Advanced Sustainable Systems最新文献_第5页

MOF-Derived FeCoO/N-Doped C Bifunctional Electrode for H2 Production Through Water and Glucose Electrolysis 通过水和葡萄糖电解产生 H2 的 MOF 衍生 FeCoO/N 掺杂 C 双功能电极

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-09-02 DOI: 10.1002/adsu.202400342

Meysam Tayebi, Zohreh Masoumi, Hyungwoo Lee, Daehyeon Hong, Bongkuk Seo, Choong-Sun Lim, Daeseung Kyung, Hyeon-Gook Kim

{"title":"MOF-Derived FeCoO/N-Doped C Bifunctional Electrode for H2 Production Through Water and Glucose Electrolysis","authors":"Meysam Tayebi, Zohreh Masoumi, Hyungwoo Lee, Daehyeon Hong, Bongkuk Seo, Choong-Sun Lim, Daeseung Kyung, Hyeon-Gook Kim","doi":"10.1002/adsu.202400342","DOIUrl":"10.1002/adsu.202400342","url":null,"abstract":"The glucose oxidation reaction (GOR) is a potential alternative to water oxidation because of its relatively low thermodynamic potential and the high availability of glucose. Herein, a FeCoO/N-doped C electrode derived from metal–organic framework (MOF) materials is applied, which is synthesized in several steps through the controlled deposition of Fe–Co oxide nanocatalysts onto Co –N-doped C nanofibers on a Ni foam substrate and demonstrate exceptional electrocatalytic activity for both the GOR and overall water splitting. Here, a bifunctional electrocatalyst derived from MOF, FeCoO/N-doped C is reported, for glucose oxidation reaction (GOR) and hydrogen evolution reaction (HER). The MOF-derived FeCoO/N-doped C (+/-) as a bifunctional electrocatalyst exhibits a cell voltage of 1.4 V for the GOR&HER, to reach a current density of 10 mA cm−2, which is 280 mV lower than that for the oxygen evolution reaction (OER)&HER (1.68 V). This study reveals that GOR is an energy-efficient and affordable source of H2 and value-added chemicals.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"8 11","pages":""},"PeriodicalIF":6.5,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202400342","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Life Cycle Assessment of Industrial Wastewater Treatment Trains 工业废水处理列车的生命周期评估

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-09-01 DOI: 10.1002/adsu.202400246

Dana Tran, Jennifer Weidhaas

{"title":"Life Cycle Assessment of Industrial Wastewater Treatment Trains","authors":"Dana Tran, Jennifer Weidhaas","doi":"10.1002/adsu.202400246","DOIUrl":"10.1002/adsu.202400246","url":null,"abstract":"Alternative technologies to granular activated carbon (GAC) are of interest to improve the sustainability and reduce the cost of munitions wastewater treatment. Research efforts have highlighted GAC alternatives, yet few reports of environmental and economic impacts associated with these technologies are available. Herein, a life cycle assessment (LCA) aids in assessment of environmental impacts associated with six munitions wastewater treatment configurations—specifically GAC, compared to five configurations that include combinations of ion exchange (IX), reverse osmosis (RO), aerobic granular reactors (AGR), UV/H2O2, and ozone technologies. The LCA compares environmental impacts generated by treating 1 m3 of munitions wastewater, impacts by life cycle stage, and effects of IX, RO, and GAC replacement frequency. Results show that IX resin pairs with AGR (for flow-through treatment) and ozone (for IX regenerant treatment) generated 22 ± 18% less impact than GAC in nine of ten environmental impact categories during production, transportation, and disposal. Treatment trains with ozone or AGR produce 35% less environmental impact than those with UV/H2O2. Production and use stages generate more environmental impacts than transportation and disposal stages for most treatment technologies. This LCA provides insights into the sustainability of six munition wastewater treatment technologies and identifies areas where treatment sustainability can be improved.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"8 12","pages":""},"PeriodicalIF":6.5,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202400246","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191550","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Masthead: (Adv. Sustainable Syst. 8/2024) 刊头：（Adv. Sustainable Syst.）

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-08-28 DOI: 10.1002/adsu.202470030

引用次数: 0

Systematic Exploration of the Benefits of Ni Substitution in Na–Fe–Mn–O Cathodes (Adv. Sustainable Syst. 8/2024) 系统探索 Na-Fe-Mn-O 阴极中镍替代的益处（Adv. Sustainable Syst.）

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-08-28 DOI: 10.1002/adsu.202470029

Marzieh Abdolhosseini, Shipeng Jia, Michael Sieffert, Maddison Eisnor, Shinichi Kumakura, Eric McCalla

引用次数: 0

Toward Sustainable Electroluminescent Devices for Lighting and Sensing (Adv. Sustainable Syst. 8/2024) 实现用于照明和传感的可持续电致发光器件（Adv. Sustainable Syst.）

