Advanced Sustainable Systems最新文献_第2页

Enhancement of Ionic Conductivity in NASICON-Structured Li3(Zr,Ti)2(Si,Ge)2PO12: An Ab Initio Study nasicon结构Li3(Zr,Ti)2(Si,Ge)2PO12中离子电导率的增强：从头算研究

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-02-19 DOI: 10.1002/adsu.202401028

Jiaqi Wang, Weirong Huo, Zhiwei Peng, Zongqing Tian, Shafiq Ur Rehman, Zongwei Mei, Yinghua Niu, Weiqiang Lv

{"title":"Enhancement of Ionic Conductivity in NASICON-Structured Li3(Zr,Ti)2(Si,Ge)2PO12: An Ab Initio Study","authors":"Jiaqi Wang, Weirong Huo, Zhiwei Peng, Zongqing Tian, Shafiq Ur Rehman, Zongwei Mei, Yinghua Niu, Weiqiang Lv","doi":"10.1002/adsu.202401028","DOIUrl":"https://doi.org/10.1002/adsu.202401028","url":null,"abstract":"The development of solid electrolytes with high ionic conductivity is crucial for advancing solid lithium-ion battery technology but is still a challenge. In this study, the ionic conductivity of NASICON-structured materials Li3(Zr,Ti)2(Si,Ge)2PO12 are explored through ab initio molecular dynamics (AIMD) simulations. This investigation reveals the significant impact of isovalent substitution on the lithium-ion diffusion pathways and the associated energy barriers. Elemental substitutions, such as replacing Zr with Ti, significantly reduce the Li site energy levels, enhance the polyhedral volume, and change the coordination structure from four-coordinate to five-coordinate, thereby facilitating lithium-ion migration. Conversely, substituting Si with Ge reduces the diffusion channel size and increases fluctuation of Li migration potential surface, leading to less favorable ion transport conditions. Li3Ti2Si2PO12 exhibits a room temperature ionic conductivity of 5.79 × 10−2 Scm−1, 163% higher than that of the pristine Li3Zr2Si2PO12, with a reduced diffusion barrier of 0.16 eV. Additionally, these analyses reveal that the critical size for effective diffusion channels is vital: below this threshold, ion migration is suppressed; while above it, the channel size no longer limits migration.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 4","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143840552","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

3D Printed Biodegradable Soft Actuators from Nanocellulose Reinforced Gelatin Composites (Adv. Sustainable Syst. 2/2025) 由纳米纤维素增强明胶复合材料制成的3D打印可生物降解软执行器（ad . Sustainable system . 2/2025）

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-02-19 DOI: 10.1002/adsu.202570021

Oliver Müller, Alexandre Poulin, Xavier Aeby, Roberto Emma, Ryo Kanno, Toshiaki Nagai, Jun Shintake, Gustav Nyström

引用次数: 0

Exploring the Influence of Etching media on the Electrochemical Behavior of Cr2CTx MXene 探讨蚀刻介质对Cr2CTx MXene电化学行为的影响

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-02-17 DOI: 10.1002/adsu.202400865

Madhushree Ramachandra, Kalathiparambil Rajendra Pai Sunajadevi, Dephan Pinheiro

{"title":"Exploring the Influence of Etching media on the Electrochemical Behavior of Cr2CTx MXene","authors":"Madhushree Ramachandra, Kalathiparambil Rajendra Pai Sunajadevi, Dephan Pinheiro","doi":"10.1002/adsu.202400865","DOIUrl":"https://doi.org/10.1002/adsu.202400865","url":null,"abstract":"MXenes, a class of 2D materials, have garnered significant attention for energy applications due to their unique properties. This study investigates the influence of different etching media on the synthesis of 2D Cr2CTx MXene derived from cost-effective Cr2AlC MAX phase. Three etching solutions- hydrofluoric acid (HF), HF-forming (lithium fluoride + Hydrochloric acid, LiF+HCl), and non-fluoride (sodium hydroxide, NaOH) have been used to treat ternary carbide Cr2AlC MAX phase under varied reaction conditions. The MXenes, Cr2CTx-HF, Cr2CTx-LiF/HCl, and Cr2CTx-NaOH are structurally, and morphologically characterized using XRD, Raman spectroscopy, TGA, XPS, SEM-EDX, and BET-BJH analysis. The electrochemical performance of Cr2CTx MXene is assessed, focusing on its performance in water splitting and supercapacitive applications. The materials exhibit lower overpotential values for hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and demonstrate improved pseudocapacitive behavior, with enhanced energy and power densities. The introduction of surface termination groups in Cr2CTx MXene (Tx = ─F, ─OH, ─O) resulted in a more open and accessible layered structure with an appreciable surface area, without any modifications. This enhanced electrochemical kinetics, improved ion transport, diffusion, and storage capacity, which are beneficial for electrochemical energy storage and production.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 4","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143840943","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Optimized EVA Decomposition in Bifacial Solar Panels: Sustainable Recovery of Polymerized Oil and Materials 优化双面太阳能电池板中的 EVA 分解：聚合油和材料的可持续回收

