Advanced Sustainable Systems最新文献_第6页

Sustainable Soft Electronics with Biodegradable Regenerated Cellulose Films and Printed Recyclable Silver Nanowires

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-12-16 DOI: 10.1002/adsu.202400713

Luz Meza, Darpan Shukla, Hasan Sadeghifar, Lilian Hsiao, Yong Zhu, Richard A. Venditti

{"title":"Sustainable Soft Electronics with Biodegradable Regenerated Cellulose Films and Printed Recyclable Silver Nanowires","authors":"Luz Meza, Darpan Shukla, Hasan Sadeghifar, Lilian Hsiao, Yong Zhu, Richard A. Venditti","doi":"10.1002/adsu.202400713","DOIUrl":"https://doi.org/10.1002/adsu.202400713","url":null,"abstract":"This study describes the production of biodegradable and recyclable flexible electronic devices created by screen-printing silver nanowires (AgNWs) onto regenerated cellulose films (RCFs). RCFs, derived from microcrystalline cellulose (MCC), are developed and further enhanced for flexibility with additives such as glycerol and poly(ethylene glycol) diglycidyl ether (PEGDE). The resulting cellulose films display relatively high tensile strength (up to 120 MPa), low Young's Modulus (down to 1500 MPa), and 90% optical transparency. Ink with AgNWs and poly(ethylene oxide) (PEO) as a binder is screen-printed on regenerated cellulose films. The printed AgNWs patterns exhibit high electrical conductivity, excellent electromechanical performance, and strong interfacial adhesion with RCFs. To demonstrate the application of printed AgNWs on RCFs for soft electronics, transparent conductive electrodes (TCEs) are fabricated. Grid and honeycomb structures are printed separately and evaluated in terms of sheet resistance and optical transparency. TCEs with ≈80% transparency and very low sheet resistance (0.045 Ω sq−1) are obtained. Furthermore, enzymatic hydrolysis of the cellulose substrate and the recovery for reuse of the AgNWs are demonstrated, showing the potential of integrating natural polymers and recyclable nanomaterials for eco-friendly and sustainable soft flexible electronics.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 2","pages":""},"PeriodicalIF":6.5,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143446693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Solar Cells Manufactured Using Concentrated Solar Energy Toward Carbon Neutralization

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-12-15 DOI: 10.1002/adsu.202400798

Shuang Liu, Jiajia Huang, Liang Tu, Xiaohui Liu, Jing Zhang, Yuejin Zhu, Like Huang

{"title":"Solar Cells Manufactured Using Concentrated Solar Energy Toward Carbon Neutralization","authors":"Shuang Liu, Jiajia Huang, Liang Tu, Xiaohui Liu, Jing Zhang, Yuejin Zhu, Like Huang","doi":"10.1002/adsu.202400798","DOIUrl":"https://doi.org/10.1002/adsu.202400798","url":null,"abstract":"The high photoelectric conversion efficiency (PCE) of solar cells and their environmentally friendly, low-carbon manufacturing processes are crucial for advancing carbon neutrality goals. This study introduces Fresnel lenses to focus sunlight for the sintering of mesoporous titanium dioxide (m-TiO2) layers as an innovative method for fabricating perovskite solar cells (PSCs), effectively circumventing the energy-intensive and carbon-emitting high-temperature furnace sintering traditionally required. Through this concentrated solar annealing technique, an efficient and eco-friendly sintering of the m-TiO2 layer is successfully achieved by removing organic residues from the precursor film and enhancing the film's transmittance, electrical conductivity, and grain size. Consequently, this has led to improved coverage of the perovskite layer and enhanced overall photovoltaic performance of the solar cells. Experimental results indicate that the m-TiO2 film subjected to 60 min of concentrated sunlight sintering (CSS) demonstrates optimal photovoltaic performance, with the fabricated compact-layer-free PSCs achieving an impressive photoelectric conversion efficiency of up to 17.69%. This research not only offers a novel, cost-effective approach for the sustainable production of PSCs but also contributes tangible solutions for the green transformation of the photovoltaic industry and the achievement of carbon neutrality. This work points the way toward using solar energy to prepare solar power generation devices.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 2","pages":""},"PeriodicalIF":6.5,"publicationDate":"2024-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143446835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synergistic Integration of a Ru(bda)-Based Catalyst in a Covalent Organic Framework for Enhanced Photocatalytic Water Oxidation

