Protection of Metals and Physical Chemistry of Surfaces最新文献_第6页

Synthesis and Characterization of Magnesium Oxide Nanoparticles Using Amaranthus dubius Leaf Extract 苋菜叶提取物纳米氧化镁的合成及表征

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-07-20 DOI: 10.1134/S2070205126700115

D. Sathya

{"title":"Synthesis and Characterization of Magnesium Oxide Nanoparticles Using Amaranthus dubius Leaf Extract","authors":"D. Sathya","doi":"10.1134/S2070205126700115","DOIUrl":"10.1134/S2070205126700115","url":null,"abstract":"Magnesium oxide nanoparticles (MgO NPs) were synthesized by using the Amaranthus dubius leaf extract through the low temperature green combustion method. MgO NPs systematically analyzed using complementary structural, optical and electrochemical techniques. The PXRD patterns confirmed the formation of the Periclase structure with the cubic phase with crystallite sizes consistent with particle size analysis, indicating high phase purity. Whereas the SEM result revealed the agglomerated roughly spherical granular structures of about ~46 nm in size. FTIR spectra confirmed the formation of the metal oxygen stretching vibration (Mg–O) bond at 419 cm–1. The formation of MgO NPs is confirmed by a visual color change from colorless to dark brown and they displayed a wavelength of 310 nm in UV-Spectrophotometry analysis and the direct band gap of ~4.6 eV, slightly blue-shifted compared to bulk MgO, attributable to quantum confinement effects. Cyclic voltammetry (CV) revealed quasi-rectangular current profiles with distinct redox features, suggesting a combination of double-layer capacitance and pseudocapacitive contributions. These results establish a clear correlation between morphology, crystallinity, band gap modulation, and electrochemical performance. The findings highlight the multifunctional potential of MgO nanoparticles for applications in photocatalysis, UV shielding, and electrochemical energy storage.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 1","pages":"80 - 89"},"PeriodicalIF":1.1,"publicationDate":"2026-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hybrid Adsorption/UV-Driven Photocatalytic Oxidation for Fast Removal of Direct Red Dye from Industrial Wastewater: Experimental Work and Modeling 混合吸附/紫外驱动光催化氧化快速去除工业废水中的直接红色染料：实验工作和建模

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-07-20 DOI: 10.1134/S207020512670005X

Mahmoud A. Sharshoh, Muayad A. Shihab, Hind J. Hadi, Jasim I. Humadi, Amer T. Nawaf, Ali A. Hassan, Saad A. Jafar

{"title":"Hybrid Adsorption/UV-Driven Photocatalytic Oxidation for Fast Removal of Direct Red Dye from Industrial Wastewater: Experimental Work and Modeling","authors":"Mahmoud A. Sharshoh, Muayad A. Shihab, Hind J. Hadi, Jasim I. Humadi, Amer T. Nawaf, Ali A. Hassan, Saad A. Jafar","doi":"10.1134/S207020512670005X","DOIUrl":"10.1134/S207020512670005X","url":null,"abstract":"The photocatalytic decolorization of the organic dye Direct Red using a synthesized TiO2 nanocatalyst was investigated, modeled, and optimized employing response surface methodology (RSM) and artificial neural network (ANN). The effect of different variables including, oxidation time, solution pH, TiO2 dosage, and dye initial concentration was studied. Various dye removal efficiencies ranging from 68.4 to 99.1% were achieved under different parameter values with the potential to reach 100% efficiency under optimized conditions. The study of factors influencing the efficiency of the photocatalytic decolorization process revealed that TiO2 concentration had the most significant impact, followed by dye concentration and pH. The second-order model developed through RSM effectively simulated the impacts of the selected variables on the process (R2 = 95.94% and (R_{{text{adj}}}^2) = 91.19%). The kinetic study of the photocatalytic decolorization process demonstrated that it follows a pseudo-first-order model. The experimental results showed strong agreement with the ANN model, a high regression coefficient (R2) of 0.9979 and a low mean square error (MSE) of 0.000134 were achieved. This model, which incorporates interactions, offers a robust framework for predicting new developments in photocatalytic decolorization.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 1","pages":"1 - 14"},"PeriodicalIF":1.1,"publicationDate":"2026-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The Influence of Electric Field on the Wetting Behavior of Liquid Droplets 电场对液滴润湿行为的影响

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-07-20 DOI: 10.1134/S2070205126700140

