Advanced Sustainable Systems最新文献

{"title":"Solid-State and Sustainable Batteries (Adv. Sustainable Syst. 7/2025)","authors":"Jie Zhao,&nbsp;Yun Song,&nbsp;Junyu Hou,&nbsp;Shubin Yang,&nbsp;Yongji Gong","doi":"10.1002/adsu.202570071","DOIUrl":"https://doi.org/10.1002/adsu.202570071","url":null,"abstract":"<p><b>Solid-State and Sustainable Batteries</b></p><p>The carbon neutrality agenda accelerates the energy storage transition, driving a paradigm shift in the battery technology towards more efficient, safer and eco-friendly solutions. This Special Issue presents 13 papers on solid-state/sustainable Li/Na-ion and wearable batteries, revealing intrinsic mechanisms from nanoscale reconfiguration to macroscopic device optimization, and demonstrating their high-energy, high-safety potential for electric vehicles, grid storage, and flexible electronics. More information can be found in the Editorial by Jie Zhao, Yun Song, Junyu Hou, Shubin Yang, and Yongji Gong (article number 2500425).\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 7","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202570071","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144681254","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High-Entropy Alloys and Oxides as Supercapacitor Electrodes: A Structural and Electrochemical Perspective for Energy Storage (Adv. Sustainable Syst. 6/2025)","authors":"Öyküm Başgöz,&nbsp;Ahmet Güngör,&nbsp;Ömer Güler,&nbsp;Emre Erdem","doi":"10.1002/adsu.202570061","DOIUrl":"https://doi.org/10.1002/adsu.202570061","url":null,"abstract":"<p><b>Supercapacitor Electrodes</b></p><p>This cover illustrates the integration of high entropy alloys (HEAs) and high entropy oxides (HEOs) into supercapacitor technology. The colorful, multi-metallic structure highlights the synergy between Cr, Fe, Mn, V, and Ni—five transition metals that form a highly capacitive, stable, and efficient electrode material. These high entropy materials demonstrate outstanding charge storage performance, reinforcing the energy and power density of supercapacitor devices. More information can be found in article 2500201, Ömer Güler, Emre Erdem, and co-workers.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 6","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202570061","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144367241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Antistatic, Flame-Retardant, and Mechanically Resistant Cellulose/Carbon Black Cryogels for Electrostatic Discharge Packaging (Adv. Sustainable Syst. 5/2025)","authors":"Gabriele Polezi,&nbsp;Diego M. Nascimento,&nbsp;Elisa S. Ferreira,&nbsp;Juliana S. Bernardes","doi":"10.1002/adsu.202570053","DOIUrl":"https://doi.org/10.1002/adsu.202570053","url":null,"abstract":"<p><b>Sustainable Antistatic Cryogels</b></p><p>The image shows a sustainable antistatic cryogel made of cationic cellulose and carbon black, designed to protect electronics from electrostatic discharge (ESD) and fire hazards. Sparks illustrate ESD generated when a hand nears the microchip, while flames below the packaging highlight its flame retardancy. More details can be found in article number 2400991 by Juliana S. Bernardes and co-workers.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 5","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202570053","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144171760","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Triboelectrification Based on the Waste Waterproof Textiles for Multisource Energy Harvesting (Adv. Sustainable Syst. 5/2025)","authors":"Kushal Ruthvik Kaja,&nbsp;Sugato Hajra,&nbsp;Swati Panda,&nbsp;Mohamed A. Belal,&nbsp;Phakkhananan Pakawanit,&nbsp;Naratip Vittayakorn,&nbsp;Chris Bowen,&nbsp;Hamideh Khanbareh,&nbsp;Hoe Joon Kim","doi":"10.1002/adsu.202570051","DOIUrl":"https://doi.org/10.1002/adsu.202570051","url":null,"abstract":"<p><b>Multisource Energy Harvesting</b></p><p>In article number 2400678, Sugato Hajra, Hoe Joon Kim, and co-workers turn discarded waterproof textiles into innovative energy solutions. By creating triboelectric nanogenerators from waste, they harness wind, water, and motion to power sensor networks. This eco-friendly tech reduces waste and promotes sustainable energy in daily life.