Peter K Peterson, Kerri A Pratt, Paul B Shepson, William R Simpson
{"title":"Impacts of Arctic oil field NO<sub><i>x</i></sub> emissions on downwind bromine chemistry: insights from 5 years of MAX-DOAS observations.","authors":"Peter K Peterson, Kerri A Pratt, Paul B Shepson, William R Simpson","doi":"10.1039/d4fd00164h","DOIUrl":"https://doi.org/10.1039/d4fd00164h","url":null,"abstract":"<p><p>Oil and gas production is a substantial source of nitrogen oxides to the atmosphere, with significant impacts particularly in remote regions without other large local NO<sub><i>x</i></sub> sources. In the Arctic, these emissions impact regional halogen and HO<sub><i>x</i></sub> chemistry, altering the oxidation of atmospheric pollutants. In this work we utilize Multiple Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) NO<sub>2</sub> and BrO measurements at Utqiaġvik, Alaska, from 2012 to 2016. During the spring months when atmospheric bromine chemistry is most prevalent, we find 8% of observations are impacted by observed NO<sub>2</sub> differential slant column densities (dSCDs) over 5 × 10<sup>15</sup> molecules per cm<sup>2</sup>, which we classify as polluted. Of this fraction, approximately half can be attributed to sources outside the immediate vicinity of Utqiaġvik. During these polluted times, observed BrO lower tropospheric column densities (LT-VCDs) are 60% lower on average than those retrieved during non-polluted times. During times when the local wind direction corresponds with a large collection of oil and gas extraction facilities approximately 300 km southeast of Utqiaġvik, observed BrO LT-VCDs were 30% lower than clean air times. These observations show that current oil and gas operations in the Arctic are impacting the natural atmospheric photochemical processes.</p>","PeriodicalId":76,"journal":{"name":"Faraday Discussions","volume":" ","pages":""},"PeriodicalIF":3.3,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143497471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Guangyu Li, André Welti, Arianna Rocchi, Germán Pérez Fogwill, Manuel Dall'Osto, Zamin A Kanji
{"title":"Terrestrial and marine sources of ice nucleating particles in the Eurasian Arctic.","authors":"Guangyu Li, André Welti, Arianna Rocchi, Germán Pérez Fogwill, Manuel Dall'Osto, Zamin A Kanji","doi":"10.1039/d4fd00160e","DOIUrl":"https://doi.org/10.1039/d4fd00160e","url":null,"abstract":"<p><p>Ice nucleating particles (INPs) catalyze primary ice formation in Arctic low-level mixed-phase clouds, influencing their persistence and radiative properties. Knowledge of the abundance and sources of INP over the remote Arctic Ocean is scarce due to limited data coverage, particularly in the Eurasian Arctic. This study presents summertime measurements of INP concentrations in seawater, fog water and air from the ship-based Arctic Century Expedition, exploring the Barents, Kara, and Laptev Seas, and the adjacent high Arctic islands and archipelagos in August and September 2021. Heat sensitivity tests of ambient aerosols revealed that heat-liable, biogenic INPs make up the majority of Arctic INP populations at temperatures above -20 °C, and to a lesser extent down to -25 °C. INP content in fog water is found to be similar to ambient aerosol, indicating that INP in marine air could also act as cloud condensation nuclei. Measurements of aerosolized INPs using an on-board sea-spray aerosol bubble tank generator exhibit a positive correlation with ambient INP concentrations, but not with INP abundance in seawater samples. INP concentrations in air derived from sea water samples (using a NaCl conversion factor representative for the Arctic) were significantly lower than those measured in ambient air or bubble tank experiments. INP concentrations in bubble tank experiments positively correlated with the phosphate and fluorescence signals in the water. This suggests an important role of the aerosolization mechanism for preferentially partitioning biogenic INPs to the atmosphere.</p>","PeriodicalId":76,"journal":{"name":"Faraday Discussions","volume":" ","pages":""},"PeriodicalIF":3.3,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143490166","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
K. Kahle, Petra M. Klinge, Jenna E. Koschnitzky, Abhaya V. Kulkarni, Nanna MacAulay, Shenandoah Robinson, Steven J. Schiff, J. Strahle
