Advanced Sustainable Systems最新文献

Cr6+ Loaded Lewis Acidic Sn-Beta Zeolites as Reusable Catalysts for Selective Production of Light Olefins via Polyolefin Cracking (Adv. Sustainable Syst. 3/2025)

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-03-24 DOI: 10.1002/adsu.202570031

Shinya Kokuryo, Soshi Tsubota, Koji Miyake, Yoshiaki Uchida, Atsushi Mizusawa, Tadashi Kubo, Norikazu Nishiyama

引用次数: 0

Electrodeposition of Carbon-Trapping Minerals in Seawater for Variable Electrochemical Potentials and Carbon Dioxide Injections (Adv. Sustainable Syst. 3/2025)

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-03-24 DOI: 10.1002/adsu.202570033

Nishu Devi, Xiaohui Gong, Daiki Shoji, Amy Wagner, Alexandre Guerini, Davide Zampini, Jeffrey Lopez, Alessandro F. Rotta Loria

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Electrodeposition of Carbon-Trapping Minerals in Seawater for Variable Electrochemical Potentials and Carbon Dioxide Injections

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-03-18 DOI: 10.1002/adsu.202400943

Nishu Devi, Xiaohui Gong, Daiki Shoji, Amy Wagner, Alexandre Guerini, Davide Zampini, Jeffrey Lopez, Alessandro F. Rotta Loria

{"title":"Electrodeposition of Carbon-Trapping Minerals in Seawater for Variable Electrochemical Potentials and Carbon Dioxide Injections","authors":"Nishu Devi, Xiaohui Gong, Daiki Shoji, Amy Wagner, Alexandre Guerini, Davide Zampini, Jeffrey Lopez, Alessandro F. Rotta Loria","doi":"10.1002/adsu.202400943","DOIUrl":"https://doi.org/10.1002/adsu.202400943","url":null,"abstract":"Seawater offers immense potential for addressing global energy and climate challenges. Electrochemical seawater splitting is a sustainable approach for hydrogen production and carbon dioxide (CO2) sequestration, producing hydrogen gas at the cathode and oxygen or chlorine gas at the anode. Simultaneously, minerals such as calcium carbonate and magnesium hydroxide precipitate at the cathode, especially when coupled with CO2 injections for the sake of CO2 sequestration. These precipitates are often dismissed as energy-intensive byproducts. However, they have untapped potential as resources for construction, manufacturing, and environmental remediation. Here, a comprehensive experimental investigation is presented into the electrochemical precipitation of minerals in seawater under varying operational conditions. By systematically varying applied voltage, current density, and CO2 flow rate, the conditions that optimize mineral yield and selectivity while minimizing energy consumption are revealed. The findings advance the understanding of electrochemical synthesis and material processing in aqueous solutions, with a particular focus on the mineralization of calcareous compounds and their transformation into large-scale aggregates. These findings also support an additional and highly scalable application of seawater electrolysis, encompassing not only oceanic renewable hydrogen production and CO2 sequestration but also the sustainable production of carbon-trapping minerals and aggregates.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 3","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202400943","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

3D Printed Biodegradable Soft Actuators from Nanocellulose Reinforced Gelatin Composites (Adv. Sustainable Syst. 2/2025)

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-02-19 DOI: 10.1002/adsu.202570021

Oliver Müller, Alexandre Poulin, Xavier Aeby, Roberto Emma, Ryo Kanno, Toshiaki Nagai, Jun Shintake, Gustav Nyström

引用次数: 0

Molten Salt Construction of Nitrogen, Oxygen, Sulfur Co-Doped Hierarchical Porous Carbon for Zinc Ion Hybrid Capacitors

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-02-10 DOI: 10.1002/adsu.202401000

Yifeng Liu, Weijian Chen, Xinyang Zhang, Baipei Liu, Yande Liu, Rui Lu, Xiaoliang Wu

