Protection of Metals and Physical Chemistry of Surfaces最新文献_第5页

The Influence of Aluminum-Alloy Composition on the Structure, Composition, and Thermophysical Properties of Coatings Formed by Microarc Oxidation 铝合金成分对微弧氧化涂层组织、成分及热物理性能的影响

IF 0.8 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-01-15 DOI: 10.1134/S2070205125700935

N. Yu. Dudareva

引用次数: 0

Thermodynamics of Sorption–Desorption Cycles of a Temperature-Controlled Conformal Methane Accumulator Loaded with a Compacted Carbon Adsorbent 负载压实碳吸附剂的温控适形甲烷蓄能器吸附-解吸循环热力学

IF 0.8 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-01-14 DOI: 10.1134/S2070205125700790

I. D. Shelyakin, I. E. Menshchikov, S. S. Chugaev, A. V. Shkolin, A. A. Fomkin

{"title":"Thermodynamics of Sorption–Desorption Cycles of a Temperature-Controlled Conformal Methane Accumulator Loaded with a Compacted Carbon Adsorbent","authors":"I. D. Shelyakin, I. E. Menshchikov, S. S. Chugaev, A. V. Shkolin, A. A. Fomkin","doi":"10.1134/S2070205125700790","DOIUrl":"10.1134/S2070205125700790","url":null,"abstract":"Methane adsorbed natural gas (ANG) is a promising technology applicable to gas storage and transportation. ANG provides higher capacity at relatively low operating pressures compared to CNG, as well as increased fire and explosion safety and energy efficiency of the charge/discharge processes. This allows us to move to new engineering principles for gas accumulators based on conformal designs instead of cylindrical cylinders. A scaled natural gas accumulator (SNGA) of a conformal design with a volume of 24 L loaded with a compacted industrial carbon adsorbent, KS-HAM, was developed, and the comprehensive study of its cyclic operation was carried out. As part of the experiment, the cyclic operation of SNGA was studied under conditions of high-speed charge (up to 2 min) and slow discharge with gas flow rates of 5 and 10 L (NTP)1/min in two modes: with active temperature control and natural convection. For theoretical studies of the cyclic operation of the SNGA, a lumped parameter model was developed and verified using experimental data. The investigations resulted in the characteristics of the cyclic operation of the SNGA that are essential for the purposes of actual usage on passenger vehicles.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"61 4","pages":"761 - 772"},"PeriodicalIF":0.8,"publicationDate":"2026-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145963620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Microstructural, Oxidation and Hot-Corrosion Properties of Diffusion Coated Superalloys for Gas Turbine Applications 燃气轮机用扩散涂层高温合金的显微组织、氧化和热腐蚀性能

IF 0.8 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-01-14 DOI: 10.1134/S2070205125700583

Mairaj Ahmad

引用次数: 0

Surface Tissue Evolution and Effect on Tensile Properties of Q345R Steel under Ultrasonic Shot Peening 超声喷丸强化Q345R钢表面组织演变及其对拉伸性能的影响

IF 0.8 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-01-14 DOI: 10.1134/S2070205125700601

