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Tunable physicochemical and biocompatibility properties of PCL/HAp/BN composite films through γ-irradiation γ辐照下PCL/HAp/BN复合膜的可调理化和生物相容性
IF 4 3区 化学
Polymer Bulletin Pub Date : 2025-07-25 DOI: 10.1007/s00289-025-05941-x
S. Monica Susai Mary, S. Raja, S. Narayana Kalkura, S. Moorthy Babu
{"title":"Tunable physicochemical and biocompatibility properties of PCL/HAp/BN composite films through γ-irradiation","authors":"S. Monica Susai Mary,&nbsp;S. Raja,&nbsp;S. Narayana Kalkura,&nbsp;S. Moorthy Babu","doi":"10.1007/s00289-025-05941-x","DOIUrl":"10.1007/s00289-025-05941-x","url":null,"abstract":"<div><p>This study explains the effects of γ-irradiation on the physical and biological properties of polycaprolactone/hydroxyapatite/boron nitride (PCL/HAp/BN) composite films with fluences of 25, 50, 75, and 100 kGy. SEM micrographs revealed a distinct microporous surface morphology in the composite film treated at 75 kGy, indicating significant structural modifications induced at this irradiation dose. AFM result showed that surface roughness was attained twice that of the pristine. Crystallinity and crystallite size were found to decrease with irradiation, and the predominant (110) peak of PHB was slightly shifted from 21.5 to 21.7° at 50 kGy. Water contact angle (WCA) measurements demonstrated increased hydrophilicity, with values rising from 83 to 89° up to 50 kGy. The composite film irradiated at 75 kGy exhibited the lowest hemolytic activity, higlighting its superior hemocompatibility than that of pristine and other irradiated samples. Cell viability assays revealed that fibroblast proliferation reached its maximum at 75 kGy, outperforming both the pristine and other irradiated composite films. These results highlight the ability of γ-irradiation to tune key properties of PHB composite films, including crystallinity, surface roughness, hydrophobicity, hemocompatiblity, and cell proliferation. By enhancing the morphological, structural, and biological performance, γ-irradiated PHB composites show great promise for tissue engineering applications.</p></div>","PeriodicalId":737,"journal":{"name":"Polymer Bulletin","volume":"82 15","pages":"10319 - 10340"},"PeriodicalIF":4.0,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of controlling the molecular weight of poly(vinyl alcohol) via cobalt mediated radical polymerization on printability and degradation behavior of poly(vinyl alcohol) scaffolds 钴介导自由基聚合控制聚乙烯醇分子量对聚乙烯醇支架可打印性和降解性能的影响
IF 4 3区 化学
Polymer Bulletin Pub Date : 2025-07-25 DOI: 10.1007/s00289-025-05927-9
Arman Ramezanpour, Alireza Sabzevari, Mojtaba Ansari, Hossein Eslami, Mohammad Javad Mohammadi Tazehabadi
{"title":"Effects of controlling the molecular weight of poly(vinyl alcohol) via cobalt mediated radical polymerization on printability and degradation behavior of poly(vinyl alcohol) scaffolds","authors":"Arman Ramezanpour,&nbsp;Alireza Sabzevari,&nbsp;Mojtaba Ansari,&nbsp;Hossein Eslami,&nbsp;Mohammad Javad Mohammadi Tazehabadi","doi":"10.1007/s00289-025-05927-9","DOIUrl":"10.1007/s00289-025-05927-9","url":null,"abstract":"<div><p>Cobalt-mediated radical polymerization (CMRP) is the best technique to obtain polyvinyl acetate (PVAc) and PVAc derivatives such as poly(vinyl alcohol) (PVA). Therefore, controlled synthesis of PVA via CMRP of vinyl acetate (VAc) can be a helpful technique to address the limitations related to the poor printability and rapid degradation rate of pure PVA for biomedical applications. In this research, PVAc was synthesized under controlled conditions using CMRP of VAc. The polymerization was performed with different initiator ratios at different temperatures using cobalt(II) acetylacetonate (Co(acac)<sub>2</sub>) as the controlling agent and benzoyl peroxide (BPO) as the initiator. Also, N,N-dimethylformamide (DMF) was used as the ligand. The increase in the initiator ratio and temperature led to an accelerated polymerization process. For instance, the polymerization