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-12-15 DOI: 10.1002/adsu.202400653

Marina Sicignano, Thomas Gobbato, Ruggero Bonetto, Paolo Centomo, Biagio Di Vizio, Federico De Biasi, Daniele Rosa-Gastaldo, Chiara Pierantoni, Alessandro Bonetto, Antonella Glisenti, Paolo Costa

{"title":"Synergistic Integration of a Ru(bda)-Based Catalyst in a Covalent Organic Framework for Enhanced Photocatalytic Water Oxidation","authors":"Marina Sicignano, Thomas Gobbato, Ruggero Bonetto, Paolo Centomo, Biagio Di Vizio, Federico De Biasi, Daniele Rosa-Gastaldo, Chiara Pierantoni, Alessandro Bonetto, Antonella Glisenti, Paolo Costa","doi":"10.1002/adsu.202400653","DOIUrl":"https://doi.org/10.1002/adsu.202400653","url":null,"abstract":"To address the urgent need for sustainable energy processes, there is a growing demand for multifunctional materials that mimic natural photosynthetic enzyme functions, specifically light-harvesting, efficient photoinduced charge separation, and integration of molecularly defined catalysts, synergistically interacting within these structures. Herein, the successful synthesis of an innovative Covalent Organic Framework (COF-TFPT-IsoQ) constructed from optically active triazine (TFPT) and isoquinoline units (IsoQ) as building blocks is reported. Post-synthetic incorporation of a Ru(bda)-based water oxidation catalyst (WOC) is achieved through the IsoQ moieties acting as coordinating sites. Leveraging the synthetic flexibility of the designed COF architecture featuring binding sites on its pore walls, various Ru@COF-TFPT-IsoQ systems at different Ru:COF ratios are synthesized and tested in the photoinduced (λ > 400 nm) oxygen evolution reaction (OER) under sacrificial conditions. All synthesized Ru@COF-TFPT-IsoQ systems demonstrate efficiency in the photocatalytic OER, with the highest turnover number (TON) of 9.1 observed for the system where the Ru-based WOC is incorporated every fourth COF-TFPT-IsoQ unit cell. This work provides valuable insights into the structural integration and catalytic behavior of Ru-based complexes within COF architectures, highlighting the potential of Ru@COF-TFPT-IsoQ as a robust, efficient, and synthetically flexible multifunctional material for light-induced water oxidation catalysis.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 2","pages":""},"PeriodicalIF":6.5,"publicationDate":"2024-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143446837","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effective Electrolyte Combination Composed of 1,1-Diethoxyethane and Lithium Bis(fluorosulfonyl)imide for Dendrite-suppressible Li Metal Anodes

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-12-15 DOI: 10.1002/adsu.202400680

Juhwi Park, Junyoung Mun, Taeeun Yim

{"title":"Effective Electrolyte Combination Composed of 1,1-Diethoxyethane and Lithium Bis(fluorosulfonyl)imide for Dendrite-suppressible Li Metal Anodes","authors":"Juhwi Park, Junyoung Mun, Taeeun Yim","doi":"10.1002/adsu.202400680","DOIUrl":"https://doi.org/10.1002/adsu.202400680","url":null,"abstract":"Although Li metal is considered the most promising anode material owing to its high theoretical capacity, there are numerous restrictions on expanding its application because of undesired surface reactions occurring at the Li anode. To solve this, an effective electrolyte combination consisting of 1,1-diethoxyethane (DEE) and lithium bis(fluorosulfonyl)imide (LiFSI) is used in this work, which can provide an organic/inorganic-hybridized solid-electrolyte interphase (SEI) at the Li anode. The DEE solvent affords flexible carbon-abundant components, whereas LiFSI offers mechanically rigid lithium fluoride-type components; these undergo electrochemical reduction to form SEI layers that are balanced in terms of organic and inorganic components. Systematic analysis results exhibit that when the SEI layer integrated with DEE and LiFSI is embedded in the lithium anode, electrolyte decomposition, and dendritic lithium growth are suppressed in Li/Li cells, thereby improving surface stability. Similarly, it provides stable cycle life characteristics even at 150 cycles in Li/S cells (72.0% vs 52.6%).","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 2","pages":""},"PeriodicalIF":6.5,"publicationDate":"2024-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143446832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A Study of the Reaction Kinetics and Solar Concentrator-Based Reactor Design for Photocatalytic Conversion of CO2 Into Fuel