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-02-14 DOI: 10.1002/adsu.202500004

Chitra Sulkan, Prashant Kumar Thakur, Shailza Sharma, Neeraj Das

{"title":"Optimized EVA Decomposition in Bifacial Solar Panels: Sustainable Recovery of Polymerized Oil and Materials","authors":"Chitra Sulkan, Prashant Kumar Thakur, Shailza Sharma, Neeraj Das","doi":"10.1002/adsu.202500004","DOIUrl":"https://doi.org/10.1002/adsu.202500004","url":null,"abstract":"The disposal of end-of-life (EOL) photovoltaic (PV) solar panels presents environmental challenges due to hazardous materials and complex structure. This study proposes an optimized method for recycling bifacial solar panels, which lack a back sheet and use ethylene-vinyl acetate (EVA) as the sole encapsulant. The process achieves 100% recovery of valuable materials, including polymerized oil, clean glass, solar cells, and copper tape. Unlike traditional PV panels with back sheet polymers like PVF, PET, or PVDF, bifacial panels simplify the recycling process. EVA, composed of hydrogen, carbon, and oxygen, is more environmentally friendly, especially without fluorinated compounds. Using a modified pyrolysis reactor, the EVA layer is degraded in inert conditions, minimizing emissions and producing polymerized oil. This oil can be used as a lubricant, while the recovered glass, solar cells, and copper tape are reusable in manufacturing new panels. Optimized oil yield is achieved using Response Surface Methodology (RSM) and Box-Behnken Design (BBD). At a heating rate of 8.92 °C min−1, a 31.82-min hold time, and a maximum temperature of 528.22 °C, the process yields 57.53% polymerized oil. The oil is characterized by thermogravimetric analysis (TGA) and Fourier-transform infrared spectroscopy (FT-IR), meeting ASTM and Australian diesel standards. This method maximizes material recovery and supports a circular economy, enhancing solar energy system sustainability.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 4","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143840688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Nitrogen-Doped Graphene/Cellulose Fibers Double-Coated Asymmetric Separator for High-Performance Lithium-Sulfur Batteries 用于高性能锂硫电池的氮掺杂石墨烯/纤维素纤维双涂层不对称隔膜

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-02-14 DOI: 10.1002/adsu.202401047

Hao-Nan Guo, Wei-Xu Dong, Zhi-Yong Fang, Lei Hu, Jingwei Chen, Li-Feng Chen

{"title":"Nitrogen-Doped Graphene/Cellulose Fibers Double-Coated Asymmetric Separator for High-Performance Lithium-Sulfur Batteries","authors":"Hao-Nan Guo, Wei-Xu Dong, Zhi-Yong Fang, Lei Hu, Jingwei Chen, Li-Feng Chen","doi":"10.1002/adsu.202401047","DOIUrl":"https://doi.org/10.1002/adsu.202401047","url":null,"abstract":"Lithium-Sulfur (Li─S) batteries have the advantages of low cost and high capacity, but the cathode shuttle effect and the growth of anode lithium dendrites have hindered their development. Among the various modification strategies, separator modification offers a promising approach to address issues on both anodes and cathodes. In this study, a bifunctional asymmetric polypropylene (PP) separator is modified with nitrogen-doped reduced graphene oxide (N–rGO) on the cathode side and cellulose fibers (CF) on the anode side to address the challenges associated with both electrodes. CF effectively promotes the uniform deposition of lithium metal and significantly inhibits the growth of lithium dendrites. In addition, N–rGO with a porous structure and nitrogen-doped active sites can not only suppress lithium polysulfide shuttling by physical and chemical adsorption but also catalyze the kinetics of the redox reaction, leading to an increased specific capacity of the battery. The Li─S battery incorporating N–rGO@PP@CF separator exhibits an impressive specific capacity of 1294 mAh g−1 at a current rate of 1 C, with a remarkably low average capacity decay of 0.076% per cycle over 500 cycles. The synergistic effect between CF and N–rGO modification on asymmetric separators provides a promising guideline for developing high-performance Li─S batteries.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 4","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143840687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Stabilizing Semi-Interpenetrated Alginate/Pedot Hydrogels via Glyoxal-Mediated Covalent Crosslinks for Water Steam Generation 通过乙二醛介导的共价交联稳定半互渗透海藻酸盐/Pedot水凝胶的水蒸汽生成