finished after 110 and 80 min for 0.75 and 1 initiator ratio, respectively. It is important to highlight that each experiment was repeated at three distinct time intervals after obtaining maximum viscosity of the polymerization system. The conversion rate of monomer to polymer and ln[M]<sub>0</sub>/[M] ratio increased over time, demonstrating the controllability of the polymerization. The Co(acac)<sub>2</sub> complex successfully acted as the controlling agent in the polymerization process. Homopolymerization of VAc was then optimized, and optimum PVAc samples were successfully hydrolyzed to PVA homopolymers, which was confirmed by proton nuclear magnetic resonance (<sup>1</sup>H NMR) analysis. PVA homopolymers were synthesized with controlled molecular weight (M<sub>n</sub>), which was illustrated by gel permeation chromatography (GPC) test. Furthermore, the polymers showed suitable printability using fused deposition modeling (FDM) technique. According to the scanning electron microscopy (SEM) analysis, pore size in PVA scaffolds increased with an increase in M<sub>n</sub>. The swelling ratio after 24 h decreased from 97.413% to 84.215% by increasing the M<sub>n</sub> from 8840 to 12,266. Also, the degradation ratio after 28 days decreased from 85.113% to 74.118% for the same M<sub>n</sub>. This phenomenon was attributed to the higher chain entanglements in higher M<sub>n</sub>. Therefore, the swelling capacity and the degradation of the PVA scaffolds were successfully controlled by controlling the M<sub>n</sub>. Hence, using CMRP method, pure PVA scaffolds can be obtained and widely used in biomedical applications such as tissue engineering and drug delivery as they are controllably degradable and biocompatible.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":737,"journal":{"name":"Polymer Bulletin","volume":"82 15","pages":"10279 - 10299"},"PeriodicalIF":4.0,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unidirectional drug release controlled by a PLA/mesoporous bioactive glass/PVA polymer composite 聚乳酸/介孔生物活性玻璃/聚乙烯醇聚合物复合材料控制药物单向释放
IF 4 3区 化学
Polymer Bulletin Pub Date : 2025-07-25 DOI: 10.1007/s00289-025-05954-6
Lijun Ji, Chendi Wang, Fengjuan Chen, Chunyu Xie, Xiang Qin, Xiaojun Yang
{"title":"Unidirectional drug release controlled by a PLA/mesoporous bioactive glass/PVA polymer composite","authors":"Lijun Ji,&nbsp;Chendi Wang,&nbsp;Fengjuan Chen,&nbsp;Chunyu Xie,&nbsp;Xiang Qin,&nbsp;Xiaojun Yang","doi":"10.1007/s00289-025-05954-6","DOIUrl":"10.1007/s00289-025-05954-6","url":null,"abstract":"<div><p>A polymer composite based on PLA/MBGs-LVFX/PVA with unidirectional drug release property was prepared with mesoporous bioactive glasses (MBGs) as a drug-loading layer, polylactic acid (PLA) as a barrier layer, and polyvinyl alcohol (PVA) as a controlled release layer. The Fourier transform infrared spectroscopy, transmission electron microscopy, scanning electron microscopy, thermogravimetric analysis, and small-angle X-ray scattering were employed to characterize the composition and structure of the PLA/MBGs-LVFX/PVA unidirectional drug release system. Nitrogen absorption characterization confirmed that the specific surface area of MBGs reached 485.6 m<sup>2</sup>/g with an average pore diameter of 6 nm. The PLA/MBGs-LVFX/PVA polymer composite exhibited a levofloxacin hydrochloride (LVFX) loading capacity of 41.17%, an encapsulation efficiency of 66.5%, and a cumulative release rate reaching 61.28% within 24 h, demonstrating excellent drug loading and release capabilities. The mechanism by which PVA controlled the release of LVFX was discussed. The biodegradation of the drug release system in PBS led to a certain increase in pH, which is conducive to bactericidal efficacy. In vitro bioactivity assessment confirmed that this drug release system had no significant cytotoxicity at a reasonable dosage. This unidirectional drug release film is expected to achieve targeted drug delivery to focal sites rich in sensitive nerves, thereby improving drug efficacy and reducing side effects on the nervous system.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":737,"journal":{"name":"Polymer Bulletin","volume":"82 15","pages":"10301 - 10317"},"PeriodicalIF":4.0,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248319","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Functionalized carboxymethyl cellulose/polyethyleneimine nanocomposite with silver nanoparticles for enhanced dye adsorption and antimicrobial properties 功能化羧甲基纤维素/聚乙烯亚胺纳米复合材料与纳米银增强染料吸附和抗菌性能
