Advanced Sustainable Systems最新文献_第7页

Cellulose-Based Electrolytes in Rechargeable Zn-Battery: An Overview 纤维素基电解质在可充电锌电池中的应用综述

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-06-08 DOI: 10.1002/adsu.202500287

Jusef Hassoun, Kento Kimura, Yoichi Tominaga

{"title":"Cellulose-Based Electrolytes in Rechargeable Zn-Battery: An Overview","authors":"Jusef Hassoun, Kento Kimura, Yoichi Tominaga","doi":"10.1002/adsu.202500287","DOIUrl":"https://doi.org/10.1002/adsu.202500287","url":null,"abstract":"Despite commercially diffused as a primary cell, zinc battery is attracting increasing interest as rechargeable system due to its low cost, safety, and environmental sustainability. Furthermore, cellulose-based ion conducting media exploiting solid, jelled, or polymer configurations are well supporting the improvement of this intriguing energy storage system. Here, an overview of recent researches on rechargeable Zn battery, often indicated as Zn-ion battery is reported, exploiting electrolytes using cellulose. It is shown that cellulose-based electrolyte may have either solid, or gel, cross-linked hydrogel, coated, biopolymer, microfibrillated, aligned, amorphous, or self-assembled configurations. In the course of the paragraphs, how the several structural, morphological, and electrochemical studies have clarified fundamental characteristics to allow their operation in battery is revealed. On the other hand, Zn-based energy storage systems are discussed, particularly focusing on Zn–MnO2, Zn–V2O5, and Zn–air as the preferred cell configurations in terms of reliability, electrochemical performances, delivered capacity, and cycling stability. Last but not the least, the review remarks that the cost of these batteries is competitive in the global energy storage market, particularly considering the raw material availability. Therefore, the work sheds light on this dated, while emerging, system of raising interest particularly for stationary storage from discontinuous renewable sources.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 9","pages":""},"PeriodicalIF":6.1,"publicationDate":"2025-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202500287","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145135344","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hydrothermal Synthesis of AlV-Rich Nonporous Amorphous Silica-Alumina for Stable Cracking of Plastics Waste into Light Olefins 水热合成富alv无孔无定形二氧化硅-氧化铝用于塑料废弃物稳定裂解制备轻质烯烃

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-06-05 DOI: 10.1002/adsu.202500432

Samira Motamednejad, Kourosh Tabar Heydar, Reza Panahi, Li Gao, Bingsen Zhang, Mozaffar Shakeri

{"title":"Hydrothermal Synthesis of AlV-Rich Nonporous Amorphous Silica-Alumina for Stable Cracking of Plastics Waste into Light Olefins","authors":"Samira Motamednejad, Kourosh Tabar Heydar, Reza Panahi, Li Gao, Bingsen Zhang, Mozaffar Shakeri","doi":"10.1002/adsu.202500432","DOIUrl":"10.1002/adsu.202500432","url":null,"abstract":"Fast coking and limited selectivity toward light olefins are two drawbacks of the zeolitic upcycling of polyolefin-based plastic waste. The AlV–rich amorphous silica-alumina (ASA) catalysts with the strong Brønsted acidic sites (BAS) might be an alternative to the zeolites; however, the existing preparations are costly and complex. A hydrothermal preparation of AlV-rich (37.90–43.46%) nonporous ASA catalysts is presented, which is achieved by collecting the synthesis gel of an FAU-type structure during its induction period. The resultant ASA catalysts demonstrated (very) strong BAS, depending on the AlV/AlIV ratio, and a high density of Lewis acidic sites (LAS), which are stronger than the industrially relevant zeolites. The ASA catalysts examined in the cracking of various polyolefin-based plastics resulted in excellent polymer degradation activity, increased light olefins production, high-quality heavy aromatics-free liquid oils, and up to zilch coking, which are clearly superior to those obtained using a crystalline zeolite. Despite having (very) strong BAS, the exceptional light olefins production and suppressed coke formation by the ASA catalysts are possibly due to the synergy between a high density of LAS and free mass transfer, which favors the monomolecular over the bimolecular cracking mechanism.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 8","pages":""},"PeriodicalIF":6.1,"publicationDate":"2025-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144909960","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Diatomic Nitrogen-Coordinated Metal-Doping Carbon for Oxygen Reduction: A Focus on Structure and Active Site 双原子氮配位金属掺杂碳氧还原：结构和活性位点的研究

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-06-05 DOI: 10.1002/adsu.202500397

Xiaohan Sun, Qiaoxia Li, Han Zhang

{"title":"Diatomic Nitrogen-Coordinated Metal-Doping Carbon for Oxygen Reduction: A Focus on Structure and Active Site","authors":"Xiaohan Sun, Qiaoxia Li, Han Zhang","doi":"10.1002/adsu.202500397","DOIUrl":"https://doi.org/10.1002/adsu.202500397","url":null,"abstract":"Diatomic nitrogen-coordinated metal-doping carbon (M-NC) electrocatalysts are marked by rearranged electronic structures and modified active sites, which are a hot frontier of oxygen reduction reaction (ORR). However, precisely prefabricating stable structures and revealing catalytic centers of diatomic M-NC are arduous tasks. In this review, a series of synthetic strategies are outlined, including MOFs and coordination carbon precursors. The significance of metal precursors is also clarified based on controlling a well-defined structure. Subsequently, various structural characterization methods to confirm diatomic dispersion and fine structure are elaborated, emphasizing on aberration-corrected electron microscope technique and X-ray absorption spectroscopy (XAFS) analysis. The poisoning experiments and in situ testing techniques with dynamic monitoring to reveal catalytic active center are discussed. Finally, a summary and several reflections in the development of diatomic M-NC are addressed. This review aims to provide valuable guidance for the preliminary exploration of enhanced diatomic catalysts.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 9","pages":""},"PeriodicalIF":6.1,"publicationDate":"2025-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145135249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Correction to “Sustainable Permeable Reactive Barrier Materials for Electrokinetic Remediation of Heavy Metals Contaminated Soil” 修正“重金属污染土壤电动修复的可持续渗透反应性屏障材料”

