Advanced Sustainable Systems最新文献

{"title":"Antistatic, Flame-Retardant, and Mechanically Resistant Cellulose/Carbon Black Cryogels for Electrostatic Discharge Packaging (Adv. Sustainable Syst. 5/2025)","authors":"Gabriele Polezi,&nbsp;Diego M. Nascimento,&nbsp;Elisa S. Ferreira,&nbsp;Juliana S. Bernardes","doi":"10.1002/adsu.202570053","DOIUrl":"https://doi.org/10.1002/adsu.202570053","url":null,"abstract":"<p><b>Sustainable Antistatic Cryogels</b></p><p>The image shows a sustainable antistatic cryogel made of cationic cellulose and carbon black, designed to protect electronics from electrostatic discharge (ESD) and fire hazards. Sparks illustrate ESD generated when a hand nears the microchip, while flames below the packaging highlight its flame retardancy. More details can be found in article number 2400991 by Juliana S. Bernardes and co-workers.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 5","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202570053","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144171760","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Triboelectrification Based on the Waste Waterproof Textiles for Multisource Energy Harvesting (Adv. Sustainable Syst. 5/2025)","authors":"Kushal Ruthvik Kaja,&nbsp;Sugato Hajra,&nbsp;Swati Panda,&nbsp;Mohamed A. Belal,&nbsp;Phakkhananan Pakawanit,&nbsp;Naratip Vittayakorn,&nbsp;Chris Bowen,&nbsp;Hamideh Khanbareh,&nbsp;Hoe Joon Kim","doi":"10.1002/adsu.202570051","DOIUrl":"https://doi.org/10.1002/adsu.202570051","url":null,"abstract":"<p><b>Multisource Energy Harvesting</b></p><p>In article number 2400678, Sugato Hajra, Hoe Joon Kim, and co-workers turn discarded waterproof textiles into innovative energy solutions. By creating triboelectric nanogenerators from waste, they harness wind, water, and motion to power sensor networks. This eco-friendly tech reduces waste and promotes sustainable energy in daily life.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 5","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202570051","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144171777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Eco-Friendly Deposition of Catalyst-Free Graphene on Diverse Substrates (Adv. Sustainable Syst. 4/2025)","authors":"Ahmed Kotbi,&nbsp;Michael Lejeune,&nbsp;Hamid Oughaddou,&nbsp;Nitul Rajput,&nbsp;Xiao Zhang,&nbsp;Jamal Belhadi,&nbsp;Yahya Zakaria,&nbsp;Damien Richert,&nbsp;François Piquemal,&nbsp;Jose Morán-Meza,&nbsp;Mimoun El Marssi,&nbsp;Mustapha Jouiad","doi":"10.1002/adsu.202570043","DOIUrl":"https://doi.org/10.1002/adsu.202570043","url":null,"abstract":"<p><b>Catalyst-Free Graphene Growth</b></p><p>In article number 2500105, Mustapha Jouiad and co-workers present an environmentally friendly and catalyst-free method for depositing high-quality graphene on various substrates, using ethylene as the sole carbon source. Using low-pressure electrochemical vapor deposition at room temperature, followed by flash annealing, the approach allows direct deposition without a complex transfer process. The resulting graphene films, 3–10 layers, exhibit excellent conductivity, opening promising prospects for sustainable graphene applications.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 4","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202570043","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143840732","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Upcycling Industrial Biomass Wastes Into Aerogels Using Zinc Chloride Salt Hydrates (Adv. Sustainable Syst. 4/2025)","authors":"Mairui Zhang,&nbsp;Yang Liao,&nbsp;Nara Han,&nbsp;Seoku Lee,&nbsp;Gyu Leem,&nbsp;Kwang Ho Kim,&nbsp;Xuejun Pan,&nbsp;Jeong Jae Wie,&nbsp;Chang Geun Yoo","doi":"10.1002/adsu.202570041","DOIUrl":"https://doi.org/10.1002/adsu.202570041","url":null,"abstract":"<p><b>Upcycling Industrial Biomass Waste</b></p><p>This cover image demonstrates an innovative method to upcycle unrecyclable biomass waste, such as food packaging and rejected fibers, into high-performance aerogels using zinc chloride salt hydrate. The process eliminates the need to separate impurities, which instead enhances the aerogel's mechanical and thermal properties. More details of this work can be found in article number 2400688 by Jeong Jae Wie, Chang Geun Yoo, and co-workers.