Li Kun, Chen Xiang

{"title":"Surface Tissue Evolution and Effect on Tensile Properties of Q345R Steel under Ultrasonic Shot Peening","authors":"Li Kun,  Chen Xiang","doi":"10.1134/S2070205125700601","DOIUrl":"10.1134/S2070205125700601","url":null,"abstract":"Nano-surface modification and the introduction of residual compressive stress can enhance the service performance of materials. This study investigates the surface integrity of steel Q345R used for pressure vessels after ultrasonic peening, elucidating the evolution of the surface microstructure and its impact on mechanical properties. The experimental results indicate that as the peening time increases, the surface roughness first increases and then decreases, while the surface hardness increases, with a maximum increase of approximately 21.1% compared to the unpeened specimens. As the shot diameter increases, the surface roughness decreases, and the surface hardness decreases, with a minimum increase of about 5.7% compared to the unpeened specimens. As the peening height increases, the surface roughness decreases, and the surface hardness continues to decrease, with a minimum increase of about 11.6% compared to the unpeened specimens. EBSD characterization revealed that peening induced significant plastic deformation on the specimen surface, with a noticeable refinement of grains, reducing in size by about 83.8%, and a significant increase in dislocation density compared to the unpeened areas. Through tensile testing and data analysis, the peening process parameters were optimized. Under the conditions of 8 min of peening time, a shot diameter of 5 mm, and a peening height of 10 cm, the tensile strength and yield strength of Q345R increased by 3.8 and 10.4%, respectively, resulting in the best comprehensive tensile performance.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"61 4","pages":"853 - 866"},"PeriodicalIF":0.8,"publicationDate":"2026-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145963754","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Physicochemical Mechanics of Surface Layers of an Antifriction Material Operating in a Surface-Active Lubricating Medium 在表面活性润滑介质中工作的减摩材料表层的物理化学力学

IF 0.8 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-01-14 DOI: 10.1134/S2070205125700716

L. I. Kuksenova, V. I. Savenko

{"title":"Physicochemical Mechanics of Surface Layers of an Antifriction Material Operating in a Surface-Active Lubricating Medium","authors":"L. I. Kuksenova, V. I. Savenko","doi":"10.1134/S2070205125700716","DOIUrl":"10.1134/S2070205125700716","url":null,"abstract":"Based on the concepts of physicochemical mechanics of contact interaction, a materials-science analysis of the tribological efficiency of a number of synthetic lubricant compositions containing a surface-active additive, lithium 12-hydroxystearate, was carried out. Tests of the “CuAl5 bronze–С45 steel” friction pair were carried out on an MT-8 reversible sliding friction machine under conditions corresponding to the operating modes of heavily loaded friction units. The role of the lubricating medium was revealed using criterial approaches based on an experimentally obtained set of macroscopic integral criteria (phenomenological indicators of friction and wear) and microscopic (microstructural) criteria (physical broadening of X-ray lines, crystal lattice period, elemental composition of the surface layer of the material of the contact deformation zone) determined using modern metallophysical research methods. For the first time, it has been experimentally proven that the use of dispersion-lubricating media containing surfactants in tribocouplings promotes the formation of a wear-resistant structure in the antifriction material aluminum bronze.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"61 4","pages":"867 - 880"},"PeriodicalIF":0.8,"publicationDate":"2026-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145963627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Experimental Study and Adsorption Characteristics of Lavandula angustifolia Extract Powder as Corrosion Inhibitor for C45 in 1 M HCl Solution 薰衣草提取物粉在1m HCl溶液中对C45的缓蚀剂吸附特性及实验研究

IF 0.8 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-01-14 DOI: 10.1134/S2070205125700595

Zineb Hamida, Saida Marmi, Malika Nouadji, Hayat Marmi, Abdelouahad Chala, Chahines Siad, Lynda Abdelli, Omar Ben Mya

