Advanced Sustainable Systems最新文献_第4页

Energy Self-Sufficient Direct Membrane Filtration of Municipal Wastewater: Impact of Biological Pre-Treatment 能源自给式城市污水直接膜过滤：生物预处理的影响

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-05-05 DOI: 10.1002/adsu.202500088

Akash Saha, Ligy Philip

{"title":"Energy Self-Sufficient Direct Membrane Filtration of Municipal Wastewater: Impact of Biological Pre-Treatment","authors":"Akash Saha, Ligy Philip","doi":"10.1002/adsu.202500088","DOIUrl":"https://doi.org/10.1002/adsu.202500088","url":null,"abstract":"Municipal wastewater treatment philosophy shall shift from the conventional energy- and chemical-intensive approach to a more circular, energy self-sufficient system aligned with Sustainable Development Goals (SDGs) 7, 9, 11, and 13. Direct membrane filtration (DMF) using ultrafiltration provides a low-energy alternative for recovering organics, which are utilized for energy recovery through anaerobic digestion (AD). However, DMF faces challenges from membrane fouling and elevated dissolved organics in the permeate. To address these issues, this study implements biological contact tank pre-treatment before DMF, with a short hydraulic retention time (HRT) of 60 min. This pre-treatment selectively removes 62% of dissolved organics without compromising the recovery of suspended or colloidal organic matter and enhances permeate quality by 40% in terms of chemical oxygen demand (COD). The DMF system without pre-treatment exhibits 1.84 times higher irreversible pore-blocking membrane resistance, with higher foulant concentrations per membrane unit area (up to 2.54 times) and enzymatic activity (up to 3.04 times). The recovered organics undergo AD, yielding methane up to 336 ± 23 mL-CH4/g-VS, making the DMF system net energy positive. Life cycle assessment (LCA) reveals that the DMF system has lesser environmental impacts than the conventional system in 10 out of 18 impact categories.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 8","pages":""},"PeriodicalIF":6.1,"publicationDate":"2025-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144909907","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Surface Reconstruction in Precious and Non-Precious Metal-Based Electrocatalysts for Oxygen Evolution Reaction: A pH-Dependent Perspective 基于贵金属和非贵金属的析氧电催化剂的表面重构：一个ph依赖的观点

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-05-04 DOI: 10.1002/adsu.202500047

Jie Huang, Zhiyin Huang, Junda Chen, Ruiming Zhang, Manrou Huang, Yuxin Liu, Lixin Xing, Siyu Ye, Lei Du

{"title":"Surface Reconstruction in Precious and Non-Precious Metal-Based Electrocatalysts for Oxygen Evolution Reaction: A pH-Dependent Perspective","authors":"Jie Huang, Zhiyin Huang, Junda Chen, Ruiming Zhang, Manrou Huang, Yuxin Liu, Lixin Xing, Siyu Ye, Lei Du","doi":"10.1002/adsu.202500047","DOIUrl":"https://doi.org/10.1002/adsu.202500047","url":null,"abstract":"Extracting hydrogen by electrochemical water splitting is the most important pathway for green hydrogen production at present whereas the corresponding anodic oxygen evolution reaction (OER) catalysts usually suffer from harsh high-potential conditions, either acidic or alkaline, leading to performance degradation and surface reconstruction. Importantly, the surface reconstruction upon some catalysts may lead to a misinterpretation of the true active centers, thereby impeding the rational design of catalysts. Consequently, understanding the dynamic evolution of catalyst surface reconstruction during OER is essential. This paper reviews the recent research progress on the surface reconstruction of both precious-metal and non-precious-metal catalysts across wide pH, i.e., under acidic and alkaline conditions, and highlights the differences between them. In addition, an analysis of the underlying causes for catalyst surface reconstruction and the impact factors that greatly influence these processes are presented. Finally, based on these discussions, perspectives for the rational design of OER catalysts are proposed.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 6","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144367375","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent Advances in Graphene-Based Metal Oxide Composites for Supercapacitors: A Comprehensive Review 超级电容器用石墨烯基金属氧化物复合材料的研究进展

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-05-03 DOI: 10.1002/adsu.202500121

Basappa C. Yallur, Madhuri P. Rao, M. Harshitha, Deepa Basrur, Prabhu H. Umesh, Vinuta Kamat, K. D. Venu Prasad, Katharigatta N. Venugopala, Ramesh S. Bhat