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 4","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202570041","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143840731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Strategies Toward the Production of Nanoporous SiOx/C Anodes from the Sustainable Diatom-SiO2 for Li-Ion Batteries: A Comparative Study of Different Carbon Amounts","authors":"Anders Gaarud,&nbsp;Kesavan Thangaian,&nbsp;Pedro Alonso-Sánchez,&nbsp;Maria Valeria Blanco","doi":"10.1002/adsu.202500117","DOIUrl":"https://doi.org/10.1002/adsu.202500117","url":null,"abstract":"<p>Nanostructured <i>SiO_x</i>/C composites are promising candidates for high energy density anodes with extended lifespan in next-generation Li-ion batteries (LIBs). However, integrating sustainable precursors for the synthesis of high performance <i>SiO_x</i>/C negative electrodesremains a key challenge. In this study, nanoporous <i>SiO</i>₂ derived from the shells of industrially cultured diatom microalgae is successfully used as a template for synthesizing <i>SiO_x</i> via the magnesiothermic reduction reaction (MgTR), while the effectiveness of different carbon coating (CC) strategies to produce diatom-<i>SiO_x</i>/C from glucose as carbon precursor is thoroughly analyzed. Notably, the original nanostructure of the diatom-<i>SiO</i>₂ frustule is preserved throughout the synthesis process, and it is demonstrated that increasing the heating ramp during MgTR enhances the Si yield, leading to a significant increase in specific capacity of the anodes from 1064 mAh.g⁻¹ (2 °C/min⁻¹) to 1846 mAh.g⁻¹ (20 °C/min⁻¹). A comparative analysis of three synthesis pathways for producing diatom-<i>SiO_x</i>/C composites: 1) MgTR of diatom-<i>SiO</i>₂ followed by CC, 2) CC of diatom-<i>SiO</i>₂ followed by MgTR, and 3) simultaneous reduction of diatom-<i>SiO</i>₂ and glucose precursor, revealed that pathway (1) is most effective for producing highcapacity diatom-<i>SiO_x</i>/C anodes. These findings provide key enablers for developing sustainable <i>SiO_x</i>/C anodes of superior electrochemical performance.</p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 5","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144171995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Global Warming Potential of Geoengineering via Radiative Cooling","authors":"Atousa Pirvaram,&nbsp;Siu Ning Leung,&nbsp;Paul G. O'Brien","doi":"10.1002/adsu.202400948","DOIUrl":"https://doi.org/10.1002/adsu.202400948","url":null,"abstract":"<p>This paper analyzes the potential to mitigate global warming using radiative cooling (RC) surfaces on a large scale. The study evaluates the net cooling power, radiative forcing (RF), and global warming potential of different RC materials compared to conventional construction and roofing materials, Earth's natural surfaces, and some reference cases. Key parameters for evaluating the above-mentioned structures include their solar reflectance (albedo) and long-wavelength infrared emissivity. Results show the cooling power that can be achieved by an ideal RC material with a solar reflectance of 100% and long-wave infrared emissivity of 100% is 164.8 W·m⁻². In practice, materials exhibiting a cooling power as high as 160.8 W·m⁻² are fabricated. Further analysis shows if 1% of Earth's surface are to be covered with this material the terrestrial RF will decrease by 1.61 W·m⁻² (from 0.6 to −1.01 W·m⁻²). The results demonstrate that RC materials with high solar reflectivity and emissivity offer substantial cooling benefits and can reduce RF when implemented on large scales. The findings underscore the effectiveness of RC materials in reducing global warming and provide a valuable perspective on their role in reducing the environmental impacts of the built environment.</p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 5","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202400948","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144171275","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advancing Molten Alkali Borate Sorbents for High-Temperature Carbon Capture by Structural Elucidation of the Ionic-Oxide Reaction Mechanism","authors":"David Unnervik,&nbsp;Takuya Harada","doi":"10.1002/adsu.202400969","DOIUrl":"https://doi.org/10.1002/adsu.202400969","url":null,"abstract":"<p>The structural complexity of alkali borates, evident in the wide range of distinct structures that typically comprise these compounds, is responsible for the significant differences observed in the physicochemical properties of their corresponding melts. In this work, the structural transformations arising from carbon capture using molten lithium-sodium orthoborate ((Li_0.5Na_0.5)₃BO₃), a promising new alkali borate sorbent for carbon capture, are investigated to better understand the evolution of various physicochemical properties of the melt by employing in situ high-temperature Fourier transform infrared spectroscopy in conjunction with density functional theory. The carbon capture mechanism is shown to proceed via polymerization of small orthoborate segments (BO₃^{3 −}) into larger structural units, ultimately reaching the metaborate composition (<span></span><math>\u0000 <semantics>\u0000 <msubsup>\u0000 <mi>BO</mi>\u0000 <mn>2</mn>\u0000 <mo>−</mo>\u0000 </msubsup>\u0000 <annotation>${rm BO}_2^-$</annotation>\u0000 </semantics></math>) in the form of Li₃NaB₄O₈ and Na₃B₃O₆ upon complete CO₂ saturation. The introduction of carbonate ions in the non-polymerized orthoborate melt via CO₂-capture has a substantial diluting effect on the density and viscosity of the resulting polymerized CO₂-saturated melt. Investigations into the melting points associated with the various compounds involved in the capture mechanism and the discovery of an apparent second-order phase transition of lithium-sodium pyroborate (Li₂Na₂B₂O₅) past 520 °C further provide new and valuable information as to potential energetically favorable operating conditions for this absorber/regenerator-based carbon capture technology.