reducing the E-factor by >36%, while improving atom efficiency by >1.6-fold. By synergizing molecular precision with scalable selectivity and covalent durability, this work establishes a programmable green catalysis paradigm for pharmaceutical and fine chemical synthesis, emphasizing waste reduction and resource optimization.","PeriodicalId":78,"journal":{"name":"Green Chemistry","volume":" 30","pages":" 9198-9210"},"PeriodicalIF":9.3,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144716407","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0