Fluorides Capture: Delving Into the Bond Between Metal–Organic Frameworks and Capture Dynamics

IF 6.1 3区材料科学 Q2 GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY

Advanced Sustainable Systems Pub Date : 2025-07-21 DOI:10.1002/adsu.202500304

Brij Mohan, Virender Virender, Vandana Pandey, Ismayil M. Garazade, Bakhtiyar Najafov, Xiaoning Liao, Armando J. L. Pombeiro, Gurjaspreet Singh, Sang Sub Kim

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Abstract

The emergence of fluoride contamination in water sources raises significant environmental and health concerns. Metal–organic frameworks (MOFs) have gained increasing attention as effective materials for fluoride removal due to their adjustable structures, high surface areas, and versatile functions. This review provides a thorough overview of recent advancements in the design and application of MOFs for fluoride remediation. Key topics discussed include the mechanisms of fluoride capture through various interactions, the effects of framework functionalization, and the importance of structural parameters such as pore size and sieving effects. The review also examines the impact of coexisting ions on fluoride adsorption performance. Additionally, it highlights the challenges and opportunities associated with developing customized MOFs for efficient and selective fluoride removal.

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氟化物捕获：钻研金属有机框架和捕获动力学之间的键

水源中氟化物污染的出现引起了重大的环境和健康问题。金属有机骨架（MOFs）由于其结构可调、比表面积大、功能多样等优点，作为一种高效的除氟材料，受到了越来越多的关注。本文综述了mof在氟修复中的设计和应用的最新进展。讨论的关键主题包括通过各种相互作用捕获氟的机制，框架功能化的影响，以及结构参数（如孔径和筛分效果）的重要性。本文还探讨了共存离子对氟吸附性能的影响。此外，它还强调了与开发用于高效和选择性除氟的定制MOFs相关的挑战和机遇。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Advanced Sustainable Systems Environmental Science-General Environmental Science

CiteScore

10.80

自引率

4.20%

发文量

186

期刊介绍： Advanced Sustainable Systems, a part of the esteemed Advanced portfolio, serves as an interdisciplinary sustainability science journal. It focuses on impactful research in the advancement of sustainable, efficient, and less wasteful systems and technologies. Aligned with the UN's Sustainable Development Goals, the journal bridges knowledge gaps between fundamental research, implementation, and policy-making. Covering diverse topics such as climate change, food sustainability, environmental science, renewable energy, water, urban development, and socio-economic challenges, it contributes to the understanding and promotion of sustainable systems.