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-02-14 DOI: 10.1002/adsu.202401005

Samuele Colombi, Julia Mingot, Jorge Morgado, Maria M. Pérez-Madrigal, José García-Torres, Elaine Armelin, Carlos Alemán

{"title":"Stabilizing Semi-Interpenetrated Alginate/Pedot Hydrogels via Glyoxal-Mediated Covalent Crosslinks for Water Steam Generation","authors":"Samuele Colombi, Julia Mingot, Jorge Morgado, Maria M. Pérez-Madrigal, José García-Torres, Elaine Armelin, Carlos Alemán","doi":"10.1002/adsu.202401005","DOIUrl":"https://doi.org/10.1002/adsu.202401005","url":null,"abstract":"The chemical and physical stability of bio-hydrogels are of utmost interest to avoid the premature degradation of the polymer and to favor cyclic material operations (i.e., material recovery and re-using). In this work, the stability of different alginate hydrogels semi-interpenetrated with poly(3,4-ethylenedioxythiophene):polystyrene sulfonate conducting polymer (Alg/PEDOT), which acts as a photothermal absorber is examined. More specifically, the behavior of Alg/PEDOT hydrogels ionically and covalently crosslinked with Ca2+ ions and glyoxal, respectively, has been compared when used as water purification platforms. The homogenous porosity and higher cycling capacity of the glyoxal-crosslinked gels provide superior performance for water-steam generation under sunlight irradiation than that of the ionically stabilized gel. Furthermore, increasing the glyoxal cross-linking reaction time prove to have little effect on the porosity and the efficiency of freshwater supply from an artificial seawater solution. Covalent cross-links provide thermal absorber (PEDOT:PSS) retention capacity in artificial seawater, which is critical to maintaining such efficiency with the increasing number of purification cycles. This research opens new frontiers to promote the use of alginate biopolymer in chemical engineering processes such as water desalination, directly addressing the United Nations Sustainable Development Goals for Clean Water & Life on Land.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 4","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143840686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Boosting Hydrogen Evolution on MoS2/N-doped-C Nanotubes via Integrated Van der Waals Engineering and Morphology Engineering 基于范德华工程和形态学工程的MoS2/ n掺杂碳纳米管析氢研究

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-02-13 DOI: 10.1002/adsu.202400971

Sizhuo Feng, Fengshun Wang, Chen Gu, Jianmei Chen, Shujuan Liu, Longlu Wang, Qiang Zhao

{"title":"Boosting Hydrogen Evolution on MoS2/N-doped-C Nanotubes via Integrated Van der Waals Engineering and Morphology Engineering","authors":"Sizhuo Feng, Fengshun Wang, Chen Gu, Jianmei Chen, Shujuan Liu, Longlu Wang, Qiang Zhao","doi":"10.1002/adsu.202400971","DOIUrl":"https://doi.org/10.1002/adsu.202400971","url":null,"abstract":"In the realm of electrocatalytic hydrogen evolution reaction (HER), molybdenum disulfide (MoS2) is a material that holds great promise as a substitute for platinum (Pt), which is both expensive and scarce. The restricted number of active sites and low conductivity of MoS2 have an impact on its catalytic efficiency, however, which hampers the application of MoS2-based catalysts in practical catalytic hydrogen production. The integrated Van der Waals (vdW) engineering and morphology engineering hold the potential to effectively boost hydrogen evolution on MoS2. Herein, hierarchical nanotubes (MoS2/N-doped-C) assembled from MoS2 nanosheets sandwiched by N-doped-C layers are synthesized utilizing an integration of hydrothermal and annealing. The 3D hierarchical structure with stepped edges, produced by directly integrating carbon layers into the MoS2 interlayers, enhances the catalytic activity and stability of the HER compared to MoS2 scattered on conductive carriers. The experimental results demonstrate that MoS2/N-doped-C shows excellent electrocatalytic HER activity under acidic conditions, exhibiting an extremely small Tafel slope of 42 mV dec−1, an extremely low overpotential of 41 mV at a geometric current density of 10 mA cm−2, and maintaining durability for more than 100 h.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 4","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143840956","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Toward Sustainable Urban Development: Identifying Principal SDG Indicators for Chinese Cities 迈向城市可持续发展：确定中国城市可持续发展目标的主要指标

