Advanced Sustainable Systems最新文献_第3页

Anode Prelithiation for Lithium-Ion Batteries: A Brief Review of Technologies Enabling Practical Industrial Applications and Large-Scale Fabrication 锂离子电池的阳极预锂化：实现实际工业应用和大规模制造的技术综述

IF 5.6 3区材料科学

Advanced Sustainable Systems Pub Date : 2026-09-09 DOI: 10.1002/adsu.70641

Lixin Jiao, Wanyao Li, Qiujiang Dong, Chengwei Liu, Zeyu He, Zhaoyong Sun, Xiaopeng Han, Wenbin Hu

{"title":"Anode Prelithiation for Lithium-Ion Batteries: A Brief Review of Technologies Enabling Practical Industrial Applications and Large-Scale Fabrication","authors":"Lixin Jiao, Wanyao Li, Qiujiang Dong, Chengwei Liu, Zeyu He, Zhaoyong Sun, Xiaopeng Han, Wenbin Hu","doi":"10.1002/adsu.70641","DOIUrl":"https://doi.org/10.1002/adsu.70641","url":null,"abstract":"<div>\u0000 \u0000 <p>Prelithiation is a key strategy for developing high‑performance lithium‑ion batteries (LIBs) with high energy density and long cycle life. It compensates for the lithium loss caused by solid electrolyte interphase (SEI) formation and improves the initial Coulombic efficiency (ICE). Anode prelithiation, which offers high reversible capacity and industrial applicability, is particularly promising compared with cathode or electrolyte prelithiation. However, a systematic comparison and practical guidance for selecting anode prelithiation routes in manufacturing are still lacking. This review focuses on industrially scalable anode prelithiation technologies, systematically categorizing their reaction mechanisms, implementation processes, and technical advantages. Special attention is paid to contact prelithiation routes using stabilized lithium metal powder (SLMP), microporous ultrathin lithium foil, and other routes, with comparisons in terms of precision, uniformity, and mass‑production compatibility. Additionally, this review analyzes the interfacial regulation mechanisms of different prelithiation strategies on graphite and silicon‑based anodes and discusses how prelithiation amount and lithium source structure influence electrode morphology, SEI composition, rate capability, and long‑term cycling stability. Based on these discussions, future directions for industrial‑grade anode prelithiation are proposed to guide the selection of optimal routes. It provides a rational foundation for guiding practical anode prelithiation techniques and accelerating the commercialization of next‑generation high performance LIBs.</p>\u0000 </div>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"10 9","pages":""},"PeriodicalIF":5.6,"publicationDate":"2026-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148942908","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Oxygen-Vacancy-Mediated Evolution from MoO3/CdMoO4 Type-II to MoO3-x/Ov−CdMoO4 S-Scheme Heterojunctions for Enhanced Photocatalytic H2 Evolution 氧空位介导的从MoO3/CdMoO4 Type-II到MoO3-x/Ov - CdMoO4 S-Scheme异质结的进化增强光催化H2演化