{"title":"Paediatric hydrocephalus","authors":"K. Kahle, Petra M. Klinge, Jenna E. Koschnitzky, Abhaya V. Kulkarni, Nanna MacAulay, Shenandoah Robinson, Steven J. Schiff, J. Strahle","doi":"10.1038/s41572-024-00519-9","DOIUrl":"https://doi.org/10.1038/s41572-024-00519-9","url":null,"abstract":"","PeriodicalId":76,"journal":{"name":"Faraday Discussions","volume":"23 9","pages":"1-16"},"PeriodicalIF":81.5,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140967670","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mark Aarts, Martin Z. Bazant, Lydéric Bocquet, Fabio Cicoira, Robert A. W. Dryfe, Sanli Faez, Y. K. Catherine Fung, Ehud Haimov, Bee Hockin, Christian Holm, Tim M. Kamsma, Frédéric Kanoufi, Alexei A. Kornyshev, Serge G. Lemay, Yan Levin, Sophie Marbach, Elalyaa Mohamed, Joan Montes de Oca, Frieder Mugele, Monica Olvera de la Cruz, Susan Perkin, Jenny Pringle, Paul Robin, Benjamin Rotenberg, Alexander Schlaich, Igor Siretanu, Zuzanna S. Siwy, Derek Stein, René van Roij, Tanja Vidaković-Koch, Kislon Voïtchovsky, Gilad Yossifon and Yujia Zhang
{"title":"Iontronic dynamics: general discussion","authors":"Mark Aarts, Martin Z. Bazant, Lydéric Bocquet, Fabio Cicoira, Robert A. W. Dryfe, Sanli Faez, Y. K. Catherine Fung, Ehud Haimov, Bee Hockin, Christian Holm, Tim M. Kamsma, Frédéric Kanoufi, Alexei A. Kornyshev, Serge G. Lemay, Yan Levin, Sophie Marbach, Elalyaa Mohamed, Joan Montes de Oca, Frieder Mugele, Monica Olvera de la Cruz, Susan Perkin, Jenny Pringle, Paul Robin, Benjamin Rotenberg, Alexander Schlaich, Igor Siretanu, Zuzanna S. Siwy, Derek Stein, René van Roij, Tanja Vidaković-Koch, Kislon Voïtchovsky, Gilad Yossifon and Yujia Zhang","doi":"10.1039/D3FD90032K","DOIUrl":"10.1039/D3FD90032K","url":null,"abstract":"","PeriodicalId":76,"journal":{"name":"Faraday Discussions","volume":"246 ","pages":" 322-355"},"PeriodicalIF":3.4,"publicationDate":"2023-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41090532","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sidahmed Abayzeed, Tarique Anwar, Alexander Barnaveli, Martin Z. Bazant, Lyderic Bocquet, Aleksandar Donev, Robert A. W. Dryfe, Sanli Faez, Amritha Janardanan, Felipe Jiménez-Ángeles, Tim M. Kamsma, Frédéric Kanoufi, Alexei A. Kornyshev, Serge G. Lemay, Yan Levin, Sophie Marbach, Joan Montes de Oca, Paul Robin, Zuzanna S. Siwy, Derek Stein, Rene van Roij, Tanja Vidaković-Koch, Gilad Yossifon and Yujia Zhang
{"title":"Iontronic coupling: general discussion","authors":"Sidahmed Abayzeed, Tarique Anwar, Alexander Barnaveli, Martin Z. Bazant, Lyderic Bocquet, Aleksandar Donev, Robert A. W. Dryfe, Sanli Faez, Amritha Janardanan, Felipe Jiménez-Ángeles, Tim M. Kamsma, Frédéric Kanoufi, Alexei A. Kornyshev, Serge G. Lemay, Yan Levin, Sophie Marbach, Joan Montes de Oca, Paul Robin, Zuzanna S. Siwy, Derek Stein, Rene van Roij, Tanja Vidaković-Koch, Gilad Yossifon and Yujia Zhang","doi":"10.1039/D3FD90031B","DOIUrl":"10.1039/D3FD90031B","url":null,"abstract":"","PeriodicalId":76,"journal":{"name":"Faraday Discussions","volume":"246 ","pages":" 157-178"},"PeriodicalIF":3.4,"publicationDate":"2023-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41090783","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nadia Balucani, Michelle Brann, Sandra Brünken, Cecilia Ceccarelli, Martin Cordiner, Eric M. Crump, Kevin M. Douglas, Adam J. Fleisher, Athena Flint, Jack Fulker, Robin T. Garrod, Murthy S. Gudipati, Divita Gupta, Joshua Halpern, Dwayne E. Heard, Eric Herbst, Emily K. Hockey, Ko-Yun Huang, Ugo Jacovella, Inga Kamp, Alexander K. Lemmens, Nikku Madhusudhan, Martin R. S. McCoustra, Brett McGuire, Anthony Meijer, Cristina Puzzarini, Daniël B. Rap, Ian R. Sims, Mark H. Stockett, Ardjan Sturm, Arthur G. Suits, Ewine F. van Dishoeck, Serena Viti, Nicholas Walker, Susanna Widicus Weaver, Laurent Wiesenfeld and Olivia H. Wilkins
{"title":"Laboratory astrochemistry of the gas phase: general discussion","authors":"Nadia Balucani, Michelle Brann, Sandra Brünken, Cecilia Ceccarelli, Martin Cordiner, Eric M. Crump, Kevin M. Douglas, Adam J. Fleisher, Athena Flint, Jack Fulker, Robin T. Garrod, Murthy S. Gudipati, Divita Gupta, Joshua Halpern, Dwayne E. Heard, Eric Herbst, Emily K. Hockey, Ko-Yun Huang, Ugo Jacovella, Inga Kamp, Alexander K. Lemmens, Nikku Madhusudhan, Martin R. S. McCoustra, Brett McGuire, Anthony Meijer, Cristina Puzzarini, Daniël B. Rap, Ian R. Sims, Mark H. Stockett, Ardjan Sturm, Arthur G. Suits, Ewine F. van Dishoeck, Serena Viti, Nicholas Walker, Susanna Widicus Weaver, Laurent Wiesenfeld and Olivia H. Wilkins","doi":"10.1039/D3FD90025H","DOIUrl":"https://doi.org/10.1039/D3FD90025H","url":null,"abstract":"","PeriodicalId":76,"journal":{"name":"Faraday Discussions","volume":"245 ","pages":" 391-445"},"PeriodicalIF":3.4,"publicationDate":"2023-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"24849612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}