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 5","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202570051","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144171777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Solid-State and Sustainable Batteries","authors":"Jie Zhao,&nbsp;Yun Song,&nbsp;Junyu Hou,&nbsp;Shubin Yang,&nbsp;Yongji Gong","doi":"10.1002/adsu.202500425","DOIUrl":"https://doi.org/10.1002/adsu.202500425","url":null,"abstract":"&lt;p&gt;The acceleration of the global carbon neutrality agenda is driving the transformation of energy storage technologies. As a result, the battery field is undergoing a paradigm shift from singular performance advantage to synergistic development of multiple aspects of efficiency, safety, and environmental friendliness. This special issue of the journal Advanced Sustainable Systems focuses on solid-state and sustainable batteries, systematically demonstrating how synergistic interactions between material innovations, structural engineering, and system architecture are key to overcoming the existing technological constraints.&lt;/p&gt;&lt;p&gt;This special issue contains 13 papers about the design and development of electrodes, electrolytes, and their interfaces in solid-state and sustainable lithium/sodium-ion (Li&lt;sup&gt;+&lt;/sup&gt;/Na&lt;sup&gt;+&lt;/sup&gt;) batteries, as well as wearable batteries. We would like to express our sincere thanks to all authors who have contributed to this special issue. A summary of all 13 accepted papers is provided as follows.&lt;/p&gt;&lt;p&gt;In terms of synergistic optimization of material systems, the fields of electrodes and electrolytes show a multifaceted innovation trend. For electrodes, Luo et al. (202300233) presented a novel Na&lt;sub&gt;4&lt;/sub&gt;MnCr(PO&lt;sub&gt;4&lt;/sub&gt;)&lt;sub&gt;3&lt;/sub&gt;/C@KB composite, which enhances rate capability and capacity retention through improved conductivity and electrolyte infiltration. Benefiting from an increase of electronic conductivity and an adequate infiltration of electrolyte by substantial pores existence in carbon layer, this novel Na&lt;sub&gt;4&lt;/sub&gt;MnCr(PO&lt;sub&gt;4&lt;/sub&gt;)&lt;sub&gt;3&lt;/sub&gt;/C@KB composite material exhibits improved rate capability of 61.2 mAh g&lt;sup&gt;−1&lt;/sup&gt; at 2 C compared to 19.5 mAh g&lt;sup&gt;−1&lt;/sup&gt; of Na&lt;sub&gt;4&lt;/sub&gt;MnCr(PO&lt;sub&gt;4&lt;/sub&gt;)&lt;sub&gt;3&lt;/sub&gt;/C and high reversible capacity of 88.0 mAh g&lt;sup&gt;−1&lt;/sup&gt; at 1 C with 73% capacity retention after 100 cycles. Gong et al. reported one type of one-dimensional (1D) sulfur chain encapsulated in SWCNTs (S@SWCNTs), which was designed as the cathode for lithium-sulfur (Li–S) batteries (202300308). Experimental studies and density functional theory calculations reveal the suppressed shuttle effect and the accelerated sulfur reduction kinetics in S@SWCNTs cathodes with the spatial confinement effect of SWCNTs. Thus, the S@SWCNTs as the self-supporting cathodes can exhibit capacity retention of 94% after 100 cycles with a high sulfur loading of 5.84 mg cm&lt;sup&gt;−2&lt;/sup&gt; and low E/S (electrolyte/sulfur) ratio of 4.3 µL mg&lt;sup&gt;−1&lt;/sup&gt;, promising for high energy-density batteries. Zhang and co-workers reported a Ru/Al dual doping strategy to enhance the cycling stability of LiCoO&lt;sub&gt;2&lt;/sub&gt; under high-voltage operation by synergistically reconfiguring the electronic structure and stabilizing the lattice framework (202300325). Consequently, an initial capacity of 197 mAh g&lt;sup&gt;−1&lt;/sup&gt; and 86% capacity retention after 100 cycles were achieved from 3.00 to 4.53 V vs Li&lt;sup&gt;+&lt;/sup&gt;/Li.&lt;","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 7","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202500425","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144680995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Surface Reconstruction in Precious and Non-Precious Metal-Based Electrocatalysts for Oxygen Evolution Reaction: A pH-Dependent Perspective","authors":"Jie Huang,&nbsp;Zhiyin Huang,&nbsp;Junda Chen,&nbsp;Ruiming Zhang,&nbsp;Manrou Huang,&nbsp;Yuxin Liu,&nbsp;Lixin Xing,&nbsp;Siyu Ye,&nbsp;Lei Du","doi":"10.1002/adsu.202500047","DOIUrl":"https://doi.org/10.1002/adsu.202500047","url":null,"abstract":"<p>Extracting hydrogen by electrochemical water splitting is the most important pathway for green hydrogen production at present whereas the corresponding anodic oxygen evolution reaction (OER) catalysts usually suffer from harsh high-potential conditions, either acidic or alkaline, leading to performance degradation and surface reconstruction. Importantly, the surface