{"title":"Recent Advances in Graphene-Based Metal Oxide Composites for Supercapacitors: A Comprehensive Review","authors":"Basappa C. Yallur, Madhuri P. Rao, M. Harshitha, Deepa Basrur, Prabhu H. Umesh, Vinuta Kamat, K. D. Venu Prasad, Katharigatta N. Venugopala, Ramesh S. Bhat","doi":"10.1002/adsu.202500121","DOIUrl":"https://doi.org/10.1002/adsu.202500121","url":null,"abstract":"Graphene-based metal oxide mixtures have emerged as a promising material suitable for high-performance supercapacitors because of their unique combination of high electrical conductivity, large surface area, and excellent electrochemical stability. Integrating metal oxides, such as Manganise dioxide (MnO2), Cobalt oxide (Co3O4) Nickel oxide (NiO), Ruthenium oxide (RuO2) etc., with graphene enhances supercapacitor electrodes, specific capacitance, energy density, and cycling stability. This review examines the latest progress in the synthesis, characterization, and performance optimization of graphene-based metal oxide composites. Various strategies for enhancing electrochemical properties, like as controlling the morphology, adjusting the metal oxide loading, and optimizing the hybridization methods, are discussed. Furthermore, graphene's role in enhancing electron conduction, increasing the stability of metal oxides, and expanding the surface area for charge storage is highlighted. The challenges in scaling up these materials are also addressed and provide insights into future directions to enhance the performance of graphene-based metal oxide supercapacitors, with an emphasis on energy density, power density, and long-term cycling stability. This review offers a comprehensive overview of the state-of-the-art research on graphene-metal oxide composites, with the goal of steering the advancement of next-generation energy storage devices.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 8","pages":""},"PeriodicalIF":6.1,"publicationDate":"2025-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144910068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Nanocrystalline Cellulose from the Solitary Tunicate Phallusia Mammillata, a Valuable Nanocellulose Precursor 一种有价值的纳米纤维素前体——单生被膜虫的纳米晶纤维素

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-05-02 DOI: 10.1002/adsu.202500139

Andrea Riccioni, Alessia Famengo, Naida El Habra, Loriano Ballarin, Lucia Manni, Annj Zamuner, Elisabetta Schievano

{"title":"Nanocrystalline Cellulose from the Solitary Tunicate Phallusia Mammillata, a Valuable Nanocellulose Precursor","authors":"Andrea Riccioni, Alessia Famengo, Naida El Habra, Loriano Ballarin, Lucia Manni, Annj Zamuner, Elisabetta Schievano","doi":"10.1002/adsu.202500139","DOIUrl":"https://doi.org/10.1002/adsu.202500139","url":null,"abstract":"Ascidians are ubiquitous filter-feeding marine invertebrates, the only animals producing cellulose in their outer tunic, in the form of a composite structure of cellulose microfibrils linked to a protein matrix. This study reports the successful processing of Phallusia mammillata, a species prevalent in the Northern Adriatic Sea, into high-quality nanocellulose (NC). An optimized extraction method followed by chemical modification is applied to produce suitable precursors for cellulose-based products. Structural, compositional, and thermal characterization demonstrated the high degree of crystallinity of the extracted cellulose, which is further processed into both cationic and anionic forms by direct reaction of nanofibril suspensions. High-aspect-ratio nanofibrillated cellulose (NFC) with a fibrils diameter of 10 ± 2 nm is directly obtained from purified tunics. Anionic nanocrystals and cationic nanofibrils with a mean diameter of 8 ± 2 nm are obtained from pristine nanofibrillated cellulose suspensions. To the best of the authors’ knowledge, this is the first report on the extraction and processing of cellulose from Phallusia mammillata, opening new possibilities toward high-grade cellulose-based materials exploiting an abundant local resource.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 8","pages":""},"PeriodicalIF":6.1,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202500139","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144909953","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

An Electrospun Polystyrene Fibrous Membrane with a Mechanically Reduced Pore Size Exhibits Efficient Gravity-Driven Separation of a Water-in-Oil Emulsion 一种具有机械减小孔径的静电纺丝聚苯乙烯纤维膜，在重力驱动下可有效分离油包水乳液

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-05-02 DOI: 10.1002/adsu.202500040

Hyeonsu Woo, Seungbin Yoon, Young June Park, Suhyeon Kim, Seong Kyong Hong, Kanghyun Kim, Geon Hwee Kim, Geunbae Lim