</p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 5","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202400969","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144171276","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unveiling the Synergistic Coupling Between Nickel Phosphide and Graphitic Carbon Nitride for Sustainable Catalytic Transfer Hydrogenation of Quinoline: Ensemble and Ligand Effects","authors":"Devendra Sharma,&nbsp;Priyanka Choudhary,&nbsp;Sajjan Sheoran,&nbsp;Sahil Kumar,&nbsp;Saswata Bhattacharya,&nbsp;Venkata Krishnan","doi":"10.1002/adsu.202401006","DOIUrl":"https://doi.org/10.1002/adsu.202401006","url":null,"abstract":"<p>In recent years, metal phosphide catalysts have garnered immense attention among the catalysis community due to their facile synthesis and excellent catalytic activity but their promising potential in the field of organic transformation is not been fully explored. The synergistic coupling between the metal phosphide and the support material plays a crucial role in enhancing the overall catalytic activity as well as the recovery of the catalyst. Herein, this study reports nickel phosphide (Ni₂P) and graphitic carbon nitride (GCN) nanosheets as an interfacial catalyst for the effective and efficient transfer hydrogenation of quinoline. The significance of the developed interface between Ni₂P and GCN is revealed by the detailed spectroscopic and theoretical investigations, which enhances the dissociation of hydrogen source and the substrate interaction with the surface of the catalyst, thereby enhancing the selective transformation of quinoline to 1,2,3,4-tetrahydroquinoline. In the proposed transfer hydrogenation protocol for quinoline, formic acid is utilized as a bio-renewable hydrogen source, which serves as a potential replacement for molecular hydrogen. Further, detailed optimization studies are carried out to achieve good selectivity and product yield by varying reaction parameters. Therefore, using detailed mechanistic studies, the nickel phosphide supported on graphitic carbon nitride (Ni₂P-GCN) catalyst provides a promising reaction protocol for the transfer hydrogenation of quinoline.</p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 5","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144171319","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Cr6+ Loaded Lewis Acidic Sn-Beta Zeolites as Reusable Catalysts for Selective Production of Light Olefins via Polyolefin Cracking (Adv. Sustainable Syst. 3/2025)","authors":"Shinya Kokuryo,&nbsp;Soshi Tsubota,&nbsp;Koji Miyake,&nbsp;Yoshiaki Uchida,&nbsp;Atsushi Mizusawa,&nbsp;Tadashi Kubo,&nbsp;Norikazu Nishiyama","doi":"10.1002/adsu.202570031","DOIUrl":"https://doi.org/10.1002/adsu.202570031","url":null,"abstract":"<p><b>Reusable Catalysts</b></p><p>In article number 2400625, Shinya Kokuryo, Koji Miyake, and co-workers show that Cr⁶⁺ loaded Lewis acidic Sn-Beta zeolites are hardly deactivated and produce light olefins selectively and repeatedly from LDPE cracking without oxidative regeneration.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 3","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202570031","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143689443","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Electrodeposition of Carbon-Trapping Minerals in Seawater for Variable Electrochemical Potentials and Carbon Dioxide Injections (Adv. Sustainable Syst. 3/2025)","authors":"Nishu Devi,&nbsp;Xiaohui Gong,&nbsp;Daiki Shoji,&nbsp;Amy Wagner,&nbsp;Alexandre Guerini,&nbsp;Davide Zampini,&nbsp;Jeffrey Lopez,&nbsp;Alessandro F. Rotta Loria","doi":"10.1002/adsu.202570033","DOIUrl":"https://doi.org/10.1002/adsu.202570033","url":null,"abstract":"<p><b>Seawater Electrolysis</b></p><p>In article number 2400943, Alessandro F. Rotta Loria and co-workers present an electrochemical approach to synthesize mineral aggregates of variable compositions, structures, shapes, and sizes in seawater while absorbing sequestered CO₂. This work advances the understanding of electrochemical synthesis and material processing in aqueous solutions, with a focus on the mineralization of calcareous compounds for use in the construction, manufacturing, and environmental protection industries.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 3","pages":""},"PeriodicalIF":6.5,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202570033","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143689444","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}