Advanced Sustainable Systems最新文献

筛选
英文 中文
Hydrochar Utilization for Saline‐Alkali Soil Amelioration and Its Carbon Sequestration Potential Assessment 利用水碳改良盐碱地及其碳固存潜力评估
IF 7.1 3区 材料科学
Advanced Sustainable Systems Pub Date : 2024-08-05 DOI: 10.1002/adsu.202400290
Jia Shen, Zili Jiang, Zhichao Tang, Fanke Guo, Hongyun Shao, Xiuxiu Ruan
{"title":"Hydrochar Utilization for Saline‐Alkali Soil Amelioration and Its Carbon Sequestration Potential Assessment","authors":"Jia Shen, Zili Jiang, Zhichao Tang, Fanke Guo, Hongyun Shao, Xiuxiu Ruan","doi":"10.1002/adsu.202400290","DOIUrl":"https://doi.org/10.1002/adsu.202400290","url":null,"abstract":"For the current situation of saline‐alkali soil amelioration, it is urgent to explore a multi‐objective amelioration strategy involving crop income increase and environmental benefits. This study used pine‐needle hydrochar to ameliorate saline‐alkali soil and conducted column and pot experiments to investigate its effects on soil properties and crop growth. And the environmental advantages of hydrochar are evaluated through Life Cycle Assessment (LCA). The electrical conductivity, exchangeable sodium percentage, and pH of saline‐alkali soil ameliorated with hydrochar using the column elution method are reduced by 60%, 58%, and 1.2 pH units, respectively, compared to the original soil. Also, the gene copy number of the ameliorated soil has doubled according to qPCR determination. Pot experiment results show that the root length, fresh weight, and germination rate of wheatgrass are increased by 107, 75, and 20%, respectively. These results demonstrated that the exchange of Na<jats:sup>+</jats:sup> with H<jats:sup>+</jats:sup> released from hydrochar reduced the soil alkalinity and the viability of organisms is enhanced. Moreover, based on this study's data including the hydrochar dosage and wheatgrass yield, the LCA results showed 3.7 × 10<jats:sup>9</jats:sup> t CO<jats:sub>2</jats:sub>e carbon sequestration potential and significant environmental benefits.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141946370","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enabling Fast Ionic Conductivity and Stable Interfaces of Composite Polymer Electrolytes by Incorporating Borohydride‐Oxide Dual Fillers for Solid State Lithium Metal Batteries 通过在固态金属锂电池中加入硼氢化氧化物双填料,实现复合聚合物电解质的快速离子传导性和稳定界面
IF 7.1 3区 材料科学
Advanced Sustainable Systems Pub Date : 2024-08-03 DOI: 10.1002/adsu.202400369
Shunqin Zeng, Kaixiang Ren, Xiaoli Ding, Hai‐Wen Li, Yongtao Li, Qingan Zhang
{"title":"Enabling Fast Ionic Conductivity and Stable Interfaces of Composite Polymer Electrolytes by Incorporating Borohydride‐Oxide Dual Fillers for Solid State Lithium Metal Batteries","authors":"Shunqin Zeng, Kaixiang Ren, Xiaoli Ding, Hai‐Wen Li, Yongtao Li, Qingan Zhang","doi":"10.1002/adsu.202400369","DOIUrl":"https://doi.org/10.1002/adsu.202400369","url":null,"abstract":"Poly ethylene oxide (PEO) composite polymer electrolytes (CPEs) are one of the most promising candidates for all‐solid‐state batteries with high energy density, flexibility and safety. However, the applications of PEO with practicability have been refrained from its poor tensile strength, limited Li‐ion migration and ionic conductivity. In this work, the compact and stable flexible CPEs are prepared by PEO matrix with dual‐fillers of LiBH4 and Al2O3, where Al2O3 with Lewis acid sites can weaken the complexation of Li+ and PEO as well as enhance the dissociation of Li salts. Meanwhile LiBH4 acts as fast ion conductor to provide free Li+ at the interfaces between fillers and PEO. Benefiting from their synergistic effects, both ionic conductivity and interface stability between electrolyte and anode of CPEs are improved greatly while the lithium dendrites is also inhibited. As a result, the PEO/Lithium bis(trifluoromethanesulfonyl)imide(LiTFSI)/(4%LiBH4/4%γ‐Al2O3) CPEs exhibit a high ionic conductivity of 0.3 mS cm−1 and the Li‐Li symmetrical battery can cycle for 800 h at 60 °C. The LiFePO4.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141946371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