{"title":"An Electrospun Polystyrene Fibrous Membrane with a Mechanically Reduced Pore Size Exhibits Efficient Gravity-Driven Separation of a Water-in-Oil Emulsion","authors":"Hyeonsu Woo, Seungbin Yoon, Young June Park, Suhyeon Kim, Seong Kyong Hong, Kanghyun Kim, Geon Hwee Kim, Geunbae Lim","doi":"10.1002/adsu.202500040","DOIUrl":"https://doi.org/10.1002/adsu.202500040","url":null,"abstract":"Electrospun fibrous membranes are widely used for water-oil separation. However, achieving effective separation often requires post-processing to enhance membrane wettability or modify pore size, which can reduce productivity. In this study, a simple method is proposed for pore size control via mechanical compression of electrospun membranes. Polystyrene (PS) fibrous membranes (PFMs) are fabricated through electrospinning and subsequently compressed using a hand tool, reducing the membrane thickness by ≈87%. The proportion of pores smaller than 10 µm in diameter increase from 4.8% before compression to a maximum of 45.6% after compression. While the uncompressed membrane allowes sub-10-µm water droplets to pass through, the compressed membrane effectively blocked them. Due to the oleophilic nature of PS, oil permeation occurres rapidly via capillary action, while water droplets are retained within the membrane's internal pores, facilitating continuous demulsification. By combining electrospinning with mechanical compression, the optimized compressed PS fibrous membrane (CPFM) successfully separated water-in-oil emulsions under gravity, achieving a separation flux of 606 L m−2h−1 with an oil purity of over 99.85%. This approach provides a simple, cost-effective, and highly efficient method for water-in-oil emulsion separation.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 8","pages":""},"PeriodicalIF":6.1,"publicationDate":"2025-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144909956","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ni Foam Supported Pd-Doped Zinc Spinel Oxide Nano-Electrocatalyst for Efficient Hydrogen Production Supported by DFT Study as Well Validated With Experimental Data 泡沫镍负载pd掺杂锌尖晶石氧化物纳米电催化剂的DFT负载高效制氢研究得到了实验数据的验证

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-04-30 DOI: 10.1002/adsu.202500142

Refah S. Alkhaldi, Mubarak A. Abdulwahab, Mohammed A. Gondal, Mohamed Jaffer Sadiq Mohamed, Munirah A. Almessiere, Abdulhadi Baykal, Abduljabar Alsayoud

{"title":"Ni Foam Supported Pd-Doped Zinc Spinel Oxide Nano-Electrocatalyst for Efficient Hydrogen Production Supported by DFT Study as Well Validated With Experimental Data","authors":"Refah S. Alkhaldi, Mubarak A. Abdulwahab, Mohammed A. Gondal, Mohamed Jaffer Sadiq Mohamed, Munirah A. Almessiere, Abdulhadi Baykal, Abduljabar Alsayoud","doi":"10.1002/adsu.202500142","DOIUrl":"https://doi.org/10.1002/adsu.202500142","url":null,"abstract":"An innovative palladium-doped zinc cobalt oxide nanoelectrocatalyst, ZnPdxCo2-xO4 (0.00 ≤ x ≤ 0.08)@NF, is successfully synthesized using a hydrothermal method. The resulting material exhibits a spinel oxide phase, as confirmed by X-ray diffraction (XRD). The electrocatalytic performance of ZnPdxCo2-xO4 (0.00 ≤ x ≤ 0.08)@NF is evaluated for the hydrogen evolution reaction (HER). The results show significant improvements in efficient hydrogen production, with an overpotential of 31 mV, a Tafel slope of 54.36 mV dec⁻1, and sustained stability for over 72 h, using chronopotentiometry methods. Doping with 8.0% Pd concentration enhances the highest electrochemical performance of the nanoelectrocatalyst, supporting the idea that Pd doping improves HER activity. The results suggest that the increased electrochemical active surface area (ECSA) and faster charge transfer kinetics at the interface between the semiconductor and electrolyte contribute to enhanced performance. The DFT calculations performed in this work confirm the role of Pd in improving the catalytic activity of the ZnCo2O4 spinel catalyst. Overall, this study has made a significant contribution to the development of sustainable energy solutions, offering a promising path toward the efficient production of hydrogen fuel.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 6","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144367334","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Tailoring the Solvation Structure through Water Soluble Tartaric Acid Additive for Stable Zn Anode 通过水溶性酒石酸添加剂调整锌阳极的溶剂化结构

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-04-27 DOI: 10.1002/adsu.202500171