IF 4 3区 化学
Polymer Bulletin Pub Date : 2025-07-25 DOI: 10.1007/s00289-025-05933-x
Zeineb Hamden, Hussain Alenezi, Jehan S. Albrahim, Ahmed K. Saleh
{"title":"Functionalized carboxymethyl cellulose/polyethyleneimine nanocomposite with silver nanoparticles for enhanced dye adsorption and antimicrobial properties","authors":"Zeineb Hamden,&nbsp;Hussain Alenezi,&nbsp;Jehan S. Albrahim,&nbsp;Ahmed K. Saleh","doi":"10.1007/s00289-025-05933-x","DOIUrl":"10.1007/s00289-025-05933-x","url":null,"abstract":"<div><p>The current study demonstrated a novel nanocomposite conducted with carboxymethyl cellulose (CMC)/polyethyleneimine (PEI) hydrogel decorated with silver nanoparticles (Ag-NPs) (CMC/PEI/Ag-NPs) was synthesized to improve the removal efficiency of anionic dyes from aqueous solutions. The resulting CMC/PEI/Ag-NPs nanocomposite was characterized through infrared spectroscopy, scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and X-ray photoelectron spectroscopy to confirm successful Ag-NPs incorporation with the CMC/PEI/Ag-NPs. The TEM images reveal that the Ag-NPs within the CMC/PEI matrix have an average diameter of approximately 100 nm​. The instrumental analysis confirms the successful synthesis of CMC/PEI/Ag-NPs nanocomposite, highlighting the chemical interaction between CMC, PEI, and Ag-NPs. Batch adsorption experiments assessed the capacity of the composite to adsorb methyl orange (MO) under varying parameters conditions. Under optimal conditions including pH 3, an incubation time of 100 min, a dye concentration of 500 mg/L, and a reaction temperature of 45 °C, the CMC/PEI/Ag-NPs nanocomposite demonstrated outstanding adsorption performance, achieving a maximum adsorption capacity of 286 mg/g. The adsorption process was well described by the Langmuir isotherm and followed a pseudo-second-order kinetic model. The reusability of the CMC/PEI/Ag-NPs nanocomposite was evaluated, and the results demonstrated that after five adsorption–desorption cycles, its adsorption capacity remained at 66 mg/g for MO. These findings confirm its effectiveness and durability for repeated use in the adsorption of anionic dyes. Compared to CMC/PEI, the CMC/PEI/Ag-NPs nanocomposite has excellent and more efficient sterilization efficacy against Escherichia coli (13 ± 0.93 mm), <i>Salmonella typhimurium</i> (11 ± 0.85 mm), <i>Pseudomonas aeruginosa</i> (12 ± 0.55 mm), <i>Staphylococcus aureus</i> (15 ± 1.02 mm), <i>Streptococcus mutans</i> (18 ± 1.14 mm), and <i>Candida albicans</i> (16 ± 1.23 mm). These findings suggest that the CMC/PEI/Ag-NPs nanocomposite holds promise for applications in wastewater treatment, as well as industrial and biomedical fields, providing a sustainable and efficient solution for water purification and microbial control.</p></div>","PeriodicalId":737,"journal":{"name":"Polymer Bulletin","volume":"82 14","pages":"9011 - 9042"},"PeriodicalIF":4.0,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145236921","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Kinetic analysis of the sulfur-driven curing and cross-linking behavior of chlorosulfonated polyethylene rubber 氯磺化聚乙烯橡胶硫化及交联动力学分析
IF 4 3区 化学
Polymer Bulletin Pub Date : 2025-07-25 DOI: 10.1007/s00289-025-05936-8
Hossein Roshanaei, Mohammad Reza Pourhossaini, Mahmoud Razavizadeh, Mohammad Khabiri, Hassan Fattahi