IF 5.6 3区材料科学

Advanced Sustainable Systems Pub Date : 2026-09-09 DOI: 10.1002/adsu.70654

Lulu Zhang, Qingjie Zhang, Wenjuan Li, Hongwen Zhang, Hua Tang, Tingjiang Yan

{"title":"Oxygen-Vacancy-Mediated Evolution from MoO3/CdMoO4 Type-II to MoO3-x/Ov−CdMoO4 S-Scheme Heterojunctions for Enhanced Photocatalytic H2 Evolution","authors":"Lulu Zhang, Qingjie Zhang, Wenjuan Li, Hongwen Zhang, Hua Tang, Tingjiang Yan","doi":"10.1002/adsu.70654","DOIUrl":"https://doi.org/10.1002/adsu.70654","url":null,"abstract":"<div>\u0000 \u0000 <p>Constructing semiconductor heterojunctions has been widely recognized as an effective strategy for enhancing photocatalytic performance. However, rational regulation of interfacial charge-transfer pathways, particularly the controllable transformation from conventional Type-II to direct S-scheme heterojunctions, remains a fundamental challenge. Herein, an oxygen-vacancy-rich MoO<sub>3-x</sub>/Ov-CdMoO<sub>4</sub> S-scheme heterostructure photocatalyst was successfully constructed through a combined defect-engineering and in situ transformation strategy, in which oxygen vacancies drive the evolution of the MoO<sub>3</sub>/CdMoO<sub>4</sub> Type-II heterojunction into a direct S-scheme heterojunction. Density functional theory calculations, together with in situ irradiated XPS and Au photodeposition experiments, reveal that oxygen vacancies reconstruct the interfacial electronic structure by introducing defect states near the Fermi level and fundamentally regulating the interfacial charge-transfer pathway. Consequently, the optimized MoO<sub>3-x</sub>/Ov-CdMoO<sub>4</sub> heterostructure exhibits a photocatalytic H<sub>2</sub> evolution rate of 25.1 µmol g<sup>−1</sup> h<sup>−1</sup>, approximately 6 times higher than that of pristine Ov-CdMoO<sub>4</sub>, while maintaining excellent structural stability. More importantly, this work demonstrates that oxygen vacancies are identified as the decisive factor governing the evolution of heterojunction charge-transfer behavior from a conventional Type-II mechanism to a direct S-scheme pathway, enabling efficient charge separation without sacrificing redox capability.</p>\u0000 </div>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"10 9","pages":""},"PeriodicalIF":5.6,"publicationDate":"2026-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148942598","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The Controlled Release of Insect Pheromones From Biobased Thermoplastic Compounds for Sustainable Pest Management 生物基热塑性化合物控制昆虫信息素释放的可持续害虫管理

IF 5.6 3区材料科学

Advanced Sustainable Systems Pub Date : 2026-09-02 DOI: 10.1002/adsu.70627

Franziska Schmitz, Patrick Widrinski, Jessica Baier, Jonas Treutwein, Bernd Smarsly, Andreas Vilcinskas, Christoph Hellmann

{"title":"The Controlled Release of Insect Pheromones From Biobased Thermoplastic Compounds for Sustainable Pest Management","authors":"Franziska Schmitz, Patrick Widrinski, Jessica Baier, Jonas Treutwein, Bernd Smarsly, Andreas Vilcinskas, Christoph Hellmann","doi":"10.1002/adsu.70627","DOIUrl":"https://doi.org/10.1002/adsu.70627","url":null,"abstract":"<p>Insect species produce unique mixtures of pheromones that influence the behavior of conspecifics, thus enabling plant protection by targeted pest control strategies such as mating disruption. However, advances in controlled-release technologies are needed to ensure sustained and efficient delivery under varying environmental conditions. Here, we describe a thermoplastic pheromone compounds that enables near linear release profiles under laboratory and field conditions. The material offers several advantages over existing application technologies used in vineyards, particularly its potential for mechanically assisted homogeneous distribution, reducing the excess pheromones released from point dispensers. To accelerate material development, we also establish a generally applicable rapid screening method to predict pheromone release rates from different matrix materials at various temperatures. This simple and rapid test determines release rate constants to evaluate controlled pheromone release from polymer compounds. Finally, we use melt blowing to relate the characteristics of ∼1.4-mm filaments to the micrometer diameter range, providing a technical solution for homogeneous field distribution. Our results confirm suitable release characteristics under field conditions and meet evolving requirements for species-targeted pest management and biodiversity conservation.</p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"10 9","pages":""},"PeriodicalIF":5.6,"publicationDate":"2026-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.70627","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148942049","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cocatalyst Engineering in Covalent Organic Frameworks Boosts Photocatalysis 共价有机框架中的助催化剂工程促进光催化

IF 5.6 3区材料科学

Advanced Sustainable Systems Pub Date : 2026-09-01 DOI: 10.1002/adsu.70642

Mengjie Li, Xinghua Wen, Ziyang Ke, Can Huang, Song Wang, Xiao Lin, Rongchen Shen, Jianmin Luo, Xin Li

