Physics of the Solid State最新文献

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Tunable Fano Resonance for Optimized Performance in High-Efficiency Photonic Filters 用于优化高效光子滤波器性能的可调谐范诺共振
IF 0.9 4区 物理与天体物理
Physics of the Solid State Pub Date : 2025-01-14 DOI: 10.1134/S1063783424601863
Younes Errouas, Ilyass El Kadmiri, Youssef Ben-Ali, Driss Bria
{"title":"Tunable Fano Resonance for Optimized Performance in High-Efficiency Photonic Filters","authors":"Younes Errouas,&nbsp;Ilyass El Kadmiri,&nbsp;Youssef Ben-Ali,&nbsp;Driss Bria","doi":"10.1134/S1063783424601863","DOIUrl":"10.1134/S1063783424601863","url":null,"abstract":"<p>A basic photonic device is engineered using two resonators attached either at two distinct points (forming a U-shaped structure) or at the same location (creating a crossed structure) along a waveguide. This configuration is designed to generate Fano and electromagnetically induced transparency (EIT) resonances within the transmission spectrum. These resonances arise due to internal interactions within the structure: Fano resonances occur when the resonance is near a transmission zero, while EIT resonances manifest when positioned between two transmission zeros. As an application, Fano resonances, characterized by their asymmetric profile, allow for the design of highly selective optical filters. These filters are capable of distinguishing between wavelengths that are very close together, which is crucial for telecommunication systems and integrated photonic circuits.</p>","PeriodicalId":731,"journal":{"name":"Physics of the Solid State","volume":"66 12","pages":"634 - 641"},"PeriodicalIF":0.9,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142976596","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and Characterization of Copper Sulfate Single Crystals 硫酸铜单晶的合成与表征
IF 0.9 4区 物理与天体物理
Physics of the Solid State Pub Date : 2025-01-14 DOI: 10.1134/S1063783424601504
Huda I. Ahemad, Ganesh E. Patil, Sarika D. Shinde, Dnyaneshwari Y. Patil, Gotan H. Jain, D. D. Kajale, S. R. Gadakh, Sharad B. Patil
{"title":"Synthesis and Characterization of Copper Sulfate Single Crystals","authors":"Huda I. Ahemad,&nbsp;Ganesh E. Patil,&nbsp;Sarika D. Shinde,&nbsp;Dnyaneshwari Y. Patil,&nbsp;Gotan H. Jain,&nbsp;D. D. Kajale,&nbsp;S. R. Gadakh,&nbsp;Sharad B. Patil","doi":"10.1134/S1063783424601504","DOIUrl":"10.1134/S1063783424601504","url":null,"abstract":"<p>In this study, copper sulfate pentahydrate (CuSO<sub>4</sub>·5H<sub>2</sub>O) single crystals, measuring up to 8 × 8 × 2 cm, were successfully grown using the hot plate technique. The synthesized crystals were characterized using several analytical methods, including X-ray diffraction (XRD), UV-visible spectroscopy, Brunauer–Emmett–Teller (BET) surface area analysis, and cyclic voltammetry (CV). XRD analysis confirmed that the crystals possess a triclinic structure. Optical property assessments revealed broad transparency in the visible spectrum, with a band gap (<i>E</i><sub>g</sub>) of 4.02 eV as determined by UV-visible spectroscopy. BET analysis showed a surface area of 1.015 cm<sup>2</sup>/g and a pore volume of 0.0025 cm<sup>3</sup>/g. Additionally, etching experiments were performed over varying durations to preserve the crystal structure and investigate surface behavior. These findings provide valuable insights into both the growth and properties of CuSO<sub>4</sub>·5H<sub>2</sub>O crystals, suggesting their potential applications in various scientific fields.</p>","PeriodicalId":731,"journal":{"name":"Physics of the Solid State","volume":"66 12","pages":"642 - 652"},"PeriodicalIF":0.9,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142976634","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Elastic Properties and Regularities in Frequencies of Optical Phonons of ({{{mathbf{A}}}^{{{mathbf{II}}}}}{mathbf{B}}_{2}^{{{mathbf{III}}}}{mathbf{C}}_{4}^{{{mathbf{VI}}}}) Compounds ({{mathbf{A}}}^{{mathbf{II}}}}}{mathbf{B}}_{2}^{{{mathbf{III}}}}mathbf{C}}_{4}^{{mathbf{VI}}}}) 的弹性特性和光学声子频率的规律性化合物