Meiyun Zhao, Jinsheng Zhang, Yufan Xiong, Guoliang Cheng, Xiang Xu

{"title":"The Influence of Electric Field on the Wetting Behavior of Liquid Droplets","authors":"Meiyun Zhao, Jinsheng Zhang, Yufan Xiong, Guoliang Cheng, Xiang Xu","doi":"10.1134/S2070205126700140","DOIUrl":"10.1134/S2070205126700140","url":null,"abstract":"Low-temperature droplet freezing poses significant challenges in multiple fields such as power transmission, communication, and aerospace. The application of an electric field is an effective method for controlling the wetting and phase transition of nanodroplets on solid surfaces. By regulating the phase transition process of droplets through an electric field, it is possible to delay the initial freezing time of droplets and reduce the adhesion force of icing, which provides new ideas and methods for solving icing problems. This study used molecular dynamics methods and LAMMPS software to establish a simulation system for nanodroplets and solid substrates. An electric field was applied inside the simulation box to study its effect of the electric field on the wetting behavior of the droplets at the microscopic level. The influence of the electric field on the freezing state of the droplets was explored based on the number of droplet molecules and the number of substrate contacts. The experimental results indicate that applying an appropriate electric field strength can change the shape of droplets and affect their wetting behavior. In addition, by applying an appropriate electric field in the direction parallel to the substrate, the interaction force between the droplet and substrate can be canceled out, the wetting situation of the droplet can be changed, and the adhesion force between the ice and substrate can be reduced, thereby achieving easier de-icing.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 1","pages":"35 - 42"},"PeriodicalIF":1.1,"publicationDate":"2026-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519508","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effects of Basic Organic Compounds on Corrosion for Fe(110), Cu(111), and Al(111): A Study Using DFT, Reduced Density Gradient, Quantum Theory of Atoms in Molecules, and Monte Carlo Methods 碱性有机化合物对Fe（110）、Cu（111）和Al（111）腐蚀的影响：使用DFT、密度梯度还原、分子原子量子理论和蒙特卡罗方法的研究

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-07-20 DOI: 10.1134/S2070205126700012

Yousif Hussein Azeez, Rebaz Obaid Kareem, Rebaz Anwar Omer, Fouad Benhiba, Aryan Fathulla Qader, Muhammad Ashfaq, Rzgar Faruq Rashid

{"title":"Effects of Basic Organic Compounds on Corrosion for Fe(110), Cu(111), and Al(111): A Study Using DFT, Reduced Density Gradient, Quantum Theory of Atoms in Molecules, and Monte Carlo Methods","authors":"Yousif Hussein Azeez, Rebaz Obaid Kareem, Rebaz Anwar Omer, Fouad Benhiba, Aryan Fathulla Qader, Muhammad Ashfaq, Rzgar Faruq Rashid","doi":"10.1134/S2070205126700012","DOIUrl":"10.1134/S2070205126700012","url":null,"abstract":"Theoretical approaches to the adsorption of compounds onto substrates contribute significantly to the improvement of corrosion inhibitors. The present research provides a calculation using DFT, reduced density gradient (RDG), quantum theory of atoms in molecules (QTAM), UV-spectroscopy, and Monte Carlo (MC) simulations to thoroughly assess the interaction features of 40 organic solvents for corrosion inhibition of the carbon steel (Fe(110)), copper (Cu(111)), and aluminum (Al(111)). Theoretical calculations show that the electron density distribution of molecular orbitals (HOMO–LUMO) occupies the majority of optimized structures, reflecting high chemical reactivity, especially in interaction with metal surfaces. Quantum chemical descriptors show that both compounds 26 (hexamethylphosphoramide) and 27 (hexamethylphosphorous triamide) exhibit high chemical reactivity, which is well confirmed by the adsorption energy values obtained from different simulation systems. RDG data show that there are three distinct types of interaction. The various simulations show that the majority of basic organic solvents adsorb completely onto the three simulation surfaces.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 1","pages":"129 - 165"},"PeriodicalIF":1.1,"publicationDate":"2026-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519513","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Influence of Surfactant Type and Concentration on the Microstructure and Overall Properties of Pulse Electrodeposited Ni–W–Al2O3 Nanocomposite Coatings 表面活性剂类型和浓度对脉冲电沉积Ni-W-Al2O3纳米复合镀层微观结构和综合性能的影响

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-07-20 DOI: 10.1134/S2070205126700048