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-12-11 DOI: 10.1002/adsu.202400732

Ragulkrishnan V., Ananya Mohanty, Aswathi P.K., Tiju Thomas, M.S. Srinivasan, Somnath C. Roy

{"title":"A Study of the Reaction Kinetics and Solar Concentrator-Based Reactor Design for Photocatalytic Conversion of CO2 Into Fuel","authors":"Ragulkrishnan V., Ananya Mohanty, Aswathi P.K., Tiju Thomas, M.S. Srinivasan, Somnath C. Roy","doi":"10.1002/adsu.202400732","DOIUrl":"https://doi.org/10.1002/adsu.202400732","url":null,"abstract":"Solar powered conversion of CO2 into fuel and other value-added chemicals is considered a holy grail toward a sustainable future. Development of materials that can catalytically convert CO2 and water vapor into hydrocarbons under sunlight has been one of the most formidable challenges in the 21st century. This study have recently demonstrates that by introducing hydrophilic and hydrophobic sites on nanostructured TiO2-reduced graphene oxide nanocomposite surfaces, yield of methane from photoreduction of CO2 can be enhanced by ≈30%. Here this study reports the study of reaction kinetics for TiO2-rGO photocatalysts through pressure and temperature dependent measurements of the product yield. By applying the Langmuir–Hinshelwood model on the pressure dependent CO2 conversion data, the reaction rates are calculated for selective adsorption of CO2 and H2O on the photocatalyst surface. These data are correlated with charge transport studies done through current-voltage (I–V) characteristics of the photocatalyst measured in presence of CO2 and H2O. On the other hand, a unique solar-concentrator based reactor design is developed. Such a prototype allows about a 20 °C rise in the temperature that enhances the rates of photocatalytic reactions. A comparative study of the CO2 photoreduction experiments in absence and in presence of the concentrated sunlight are presented.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 2","pages":""},"PeriodicalIF":6.5,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143446887","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Green Hydrogen and Its Supply Chain. A Critical Assessment of the Environmental Impacts

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-12-10 DOI: 10.1002/adsu.202400708

Antonella Sola, Roberto Rosa, Anna Maria Ferrari

引用次数: 0

Green Nanoengineered Keratin Derived Bio-Adsorbent for Heavy Metals Removal from Aqueous Media

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-12-08 DOI: 10.1002/adsu.202400491

Muhammad Zubair, M. S. Roopesh, Aman Ullah

{"title":"Green Nanoengineered Keratin Derived Bio-Adsorbent for Heavy Metals Removal from Aqueous Media","authors":"Muhammad Zubair, M. S. Roopesh, Aman Ullah","doi":"10.1002/adsu.202400491","DOIUrl":"https://doi.org/10.1002/adsu.202400491","url":null,"abstract":"Exploiting poultry chicken feathers, a keratin-rich by-product offers a sustainable raw material for bio-adsorbents in water remediation. This study developed a bio-adsorbent from chicken feathers keratin (CFK), functionalized with surface-modified graphene oxide (SMGO). The bio-adsorbent was tested for adsorbing metal cations (Pb, Cd, Ni, Zn, Co) and oxyanions (As, Se, Cr) from water contaminated with 600 µg/L of each metal at pH 5.5, 7.5, and 10.5. Results showed optimal removal efficiencies at pH 7.5, with anions achieving ≥91.10% for As (III), ≥89.55% for Cr (VI), and ≥74.33% for Se (IV). Cations removal reached 96.34% for Co (II), 97.36% for Ni (II), 99.03% for Cd (II), 99.21% for Pb (II), and 59.06% for Zn (II). Kinetic studies indicated rapid initial uptake within the first 6 hours, reaching equilibrium at 24 hours. The bio-adsorbent maintained high adsorption capacities over four regeneration cycles with minimal efficiency loss, showing strong stability and reusability. Removal efficiency followed the order: Pb (II) 〉 Cd (II) 〉 Ni (II) 〉 Co (II) 〉 Zn (II), correlating with their ionic radii. Ni2+ adsorbed more effectively than Co2+ due to a smaller ionic radius and stronger electrostatic attraction. These findings highlight CFK-SMGO's efficacy in wastewater treatment, promoting bio-based sustainable adsorbents.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 2","pages":""},"PeriodicalIF":6.5,"publicationDate":"2024-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202400491","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143446774","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sustainable Synthesis of Palladium-Immobilized Covalent Organic Frameworks: A One-step Sonochemical Strategy