IF 0.9 4区 物理与天体物理
Physics of the Solid State Pub Date : 2024-11-14 DOI: 10.1134/S1063783424601322
I. A. Mamedova, Z. A. Jahangirli, S. S. Osmanova, N. A. Abdullayev
{"title":"Elastic Properties and Regularities in Frequencies of Optical Phonons of ({{{mathbf{A}}}^{{{mathbf{II}}}}}{mathbf{B}}_{2}^{{{mathbf{III}}}}{mathbf{C}}_{4}^{{{mathbf{VI}}}}) Compounds","authors":"I. A. Mamedova,&nbsp;Z. A. Jahangirli,&nbsp;S. S. Osmanova,&nbsp;N. A. Abdullayev","doi":"10.1134/S1063783424601322","DOIUrl":"10.1134/S1063783424601322","url":null,"abstract":"<p>Elastic constants <i>с</i><sub><i>ij</i></sub> of thiogalates CdGa<sub>2</sub>S<sub>4</sub>, CdGa<sub>2</sub>Se<sub>4</sub>, CdGa<sub>2</sub>Te<sub>4</sub>, and ZnGa<sub>2</sub>Sе<sub>4</sub> are calculated using the density functional theory (DFT). The elastic moduli <i>B</i> have been calculated. The regularities have been found in the dependences of the optical phonon frequencies on the atomic masses in <span>({{{text{A}}}^{{{text{II}}}}}{text{B}}_{2}^{{{text{III}}}}{text{C}}_{4}^{{{text{VI}}}})</span> compounds. The force constants of interatomic bonds in CdGa<sub>2</sub>Te<sub>4</sub> and ZnGa<sub>2</sub>Sе<sub>4</sub> compounds are determined.</p>","PeriodicalId":731,"journal":{"name":"Physics of the Solid State","volume":"66 11","pages":"529 - 536"},"PeriodicalIF":0.9,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142636796","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of Insulator-to-Semiconductor Fast Transition in Sheet-Like Polyaniline Films 片状聚苯胺薄膜中绝缘体到半导体快速转变的研究
IF 0.9 4区 物理与天体物理
Physics of the Solid State Pub Date : 2024-11-14 DOI: 10.1134/S1063783424601334
Ibrahim Morad, Ghada El-Barbary, Said M. El-Sheikh, Y. A. Sharaby
{"title":"Investigation of Insulator-to-Semiconductor Fast Transition in Sheet-Like Polyaniline Films","authors":"Ibrahim Morad,&nbsp;Ghada El-Barbary,&nbsp;Said M. El-Sheikh,&nbsp;Y. A. Sharaby","doi":"10.1134/S1063783424601334","DOIUrl":"10.1134/S1063783424601334","url":null,"abstract":"<p>Ethylenediamine-doped (EDA-doped) polyaniline (PANI) films were deposited via spin coating technique on a glass substrate. The samples were annealed at different times and temperatures. The characterizations of the prepared PANI films were described by X-ray diffraction (XRD), transmission electron microscopy (TEM), and Fourier transform infrared spectroscopy (FT-IR). It is found that the conductivity changes under deep mouth exhaling for 150/1 h sample is 1.65 times faster than the films annealed at 100°C/4 h. The response and recovery time of the 150/1 h EDA-doped PANI film is decreased by order of 0.63 and 1.29 s than those films dried at 100°C for 4 h, respectively. The 150/1 h EDA doped PANI film during deep exhaling its conductivity increased abruptly from 2.2 × 10<sup>–7</sup> to 0.026 S/cm<sup>–1</sup>. In a few seconds, following an inhalation, there occurs a complete transition to the dry state conductivity. Furthermore, the increment in conductivity of the EDA-doped PANI films was determined at various RH levels (20, 40, 60, 80, and 90%) with exposure and evacuation of the humid air. The doped PANI sample annealed at 150°C for 1 h exhibit the highest conductivity at 90% RH. The conductivity was increased from 2.16 × 10<sup>–7</sup> S/cm for the insulating state at the dry state to 0.23 S/cm for the semiconducting state at 90% RH. Consequently, the 150/1 h sample showed an increase in conductivity by order of 10<sup>6</sup> at 90% RH. For all samples, the conductivity progressively rises as the RH value increases till 90% of RH value samples exhibit an abrupt increase in conductivity except the 100°C/4 h sample. The highest conductivity is 0.041 S/cm at 90% RH obtained for the case of 150/30 min sample, whereas the 150/1 min and 100/4 h films show maximum conductivity of 0.027 and 0.007, respectively.</p>","PeriodicalId":731,"journal":{"name":"Physics of the Solid State","volume":"66 11","pages":"505 - 515"},"PeriodicalIF":0.9,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142636966","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermoelectric Power Characteristics of Quaternary Layered Structured Tl4In3GaS8 Crystals 四元层状结构 Tl4In3GaS8 晶体的热电功率特性