{"title":"Cocatalyst Engineering in Covalent Organic Frameworks Boosts Photocatalysis","authors":"Mengjie Li, Xinghua Wen, Ziyang Ke, Can Huang, Song Wang, Xiao Lin, Rongchen Shen, Jianmin Luo, Xin Li","doi":"10.1002/adsu.70642","DOIUrl":"https://doi.org/10.1002/adsu.70642","url":null,"abstract":"<div>\u0000 \u0000 <p>As emerging crystalline porous organic polymers, covalent organic frameworks (COFs) have shown great potential in photocatalysis due to their designable structures, high surface areas, ordered pores, excellent stability, and tunable optoelectronic properties. However, COFs typically suffer from rapid charge recombination, sluggish surface reaction kinetics, and insufficient reactant activation, which severely limit their photocatalytic efficiency. To overcome these challenges, introducing cocatalysts into COF matrices has proven effective. Cocatalysts act as charge-trapping centers to promote electron–hole separation and provide highly active catalytic sites to lower reaction barriers, thereby enhancing the overall quantum efficiency and reaction rate. This review systematically summarizes recent progress on various cocatalysts in COF photocatalytic systems, focusing on four types: noble metal, non-precious metal, molecular, and single-atom cocatalyst. We further discuss how cocatalyst engineering optimizes photocatalytic performance. Finally, we summarize the current challenges faced by COF photocatalysts and outline future directions, aiming to provide theoretical guidance for the design and development of more efficient and stable COF-based composite photocatalysts.</p>\u0000 </div>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"10 9","pages":""},"PeriodicalIF":5.6,"publicationDate":"2026-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148942024","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Turning Trash Into Treasure: Waste-Derived Aerogels and Their Multifunctional Applications—A Comprehensive Review 变废为宝：垃圾衍生气凝胶及其多功能应用综述

IF 5.6 3区材料科学

Advanced Sustainable Systems Pub Date : 2026-09-01 DOI: 10.1002/adsu.70637

Youjia Zhang, Jiangyi Chen, Chenyang Zhang, Siyuan He, Jinglei Yang, Yaqi Feng, Huiting Liu, Shiman Xu, Xianbao Wang, Shimin Wang, Li Wan

{"title":"Turning Trash Into Treasure: Waste-Derived Aerogels and Their Multifunctional Applications—A Comprehensive Review","authors":"Youjia Zhang, Jiangyi Chen, Chenyang Zhang, Siyuan He, Jinglei Yang, Yaqi Feng, Huiting Liu, Shiman Xu, Xianbao Wang, Shimin Wang, Li Wan","doi":"10.1002/adsu.70637","DOIUrl":"https://doi.org/10.1002/adsu.70637","url":null,"abstract":"<div>\u0000 \u0000 <p>Aerogels are renowned for their extraordinary nanoporous architecture and physicochemical properties. However, their widespread deployment is impeded by prohibitive production costs and intrinsic mechanical brittleness. Concurrently, the exponential accumulation of solid wastes ranging from agricultural biomass to recalcitrant plastics and tires has posed a critical threat to global ecological integrity. This review systematically elucidated the state-of-the-art methods of valorizing diverse waste materials into high-performance aerogels, championing a “waste-to-wealth” paradigm. Precursors derived from cellulosic, proteinaceous, polymeric, and inorganic residues are systematically classified, providing a critical analysis of microstructural tailoring via advanced sol-gel and drying protocols. Emphasis is placed on the functional versatility of these recycled materials across five key types: efficient adsorption for environmental remediation, advanced thermal management for insulation and fire retardancy, mechanical engineering of leveraging the intrinsic elasticity of waste rubber to overcome brittleness, and emerging applications in acoustic damping and electromagnetic shielding. Notably, based on our research of rubber powder aerogels, we benchmarked these eco-friendly alternatives against commercial standards to validate their industrial viability. The review concludes by identifying the “lab-to-fab” gap, highlighting the urgent need for standardized sources and scalable manufacturing to transition waste-derived aerogels from academic novelties to sustainable engineering solutions.</p>\u0000 </div>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"10 9","pages":""},"PeriodicalIF":5.6,"publicationDate":"2026-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148942204","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fabrication of Fe Single-Atom Catalytic Composite Membranes with Excellent Antifouling Performance for High-Efficiency Water Purification 高效水净化用优异防污性能铁单原子催化复合膜的制备