reconstruction upon some catalysts may lead to a misinterpretation of the true active centers, thereby impeding the rational design of catalysts. Consequently, understanding the dynamic evolution of catalyst surface reconstruction during OER is essential. This paper reviews the recent research progress on the surface reconstruction of both precious-metal and non-precious-metal catalysts across wide pH, i.e., under acidic and alkaline conditions, and highlights the differences between them. In addition, an analysis of the underlying causes for catalyst surface reconstruction and the impact factors that greatly influence these processes are presented. Finally, based on these discussions, perspectives for the rational design of OER catalysts are proposed.</p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 6","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144367375","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ni Foam Supported Pd-Doped Zinc Spinel Oxide Nano-Electrocatalyst for Efficient Hydrogen Production Supported by DFT Study as Well Validated With Experimental Data","authors":"Refah S. Alkhaldi,&nbsp;Mubarak A. Abdulwahab,&nbsp;Mohammed A. Gondal,&nbsp;Mohamed Jaffer Sadiq Mohamed,&nbsp;Munirah A. Almessiere,&nbsp;Abdulhadi Baykal,&nbsp;Abduljabar Alsayoud","doi":"10.1002/adsu.202500142","DOIUrl":"https://doi.org/10.1002/adsu.202500142","url":null,"abstract":"<p>An innovative palladium-doped zinc cobalt oxide nanoelectrocatalyst, ZnPd_xCo_2-xO₄ (0.00 ≤ x ≤ 0.08)@NF, is successfully synthesized using a hydrothermal method. The resulting material exhibits a spinel oxide phase, as confirmed by X-ray diffraction (XRD). The electrocatalytic performance of ZnPd_xCo_2-xO₄ (0.00 ≤ x ≤ 0.08)@NF is evaluated for the hydrogen evolution reaction (HER). The results show significant improvements in efficient hydrogen production, with an overpotential of 31 mV, a Tafel slope of 54.36 mV dec⁻¹, and sustained stability for over 72 h, using chronopotentiometry methods. Doping with 8.0% Pd concentration enhances the highest electrochemical performance of the nanoelectrocatalyst, supporting the idea that Pd doping improves HER activity. The results suggest that the increased electrochemical active surface area (ECSA) and faster charge transfer kinetics at the interface between the semiconductor and electrolyte contribute to enhanced performance. The DFT calculations performed in this work confirm the role of Pd in improving the catalytic activity of the ZnCo₂O₄ spinel catalyst. Overall, this study has made a significant contribution to the development of sustainable energy solutions, offering a promising path toward the efficient production of hydrogen fuel.</p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 6","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144367334","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Rigid Macroporous Wood Microparticles Impart Universality and Scalability to Lightweight Foam Insulation","authors":"Elizabeth Dobrzanski,&nbsp;Jonas Schnell,&nbsp;Weijia Zhang,&nbsp;Elisa S. Ferreira,&nbsp;Janne Keränen,&nbsp;Prashant Agrawal,&nbsp;Yufeng Yuan,&nbsp;Richard Chen,&nbsp;Praphulla Tiwary,&nbsp;Emily D. Cranston","doi":"10.1002/adsu.202400986","DOIUrl":"https://doi.org/10.1002/adsu.202400986","url":null,"abstract":"<p>Foam-formed nonwoven materials have recently experienced a surge in popularity, but research focuses on flexible fibres with scant information on rigid particles. This work showcases how rigid, minimally-processed, macroporous wood microparticles work synergistically with the foam-forming method to offer a robust manufacturing strategy that is insensitive to feedstock and water quality. Lightweight oven-dried foams suitable for rigid thermal insulation are produced using four types of wood residue and can be made using ocean water instead of ultrapure water. The bio-based content in the foam can be increased by partially/fully replacing the polymer binder with mechanical pulp or using a biosurfactant. For the 15 foams produced with slightly modulated compositions, the densities are low (90–130 kg m⁻³), the thermal conductivities are low (38–45 mW m⁻¹ K⁻¹), and many meet ASTM insulation standards for compressive strength. Pilot plant scaling produced large-scale (100×50×4 cm) foam boards. The structure-property relationships elucidated offer new guidelines to optimize foam performance by matching microparticle size to bubble size, having a distribution of microparticle lengths, and preserving wood's natural macroporous character. This work demonstrates how to harness the functionality that nature has already engineered for plants in the design of novel, sustainable and advanced bioproducts.