IF 0.9 4区 物理与天体物理
Physics of the Solid State Pub Date : 2024-11-14 DOI: 10.1134/S1063783424601231
Khairiah Alshehri
{"title":"Thermoelectric Power Characteristics of Quaternary Layered Structured Tl4In3GaS8 Crystals","authors":"Khairiah Alshehri","doi":"10.1134/S1063783424601231","DOIUrl":"10.1134/S1063783424601231","url":null,"abstract":"<p>A modified Bridgman technique was used to crystallize the Tl<sub>4</sub>In<sub>3</sub>GaS<sub>8</sub> compound. The rate of change in the thermoelectric power (TEP) as a function of temperature of the Tl<sub>4</sub>In<sub>3</sub>GaS<sub>8</sub> compound is measured within the temperature range (218–402 K). Measurements revealed that the conductivity of the crystals was n-type. Investigations were conducted into the connection between TEP, charge carrier concentration, and electrical conductivity. The experimental results were used to calculate a number of physical properties, including as mobilities, diffusion coefficients, diffusion lengths, effective masses, and carrier relaxation periods. The overall behavior of the semiconductor is shown by these features. According to our findings, asgrown Tl<sub>4</sub>In<sub>3</sub>GaS<sub>8</sub> crystals are typically <i>n</i>-type and have the potential to be employed as thermoelectric power generating possibilities.</p>","PeriodicalId":731,"journal":{"name":"Physics of the Solid State","volume":"66 11","pages":"516 - 520"},"PeriodicalIF":0.9,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142636795","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ammonia Gas Sensing Properties of Bismuth Oxide Thick Films and Its Structural, Optical, Morphological Characterization 氧化铋厚膜的氨气传感特性及其结构、光学和形态学表征
IF 0.9 4区 物理与天体物理
Physics of the Solid State Pub Date : 2024-11-14 DOI: 10.1134/S1063783424601243
Mahendra S. Shinde, Abhinay S. Mandawade, Manoj A. More, Swapnil S. Tayade, Laxman N. Bhoy, Ganesh E. Patil
{"title":"Ammonia Gas Sensing Properties of Bismuth Oxide Thick Films and Its Structural, Optical, Morphological Characterization","authors":"Mahendra S. Shinde,&nbsp;Abhinay S. Mandawade,&nbsp;Manoj A. More,&nbsp;Swapnil S. Tayade,&nbsp;Laxman N. Bhoy,&nbsp;Ganesh E. Patil","doi":"10.1134/S1063783424601243","DOIUrl":"10.1134/S1063783424601243","url":null,"abstract":"<p>This paper successfully synthesized Bismuth oxide (Bi<sub>2</sub>O<sub>3</sub>) nanoparticles (NPs) using the sol–gel method as Bismuth nitrate pentahydrate as a precursor. The average crystallite size of the NPs was characterized by X-ray diffraction (XRD) analysis and the size of the NPs found to be 17 nm. For the band gap measurement UV-visible spectra of NPs were recorded and it was found to be 2.7 eV. The surface morphology of Bi<sub>2</sub>O<sub>3</sub> NPs was examined through field emission scanning electron microscopy (FESEM) showing spherical nature-like morphology. The gas sensor was fabricated using as-prepared Bi<sub>2</sub>O<sub>3</sub> NPs by standard screen-printing technique and it was tested for various gases such as NH<sub>3</sub>, NO<sub>2</sub>, ethanol, LPG, and methanol as a function of operating temperature. The effect of operating temperature and gas concentration were investigated in detail to understand Bi<sub>2</sub>O<sub>3</sub> NPs sensor for NH<sub>3</sub> gas and found to be very efficient.</p>","PeriodicalId":731,"journal":{"name":"Physics of the Solid State","volume":"66 11","pages":"537 - 542"},"PeriodicalIF":0.9,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142636962","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magnetic, Optical, and Antibacterial Properties of Ag+ and Ti4+ Doped Cobalt Ferrite Nanocrystals 掺杂 Ag+ 和 Ti4+ 的钴铁氧体纳米晶体的磁学、光学和抗菌特性