IF 5.6 3区材料科学

Advanced Sustainable Systems Pub Date : 2026-09-01 DOI: 10.1002/adsu.70647

Tieliang Bai, Xinyu Chen, Haonan Huang, Fuhao Yin, Xuanyang Gao, Lei Chen, Xianchun Lu, Benxia Li

{"title":"Fabrication of Fe Single-Atom Catalytic Composite Membranes with Excellent Antifouling Performance for High-Efficiency Water Purification","authors":"Tieliang Bai, Xinyu Chen, Haonan Huang, Fuhao Yin, Xuanyang Gao, Lei Chen, Xianchun Lu, Benxia Li","doi":"10.1002/adsu.70647","DOIUrl":"https://doi.org/10.1002/adsu.70647","url":null,"abstract":"<div>\u0000 \u0000 <p>The development of self-cleaning catalytic membranes holds great promise for advancing wastewater treatment and addressing water pollution challenges. Herein, a novel Fe-single-atom-anchored carbon-doped graphitic carbon nitride (Fe-C-CN) catalyst was synthesized by calcining a self-assembled precursor. The catalytic composite membrane (Fe-C-CN/AC/PVDF) was further fabricated via non-solvent induced phase separation, where Fe-C-CN was dispersed in poly(vinylidene fluoride) (PVDF) matrix with activated carbon (AC) incorporated to boost pollutant adsorption. Synergistic physical adsorption and photo-Fenton-like catalysis endow the composite membrane with prominent water purification and antifouling performance. Through a single-pass filtration under photo-Fenton-like reaction conditions, the composite membrane achieved a degradation efficiency of 93.4% and a total organic carbon (TOC) removal efficiency of 61.9% for 40 ppm tetracycline (TC) aqueous solution. The composite membrane maintained excellent performance across 10 consecutive cycles with negligible iron leaching, verifying its robust structural and operational stability. The TC degradation mechanism was elucidated by identifying the dominant reactive radicals and intermediate reaction products. This membrane exhibited universal removal performance for various organic pollutants, including antibiotics, dyes, and phenolic compounds, and achieved a bactericidal efficiency of 99.8%. This work proposes a feasible strategy for the fabrication of multifunctional membranes and provides new insights for the remediation of complex wastewater.</p>\u0000 </div>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"10 9","pages":""},"PeriodicalIF":5.6,"publicationDate":"2026-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148942269","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Carbon-Based Materials for Rechargeable Magnesium Batteries: Multifunctional Roles, Mechanistic Insights, and Future Perspectives 可充电镁电池的碳基材料：多功能作用、机理洞察和未来展望