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-08-28 DOI: 10.1002/adsu.202470028

Rita Polícia, Nikola Peřinka, Cristian Mendes-Felipe, Pedro Martins, Daniela Maria Correia, Senentxu Lanceros-Méndez

引用次数: 0

Upcycling Waste Biomass–Production of Porous Carbonaceous Supports from Paper Mill Sludge and Application to CO2 Conversion (Adv. Sustainable Syst. 8/2024) 废弃生物质的升级再利用--利用造纸厂污泥生产多孔碳质支撑物并应用于二氧化碳转化（Adv. Sustainable Syst.）

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-08-28 DOI: 10.1002/adsu.202470031

Mónica Stanton Ribeiro, Maria M. R. A. Lima, Márcia Vilarigues, Marcileia Zanatta, Marta C. Corvo

引用次数: 0

Enhanced Photocatalytic Activity of Direct Z-Scheme K4Nb6O17/Carbon-Rich Melon Heterostructures 增强直接 Z 型 K4Nb6O17/富碳甜瓜异质结构的光催化活性

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-08-27 DOI: 10.1002/adsu.202400352

Celal Avcıoğlu, Aleksander Gurlo, Maged F. Bekheet

{"title":"Enhanced Photocatalytic Activity of Direct Z-Scheme K4Nb6O17/Carbon-Rich Melon Heterostructures","authors":"Celal Avcıoğlu, Aleksander Gurlo, Maged F. Bekheet","doi":"10.1002/adsu.202400352","DOIUrl":"10.1002/adsu.202400352","url":null,"abstract":"Melon (also known as graphitic carbon nitride, g-C3N4) holds promise for photocatalysis, but challenges such as severe charge recombination, low oxidation potential, and sluggish exciton dissociation hinder its performance. Herein, a series of carbon-rich, melon-based photocatalysts are synthesized via one-pot, temperature-induced condensation of urea with the addition of a trace amount of citric acid. The addition of citric acid enhances crystallinity, extends melon chains, increases the C/N ratio, and improves π–π layer stacking of heptazine units, thereby enhancing charge transport properties and visible-light harvesting capacity. These carbon nitride samples are then coupled with molten salt synthesized K4Nb6O17 crystals by a straightforward self-assembly method to construct 2D/2D heterostructure photocatalysts. Z-scheme electron transfer from K4Nb6O17 to the melon samples is established based on their work functions and band edge positions. This efficient charge transfer in the Z-scheme heterostructure facilitates the spatial separation of charge carriers, resulting in a nearly fivefold enhancement in photocatalytic performance compared to the individual constituents.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"8 12","pages":""},"PeriodicalIF":6.5,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202400352","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191553","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhanced CO₂ Detection Using Potentiometric Sensors Based on PIM-1/DBU Imidazolate Membranes 利用基于 PIM-1/DBU 亚咪唑酸盐膜的电位传感器增强 CO₂ 检测能力

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-08-27 DOI: 10.1002/adsu.202400415

Davide Molino, Giuseppe Ferraro, Stefania Lettieri, Pietro Zaccagnini, Marco Etzi, Carmela Astorino, Eugenio De Nardo, Mattia Bartoli, Andrea Lamberti, Candido Fabrizio Pirri, Sergio Bocchini

{"title":"Enhanced CO₂ Detection Using Potentiometric Sensors Based on PIM-1/DBU Imidazolate Membranes","authors":"Davide Molino, Giuseppe Ferraro, Stefania Lettieri, Pietro Zaccagnini, Marco Etzi, Carmela Astorino, Eugenio De Nardo, Mattia Bartoli, Andrea Lamberti, Candido Fabrizio Pirri, Sergio Bocchini","doi":"10.1002/adsu.202400415","DOIUrl":"10.1002/adsu.202400415","url":null,"abstract":"A novel potentiometric sensor for carbon dioxide (CO2) detection utilizing a composite membrane of Polymer of Intrinsic Microporosity (PIM-1) and 18-diazabicyclo[5.4.0]undec-7-ene imidazolate (DBU-imidazolate) is presented. The high surface area and gas permeability of PIM-1, combined with the chemical affinity and ion-exchange properties of DBU-imidazolate, contribute to enhanced CO2 sensitivity and selectivity. The research objectives included the synthesis of PIM-1 and DBU-imidazolate, the preparation of composite membranes, and the evaluation of their performance as CO2 sensors. Solvent casting and impregnation methods are employed to prepare the membranes, which are characterized using Thermal Gravimetric Analysis (TGA), and Field Emission Scanning Electron Microscopy (FESEM). CO₂ absorption tests and Electrochemical Impedance Spectroscopy (EIS) are conducted to assess the sensors' performance. The PIM-1/DBU-imidazolate membrane exhibited high efficiency in CO₂ capture and release. Open circuit voltage (OCV) measurements are performed under varying concentrations of CO2 exposure and cycles of adsorption/desorption. Results show that the membrane achieves steady state faster at higher CO2 concentrations, with a logarithmic relationship between CO2 concentration and voltage variation, indicating potential for CO2 detection in human environments. These results confirm the sensor's ability to detect varying CO2 concentrations, highlighting its potential for reliable and efficient CO2 monitoring in environmental and industrial applications.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"8 12","pages":""},"PeriodicalIF":6.5,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202400415","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191552","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Selective and Efficient Electrocatalytic Synthesis of Ammonia from Nitrate with Copper-Based Catalysts 铜基催化剂从硝酸盐选择性高效电催化合成氨