{"title":"Kinetic analysis of the sulfur-driven curing and cross-linking behavior of chlorosulfonated polyethylene rubber","authors":"Hossein Roshanaei,&nbsp;Mohammad Reza Pourhossaini,&nbsp;Mahmoud Razavizadeh,&nbsp;Mohammad Khabiri,&nbsp;Hassan Fattahi","doi":"10.1007/s00289-025-05936-8","DOIUrl":"10.1007/s00289-025-05936-8","url":null,"abstract":"<div><p>The present research investigated the influence of the sulfur concentration on the curing behavior of chlorosulfonated polyethylene (CSM) rubber, highlighting its critical role in optimizing the cross-linking efficiency and curing kinetics. The results demonstrated that the formulation containing 2.5 phr of sulfur presented the highest cross-link density (1.56 × 10⁻<sup>4</sup> mol/cm<sup>3</sup>) and curing enthalpy (10.9 J/g). However, specific properties were superior for the compound with 2 phr sulfur. With the lowest activation energy (91.48 kJ/mol), the highest reaction rate constant at 150, 160, and 170 °C (0.45, 0.83, and 1.45 min⁻<sup>1</sup>), the lowest cross-link density (1.24 × 10⁻<sup>5</sup> mol/cm<sup>3</sup>), and the lowest curing enthalpy 3.16 J/g, the sulfur-free sample stood out. Additionally, a strong correlation was detected between the cross-link network, which was determined by swelling tests and rheological measurements. These findings offer valuable insights into the design of sulfur curing systems, enabling the optimal selection of the sulfur concentration in CSM rubber formulations, with significant implications for advanced material applications.</p></div>","PeriodicalId":737,"journal":{"name":"Polymer Bulletin","volume":"82 15","pages":"10359 - 10388"},"PeriodicalIF":4.0,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248369","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nanogels as multifunctional platforms: from drug delivery to gene therapy 纳米凝胶作为多功能平台:从药物输送到基因治疗
IF 4 3区 化学
Polymer Bulletin Pub Date : 2025-07-25 DOI: 10.1007/s00289-025-05939-5
Alina Javaid, Nadia Shamshad Malik, Ume Ruqia Tulain, Arshad Mahmood, Muhammad Farhan Ali Khan, Sohail Akram, Asmaa Jabeen, Sajjad Hussain
{"title":"Nanogels as multifunctional platforms: from drug delivery to gene therapy","authors":"Alina Javaid,&nbsp;Nadia Shamshad Malik,&nbsp;Ume Ruqia Tulain,&nbsp;Arshad Mahmood,&nbsp;Muhammad Farhan Ali Khan,&nbsp;Sohail Akram,&nbsp;Asmaa Jabeen,&nbsp;Sajjad Hussain","doi":"10.1007/s00289-025-05939-5","DOIUrl":"10.1007/s00289-025-05939-5","url":null,"abstract":"<div><p>Nanogels, as three-dimensional nanoscale hydrogels, serve as versatile platforms for biomedical and drug delivery applications. They are designed for precise and controlled drug administration owing to their distinctive characteristics, which include a large surface area, high loading capacity, scalability, and stimuli-responsiveness. Composed of natural or synthetic polymers such as chitosan, poly(ethylene glycol), and poly(N-isopropyl acrylamide), nanogels leverage crosslinked polymeric networks to achieve stability, biocompatibility, and tailored functionality. These polymeric systems are particularly promising for next-generation therapies, including CRISPR-Cas9 gene editing, cancer treatment, and central nervous system drug delivery. Special emphasis is placed on stimuli-responsive nanogels, which leverage environmental triggers (e.g., pH, temperature and redox potential) for site-specific drug release, enhancing therapeutic efficacy while minimizing off-target effects. Additionally, the integration of theranostic functionalities within nanogels bridges diagnostics and therapy, offering real-time monitoring and treatment. This review also highlights sustainable green chemistry approaches for nanogel synthesis, emphasizing eco-friendly polymeric design to reduce environmental impact. Despite their potential, clinical translation faces challenges such as scalability, stability, and regulatory hurdles. By addressing these limitations, polymeric nanogels hold transformative promise for precision medicine, offering a pathway to personalized and targeted therapeutics.</p></div>","PeriodicalId":737,"journal":{"name":"Polymer Bulletin","volume":"82 15","pages":"9683 - 9719"},"PeriodicalIF":4.0,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248147","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polyacrylamide lactic acid modification: a novel approach to preparation of a water-soluble and high-performance glue 聚丙烯酰胺乳酸改性:制备水溶性高性能胶水的新方法
