Protection of Metals and Physical Chemistry of Surfaces最新文献_第5页

Synthesis of Bio-Based NP-GLIDE Coatings for Easy-to-Clean Applications 易于清洁应用的生物基NP-GLIDE涂层的合成

IF 0.8 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2025-07-17 DOI: 10.1134/S2070205125700042

Utkarsha Gwalwanshi, Harshala Kapadane, Ravindra Puri, Uday Bagale, Jitendra Narkhede, Pawan Meshram

{"title":"Synthesis of Bio-Based NP-GLIDE Coatings for Easy-to-Clean Applications","authors":"Utkarsha Gwalwanshi, Harshala Kapadane, Ravindra Puri, Uday Bagale, Jitendra Narkhede, Pawan Meshram","doi":"10.1134/S2070205125700042","DOIUrl":"10.1134/S2070205125700042","url":null,"abstract":"Efforts to produce environmentally friendly surface coatings with easy-to-clean qualities have gained momentum due to their ability to save water and chemicals while improving surface hygiene. nanopools of grafted lubricating layer for dewetting enablement (NP-GLIDE) coatings represent an innovative approach in surface engineering, combining nanoparticle technology with a unique polymer matrix. The present study focuses on the synthesis of bio-based NP-GLIDE coatings designed for easy-to-clean applications, with the goal of providing sustainable alternatives for a variety of sectors. In this work polyester-based coatings are formulated from itaconic acid as a bio-based resource, butane diol and it also contains H-polydimethylsiloxane (H-PDMS) as another diol to provide low surface energy. The synthesis procedure comprises grafting of PDMS onto a polyester chain by chemical pathways, further crosslinking with polyisocyanates resulting in coatings with tailored surface qualities that are easy to clean. The addition of PDMS in the polymer matrix helps in increasing the surface roughness and ultimately the hydrophobicity of the coatings. The synthesized resin and its coatings were examined using several analytical methods, including FTIR, NMR, DSC, TGA, SEM and contact angle. The contact angle study reveals the increase in contact angle from 56.68° of coating without PDMS to 105.25° of the coating with highest PDMS content. The SEM analysis also confirms the formation of nano-pools of PDMS which helps in creating a self-lubricating layer thus preventing adhesion of contaminants and facilitating their removal with minimal effort. The stain test showed that the coatings have good resistance to oil, inks and lipstick with the increase in content of PDMS. The cured coatings were further analyzed for general coating qualities in order to examine their performance properties.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"61 1","pages":"99 - 112"},"PeriodicalIF":0.8,"publicationDate":"2025-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145166953","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Investigation of Corrosion Behavior of High Entropy Alloy Coated Ductile Iron by Electro Spark Deposition (ESD) Method 电火花沉积法研究高熵合金包覆球墨铸铁的腐蚀行为

IF 0.8 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2025-07-17 DOI: 10.1134/S2070205125700078

Yusuf Kayali

{"title":"Investigation of Corrosion Behavior of High Entropy Alloy Coated Ductile Iron by Electro Spark Deposition (ESD) Method","authors":"Yusuf Kayali","doi":"10.1134/S2070205125700078","DOIUrl":"10.1134/S2070205125700078","url":null,"abstract":"In order to increase the service life of ductile iron (DI) components, various coating methods are used to improve surface properties such as hardness, wear resistance, and corrosion resistance. In recent years, the electrospark deposition (ESD) method has become a preferred surface coating process. This is due to its numerous advantages, including simple equipment and ease of use, strong metallurgical bonding, environmental friendliness, and cost-effectiveness. In this study, a high-entropy alloy was produced on unalloyed ductile iron using the ESD method at different voltages. The microstructures of the high-entropy alloy-coated ductile iron were examined, and properties such as micro hardness, layer thickness, and corrosion resistance were evaluated. To characterize the microstructure and composition of the coatings, optical microscopy, scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX) analyses were performed. The results showed that the corrosion resistance of the Ductile iron coated with the high-entropy alloy increased. The best corrosion resistance and homogeneous coatings were obtained at upper voltages.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"61 1","pages":"146 - 160"},"PeriodicalIF":0.8,"publicationDate":"2025-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145166954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Retraction Note: Dynamic Mechanical and Electrochemical Analysis of Newly Synthesized Polyurethane/CuO–NiO Mixed Metal Oxide Nanocomposite Coated Steel in 3.5% NaCl Solution 新合成的聚氨酯/ CuO-NiO混合金属氧化物纳米复合涂层钢在3.5% NaCl溶液中的动态力学和电化学分析