{"title":"Experimental Study and Adsorption Characteristics of Lavandula angustifolia Extract Powder as Corrosion Inhibitor for C45 in 1 M HCl Solution","authors":"Zineb Hamida, Saida Marmi, Malika Nouadji, Hayat Marmi, Abdelouahad Chala, Chahines Siad, Lynda Abdelli, Omar Ben Mya","doi":"10.1134/S2070205125700595","DOIUrl":"10.1134/S2070205125700595","url":null,"abstract":"The corrosion inhibition properties of Lavandula angustifolia (LA) extract for C45 steel in a 1 M HCl solution were investigated using weight loss measurements to determine the optimal inhibitor concentrations at room temperature. The performance of LA at deferent temperature (20–50°C) was further evaluated using electrochemical impedance spectroscopy (EIS), including polarization measurements and open circuit potential analysis. The corrosion rates were corroborated by UV-Vis spectroscopy and scanning electron microscopy (SEM). The results demonstrated that LA extract effectively inhibits the corrosion of carbon steel in acidic environments, achieving a maximum inhibition efficiency of 93.87% at an inhibitor concentration of 7 g/L and a temperature of 50°C. Potentiodynamic polarization studies revealed that the inhibitor adsorbs onto the carbon steel surface following the Langmuir adsorption isotherm model, classifying LA as a mixed-type inhibitor. Additionally, the low equilibrium constant Kads values for the adsorption–desorption process suggest that the inhibition mechanism involves physical adsorption. The LA inhibitor effectively protects the surface against additional corrosion attacks, according to SEM and UV studies. Because the computed quantum parameters agreed with the experimental findings, LA can be utilized as a substitute inhibitor to prevent corrosion in carbon steel.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"61 4","pages":"974 - 987"},"PeriodicalIF":0.8,"publicationDate":"2026-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145963697","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Tribological Properties of Ta–Si–C–N Coatings Obtained by Magnetron Sputtering 磁控溅射制备Ta-Si-C-N涂层的摩擦学性能

IF 0.8 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-01-14 DOI: 10.1134/S2070205125700789

A. D. Chertova, A. V. Bondarev, E. A. Levashov, F. V. Kiryukhantsev-Korneev

引用次数: 0

Enhanced Acid Resistance of High-Performance Self-Compacting Concrete with Supplementary Cementitious Materials: Experimental and Predictive Insights 补充胶凝材料增强高性能自密实混凝土的耐酸性能：实验和预测见解

IF 0.8 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-01-14 DOI: 10.1134/S2070205125700625

Abderahmane Seddik, A. Beroual, M. N. Guetteche, Talal M. Althagafi, M.A. Ghebouli, K. Bouferrache, M. Fatmi, A. Djemli

{"title":"Enhanced Acid Resistance of High-Performance Self-Compacting Concrete with Supplementary Cementitious Materials: Experimental and Predictive Insights","authors":"Abderahmane Seddik, A. Beroual, M. N. Guetteche, Talal M. Althagafi, M.A. Ghebouli, K. Bouferrache, M. Fatmi, A. Djemli","doi":"10.1134/S2070205125700625","DOIUrl":"10.1134/S2070205125700625","url":null,"abstract":"This study examines the durability and performance of high-performance self-compacting concrete (HP-SCC) incorporating supplementary cementitious materials (SCMs) such as natural pozzolan, blast furnace slag, and silica fume when exposed to aggressive acidic environments (HCl and H2SO4). In addition to standard tests for fresh concrete properties (slump flow, L-box, V-funnel, sieve stability) and compressive strength, the research integrates analytical chemistry techniques to investigate the degradation mechanisms. Mass loss was measured to quantify acid attack, while X-ray diffraction (XRD) analysis was used to monitor mineralogical changes, such as the dissolution of portlandite and formation of secondary salts due to leaching. Chemical analysis of the immersion solutions provided insight into the dissolution behavior of cementitious phases and shifts in chemical equilibria under acidic conditions. The experimental data were used to calibrate a predictive computational model simulating the kinetics of degradation. Results demonstrated that mixtures containing silica fume and blast furnace slag exhibited superior chemical stability, retaining mechanical strength and microstructural integrity over time. These findings highlight the value of incorporating analytical methods in concrete durability studies, especially for designing materials intended for harsh industrial environments.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"61 4","pages":"929 - 942"},"PeriodicalIF":0.8,"publicationDate":"2026-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145963691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Preparation and Electromagnetic Wave Absorption Property of Carbon Fiber Based YSPM Composites 碳纤维基YSPM复合材料的制备及其电磁波吸收性能

IF 0.8 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-01-14 DOI: 10.1134/S2070205125700613