All Bio‐Based µ‐Beads from Microalgae for Probiotics Delivery 用于输送益生菌的微藻生物基微胶囊
IF 7.1 3区 材料科学
Advanced Sustainable Systems Pub Date : 2024-08-02 DOI: 10.1002/adsu.202400384
Danilo Vona, Stefania Roberta Cicco, Flavia Maria la Forgia, Mirco Vacca, Annalisa Porrelli, Gianvito Caggiano, Maria De Angelis, Loreto Gesualdo, Gianluca Maria Farinola
{"title":"All Bio‐Based µ‐Beads from Microalgae for Probiotics Delivery","authors":"Danilo Vona, Stefania Roberta Cicco, Flavia Maria la Forgia, Mirco Vacca, Annalisa Porrelli, Gianvito Caggiano, Maria De Angelis, Loreto Gesualdo, Gianluca Maria Farinola","doi":"10.1002/adsu.202400384","DOIUrl":"https://doi.org/10.1002/adsu.202400384","url":null,"abstract":"The food of the future aims to offer several essential qualities: i) environmental respect in sourcing raw materials; ii) sustainable transformation processes; iii) enrichment with probiotic microorganisms; iv) biocompatible natural matrices. These features both enhance the nutritional value of the food and improve its pharmacological and immunological properties. When probiotics are introduced into gut in adequate densities through diet, they symbiotically promote health by boosting immune defense, producing beneficial organic molecules, and providing essential metabolic pathways for better nutrient assimilation and biotransformation. A major challenge with probiotics is their low resistance to gastrointestinal (GI) transit due to pH and other adverse hydro‐ionic conditions affecting their viability. Here, diatom microalgae (<jats:italic>Coscinodiscus granii</jats:italic>) is presented as a natural source of micro‐pills, functionalized with biopolymers (Shellac and Chitosan) for enteric protection, with a loading value of 71 ± 7%, higher in comparison with the loading capacity tested for two other commercial polymers. Moreover, biosilica embedded and sealed with the enteric polymers best‐protected probiotics under pH changes, and thermal and storage stresses by one‐fold more than the control probiotics without or with the lone shielding polymers. These work outcomes describe envisaging silica hybrid microcarriers obtained from living microalgae, effectively protecting probiotics in an entirely biological formulation.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141882980","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Thermodynamic‐Analysis‐Derived Structure Optimization on the Solar Thermal Localized Desalination and Water‐Treatments 基于热力学分析的太阳能热局部脱盐和水处理结构优化
IF 7.1 3区 材料科学
Advanced Sustainable Systems Pub Date : 2024-07-31 DOI: 10.1002/adsu.202400121
Yongchao Huang, Heyu Li, Yan Cao
{"title":"The Thermodynamic‐Analysis‐Derived Structure Optimization on the Solar Thermal Localized Desalination and Water‐Treatments","authors":"Yongchao Huang, Heyu Li, Yan Cao","doi":"10.1002/adsu.202400121","DOIUrl":"https://doi.org/10.1002/adsu.202400121","url":null,"abstract":"The solar thermal localization (STL) technology is promising and cost‐effective for desalination or wastewater treatments, but currently in an insufficient status on its structure optimization. This study emphasized the water‐cooled STL (WSTL) system and its step‐forward modifications, involving the air‐insulated WSTL (AWSTL) system and the vacuum WSTL (VWSTL) system, together with their thermodynamic modeling analysis on energy‐water conversions, heat‐mass transfers, and energy losses. Results indicated the best‐performing VWSTL mode can achieve a freshwater yield as high as 1.503 kg·m<jats:sup>−2</jats:sup>·h<jats:sup>−1</jats:sup> at energy efficiency of 68.0% (the light intensity at 1500 W·m<jats:sup>−2</jats:sup> indoor), and that of 4.31 kg·m<jats:sup>−2</jats:sup>·day<jats:sup>−1</jats:sup> at energy efficiency of 47.5% (the 8‐h averaged solar light intensity at 769.7 W·m<jats:sup>−2</jats:sup> outdoor per‐day) whose energy efficiency is exceeded all competitors in open literature. There likely is an improvement space in applying better evaporation materials.