IF 0.9 4区 物理与天体物理
Physics of the Solid State Pub Date : 2024-11-14 DOI: 10.1134/S1063783424601255
Krishna Kumar Keshri, Manoj Kumar Rout, Rajdeep Saha, Sunita Keshri
{"title":"Magnetic, Optical, and Antibacterial Properties of Ag+ and Ti4+ Doped Cobalt Ferrite Nanocrystals","authors":"Krishna Kumar Keshri,&nbsp;Manoj Kumar Rout,&nbsp;Rajdeep Saha,&nbsp;Sunita Keshri","doi":"10.1134/S1063783424601255","DOIUrl":"10.1134/S1063783424601255","url":null,"abstract":"<p>In this paper, we explore the magnetic, optical, and antibacterial properties of <span>({text{CoF}}{{{text{e}}}_{2}}{{{text{O}}}_{4}})</span> (CFO), <span>({text{C}}{{{text{o}}}_{{0.98}}}{text{A}}{{{text{g}}}_{{0.02}}}{text{F}}{{{text{e}}}_{2}}{{{text{O}}}_{4}})</span> (CAFO), and <span>({text{C}}{{{text{o}}}_{{0.98}}}{text{T}}{{{text{i}}}_{{0.02}}}{text{F}}{{{text{e}}}_{2}}{{{text{O}}}_{4}})</span> (CTFO) and spinel ferrite nanocrystals. The XRD analysis of these crystals reveals a single-phase cubic structure of <span>(Fdbar {3}m)</span> space group with a crystallite size of 45, 46, and 41 nm, respectively. The room temperature magnetic measurement shows that CTFO has the highest saturation and remanent magnetization, whereas CFO has the highest coercivity and magnetic squareness ratio. Optical properties of these samples have been taken in the range of 300–900 nm. The band gap is calculated using Tauc’s plot, and it decreases with the doping of <span>({text{A}}{{{text{g}}}^{ + }})</span> and <span>({text{T}}{{{text{i}}}^{{4 + }}})</span> ions. Antibacterial studies of these samples have been done by disc diffusion method for Gram-positive and Gram-negative bacteria, <i>Staphylococcus aureus</i> (<i>S</i>. <i>aureus</i>) and <i>Escherichia coli</i> (<i>E. coli</i>), respectively. The compositions have shown better antibacterial response for <i>S</i>. <i>aureus</i> over <i>E. coli</i>. The 200 mg/mL CTFO sample has shown the most effective result against <i>S. aureus</i> bacteria, with 18 mm diameter value of zone of inhibition.</p>","PeriodicalId":731,"journal":{"name":"Physics of the Solid State","volume":"66 11","pages":"521 - 528"},"PeriodicalIF":0.9,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142636965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optical Properties of GaS Nanoparticles Prepared by Laser Ablation 激光烧蚀制备的 GaS 纳米粒子的光学特性
IF 0.9 4区 物理与天体物理
Physics of the Solid State Pub Date : 2024-11-14 DOI: 10.1134/S106378342460153X
V. M. Salmanov, A. G. Guseinov, M. A. Jafarov, R. M. Mammadov, M. M. Dzhakhangirov, T. A. Mamedova, F. Sh. Akhmedova
{"title":"Optical Properties of GaS Nanoparticles Prepared by Laser Ablation","authors":"V. M. Salmanov,&nbsp;A. G. Guseinov,&nbsp;M. A. Jafarov,&nbsp;R. M. Mammadov,&nbsp;M. M. Dzhakhangirov,&nbsp;T. A. Mamedova,&nbsp;F. Sh. Akhmedova","doi":"10.1134/S106378342460153X","DOIUrl":"10.1134/S106378342460153X","url":null,"abstract":"<p>GaS Nanoparticles prepared by laser ablation in a liquid. The nanoparticle structure is studied by XRD, SEM, and EDAX methods. The energy gap width and the character of optical transitions are determined using the optical absorption and photoluminescence spectra.</p>","PeriodicalId":731,"journal":{"name":"Physics of the Solid State","volume":"66 11","pages":"484 - 488"},"PeriodicalIF":0.9,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142636798","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluating the Potential of Ca3SbBr3 Halide Perovskite for Photovoltaics: A Structural, Mechanical, and Optoelectronic Study Using GGA-PBE and HSE06 Functionals 评估 Ca3SbBr3 卤化物包光体在光伏领域的潜力:使用 GGA-PBE 和 HSE06 函数进行的结构、机械和光电研究
IF 0.9 4区 物理与天体物理
Physics of the Solid State Pub Date : 2024-11-14 DOI: 10.1134/S1063783424601486
Krishna Kumar Mishra