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-12-08 DOI: 10.1002/adsu.202400700

Chelsea Harrod, Ziad Alsudairy, Qi Zheng, Allea Campbell, Normanda Brown, Md Hanif Uddin, Songliang Cai, Xinle Li

{"title":"Sustainable Synthesis of Palladium-Immobilized Covalent Organic Frameworks: A One-step Sonochemical Strategy","authors":"Chelsea Harrod, Ziad Alsudairy, Qi Zheng, Allea Campbell, Normanda Brown, Md Hanif Uddin, Songliang Cai, Xinle Li","doi":"10.1002/adsu.202400700","DOIUrl":"https://doi.org/10.1002/adsu.202400700","url":null,"abstract":"The rapid and environmentally benign synthesis of metal-immobilized covalent organic frameworks (metal/COFs) for heterogeneous catalysis is a pervasive challenge, as the mainstream synthesis is exceedingly time-consuming (up to four days) and demands the use of hazardous solvents. Herein, we describe a sustainable and efficient one-step sonochemical strategy for constructing diverse palladium (II)-immobilized COFs (Pd(II)/COFs). By merging the sonochemistry-assisted COF synthesis and in situ Pd (II) immobilization into a single step, this strategy enables the rapid formation of Pd(II)/COF hybrids within an hour under ambient conditions using water as the solvent. Notably, gram-scale synthesis of Pd(II)/COFs is achievable. The resulting Pd(II)/COFs exhibit superb crystallinity and high surface area, leading to remarkable activity, excellent functionality tolerance, and high recyclability for the Suzuki–Miyaura cross-coupling reaction of aryl bromides and arylboronic acids at room temperature. This one-step sonochemical strategy effectively addresses the long-lasting limitations of traditional multistep synthesis, paving a fast and sustainable avenue to diversified metal/COF hybrids for heterogeneous catalysis and potentially other applications.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 2","pages":""},"PeriodicalIF":6.5,"publicationDate":"2024-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143446775","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent Advances in the Synthesis and Application of TS-1 Zeolite for Green Catalytic Oxidation

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-12-08 DOI: 10.1002/adsu.202400719

Jiawen Wang, Ning Duan, Pan Li, Yanyan Liu, Xianli Wu, Baojun Li

{"title":"Recent Advances in the Synthesis and Application of TS-1 Zeolite for Green Catalytic Oxidation","authors":"Jiawen Wang, Ning Duan, Pan Li, Yanyan Liu, Xianli Wu, Baojun Li","doi":"10.1002/adsu.202400719","DOIUrl":"https://doi.org/10.1002/adsu.202400719","url":null,"abstract":"TS-1 has a unique structure, and TS-1/H2O2 oxidation system for composition shows excellent catalytic performance in the oxidation of a variety of organic matter. The response conditions of the reaction system are mild, and the ultimate oxidation product is water. It is a typical “green catalytic” system and has received widespread attention from researchers. Here, the synthesis progress of TS-1 to improve the accessibility and activity of active sites by doping mesoporous and microporous structures into traditional TS-1 zeolite in recent five years are reviewed, including hydrothermal synthesis, dry gel conversion synthesis, solvent-free synthesis, microwave assisted synthesis, and isomorphous substitution. Meanwhile, the application of TS-1/H2O2 system in oxidative desulfurization, ketone ammonia oxidation, olefin epoxidation, and hydroxylation of aromatic hydrocarbons reactions are summarized and discussed. What's more, the reaction mechanism based on TS-1/H2O2 system is proposed on regarding the isolated skeleton Ti site in titanium-silicon zeolite as the active central site. Finally, the challenges and future development prospects of TS-1 zeolite in synthesis and catalytic applications are predicted.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 2","pages":""},"PeriodicalIF":6.5,"publicationDate":"2024-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143446828","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Bio-Mass Radiative Cooling Materials: Progress and Prospects

IF 6.5 3区材料科学

Advanced Sustainable Systems Pub Date : 2024-12-08 DOI: 10.1002/adsu.202400773

Han Jia, Jingna Zhang, Yangzhe Hou, Yamin Pan, Chuntai Liu, Changyu Shen, Jun Ma, Xianhu Liu

引用次数: 0