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141871121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Systematic Assessment of Mechanisms, Developments, Innovative Solutions, and Future Perspectives of Microplastics and Ecotoxicity – A Review 系统评估微塑料和生态毒性的机理、发展、创新解决方案和未来展望--综述
IF 7.1 3区 材料科学
Advanced Sustainable Systems Pub Date : 2024-07-30 DOI: 10.1002/adsu.202400294
S. Manikandan, B. Preethi, S. R. Deena, D. S. Vijayan, R. Subbaiya, Sundaram Vickram, N. Karmegam, Woong Kim, M. Govarthanan
{"title":"Systematic Assessment of Mechanisms, Developments, Innovative Solutions, and Future Perspectives of Microplastics and Ecotoxicity – A Review","authors":"S. Manikandan, B. Preethi, S. R. Deena, D. S. Vijayan, R. Subbaiya, Sundaram Vickram, N. Karmegam, Woong Kim, M. Govarthanan","doi":"10.1002/adsu.202400294","DOIUrl":"https://doi.org/10.1002/adsu.202400294","url":null,"abstract":"As plastics become more ubiquitous, their impact on the environment and on human health cannot be overlooked. Once generated, micro‐ and nano‐plastics end‐up in the environment, causing widespread health and environmental risks. This is a significant environmental problem given the minuscule sizes of microplastics, and therefore warrants further investigation. This study presents a comprehensive review of the ecotoxicology of microplastics and methods for their degradation and decomposition besides discussing the fate and transport processes, recent progress, emerging strategies, challenges and potential future directions. The authors carefully evaluate the processes through which microplastics cause harm, from molecular interactions in species, to ecological impacts, and end with advances in microplastic biodegradation. Different kinds of microplastics found in the environment include polyethylene, polystyrene, polypropylene, polyvinyl chloride, polycarbonate, polyurethane, polypropylene, and polyethylene terephthalate. Analysis of microbial and enzymatic decomposition provides several swelling mitigation strategies designed to reduce environmental threats. In‐depth investigations of microplastic ecotoxicity and biodegradation are being facilitated by interdisciplinary proposals in the areas of nanotechnology, new analytical methods, and synthetic biology. The extensive study helps understand microplastics comprehensively which in‐turn ensures informed actions to mitigate the challenge of the environmental impact of microplastics for sustainable future.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141871122","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable Development of Biodegradable Antimicrobial Electrospun Membranes for Active Food Packaging and Economic Analysis 用于活性食品包装的可生物降解抗菌电纺丝膜的可持续发展和经济分析
IF 7.1 3区 材料科学
Advanced Sustainable Systems Pub Date : 2024-07-29 DOI: 10.1002/adsu.202400360
Emanuela Drago, Roberta Campardelli, Patrizia Perego