{"title":"Molten Salt Construction of Nitrogen, Oxygen, Sulfur Co-Doped Hierarchical Porous Carbon for Zinc Ion Hybrid Capacitors","authors":"Yifeng Liu, Weijian Chen, Xinyang Zhang, Baipei Liu, Yande Liu, Rui Lu, Xiaoliang Wu","doi":"10.1002/adsu.202401000","DOIUrl":"https://doi.org/10.1002/adsu.202401000","url":null,"abstract":"Heteroatoms doped hierarchical porous carbon shows great potentiality as electrode materials for zinc ion hybrid capacitors. Herein, nitrogen, oxygen, and sulfur co-doped hierarchical porous carbon (NSPC) is synthesized by one-step pyrolysis of the mixture of KHCO3, starch, and acesulfame potassium. The obtained NSPC-700 samples possess 3D interconnected hierarchical porous architecture, high specific surface area, and rich nitrogen, oxygen, and sulfur functional groups. Result from the synergistic effect, the obtained NSPC-700 electrode shows a high specific capacitance of 382 F g−1 at 0.5 A g−1 and outstanding electrochemical stabilization with the capacitance retention of 101.5%. Density functional theory (DFT) results show that co-doping with N, O, and S can improve the adsorption capacity of zinc ions and enhance the charge transfer rate. The assembled Zn//ZnSO4(aq)//NSPC-700 hybrid capacitor achieves an energy density of 120.84 Wh kg−1 at a power density of 100 W kg−1 with excellent electrochemical stabilization (90.9% capacity retention after 10,000 cycles).","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 3","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enabling Highly Recoverable and Efficient Nanosized Photocatalysts via Constructing Robust Submillimetric Patchy Particles

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-02-10 DOI: 10.1002/adsu.202401021

Zhudan Jiang, Jiale Huang, Jingjin Cai, Shanglin Xiang, Dongyu Cai

引用次数: 0

N, O Co-Doped Porous Carbon Decorated on Porous Graphene for Zinc Ion Hybrid Capacitor

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-02-10 DOI: 10.1002/adsu.202400807

Te Huo, Yanyan Wang, Jiayi Wang, Chunxia Chen, Yunhe Zhao, Li Guo, Xiaoliang Wu

{"title":"N, O Co-Doped Porous Carbon Decorated on Porous Graphene for Zinc Ion Hybrid Capacitor","authors":"Te Huo, Yanyan Wang, Jiayi Wang, Chunxia Chen, Yunhe Zhao, Li Guo, Xiaoliang Wu","doi":"10.1002/adsu.202400807","DOIUrl":"https://doi.org/10.1002/adsu.202400807","url":null,"abstract":"Metal–organic frameworks (MOFs) derived porous carbon shows tremendous potential in the energy storage field. Herein, N, O co-doped porous carbon decorated on porous graphene composites is prepared by carbonized MOF/graphene composites with followed activated by KOH. MOF-derived porous carbon decorated on porous graphene not only can improve conductivity, but also enhance structural stability. Due to the 3D porous structure, unique structure and conductive support, suitable specific surface area, and abundant N and O functional groups, the obtained ZGCA electrode shows a high specific capacitance of 284.7 F g−1 at 0.5 A g−1, superior rate performance, and good electrochemical stability. More importantly, the constructed Zn//ZnSO4//ZGCA-700 zinc ion hybrid capacitor delivers a specific capacity of 184.4 mAh g−1 at 0.1 A g−1 and a high energy density of 147.5 Wh kg−1 at a power density of 80.1 W kg−1. At the same time, the capacity retention rate of the ZGCA electrode is 85.2% after 10,000 cycles. This paper provides new ideas and feasible methods for preparing high-performance MOF-based porous carbon for zinc ion hybrid capacitors.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 3","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advancing Vanadium MXene Cathodes: Strategic Enhancements for Superior Performance in Zinc-Ion Batteries

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-01-29 DOI: 10.1002/adsu.202400844

Jenitha M, Durgalakshmi D., Ashwin Kishore M. R., Balakumar S., Ajay Rakkesh R

引用次数: 0

Design and Construct Cyclic Carbonate Functionalized Chitosan-Based Hydrogel Enabling Photodecarboxylase Immobilization with Enhanced Stability and Reusability