IF 0.8 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2025-05-23 DOI: 10.1134/S2070205125010010

Joseph Raj Xavier

引用次数: 0

Electrodeposition and Electrocatalytic Study of Ni–Co Alloy Coatings 镍钴合金镀层的电沉积及电催化研究

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2025-03-26 DOI: 10.1134/S2070205124702514

Yathish Rai T., A. Chitharanjan Hegde

引用次数: 0

Effect of Sintering Time on the Corrosion Resistance of PTFE Coatings on AZ31 Mg Alloy 烧结时间对 AZ31 镁合金聚四氟乙烯涂层耐腐蚀性的影响

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2025-03-26 DOI: 10.1134/S2070205124702472

Di Liu, Qing Xiang, Yu Fang, Yuheng Cui, Qin Zou, Zhen Wang, Daixiong Zhang

{"title":"Effect of Sintering Time on the Corrosion Resistance of PTFE Coatings on AZ31 Mg Alloy","authors":"Di Liu, Qing Xiang, Yu Fang, Yuheng Cui, Qin Zou, Zhen Wang, Daixiong Zhang","doi":"10.1134/S2070205124702472","DOIUrl":"10.1134/S2070205124702472","url":null,"abstract":"Corrosion is one of the key technical problems impeding the widespread use of magnesium (Mg) and its alloys. Consequently, enhancing the corrosion resistance of Mg alloys is an urgent issue that necessitates immediate attention in their applications. Polytetrafluoroethylene (PTFE), often termed the ‘king of plastics’ because of its exceptional chemical inertness and non-reactivity, forms coatings that effectively shield metal substrates from corrosive environments. This capability substantially reduces corrosion rates, underscoring its considerable potential in corrosion prevention. In this study, PTFE coatings were successfully prepared on Mg–3Al–1Zn (AZ31) alloy sheets through electrophoretic deposition (EPD). The coatings underwent sintering treatments of varying durations, and their corrosion resistance properties were systematically evaluated. The results indicate that sintering duration critically influences the microstructural morphology of the PTFE coatings; extending the sintering duration within a specific range enhances the microstructure’s compactness. Furthermore, the study examined the corrosion behavior of Mg alloys coated with sintered PTFE in a 3.5 wt % NaCl solution, where the corrosion resistance of the sintered PTFE-coated AZ31 was significantly enhanced. Notably, coatings sintered for 14 h exhibited the highest corrosion resistance, with the corrosion current density decreasing from 4.05 × 10–5 A cm–2 for the bare AZ31 to 1.20 × 10–7 A cm–2 for the sintered PTFE-coated AZ31. Concurrently, the charge transfer resistance increased significantly from 227 to 2.72 × 105 Ω cm2. The coatings achieved a contact angle exceeding 123° and an adhesion rating of 5B. This offers a novel approach for mitigating corrosion in Mg and its alloys.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"60 6","pages":"1120 - 1135"},"PeriodicalIF":1.1,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143698568","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

High Temperature Oxidation and Surface Microstructure Evolution of Nickel-Based Superalloy GH3039 via Aluminized Embedding 镀铝包埋镍基高温合金GH3039的高温氧化及表面组织演变

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2025-03-26 DOI: 10.1134/S207020512470254X