{"title":"Evaluating the Potential of Ca3SbBr3 Halide Perovskite for Photovoltaics: A Structural, Mechanical, and Optoelectronic Study Using GGA-PBE and HSE06 Functionals","authors":"Krishna Kumar Mishra","doi":"10.1134/S1063783424601486","DOIUrl":"10.1134/S1063783424601486","url":null,"abstract":"<p>In this study, we delve into the potential of the halide perovskite material Ca<sub>3</sub>SbBr<sub>3</sub> for solar cell applications, using QuantumATK simulation tool. By employing DFT with both GGA-PBE and HSE06 functionals, we thoroughly explored its structural, mechanical, electronic and optical properties. Our study reveals that Ca<sub>3</sub>SbBr<sub>3</sub> adopts a cubic crystal structure. The lattice constant for this structure is measured to be 6.336 Å. Notably, the material exhibits a direct band gap of 1.782 eV with GGA and 2.592 eV with HSE06, underscoring its efficiency in solar energy conversion. Moreover, Ca<sub>3</sub>SbBr<sub>3</sub> shows strong light absorption, with significant peaks at 629, 396 cm<sup>–1</sup> (3.52 eV) and 245, 951 cm<sup>–1</sup> (3.76 eV), and refractive indices of 2.10 (GGA) and 1.825 (HSE06). These results suggest that Ca<sub>3</sub>SbBr<sub>3</sub> holds great promise as a next-generation solar material, thanks to its advantageous electronic and optical properties.</p>","PeriodicalId":731,"journal":{"name":"Physics of the Solid State","volume":"66 11","pages":"464 - 475"},"PeriodicalIF":0.9,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142636799","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and Characterization of WO3 Thin Film by Spray Pyrolysis for Gas Sensing Application 利用喷雾热解技术合成气体传感用 WO3 薄膜并确定其特性
IF 0.9 4区 物理与天体物理
Physics of the Solid State Pub Date : 2024-11-14 DOI: 10.1134/S1063783424601309
Yogesh B. Aher, Gotan H. Jain, Sarika D. Shinde, Abhinay S. Mandawade, Laxmi D. Sonawane, Dnyaneshwari Y. Patil, Huda I. Ahemad, Matthew D. Femi, Manoj A. More, Dnyaneshwar D. Kajale, Ganesh E. Patil
{"title":"Synthesis and Characterization of WO3 Thin Film by Spray Pyrolysis for Gas Sensing Application","authors":"Yogesh B. Aher,&nbsp;Gotan H. Jain,&nbsp;Sarika D. Shinde,&nbsp;Abhinay S. Mandawade,&nbsp;Laxmi D. Sonawane,&nbsp;Dnyaneshwari Y. Patil,&nbsp;Huda I. Ahemad,&nbsp;Matthew D. Femi,&nbsp;Manoj A. More,&nbsp;Dnyaneshwar D. Kajale,&nbsp;Ganesh E. Patil","doi":"10.1134/S1063783424601309","DOIUrl":"10.1134/S1063783424601309","url":null,"abstract":"<p>Nanostructured tungsten oxide (WO<sub>3</sub>) thin-film sensor materials were deposited on a glass substrate by spray pyrolysis technique (SPT) and investigated their gas sensor properties. As prepared WO<sub>3</sub> thin films were characterized by different techniques such as UV-Visible Spectroscopy, X-ray diffraction (XRD), Raman spectroscopy, field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM). The optical band gap of film was determined using the absorption spectra obtained with UV-visible spectroscopy which was found to be 2.9 eV. XRD results of the as prepared WO<sub>3</sub> exhibits crystalline structure and favored alignment along the (002) axis. The spray pyrolysis technique used for the preparation of the WO<sub>3</sub> thin film often results in a porous and rough surface with a network of interconnected fiber-like structures., which are ideal for gas sensor applications due to increased surface exposure. The gas sensing performance of the WO<sub>3</sub> thin film was tested towards various gases such as H<sub>2</sub>S, NH<sub>3</sub>, LPG, H<sub>2</sub>, ethanol, CO<sub>2</sub>, Cl<sub>2</sub> at different operating temperatures. The WO<sub>3</sub> thin films exhibited their highest gas response to H<sub>2</sub>S gas at an operating temperature of 50°C, with fast response and recovery times of 18 and 31 s, respectively. These results suggest that WO<sub>3</sub> thin films could serve as effective H<sub>2</sub>S gas sensors.</p>","PeriodicalId":731,"journal":{"name":"Physics of the Solid State","volume":"66 11","pages":"497 - 504"},"PeriodicalIF":0.9,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142636964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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