IF 4 3区 化学
Polymer Bulletin Pub Date : 2025-07-25 DOI: 10.1007/s00289-025-05935-9
Sevara Khazratkulova, Mukhtarjan Mukhamediev, Nodira Zokirova, Basant Lal, Mavjuda Rakhmatullaeva, Dilroba Mukhammdieva, Parida Mirkhamidova, Elyor Berdimurodov, Fotima Sobirova, Ahmad Hosseini-Bandegharaei
{"title":"Polyacrylamide lactic acid modification: a novel approach to preparation of a water-soluble and high-performance glue","authors":"Sevara Khazratkulova,&nbsp;Mukhtarjan Mukhamediev,&nbsp;Nodira Zokirova,&nbsp;Basant Lal,&nbsp;Mavjuda Rakhmatullaeva,&nbsp;Dilroba Mukhammdieva,&nbsp;Parida Mirkhamidova,&nbsp;Elyor Berdimurodov,&nbsp;Fotima Sobirova,&nbsp;Ahmad Hosseini-Bandegharaei","doi":"10.1007/s00289-025-05935-9","DOIUrl":"10.1007/s00289-025-05935-9","url":null,"abstract":"<div><p>Modern adhesive technologies demand environmentally friendly solutions with high performance. This study explores the innovative use of polyacrylamide lactic acid modification (PAM-LA) as a water-soluble, pH-responsive glue to addresses the need through its enhanced adhesive properties and environmental safety. Polyacrylamide was modified with lactic acid to introduce carboxyl groups, significantly improving its adhesive capabilities via increased hydrogen bonding and electrostatic repulsion. Spectroscopic analyses (IR, <sup>1</sup>H NMR, <sup>13</sup>C NMR) confirmed the successful incorporation of lactic acid into the polyacrylamide backbone. Viscosity measurements demonstrated unique behaviors, typical of polyelectrolytes, with a notable increase in viscosity upon dilution due to enhanced ionization of carboxyl groups. Potentiometric titration revealed that the amount of alkali required for titration was proportional to the modification time, indicating an increase in carboxyl groups. Key results show that the pH-responsive nature of PAM-LA allows for tunable adhesive properties, with higher pH levels leading to greater swelling and stronger adhesion. The rate constants for PAM-LA at different pH values were measured, with values such as 8.2 × 10<sup>−3</sup> at pH 1.68, 10.5 × 10<sup>−3</sup> at pH 6.85, and 15.5 × 10<sup>−3</sup> at pH 9.15, indicating increased reactivity and adhesion with rising pH. PAM-LA introduces a novel pH-responsive adhesive system by modifying polyacrylamide with lactic acid, enhancing its hydrogen bonding and electrostatic interactions for superior adhesion. Its primary application prospects include environmentally friendly, water-soluble glues for biomedical, packaging, and industrial uses where tunable adhesion is required.</p></div>","PeriodicalId":737,"journal":{"name":"Polymer Bulletin","volume":"82 15","pages":"10255 - 10277"},"PeriodicalIF":4.0,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Systematically investigating dissolution properties of silk sericin from industrialized silkworm rearing cocoons 系统研究了工业化蚕茧中丝胶素的溶出特性
IF 4 3区 化学
Polymer Bulletin Pub Date : 2025-07-24 DOI: 10.1007/s00289-025-05952-8
Yuwei Jin, Mengyao Pan, Kexin Jiang, Ying Mao, Wangyang Lu, Wenbin Jiang, Wenxing Chen
{"title":"Systematically investigating dissolution properties of silk sericin from industrialized silkworm rearing cocoons","authors":"Yuwei Jin,&nbsp;Mengyao Pan,&nbsp;Kexin Jiang,&nbsp;Ying Mao,&nbsp;Wangyang Lu,&nbsp;Wenbin Jiang,&nbsp;Wenxing Chen","doi":"10.1007/s00289-025-05952-8","DOIUrl":"10.1007/s00289-025-05952-8","url":null,"abstract":"<div><p>Artificial diet-rearing silkworms are strongly developed due to climate constraints and market demand. However, research on the industrialized artificial diet-rearing silkworms at all industrialized silkworm rearing) remains relatively limited. This study comprehensively investigated the dissolution properties