IF 5.6 3区材料科学

Advanced Sustainable Systems Pub Date : 2026-09-01 DOI: 10.1002/adsu.70645

Jingxuan Bi, Xiaojie Sun, Zhenkai Zhou, Wei Ai

{"title":"Carbon-Based Materials for Rechargeable Magnesium Batteries: Multifunctional Roles, Mechanistic Insights, and Future Perspectives","authors":"Jingxuan Bi, Xiaojie Sun, Zhenkai Zhou, Wei Ai","doi":"10.1002/adsu.70645","DOIUrl":"https://doi.org/10.1002/adsu.70645","url":null,"abstract":"<div>\u0000 \u0000 <p>Rechargeable magnesium batteries (RMBs) have emerged as highly promising alternatives to lithium-ion batteries because of the high volumetric capacity, natural abundance, and potentially improved safety of magnesium metal anodes. However, their practical development remains severely hindered by sluggish Mg<sup>2+</sup> transport kinetics, limited rate capability, and insufficient cycling reversibility. Carbon-based materials, owing to their high electrical conductivity, low density, excellent chemical stability, corrosion resistance, and structural tunability, offer versatile opportunities to address these challenges and improve the electrochemical performance of RMBs. This review systematically examines the multifunctional roles of carbon-based materials across different battery components, including their use as active hosts for Mg storage, conductive and structural supports for stabilizing electrode architectures, functional interlayers for regulating polysulfide behavior in magnesium–sulfur batteries, conductive additives, separator modifiers, and corrosion-resistant current collectors. Particular emphasis is placed on the mechanisms by which carbon materials regulate charge transport, interfacial stability, reaction kinetics, and sulfur-species conversion. By correlating carbon structure, surface chemistry, and dimensional architecture with electrochemical function, this review establishes structure–property–function relationships that distinguish the roles of carbon in RMBs from those in other battery chemistries. Finally, the remaining challenges and future research directions for the rational design of carbon-based materials toward advanced RMBs are discussed.</p>\u0000 </div>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"10 9","pages":""},"PeriodicalIF":5.6,"publicationDate":"2026-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148942028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Surface Phosphorylation Modulates {001}-Faceted TiO2 for Efficient Photocatalytic Formaldehyde Degradation 表面磷酸化调节{001}面TiO2的有效光催化甲醛降解

IF 5.6 3区材料科学

Advanced Sustainable Systems Pub Date : 2026-09-01 DOI: 10.1002/adsu.70638

Zhenbing Xu, Aoyu Shu, Xiaodan Cheng, Yu-Quan Zhu, Xiufan Liu, Guohong Wang

{"title":"Surface Phosphorylation Modulates {001}-Faceted TiO2 for Efficient Photocatalytic Formaldehyde Degradation","authors":"Zhenbing Xu, Aoyu Shu, Xiaodan Cheng, Yu-Quan Zhu, Xiufan Liu, Guohong Wang","doi":"10.1002/adsu.70638","DOIUrl":"https://doi.org/10.1002/adsu.70638","url":null,"abstract":"<div>\u0000 \u0000 <p>This work systematically investigated the photocatalytic formaldehyde (HCHO) degradation performance of facet-phosphated {001} TiO<sub>2</sub> (P-TiO<sub>2</sub>) photocatalysts. The experimental results clearly showed that surface phosphate modification significantly enhanced the photocatalytic activity, achieving complete HCHO elimination (0 ppm residual concentration after 1 h) and maintaining stable catalytic performance for 12 h, outperforming pristine TiO<sub>2</sub>, which only reached a 78.8% degradation efficiency under the same conditions. Combined spectroscopic and theoretical analyses indicate that stable P─O─Ti bonds enhance the intrinsic activity of P-TiO<sub>2</sub>. These structural features optimize the interfacial electronic configuration, driving efficient photogenerated carrier separation and directing interfacial electrons toward adsorbed O<sub>2</sub> molecules. Consequently, the activated O<sub>2</sub> molecules exhibit weakened O─O bonds, leading to the proliferation of critical O<sup>−</sup> radicals for oxidation of HCHO. Mechanistic studies further demonstrate that O<sup>−</sup> radicals on P-TiO<sub>2</sub> oxidize HCHO via a dioxymethylene (DOM) and formate intermediate pathway, with reduced reaction energy barriers. This study elucidated the pivotal role of the adsorbed phosphate in the modulation of oxygen activation and provided novel insights and practical strategies for the design of high-efficiency TiO<sub>2</sub>-based indoor VOC purification materials.</p>\u0000 </div>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"10 9","pages":""},"PeriodicalIF":5.6,"publicationDate":"2026-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148942026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cellulose-Based Passive Daytime Radiative Cooling Materials: Structures, Properties, and Applications 基于纤维素的被动日间辐射冷却材料：结构、性能和应用