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-02-13 DOI: 10.1002/adsu.202400894

Lu Chen, Chenyang Shuai, Xi Chen, Jingran Sun, Bu Zhao

{"title":"Toward Sustainable Urban Development: Identifying Principal SDG Indicators for Chinese Cities","authors":"Lu Chen, Chenyang Shuai, Xi Chen, Jingran Sun, Bu Zhao","doi":"10.1002/adsu.202400894","DOIUrl":"https://doi.org/10.1002/adsu.202400894","url":null,"abstract":"Urban transformation plays a decisive role in China's achievement of the United Nations 2030 Agenda for Sustainable Development. However, a comprehensive and authoritative sustainable development goal (SDG) indicator framework is currently lacking at the city level. To address this gap, we first developed an integrated framework comprising 357 indicators for 297 Chinese cities through a literature review. Nevertheless, the sheer number of reviewed indicators presents significant challenges in data collection. The study then used principal component analysis and multiple regression to identify a small set of SDG indicators (principal indicators) with the consideration of data collection difficulty. Finally, we tested their effectiveness up to 2030. The key findings of our study are as follows: 1) 187 principal indicators are identified to explain the 90% variance of all the 357 indicators with lowest data collection difficulty, providing comprehensive coverage of the SDGs and achieving efficient information aggregation; 2) these principal indicators demonstrated good variance effectiveness and data availability in the vast majority of cities (284 out of 297), highlighting priority areas for future data infrastructure development; 3) the continued applicability of these principal indicators up to 2030 is validated. This study offers insights to guide investments in data infrastructure supporting China's sustainable urban development.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 4","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143840960","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Stable Organic Solar Cells with Enhanced Efficiency Built on Sodium Alginate 基于海藻酸钠的高效稳定有机太阳能电池

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-02-13 DOI: 10.1002/adsu.202401026

Marco Natali, Piera Maccagnani, Franco Dinelli, Cristiano Albonetti, Massimo Cocchi, Monica Bertoldo, Mirko Seri

{"title":"Stable Organic Solar Cells with Enhanced Efficiency Built on Sodium Alginate","authors":"Marco Natali, Piera Maccagnani, Franco Dinelli, Cristiano Albonetti, Massimo Cocchi, Monica Bertoldo, Mirko Seri","doi":"10.1002/adsu.202401026","DOIUrl":"https://doi.org/10.1002/adsu.202401026","url":null,"abstract":"Bulk heterojunction (BHJ) organic solar cells can offer a range of specific advantages, making them suitable for potential integration into a wide variety of applications. This circumstance is driving an ever increasing attention to the environmental profile of this technology throughout its entire life cycle. Consequently, alternative materials and processes with a reduced environmental impact attract interest from researchers focused on developing a new generation of eco-designed devices. In this context, biomaterials represent an emerging class of sustainable alternatives suitable for use as active and passive components. For instance, some biomaterials can be successfully employed as alternative substrates for flexible solar cells, achieving performances comparable to those of state-of-the-art devices built on plastic. In this work, the preparation of organic solar cells is presented, integrating a water-processed sodium alginate film as a substrate, with the dual purpose of optimizing the efficiency of the resulting devices and investigating their stability. Specifically, PM6:Y6-based cells built on SA substrates exhibit a power conversion efficiency that exceeds 10% while showing excellent thermal and mechanical stabilities. These results demonstrate the potential of sodium alginate as a viable candidate for the realization of efficient and stable eco-designed devices.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 4","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143840957","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis of Nitrogen-Doped Platinum–Neodymium Nanoalloy Catalyst by Liquid-Phase Reduction for Oxygen Reduction Reaction 液相还原法制备氮掺杂铂钕纳米合金氧还原催化剂

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-02-11 DOI: 10.1002/adsu.202400944

Hang Jiang, Qianwen Liu, Wei Song, Pei Gong, Zhihong Yu, Zhicheng Liang

引用次数: 0