Jiantao Wang, Conglin Zhang, Yaqi Liu, Binghao Dong, Xiyue Xing

{"title":"High Temperature Oxidation and Surface Microstructure Evolution of Nickel-Based Superalloy GH3039 via Aluminized Embedding","authors":"Jiantao Wang, Conglin Zhang, Yaqi Liu, Binghao Dong, Xiyue Xing","doi":"10.1134/S207020512470254X","DOIUrl":"10.1134/S207020512470254X","url":null,"abstract":"This study investigates the effect of an aluminized coating on the oxidation resistance of GH3039 superalloy. A powder embedding technique at 900°C with 60 wt % aluminum was employed to prepare the coating. The phase composition and surface morphology of oxidation products were analyzed using X-ray diffraction (XRD) and scanning electron microscopy (SEM). Untreated and aluminized samples were subjected to oxidation at 800, 900, and 1000°C for 100 h. Post-treatment, the GH3039 alloy exhibited a uniformly distributed aluminized layer about 90 μm thick. This layer comprised three distinct sub-layers: a top layer with Ni2Al3 and minor NiAl3 phases, a middle layer of mainly Ni2Al3, and a β-NiAl phase-rich bottom layer. Oxide weight measurements indicated an initial rapid increase followed by a significant reduction at high temperatures, primarily due to Cr2O3 volatilization into gaseous CrO3. Oxidation curves for the aluminized samples showed reduced and stable weight gain patterns, adhering mostly to the parabolic law with no further increase at advanced stages. The untreated samples presented a porous oxide film with complex components including Cr2O3, NiCr2O4, TiO2, which adversely affected their oxidation resistance. In contrast, the aluminized samples predominantly displayed an Al2O3 film that transitioned from flaky θ-Al2O3 to a compact α-Al2O3 structure at increased temperatures, thereby significantly enhancing the alloy’s resistance against high-temperature oxidation.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"60 6","pages":"1136 - 1146"},"PeriodicalIF":1.1,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143698569","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Investigation of Electrodeposited Mn–Co–Y2O3 Coating on Crofer 22 APU for the SOFC Interconnect Application SOFC互连用Crofer 22 APU电沉积Mn-Co-Y2O3涂层的研究

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2025-03-26 DOI: 10.1134/S2070205124702496

Farhad Mohsenifar, Hadi Ebrahimifar, Ahmad Irannejad

{"title":"Investigation of Electrodeposited Mn–Co–Y2O3 Coating on Crofer 22 APU for the SOFC Interconnect Application","authors":"Farhad Mohsenifar, Hadi Ebrahimifar, Ahmad Irannejad","doi":"10.1134/S2070205124702496","DOIUrl":"10.1134/S2070205124702496","url":null,"abstract":"The electrodeposition technique was successfully used for the co-deposition of Mn and Co metals and Y2O3 particles on Corofer 22 APU interconnects. The uncoated and Mn–Co–Y2O3-coated samples were oxidized in an electric furnace for 500 h at 800°C. The surface morphology and phase structure of these samples were examined by field emission scanning electron microscopy (FESEM) and XRD analysis, respectively. The electrical conductivity of the samples was investigated by measuring area specific resistance. The results showed that the weight gain of uncoated and Mn–Co–Y2O3-coated samples after isothermal oxidation for 500 h was 0.52 and 0.4 mg cm–2, respectively. Microscopic investigations demonstrated that a non-continuous thin oxide scale forms underneath the applied coating, while high outward diffusion of Fe, Mn, and Cr occurred in uncoated steel after 500 h of oxidation at 800°C. Findings also implied that the applied coating significantly improve the electrical conductivity of steel interconnects after long-term oxidation at high temperatures.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"60 6","pages":"1033 - 1049"},"PeriodicalIF":1.1,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143698460","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Physical Properties of NiFeS2 Thin Films Prepared by Spray Pyrolysis Method 喷雾热解法制备NiFeS2薄膜的物理性质

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2025-03-26 DOI: 10.1134/S2070205124702484

A. Mhamdi

引用次数: 0

Investigation of Mild Steel Corrosion Inhibition with Tamarindus indica Fiber Extract in 0.5 M Trichloroacetic Acid: Adsorption, Antifouling, Electrochemical and DFT Studies 罗望子纤维提取物在 0.5 M 三氯醋酸中抑制低碳钢腐蚀的研究：吸附、防污、电化学和 DFT 研究