Tao Gu, Yongfeng Li, Wei Wang, Lisheng Zhang, Weiran Liu

{"title":"Influence of Surfactant Type and Concentration on the Microstructure and Overall Properties of Pulse Electrodeposited Ni–W–Al2O3 Nanocomposite Coatings","authors":"Tao Gu, Yongfeng Li, Wei Wang, Lisheng Zhang, Weiran Liu","doi":"10.1134/S2070205126700048","DOIUrl":"10.1134/S2070205126700048","url":null,"abstract":"Agglomeration of Al2O3 nanoparticles during electrodeposition often results in increased porosity and compromised mechanical and electrochemical properties of Ni–W–Al2O3 composite coatings. To address this challenge, the present study explores the influence of surfactant type and concentration on the dispersion behavior of Al2O3 nanoparticles and the resulting coating performance. Ni–W–Al2O3 coatings were synthesized via pulse electrodeposition using the cationic surfactant cetyltrimethylammonium bromide (CTAB) and the anionic surfactant sodium dodecylbenzene sulfonate (SDBS) at various concentrations. The results reveal that CTAB at 1.5 times the critical micelle concentration (1.5×CMC) significantly promotes nanoparticle dispersion through electrostatic anchoring, leading to enhanced coating density, increased microhardness to 802 HV, reduced surface roughness to Ra = 100.19 nm, decreased friction coefficient to 0.10, and improved corrosion resistance, with a corrosion current density of 5.53 × 10–6 A cm–2 and a corrosion rate of 0.06491 mm year–1. In contrast, SDBS exhibited limited efficacy due to electrostatic repulsion and micelle-induced nanoparticle encapsulation. These findings underscore the pivotal role of surfactant charge characteristics in determining the microstructure and multifunctional properties of composite coatings, offering valuable insights for the development of high-performance, wear- and corrosion-resistant electrodeposited systems.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 1","pages":"43 - 59"},"PeriodicalIF":1.1,"publicationDate":"2026-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hydrophilic and Hydrophobic Coatings: Production and Application 亲疏水涂料：生产与应用

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-07-20 DOI: 10.1134/S2070205126700164

E. N. Evdokimova, T. A. Kochina

引用次数: 0

Hydrogen Sorption on the Surface of Silica–Germania Anode Material in Light Metal Li-Ion Battery: DFT Modeling towards Eco-Friendly Energy Conservation 轻金属锂离子电池二氧化硅-锗负极材料表面的氢吸附：面向环保节能的DFT建模

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-07-20 DOI: 10.1134/S2070205126700073

Fatemeh Mollaamin

{"title":"Hydrogen Sorption on the Surface of Silica–Germania Anode Material in Light Metal Li-Ion Battery: DFT Modeling towards Eco-Friendly Energy Conservation","authors":"Fatemeh Mollaamin","doi":"10.1134/S2070205126700073","DOIUrl":"10.1134/S2070205126700073","url":null,"abstract":"Novel silica–germania-based nanomaterials have been designed as a potential solid hydrogen conservation medium. As applied materials for energy conservation, silicon–germanium dioxide (SiGeO2) can attract considerable attention in materials science. A comprehensive investigation on hydrogen grabbing by SiGeO2 was carried out including using DFT computations at the “CAM–B3LYP–D3/6-311+G(d,p)” level of theory. The hypothesis of the hydrogen sorption phenomenon was confirmed by density distributions of CDD, TDOS, and LOL for hydrated nanoclusters of H2(SiGeO2) and Li2[SiGeO2]H4. The fluctuation in charge density demonstrates that the electronic densities were mainly located in the boundary of adsorbate/adsorbent atoms during the sorption status. Therefore, by combination of SiO and GeO, it can be concluded that SiGeO2 nanocluster might be appropriate candidate for hydrogen conservation in transistors. As the advantages of lithium over Si/Ge possess its higher electron and hole motion, allowing lithium instruments to operate at higher frequencies than Si/Ge instruments.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 1","pages":"15 - 24"},"PeriodicalIF":1.1,"publicationDate":"2026-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519440","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Thermal Quenching Behavior and Luminescence Stability of Sr3SiO5:Ce3+ Phosphor for High-Power White LED Applications 大功率白光LED用Sr3SiO5:Ce3+荧光粉的热猝灭性能和发光稳定性

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-07-20 DOI: 10.1134/S2070205126700024

Deepak Kumar Barla, Rohit Kandulna, Namita Singh, Barkha Kachhap, Ashwini Kumar Sharma, Anupam Kumar

引用次数: 0

Chemical Sensors Based on Quartz-Crystal Microtuning Forks and Metal–Organic Framework UiO-66 基于石英晶体微音叉和金属有机骨架UiO-66的化学传感器

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-07-20 DOI: 10.1134/S2070205126700176

V. N. Simonov, O. V. Solovtsova, A. A. Fomkin

引用次数: 0

Modern Approaches to the Processing of Used Lithium-Ion Batteries 废旧锂离子电池处理的现代方法

IF 0.8 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-02-06 DOI: 10.1134/S2070205125701205

A. Yu. Tsivadze, A. S. Oryshchenko, V. I. Zhilov, G. V. Kostikova, A. A. Bezdomnikov, V. E. Sharov, Yu. G. Pokrovskii, A. D. Kashtanov

引用次数: 0