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-08-25 DOI: 10.1002/adsu.202400507

Shiyue Yin, Zhixi Guan, Yuchuan Zhu, Daying Guo, Xi'an Chen, Shun Wang

{"title":"Selective and Efficient Electrocatalytic Synthesis of Ammonia from Nitrate with Copper-Based Catalysts","authors":"Shiyue Yin, Zhixi Guan, Yuchuan Zhu, Daying Guo, Xi'an Chen, Shun Wang","doi":"10.1002/adsu.202400507","DOIUrl":"10.1002/adsu.202400507","url":null,"abstract":"The high stability and persistence of nitrates in water poses a serious threat to human health and ecosystems. To effectively reduce the nitrate content in wastewater, the electrochemical nitrate reduction reaction (e-NO3RR) is widely recognized as an ideal treatment method due to its high reliability and efficiency. The selection of catalyst material plays a decisive role in e-NO3RR performance. Copper-based catalysts, with their ease of acquisition, high activity, and selectivity for NH3, have emerged as the most promising candidates for e-NO3RR applications. In this paper, the mechanism of e-NO3RR is first introduced. Then the relationship between structural properties and catalytic performance of copper-based catalysts is analyzed in detail from four aspects: nanomaterials, oxides, monoatomic, and bimetallic materials. Strategies for constructing efficient catalysts are discussed, including surface modulation, defect engineering, heteroatom doping, and coordination effects. Finally, the challenges and prospects of copper-based catalysts with high e-NO3RR performance in practical applications are outlined.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"8 12","pages":""},"PeriodicalIF":6.5,"publicationDate":"2024-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Boron and Nitrogen Co-Doped Porous Carbon with Ultrahigh Volumetric Performance for Zinc-Ion Hybrid Supercapacitors 用于锌-离子混合超级电容器的具有超高容积性能的硼氮共掺杂多孔碳

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-08-23 DOI: 10.1002/adsu.202400467

Tingting Song, Jiayi Chen, Weijian Chen, Xinyang Zhang, Xiaoliang Wu, Xin Wang

{"title":"Boron and Nitrogen Co-Doped Porous Carbon with Ultrahigh Volumetric Performance for Zinc-Ion Hybrid Supercapacitors","authors":"Tingting Song, Jiayi Chen, Weijian Chen, Xinyang Zhang, Xiaoliang Wu, Xin Wang","doi":"10.1002/adsu.202400467","DOIUrl":"10.1002/adsu.202400467","url":null,"abstract":"It is a huge challenge for carbon materials to obtain high volumetric capacitance without sacrificing gravimetric capacitance for supercapacitors with limited space. Herein, B/N/O co-doped porous carbon materials are prepared by one-step carbonization method using boric acid as the template and boron source, polyacrylamide as the carbon and nitrogen sources. Boric acid and polyacrylamide can be closely combined by hydrogen bond, so as to not only give full play to the role of boric acid template, but also to achieve high content of nitrogen and boron functional groups. Benefiting from the high bulk density (1.51 g cm−3), suitable specific surface area (243.2 m2 g−1) and numerous B (7.55 at.%), N (14.38 at.%), O (8.89 at.%) functional groups, the prepared BNPC-700 electrode shows an ultrahigh volumetric specific capacitance of 545.6 F cm−3 at 0.5 A g−1, excellent rate characteristic and superior electrochemical performance. Furthermore, the assembled BNPC-700 symmetric supercapacitor achieves a high volumetric energy density of 31.1 Wh L−1 (20.6 Wh kg−1) in ZnSO4 aqueous electrolyte. More importantly, the assembled Zn//ZnSO4//BNPC-700 hybrid supercapacitor delivers a high volumetric capacity of 210.8 mAh cm−3 and a high volumetric energy density of 147.7 Wh L−1(97.8 Wh kg−1).","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"8 12","pages":""},"PeriodicalIF":6.5,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0