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2025-03-26 DOI: 10.1134/S2070205124702538

Baluchamy Tamilselvi, Durvas Seshian Bhuvaneshwari, Sethuramasamy Padmavathy, Varatharaj Rajapandian, Periyakaruppan Karuppasamy

{"title":"Investigation of Mild Steel Corrosion Inhibition with Tamarindus indica Fiber Extract in 0.5 M Trichloroacetic Acid: Adsorption, Antifouling, Electrochemical and DFT Studies","authors":"Baluchamy Tamilselvi, Durvas Seshian Bhuvaneshwari, Sethuramasamy Padmavathy, Varatharaj Rajapandian, Periyakaruppan Karuppasamy","doi":"10.1134/S2070205124702538","DOIUrl":"10.1134/S2070205124702538","url":null,"abstract":"The as-extracted Tamarindus indica fiber (TIF) extract and its structural insights were analyzed successfully by spectral, electrochemical, analytical and theoretical techniques. The maximum corrosion inhibition efficiency (90.16%) was found by weight loss technique at 308 K. Monolayer adsorption was found and it obeyed the Langmuir adoption model. The –∆H* values support an exothermic process and –∆S* values confirm TIF adsorbed on mild steel surface. The –∆G° values reveal that the TIF adsorption on mild steel is a spontaneous process. Mixed type inhibition behavior was confirmed by Tafel plots. Increased trend of charge transfer resistance (Rct) and decreased trend of double layer capacitance (Cdl) with increasing TIF (0–25 mg/L) concentration by Nyquist plots. FTIR and UV-Visible result confirms the mild steel-TIF extract complex formation. FE-SEM, EDAX, mapping analysis and XPS study supports the adsorption of TIF extract on mild steel surface. DFT study suggests that the biomolecules present in TIF extract is responsible for the formation mono adsorption layer on mild steel surface. An appropriate mechanism for mild steel corrosion inhibition with TIF extract in 0.5 M TCA was proposed.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"60 6","pages":"1200 - 1221"},"PeriodicalIF":1.1,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143698661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of Heat Treatment on Corrosion Resistance of Electroless Duplex Ni–P/Ni–B Coatings 热处理对化学镀Ni-P / Ni-B双相镀层耐蚀性的影响

IF 1.1 4区材料科学

Protection of Metals and Physical Chemistry of Surfaces Pub Date : 2025-03-26 DOI: 10.1134/S2070205124702447

Gökçe Dil, Behiye Yüksel, Faiz Muhaffel, İhsan Gökhan Serin, Ergin Kosa, Ali Gökşenli

{"title":"Effect of Heat Treatment on Corrosion Resistance of Electroless Duplex Ni–P/Ni–B Coatings","authors":"Gökçe Dil, Behiye Yüksel, Faiz Muhaffel, İhsan Gökhan Serin, Ergin Kosa, Ali Gökşenli","doi":"10.1134/S2070205124702447","DOIUrl":"10.1134/S2070205124702447","url":null,"abstract":"As-plated and heat-treated Ni–P, Ni–B, and Ni–P/Ni–B coatings (Ni–P as an internal layer) on steel by electroless plating and their morphology, microstructure, and corrosion performance were evaluated in this study. Scanning electron microscopy analysis demonstrated that all coatings are uniform and adhesion between the substrate and coating was good. Ni–P and Ni–B coatings were amorphous-like structures in their as-plated condition, and by applying heat treatment nickel fully crystallized, nickel borides and nickel phosphides were formed. Immersion tests in 10% HCl and 5% H2SO4 solutions and potentiodynamic polarisation measurements in 3.5% NaCl aqueous solution were applied to investigate the corrosion resistance of the coatings. The results demonstrated that all coatings exhibit better corrosion performance than the substrate steel. Applying heat treatment did not change the corrosion resistance of Ni–P coating, conversely, heat treatment had a dominant positive effect on the corrosion performance of Ni–B and a minor effect on Ni–P/Ni–B duplex coatings.","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"60 6","pages":"1094 - 1103"},"PeriodicalIF":1.1,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143698562","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0