Longqi Wang, Miao Wang, Yiran Liu, Mengdie Han, Qianyu Xuan, Junru Ma, Jiazheng Li, Shiyan Zhao, Yuqian Fan, Wenfeng Guo, Yufeng Zhao

{"title":"Tailoring the Solvation Structure through Water Soluble Tartaric Acid Additive for Stable Zn Anode","authors":"Longqi Wang, Miao Wang, Yiran Liu, Mengdie Han, Qianyu Xuan, Junru Ma, Jiazheng Li, Shiyan Zhao, Yuqian Fan, Wenfeng Guo, Yufeng Zhao","doi":"10.1002/adsu.202500171","DOIUrl":"https://doi.org/10.1002/adsu.202500171","url":null,"abstract":"Aqueous zinc-ion batteries (AZIBs) with inherent safety, cost-effectiveness and environmental compatibility have garnered significant attention for large-scale energy storage. However, AZIBs still suffer from the hydrogen evolution reaction, Zn dendrite and Zn corrosion, which are closely correlated with Zn2+ solvation structure. Therefore, designing an optimized Zn2+ solvation structure with reduced water molecules in the solvation shell is expected to achieve stable and reversible Zn2+ plating/stripping. In this study, water-soluble Tartaric Acid containing abundant ─COOH groups as electrolyte additive for AZIBs is employed. The dissociated ─COOH can replace water molecules around Zn2⁺, leading to a restructured solvation shell, which not only inhibits side reactions, but also enhances the kinetics of de-solvation process, promoting the formation of a flat and dense zinc deposition layer. The as-prepared Zn electrode exhibits an impressive areal capacity of 28.21 mAh cm−2 after resting 6 h and excellent long-term stability (800 cycles with capacity retention of 81.76%). In addition, in situ microscope and in situ electrochemical impedance spectroscopy (EIS) synergistically identify the outstanding structural stability and enhanced kinetics, respectively. This work sheds light on constructing a highly reversible Zn anode in the seawater-based electrolyte for AZIBs.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 8","pages":""},"PeriodicalIF":6.1,"publicationDate":"2025-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144910141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Rigid Macroporous Wood Microparticles Impart Universality and Scalability to Lightweight Foam Insulation 刚性大孔木材微粒赋予轻量化泡沫保温材料的通用性和可扩展性

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-04-21 DOI: 10.1002/adsu.202400986

Elizabeth Dobrzanski, Jonas Schnell, Weijia Zhang, Elisa S. Ferreira, Janne Keränen, Prashant Agrawal, Yufeng Yuan, Richard Chen, Praphulla Tiwary, Emily D. Cranston

{"title":"Rigid Macroporous Wood Microparticles Impart Universality and Scalability to Lightweight Foam Insulation","authors":"Elizabeth Dobrzanski, Jonas Schnell, Weijia Zhang, Elisa S. Ferreira, Janne Keränen, Prashant Agrawal, Yufeng Yuan, Richard Chen, Praphulla Tiwary, Emily D. Cranston","doi":"10.1002/adsu.202400986","DOIUrl":"https://doi.org/10.1002/adsu.202400986","url":null,"abstract":"Foam-formed nonwoven materials have recently experienced a surge in popularity, but research focuses on flexible fibres with scant information on rigid particles. This work showcases how rigid, minimally-processed, macroporous wood microparticles work synergistically with the foam-forming method to offer a robust manufacturing strategy that is insensitive to feedstock and water quality. Lightweight oven-dried foams suitable for rigid thermal insulation are produced using four types of wood residue and can be made using ocean water instead of ultrapure water. The bio-based content in the foam can be increased by partially/fully replacing the polymer binder with mechanical pulp or using a biosurfactant. For the 15 foams produced with slightly modulated compositions, the densities are low (90–130 kg m−3), the thermal conductivities are low (38–45 mW m−1 K−1), and many meet ASTM insulation standards for compressive strength. Pilot plant scaling produced large-scale (100×50×4 cm) foam boards. The structure-property relationships elucidated offer new guidelines to optimize foam performance by matching microparticle size to bubble size, having a distribution of microparticle lengths, and preserving wood's natural macroporous character. This work demonstrates how to harness the functionality that nature has already engineered for plants in the design of novel, sustainable and advanced bioproducts.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 6","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202400986","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144367549","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Tailored Brønsted Acidic Sites Anchored Over Covalent Organic Framework and Its Potential in Acid-Catalyzed Reactions 共价有机骨架上固定的Brønsted酸性位点及其在酸催化反应中的潜力