{"title":"Sustainable Development of Biodegradable Antimicrobial Electrospun Membranes for Active Food Packaging and Economic Analysis","authors":"Emanuela Drago, Roberta Campardelli, Patrizia Perego","doi":"10.1002/adsu.202400360","DOIUrl":"https://doi.org/10.1002/adsu.202400360","url":null,"abstract":"Electrospinning is a much‐explored technique in the membrane fabrication field, particularly in active food packaging. Despite the widespread use of this technique, there remains a significant gap in the literature regarding the actual economic evaluation of the viability of biomaterials compared to traditional plastics. This study seeks to fill this gap by developing electrospun, vanillin‐loaded zein membranes to evaluate their efficacy in terms of antimicrobial activity, biodegradability, and economic viability. From a sustainability perspective, the newly developed membranes show an impressive ability to inhibit yeast growth by 75%, with complete degradation observed in only 7 days. This underscores their potential to mitigate environmental impact and promote environmentally friendly packaging solutions to reduce both plastic waste and food loss while maintaining safety and quality. However, the economic sustainability of these membranes is still an open challenge. It becomes clear that the main bottleneck does not lie in the innovative production technology, but rather in the prices of raw materials, particularly natural additives. This underscores the need for supportive measures from institutions to incentivize the transition to sustainable packaging alternatives and the importance of the full circularity concept. This work shows that achieving the European goal of zero plastic waste requires concrete efforts.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141870973","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrasound-Assisted Deposition of Sepia Melanin and Multiwalled Carbon Nanotubes on Carbon Cloth: Toward Sustainable Surface Engineering for Flexible Supercapacitors 超声波辅助在碳布上沉积墨兰素和多壁碳纳米管:实现柔性超级电容器的可持续表面工程
IF 7.1 3区 材料科学
Advanced Sustainable Systems Pub Date : 2024-07-26 DOI: 10.1002/adsu.202400302
Molood Hoseinizadeh, Nila Davari, Abdelaziz Gouda, Hamza Hyat, Mohini Sain, Daria C. Boffito, Clara Santato
{"title":"Ultrasound-Assisted Deposition of Sepia Melanin and Multiwalled Carbon Nanotubes on Carbon Cloth: Toward Sustainable Surface Engineering for Flexible Supercapacitors","authors":"Molood Hoseinizadeh, Nila Davari, Abdelaziz Gouda, Hamza Hyat, Mohini Sain, Daria C. Boffito, Clara Santato","doi":"10.1002/adsu.202400302","DOIUrl":"https://doi.org/10.1002/adsu.202400302","url":null,"abstract":"The rising global demand for energy requires, among others, sustainable energy storage devices. Biosourced redox-active molecules are interesting for eco-designed electrochemical energy storage as they increase the energy density of the electrodes adding the Faradaic (redox) storage mechanism to the electrostatic one. The engineering of the electrode surface and electrode surface/molecule interface is key to optimizing storage. Here, (i) electrodes prepared by ultrasound-assisted modification of carbon cloth in the presence of Sepia melanin, a quinone macromolecule, and multiwalled carbon nanotubes (MWCNTs) and (ii) their use in flexible symmetric electrochemical capacitors assembled with polyvinyl alcohol (PVA)-based hydrogel electrolyte is reported. Electrodes exhibit an areal capacitance as high as 274 mF cm<sup>−2</sup>. Corresponding semi-solid-state symmetric supercapacitors feature high energy density of 18 W<i>h</i> kg<sup>−1</sup>, power density up to 221 W kg<sup>−1</sup> (evaluated at 0.5 A g<sup>−1</sup>), outstanding cycling stability (100% capacitance retention, and 100% Coulombic efficiency after 10 000 cycles) along with excellent flexibility. This work contributes to the development of sustainable surface engineering approaches for environmentally benign electrochemical energy storage devices.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141784771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced Efficient Solar Evaporation of Co/CoO Loaded on the Tobacco Stem Under Visible Light 在可见光下提高烟草茎秆上负载的 Co/CoO 的太阳能蒸发效率