Jingyan Liu, Tiantian Liu, Qianjun Xia, Rong Li, Kejing Yu

{"title":"Preparation and Electromagnetic Wave Absorption Property of Carbon Fiber Based YSPM Composites","authors":"Jingyan Liu, Tiantian Liu, Qianjun Xia, Rong Li, Kejing Yu","doi":"10.1134/S2070205125700613","DOIUrl":"10.1134/S2070205125700613","url":null,"abstract":"In order to broaden the effective absorption bandwidth (EAB) of the electromagnetic wave absorption material (YSPM) prepared in our previous work, carbon fibers (CF) were introduced to effectively optimized the dielectric constant of YSPM. Polydopamine (PDA) was used as adhesive agent to facilitate the attachment of YSPM onto the CF surface, constructing a structurally stable and high-performance fiber-based electromagnetic wave absorbing material (CF@YSPM). By optimizing the concentration of DA·HCl, the weight ratio of CF to YSPM, and the reaction time, the performance of CF@YSPM electromagnetic wave absorbing composite was systematically enhanced. The results revealed that the incorporation of CF established an efficient conductive network, and significantly improved the loss characteristics of CF@YSPM, enabling effective electromagnetic energy absorption and dissipation without increasing thickness or additives. Through range analysis, the optimal preparation parameters were determined as follows: DA·HCl concentration of 1.5 mol/L, CF-to-YSPM weight ratio of 1 : 3, and reaction time of 24 h. At 8.45 GHz, the composite achieved superior absorption with a minimum reflection loss (RLmin) of –51.23 dB. With a thickness of 2.2 mm, EAB extended to 14.02 GHz, covering multiple important electromagnetic wave frequency bands. Consequently, this study successfully developed a novel carbon fiber-based composite with exceptional broadband electromagnetic wave-absorbing properties through hierarchical structural design and compositional optimization.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"61 4","pages":"808 - 819"},"PeriodicalIF":0.8,"publicationDate":"2026-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145963698","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Development of Nanolaminated Multilayer Ni–Co Alloy Coating of Better Corrosion Resistance 耐腐蚀纳米多层镍钴合金涂层的研制

IF 0.8 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2026-01-14 DOI: 10.1134/S2070205125700649

Aishwarya S. Suvarna, A. Chitharanjan Hegde

{"title":"Development of Nanolaminated Multilayer Ni–Co Alloy Coating of Better Corrosion Resistance","authors":"Aishwarya S. Suvarna,  A. Chitharanjan Hegde","doi":"10.1134/S2070205125700649","DOIUrl":"10.1134/S2070205125700649","url":null,"abstract":"Electrodeposition of composition modulated multilayer (CMM) coatings of Ni–Co alloy was accomplished on mild steel using single bath technique (SBT). Multilayer coatings, having layers of alternatively different compositions have been produced on the mild steel using the electrolytic bath having both Ni and Co ions by periodic pulsing of the current density between two set values, known as cyclic cathode current densities (CCCD’s). The deposition conditions, in terms of the composition and thickness of alternate layers were identified for best performance of those coatings against the corrosion. Electrochemical corrosion study of alloy coatings has been made using electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization methods. It was found that CMM(Ni–Co)1.0/3.0/60 coatings shows approximately three times better corrosion resistance than its monolayer counterpart, deposited from same bath for same duration. The experimental study demonstrated that corrosion protection efficacy of CMM Ni–Co alloy increased with number of layers up to 60 layers, and then started decreasing. The observed increase of corrosion rate at high degree of layering (after 60 layers) was attributed to the diffusion of layers, affected due to rapid change of current densities during deposition. Improved corrosion protection efficacy of multilayer coating is attributed to the alternate layers of alloys having different composition, confirmed by energy dispersion spectroscopy (EDS) and X-ray diffraction (XRD) techniques. The deposited coatings were analyzed for both surface and cross-sectional features using scanning electron microscopy (SEM), and results are discussed.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"61 4","pages":"962 - 973"},"PeriodicalIF":0.8,"publicationDate":"2026-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145963699","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0