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-04-21 DOI: 10.1002/adsu.202500069

Sudip Bhattacharjee, Santu Ruidas, Bhabani Malakar, Sumanta Mondal, Sasanka Dalapati, Asim Bhaumik

{"title":"Tailored Brønsted Acidic Sites Anchored Over Covalent Organic Framework and Its Potential in Acid-Catalyzed Reactions","authors":"Sudip Bhattacharjee, Santu Ruidas, Bhabani Malakar, Sumanta Mondal, Sasanka Dalapati, Asim Bhaumik","doi":"10.1002/adsu.202500069","DOIUrl":"https://doi.org/10.1002/adsu.202500069","url":null,"abstract":"For green chemical synthesis, designing a metal-free heterogeneous organocatalyst is very challenging as it offers an environment-friendly route over conventional metal-based catalysts. Covalent organic frameworks (COFs) have huge potential to be explored as heterogeneous organocatalysts because they contain several important features in one system, viz. high specific surface area, metal-free, desired organic functionalization, and outstanding stability. Herein, a ─SO3H group anchored COF is synthesized, TFR-PDS-COF by employing a Schiff base extended condensation reaction. The material is highly crystalline in nature, exhibiting moderate BET surface area (115 m2 g−1) and very high NH3 uptake capacity (1045 µmol g−1). The high chemisorption property toward NH3 suggests the highly acidic nature of the material, which motivate to explore it in the acid-catalyzed reaction. Initially, the amination of epoxide, which is a classic example of an acid-catalyzed epoxide activation reaction is chosen. TFR-PDS-COF exhibit good catalytic activity toward the amination of epoxides to β-amino alcohol synthesis for both simple and complex systems at room temperature under solvent-free conditions. The catalyst exhibits high recyclability for several cycles with the retention of its framework. The catalyst has been employed for other acid catalytic reactions such as cycloaddition and acetalization reactions, and displays excellent conversion with high selectivity. All of these results suggest that TFR-PDS-COF is a potential candidate for large-scale and highly sustainable acid-catalytic reactions.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 6","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144367547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Chitosan, Gelatine, and Cellulose Based Hydrogels for the Removal of Potentially Toxic Elements from Aquaculture Water: A Comparative Study 壳聚糖、明胶和纤维素基水凝胶去除水产养殖水中潜在有毒元素的比较研究

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-04-18 DOI: 10.1002/adsu.202400933

Monica Rigoletto, Rossella Sesia, Silvia Berto, Paola Calza, Marco Sangermano, Enzo Laurenti, Mery Malandrino

{"title":"Chitosan, Gelatine, and Cellulose Based Hydrogels for the Removal of Potentially Toxic Elements from Aquaculture Water: A Comparative Study","authors":"Monica Rigoletto, Rossella Sesia, Silvia Berto, Paola Calza, Marco Sangermano, Enzo Laurenti, Mery Malandrino","doi":"10.1002/adsu.202400933","DOIUrl":"https://doi.org/10.1002/adsu.202400933","url":null,"abstract":"Since aquaculture is playing an increasingly important role in food supply, ensuring the healthiness of aquatic environments is a fundamental issue. Anthropogenic activities are often a source of contamination for water and, among the pollutants released, potentially toxic elements (PTEs) represent a well-known hazard to human health and ecosystem safety. In this study, carboxymethylcellulose-alginate (HY-ACMC), methacrylated-chitosan (HY-MCHI), and methacrylated-gelatine (HY-MGEL) hydrogels are synthesized, characterized, and tested as sorbents for PTEs removal. The removal efficiency is significantly affected by pH and contaminants’ concentration. Furthermore, experiments in real aquaculture samples from Italy and Denmark farms are carried out to evaluate the matrix effect. Finally, hydrogel regeneration is optimized and sorbent efficiency for multiple cycles of water remediation treatment is investigated. All tested materials show promising removal capabilities even in real water. HY-ACMC has proven to be the most effective for single-cycle remediation treatments thanks to its high performance in all the studied conditions, although it is unstable to regeneration. On the other hand, regeneration with Na2EDTA improves HY-MCHI efficiency, granting its prolonged employment over time. Considering both performances in real water samples and reusability results, HY-MGEL seems to be the most reliable material for multiple cycles of water remediation treatments.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 8","pages":""},"PeriodicalIF":6.1,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202400933","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144910025","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0