IF 7.1 3区 材料科学
Advanced Sustainable Systems Pub Date : 2024-07-26 DOI: 10.1002/adsu.202400349
Yu Liu, Chunyan Zhang, Anlong Zhang, Jindi Zhang, Lili Zhang, Mengyang Huang, Jiaqiang Wang
{"title":"Enhanced Efficient Solar Evaporation of Co/CoO Loaded on the Tobacco Stem Under Visible Light","authors":"Yu Liu, Chunyan Zhang, Anlong Zhang, Jindi Zhang, Lili Zhang, Mengyang Huang, Jiaqiang Wang","doi":"10.1002/adsu.202400349","DOIUrl":"https://doi.org/10.1002/adsu.202400349","url":null,"abstract":"Solar‐driven water evaporation is an emerging technology in green technology of seawater desalination and sewage treatment. However, the quality of high cost, complex manufacturing, and a small amount of synthetic materials is the main obstacle to large‐scale applications. Biological carbon‐based materials have a large and efficient heat exchange area due to the naturally abundant pore structure, which plays an important role in regulating convection and radiant heat loss. However, single‐component carbon materials have limited photothermal conversion performance, which limits their large‐scale application. In this work, tobacco stem (TS) organisms loaded with Co/CoO nanoparticles are successfully prepared by one‐step pyrolysis. The synergistic effect of Co/CoO nanostructures and biocarbon materials enhances water evaporation performance, widening the absorption range of the material across the entire solar spectrum, and expanding the range of energy that can be converted into heat. Specifically, the water evaporation rate and photothermal conversion efficiency of TS ‐Co/CoO (0.20) reached 2.22 kg m<jats:sup>−2</jats:sup> h<jats:sup>−1</jats:sup> and 139.4%, respectively, and its evaporation rate is 1.7 times the direct carbonized tobacco and 4.35 times the pure water. This work provides a research idea for the multifunctional and effective utilization of waste biomass materials and the construction of bionic structure solar photothermal materials.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141769812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrochemical Deposition of Manganese Oxide on Paper‐Based Laser‐Induced Graphene for the Fabrication of Sustainable High‐Energy‐Density Supercapacitors 在纸基激光诱导石墨烯上电化学沉积氧化锰以制造可持续的高能量密度超级电容器
IF 7.1 3区 材料科学
Advanced Sustainable Systems Pub Date : 2024-07-25 DOI: 10.1002/adsu.202400254
Maykel dos Santos Klem, Rodrigo Abreu, Tomás Pinheiro, João Coelho, Neri Alves, Rodrigo Martins
{"title":"Electrochemical Deposition of Manganese Oxide on Paper‐Based Laser‐Induced Graphene for the Fabrication of Sustainable High‐Energy‐Density Supercapacitors","authors":"Maykel dos Santos Klem, Rodrigo Abreu, Tomás Pinheiro, João Coelho, Neri Alves, Rodrigo Martins","doi":"10.1002/adsu.202400254","DOIUrl":"https://doi.org/10.1002/adsu.202400254","url":null,"abstract":"Laser‐induced graphene (LIG) is widely used to fabricate microsupercapacitors (MSCs) on various sustainable substrates, such as wood, cork, and lignin. However, the fabrication of MSCs, especially high energy density devices on paper, has rarely been reported. In this work, LIG electrodes are fabricated on wax‐coated paper, followed by electrochemical deposition of manganese oxide (MnO<jats:sub>2</jats:sub>). The obtained LIG/MnO<jats:sub>2</jats:sub> supercapacitors exhibit a maximum areal capacitance of 86.9 mF cm<jats:sup>−2</jats:sup>, while a device with pristine LIG electrodes exhibit a capacitance of 9.1 mF cm<jats:sup>−2</jats:sup>, both measured at a current density of 0.1 mA cm<jats:sup>−2</jats:sup>. In addition, the supercapacitor exhibits good cycling stability, retaining 80% of its initial capacitance after 1000 charge/discharge cycles at a current density of 1 mA cm<jats:sup>−2</jats:sup>. Notably, the LIG/MnO<jats:sub>2</jats:sub> supercapacitor exhibits an exceptionally high energy density of 7.3 µWh cm<jats:sup>−2</jats:sup> at a power density of 38.8 µW cm<jats:sup>−2</jats:sup>. In summary, a simple, fast, scalable, reproducible, and energy‐efficient fabrication method is represented using electrochemical deposition of manganese oxide on paper‐based laser‐induced graphene, which are natural, abundant, and sustainable materials, paving the way for large‐scale production of environmentally friendly supercapacitors.