IF 5.6 3区材料科学

Advanced Sustainable Systems Pub Date : 2026-09-01 DOI: 10.1002/adsu.70648

Jiawei Han, Jingpeng Li, Zongying Fu, Dengkang Guo, Yun Lu

{"title":"Cellulose-Based Passive Daytime Radiative Cooling Materials: Structures, Properties, and Applications","authors":"Jiawei Han, Jingpeng Li, Zongying Fu, Dengkang Guo, Yun Lu","doi":"10.1002/adsu.70648","DOIUrl":"https://doi.org/10.1002/adsu.70648","url":null,"abstract":"<div>\u0000 \u0000 <p>Refrigeration is vital for modern society, yet conventional vapor-compression systems suffer high energy consumption, significant greenhouse emissions, and miniaturization challenges. Passive daytime radiative cooling (PDRC) offers a promising eco-friendly alternative by exploiting thermal radiation to dissipate heat through the atmospheric window (8–13 µm) into cold outer space, requiring zero energy input and enabling substantial energy savings. Cellulose, as an Earth-abundant natural polymer, is highly attractive for PDRC due to its molecular hydroxyl groups enabling high infrared emissivity and excellent structural tunability for chemical modification. Cellulose-based PDRC materials exhibit remarkable sustainability, diverse forms, and superior cooling performance, making them ideal for advanced thermal management. This comprehensive review details the fundamentals of solar radiation and radiative cooling, then systematically examines structure-property relationships across various cellulose-based PDRC materials. It discusses optimization strategies via macro/microstructural control and bioinspired design, alongside functional enhancements like coloration and self-cleaning. Key applications in energy-efficient buildings, smart textiles, and food preservation are highlighted, demonstrating significant cooling effects and energy-saving potential. Finally, current challenges and future prospects for next-generation sustainable cellulose PDRC technologies are outlined.</p>\u0000 </div>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"10 9","pages":""},"PeriodicalIF":5.6,"publicationDate":"2026-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148942203","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fabrication of Flexible Nickel Phosphide ITO-PET Electrode Using a Screen-Printing Strategy for Robust Electrochemical Water Electrolysis 丝网印刷法制备柔性磷化镍ITO-PET电极的研究

IF 5.6 3区材料科学

Advanced Sustainable Systems Pub Date : 2026-09-01 DOI: 10.1002/adsu.70629

Abdul Kareem, Arunkumar Prabhakaran Shyma, Myriam Mansour, Ali S. Alnaser, Oussama M. El-Kadri

{"title":"Fabrication of Flexible Nickel Phosphide ITO-PET Electrode Using a Screen-Printing Strategy for Robust Electrochemical Water Electrolysis","authors":"Abdul Kareem, Arunkumar Prabhakaran Shyma, Myriam Mansour, Ali S. Alnaser, Oussama M. El-Kadri","doi":"10.1002/adsu.70629","DOIUrl":"https://doi.org/10.1002/adsu.70629","url":null,"abstract":"<div>\u0000 \u0000 <p>The development of cost-effective, stable, and highly active electrocatalysts is crucial for improving the kinetics of overall water splitting in alkaline media, ultimately reducing hydrogen production costs. In this work, we synthesized nickel phosphide nanostructures (Ni<sub>2</sub>P NSs) and introduced phosphorus vacancies via annealing. To achieve a durable and efficient electrode, the material was coated onto ITO-PET substrates using a screen-printing technique. The phosphorus vacancies effectively modulate active sites, enhancing the electrocatalytic performance of Ni<sub>2</sub>P NSs, while the ITO-PET provides a flexible conductive platform that enables stable catalyst immobilization through the screen-printing method. Unlike previously reported Ni<sub>2</sub>P-based catalysts that primarily focus on powder systems or rigid substrates, this work integrates vacancy engineering with a scalable screen-printing strategy on a flexible, conductive platform, thereby enabling enhanced catalytic activity and mechanical robustness. The vacancy-rich Ni<sub>2</sub>P NSs (Ni<sub>2</sub>P-400) coated on ITO-PET demonstrated remarkable electrocatalytic activity, achieving low overpotentials of 318 mV for HER and 316 mV for OER at 100 mA cm<sup>−2</sup>. The prepared electrode materials also showed excellent performance towards overall water electrolysis in a two-electrode setup, requiring only 1.87 V to reach 100 mA cm<sup>−2</sup>, and maintained stability for 90 h under alkaline conditions.</p>\u0000 </div>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"10 9","pages":""},"PeriodicalIF":5.6,"publicationDate":"2026-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148860019","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0