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-01-26 DOI: 10.1002/adsu.202400862

Jianle Zhou, Xiongliang He, Yanyan Ye, Zhuoxin Zhuang, Xingyu Tang, Junpeng Zhao, Yunjian Ma, Yonghua Wang

{"title":"Design and Construct Cyclic Carbonate Functionalized Chitosan-Based Hydrogel Enabling Photodecarboxylase Immobilization with Enhanced Stability and Reusability","authors":"Jianle Zhou, Xiongliang He, Yanyan Ye, Zhuoxin Zhuang, Xingyu Tang, Junpeng Zhao, Yunjian Ma, Yonghua Wang","doi":"10.1002/adsu.202400862","DOIUrl":"https://doi.org/10.1002/adsu.202400862","url":null,"abstract":"Fatty acid photodecarboxylase (FAP) plays a crucial role in the green production of biofuel and other valuable biochemicals. However, the reusability of immobilized FAP has been limited due to inadequate durability. Here, a porous, translucent chitosan hydrogel sphere carrier functionalized with cyclic carbonate group to enhance the reusability of immobilized FAP is presented. Based on the arrangement of basic amino acid residues on the surface of FAP, bis(cyclic carbonate) containing a flexible chain from CO2 is designed and synthesized. This compound is used to modify porous hydrogels obtained via a template-etching process. FAP is then covalently immobilized within the hydrogel framework through a reaction with the remaining cyclic carbonate groups, as evidenced by quartz crystal microbalance analysis. The modified porous hydrogel carrier, PH3-BC-II, significantly improves the activity of FAP, achieving a maximum conversion of 70.0%, with the enzyme loading of 125.3 mg g−1 (dry carrier). Furthermore, PH3-BC-II retains >50% of its initial activity after eight consecutive reaction cycles (total runtime of 24 h) at high fatty acid substrate concentrations. This study provides an effective strategy for constructing stable immobilized (photo)enzymes from sustainable materials.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 3","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143689806","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

UV-Solar Photocatalysis for the Simultaneous Removal of Arsenic and Mercury in Washing Solutions from Polluted Marine Sediments

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-01-24 DOI: 10.1002/adsu.202400857

Marica Muscetta, Marco Race, Fabio D'Agostino, Mario Sprovieri, Laura Clarizia

{"title":"UV-Solar Photocatalysis for the Simultaneous Removal of Arsenic and Mercury in Washing Solutions from Polluted Marine Sediments","authors":"Marica Muscetta, Marco Race, Fabio D'Agostino, Mario Sprovieri, Laura Clarizia","doi":"10.1002/adsu.202400857","DOIUrl":"https://doi.org/10.1002/adsu.202400857","url":null,"abstract":"An environmentally sustainable strategy has been developed for simultaneously removing arsenic and mercury from wastewater, potentially coming from washing of polluted marine sediments. Citric acid (CA), a biodegradable chelating agent, forms stable complexes with both metals, which can be extracted from contaminated sediments through ex situ sediment washing. A solar photocatalytic method has been developed to separate toxic metals from wastewater and degrade CA. Increasing the TiO2 photocatalyst load enhances arsenic adsorption under dark conditions. Total arsenic removal is achieved during photocatalytic decontamination using 1000 ppm of TiO2. Fe(III)–hydroxides formed in the presence of Fe(III) further adsorb arsenic. Nearly total arsenic removal is achieved even under seawater conditions and visible light irradiation only. The removal of arsenic in different oxidation states has been successfully demonstrated. The UV–vis/TiO2/CA photocatalytic system has also proven highly effective for mercury removal from wastewater. Although seawater conditions slightly slow the removal process, complete mercury removal is achieved even under visible light irradiation. Finally, a combined photocatalytic approach has been developed for the removal of both arsenic and mercury, achieving 100% removal within few minutes of light irradiation. The reaction mechanism has been depicted based on intermediates and reaction products detected during the photocatalytic process.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 3","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202400857","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143689585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0