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141769807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improving High‐Rate and Long‐Life Cycling of Li4Ti5O12 Anode by Dual Doping of Cd2+ and Ge4+ 通过 Cd2+ 和 Ge4+ 双掺杂提高 Li4Ti5O12 阳极的高倍率和长寿命循环性能
IF 7.1 3区 材料科学
Advanced Sustainable Systems Pub Date : 2024-07-25 DOI: 10.1002/adsu.202400337
Basit Ali, Raz Muhammad, Iqra Moeez, Jae‐Ho Park, Mobinul Islam, Min‐Kyung Cho, Ji‐Young Kim, Kyung Yoon Chung, Kyung‐Wan Nam
{"title":"Improving High‐Rate and Long‐Life Cycling of Li4Ti5O12 Anode by Dual Doping of Cd2+ and Ge4+","authors":"Basit Ali, Raz Muhammad, Iqra Moeez, Jae‐Ho Park, Mobinul Islam, Min‐Kyung Cho, Ji‐Young Kim, Kyung Yoon Chung, Kyung‐Wan Nam","doi":"10.1002/adsu.202400337","DOIUrl":"https://doi.org/10.1002/adsu.202400337","url":null,"abstract":"A kinetically favored Cd<jats:sup>2+</jats:sup> and Ge<jats:sup>4+</jats:sup> dual‐doped lithium titanate (Li<jats:sub>4</jats:sub>Ti<jats:sub>5</jats:sub>O<jats:sub>12</jats:sub>) anode material is designed for lithium‐ion batteries (LIBs). Rietveld refinement reveals that introducing a 0.05 wt.% of Cd<jats:sup>2+</jats:sup> at Li(8<jats:italic>a</jats:italic>) and Ge<jats:sup>4+</jats:sup> at Ti(16<jats:italic>d</jats:italic>) sites brings no structural change in the spinel Li<jats:sub>4</jats:sub>Ti<jats:sub>5</jats:sub>O<jats:sub>12</jats:sub>. Scanning transmission electron microscopy (STEM) identifies Cd<jats:sup>2+</jats:sup> and Ge<jats:sup>4+</jats:sup> are homogenously doped in the Li<jats:sub>4</jats:sub>Ti<jats:sub>5</jats:sub>O<jats:sub>12</jats:sub> lattice. High‐resolution powder diffraction (HRPD) confirmed that Cd<jats:sup>2+</jats:sup> and Ge<jats:sup>4+</jats:sup> doping in Li<jats:sub>4</jats:sub>Ti<jats:sub>5</jats:sub>O<jats:sub>12</jats:sub> brings expansion in the lattice, field emission scanning electron microscopy (FE‐SEM) shows the reduction in the particle size due to of Cd and Ge in the LTO lattice, and X‐ray photoluminescence spectroscopy (XPS) confirms the partial reduction of Ti<jats:sup>4+</jats:sup> to Ti<jats:sup>3+</jats:sup> ions on the surface of 0.05‐Cd‐Ge‐LTO electrodes to the pristine LTO. Furthermore, the 0.05‐Cd‐Ge‐Li<jats:sub>4</jats:sub>Ti<jats:sub>5</jats:sub>O<jats:sub>12</jats:sub> electrode exhibits a superior rate performance and delivers a discharge capacity of ≈169.1 mAhg<jats:sup>−1</jats:sup> at 0.1 current rates. It is worth mentioning that, the 0.05‐Cd‐Ge‐Li<jats:sub>4</jats:sub>Ti<jats:sub>5</jats:sub>O<jats:sub>12</jats:sub> electrode brings outstanding cycling stability in Li<jats:sup>+</jats:sup> half‐cell, having a capacity retention of 98.79% after 300 cycles at 2C. This proves that dual‐doping of Cd<jats:sup>2+</jats:sup> at Li(8<jats:italic>a</jats:italic>) and Ge<jats:sup>4+</jats:sup> at Ti(16<jats:italic>d</jats:italic>) sites in the Li<jats:sub>4</jats:sub>Ti<jats:sub>5</jats:sub>O<jats:sub>12</jats:sub> lattice is an effective approach to obtain superior electrochemical performance as anode material in LIBs.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":null,"pages":null},"PeriodicalIF":7.1,"publicationDate":"2024-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141769806","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信