of sericin derived from industrialized silkworm rearing cocoons. The physicochemical features were systematically characterized through amino acid analyses, molecular weight distribution tests, Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). Under identical degumming conditions, the sericin from industrialized silkworm rearing cocoons exhibited superior dissolution properties, particularly faster dissolution speed and less remaining sericin content than that from mulberry leaf-rearing silkworm cocoons. In comparison, no significant differences were observed in amino acid composition, secondary structure, and thermal stability between sericin samples from these two cocoons. Importantly, for industrialized silkworm rearing cocoons, degumming treatment and sericin extraction will consume less energy, aligning with the principles of low-carbon production and environmental protection. Additionally, this work highlights the broad development potential and application prospects of industrialized silkworm rearing and the resulting sericin.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":737,"journal":{"name":"Polymer Bulletin","volume":"82 15","pages":"10235 - 10253"},"PeriodicalIF":4.0,"publicationDate":"2025-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145248381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A novel poly(vinyl N-furfuryl-N-benzoylthiourea) and its metal complexes: synthesis, properties, and food packaging applications 一种新型聚(乙烯基n -糠酰- n -苯甲酰硫脲)及其金属配合物:合成、性能及食品包装应用
IF 4 3区 化学
Polymer Bulletin Pub Date : 2025-07-23 DOI: 10.1007/s00289-025-05930-0
Gülşah Kurt, Nuran Erdem, Burhan Ünlü
{"title":"A novel poly(vinyl N-furfuryl-N-benzoylthiourea) and its metal complexes: synthesis, properties, and food packaging applications","authors":"Gülşah Kurt,&nbsp;Nuran Erdem,&nbsp;Burhan Ünlü","doi":"10.1007/s00289-025-05930-0","DOIUrl":"10.1007/s00289-025-05930-0","url":null,"abstract":"<div><p>4-vinyl-<i>N</i>-furfuryl-<i>N</i>-benzoylthiourea monomer (4VBT1) was successfully polymerized using free radical polymerization conditions with high yields and molecular weights, <i>M</i><sub>n</sub> = 674 kDa with 2.0 molecular weight distribution (PDI). Ag(I), Zn(II) and Cu(II) complexes of this polymer have also been successfully synthesized and characterized. The films of polymer (P4VBT1) and its silver complex (P4VBT1-Ag) were evaluated to determine their food preservation properties. Physicochemical and microbiological analyses of the packaged beef with P4VBT1 and P4VBT1-Ag films were carried out on the 1st, 5th, 10th, and 14th days of the storage process. Moisture levels in P4VBT1 and P4VBT1-Ag stayed stable, and no significant pH difference was detected between the groups at the end of the storage period. The beef’s peroxide in P4VBT1-Ag packaging was lower than others at storage end. During storage, insignificant changes were observed in <i>a*</i> values for group B and <i>b*</i> values for groups A (P4VBT1) and B (P4VBT1-Ag). Throughout the storage period, group B demonstrated the lowest levels of total mesophilic aerobic bacteria (TMAB) and total psychrotrophic aerobic bacteria (TPAB). On day 14, it also had the fewest Escherichia coli, but samples showed no statistical difference. By day ten, P4VBT1 and P4VBT1-Ag packaging showed reduced effectiveness in suppressing Coliform bacteria. Utilizing P4VBT1 and P4VBT1-Ag materials for packaging has led to a slowdown in microbial expansion.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":737,"journal":{"name":"Polymer Bulletin","volume":"82 14","pages":"8991 - 9010"},"PeriodicalIF":4.0,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145236823","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review study on the mechanical behaviour of natural fibre-reinforced epoxy composite 天然纤维增强环氧复合材料力学性能研究综述
IF 4 3区 化学
Polymer Bulletin Pub Date : 2025-07-23 DOI: 10.1007/s00289-025-05902-4
Vikash Chandra Dinkar, Vikash Kumar
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