</p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 6","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202400986","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144367549","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Tailored Brønsted Acidic Sites Anchored Over Covalent Organic Framework and Its Potential in Acid-Catalyzed Reactions","authors":"Sudip Bhattacharjee,&nbsp;Santu Ruidas,&nbsp;Bhabani Malakar,&nbsp;Sumanta Mondal,&nbsp;Sasanka Dalapati,&nbsp;Asim Bhaumik","doi":"10.1002/adsu.202500069","DOIUrl":"https://doi.org/10.1002/adsu.202500069","url":null,"abstract":"<p>For green chemical synthesis, designing a metal-free heterogeneous organocatalyst is very challenging as it offers an environment-friendly route over conventional metal-based catalysts. Covalent organic frameworks (COFs) have huge potential to be explored as heterogeneous organocatalysts because they contain several important features in one system, viz. high specific surface area, metal-free, desired organic functionalization, and outstanding stability. Herein, a ─SO₃H group anchored COF is synthesized, TFR-PDS-COF by employing a Schiff base extended condensation reaction. The material is highly crystalline in nature, exhibiting moderate BET surface area (115 m² g⁻¹) and very high NH₃ uptake capacity (1045 µmol g⁻¹). The high chemisorption property toward NH₃ suggests the highly acidic nature of the material, which motivate to explore it in the acid-catalyzed reaction. Initially, the amination of epoxide, which is a classic example of an acid-catalyzed epoxide activation reaction is chosen. TFR-PDS-COF exhibit good catalytic activity toward the amination of epoxides to β-amino alcohol synthesis for both simple and complex systems at room temperature under solvent-free conditions. The catalyst exhibits high recyclability for several cycles with the retention of its framework. The catalyst has been employed for other acid catalytic reactions such as cycloaddition and acetalization reactions, and displays excellent conversion with high selectivity. All of these results suggest that TFR-PDS-COF is a potential candidate for large-scale and highly sustainable acid-catalytic reactions.</p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 6","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144367547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Thermal Management Performances of Low Environmental-Impact Metallocene-Catalyzed Poly-α-Olefin (mPAO) Liquid for High-Power-Density Applications","authors":"Yuchen Li,&nbsp;Derya Baran,&nbsp;Dachang Du,&nbsp;Dongchu Wei,&nbsp;Xiaojing Lu,&nbsp;Hanying Li,&nbsp;Wee-Liat Ong","doi":"10.1002/adsu.202500015","DOIUrl":"https://doi.org/10.1002/adsu.202500015","url":null,"abstract":"<p>Direct-contact liquid cooling has emerged as one of the most effective thermal management techniques for high-power-density applications. In this study, key physical properties, including density, viscosity, heat capacity, and thermal conductivity are experimentally measured and simulated for three different metallocene-catalyzed poly-α-olefin (mPAO) with different branch lengths and numbers. The results indicate minimal differences in density, heat capacity, and thermal conductivity, but a significant change in the viscosity, with longer and more branched molecules exhibiting higher viscosity. A comparative analysis with common coolants highlights mPAO's superior heat transfer and environmental attributes, positioning it as a competitive environmentally friendly coolant. Using molecular dynamics simulations, mPAO's convective heat transfer behavior of mPAOs in nanochannels is examined to discover enhanced convective heat transfer with increased wall-liquid atomic interactions and reduced liquid inter-molecular interactions. These enhancements arise from the denser atomic arrangement in the liquid and closer proximity to the wall. The results indicate that for forced convection under laminar flow in smooth-walled nanochannels, the Nusselt number depends only on the normalized Kapitza length. It is independent of wall and liquid materials.</p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 6","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144367566","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}