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-06-05 DOI: 10.1002/adsu.202500663

Ufra Naseer, Muhammad Ali, Muhammad Adnan Younis, Zhengping Du, Asim Mushtaq, Muhammad Yousaf, Chuntian Qiu, Tianxiang Yue

引用次数: 0

Starch-Rich Rice By-Products as a Renewable Resource for Sustainable Production of Flexible, Water Tolerant, Antioxidant, and UV-Protective Bioplastics 富含淀粉的稻米副产品作为可持续生产柔性、耐水、抗氧化和防紫外线生物塑料的可再生资源

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-06-05 DOI: 10.1002/adsu.202500278

Paulo Brites, Jorge Luís, Kamila Kapusniak, Malwina Wojcik, Cláudia Nunes, Manuel A. Coimbra, Amparo López-Rubio, Martinho Oliveira, Paula Ferreira, Idalina Gonçalves

{"title":"Starch-Rich Rice By-Products as a Renewable Resource for Sustainable Production of Flexible, Water Tolerant, Antioxidant, and UV-Protective Bioplastics","authors":"Paulo Brites, Jorge Luís, Kamila Kapusniak, Malwina Wojcik, Cláudia Nunes, Manuel A. Coimbra, Amparo López-Rubio, Martinho Oliveira, Paula Ferreira, Idalina Gonçalves","doi":"10.1002/adsu.202500278","DOIUrl":"https://doi.org/10.1002/adsu.202500278","url":null,"abstract":"The development of multifunctional materials from agrifood residues supports circular bioeconomy strategies by reducing waste and promoting renewable feedstocks. This study investigates rejected rice dust (RD) and colored rice (CR), two starch-rich rice processing by-products, as alternative sources for natural starch-based bioplastics, using purified rice starch (PRS) as a benchmark. RD and CR contained 79.9% and 82.9% total carbohydrates (48.6% and 51.8% starch), versus 98.3% carbohydrates and 70.2% starch in PRS. CR exhibited the highest amylose (29.5%) and phenolic content (20.9 mg GAE/100 g), compared to RD (21.3%; 8.8 mg GAE/100 g) and PRS (15.8%; 2.3 mg GAE/100 g). Gelatinization peak temperatures are elevated in RD (74.2°C) and CR (73.9°C) versus PRS (66.7°C). RD-based films showed mechanical strength (5.4 MPa) and modulus (146 MPa) comparable to PRS (5.5 MPa; 175 MPa), while CR-based films have lower modulus (53 MPa) but greater elongation at break (20.2%). Contact angles are highest in CR (119°), followed by PRS (102°) and RD (70°). Antioxidant activity reached 88% (CR), 33% (RD), and 10% (PRS). Only CR-based films provided UV-B protection. These results highlight RD and CR as renewable matrices for producing environmentally sustainable, functionally enhanced starch-based materials for packaging and coating applications.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 9","pages":""},"PeriodicalIF":6.1,"publicationDate":"2025-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145135243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Mechanism Study of CH4 Decomposition on Carbon Black-Loaded Activated Carbon by DFT Calculation DFT法研究负载炭黑活性炭分解CH4的机理

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-06-05 DOI: 10.1002/adsu.202500433

Duo Xu, Wenzhe Zhang, Zhiwei Chu, Qiangyu Zong, Fang Liu, Li Yang, Yuanzhuo Jing, Yingjie Li

{"title":"Mechanism Study of CH4 Decomposition on Carbon Black-Loaded Activated Carbon by DFT Calculation","authors":"Duo Xu, Wenzhe Zhang, Zhiwei Chu, Qiangyu Zong, Fang Liu, Li Yang, Yuanzhuo Jing, Yingjie Li","doi":"10.1002/adsu.202500433","DOIUrl":"https://doi.org/10.1002/adsu.202500433","url":null,"abstract":"Carbon black-loaded activated carbon (CB-loaded AC) is a cost-effective catalyst for CH4 decomposition to produce H2. CB induces defects on the AC surface, enhancing catalytic activity. Current studies on the role of defects in promoting CH4 decomposition are primarily experimental, with unclear mechanisms. Hence, exploring the reaction mechanism of defects in CH4 decomposition is crucial. In this work, the Grand Canonical Monte Carlo (GCMC) and Density Functional Theory (DFT) are used to construct defects (Mono-Vacancy defect, Di-Vacancy defect, and Stone-Wales defect) on the AC surface, determining the catalytic mechanism of defects in CH4 decomposition. The results show that during the CH4 decomposition (C─H bond cleavage) phase, defective AC reduces the energy barriers for CH4 decomposition. Under identical conditions, the rate-determining step of C─H bond cleavage in CH4 occurs more readily on AC with Mono-Vacancy, Di-Vacancy, and Stone-Wales defects, with corresponding reductions in energy barriers of 4.64, 2.36, and 3.12%, respectively. The total energy barriers for the reaction are reduced by 12.95, 27.58, and 8.43%, respectively. This indicates that the defects significantly lower the energy barrier for CH4 decomposition, thereby facilitating the reaction and confirming that these defects act as active sites for the catalytic decomposition of CH4 on AC.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 9","pages":""},"PeriodicalIF":6.1,"publicationDate":"2025-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145135244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Tunable Control of Indium Cluster in Carbon Nanofibers for High-Performance Zinc-Ion Hybrid Capacitors 高性能锌离子杂化电容器用碳纳米纤维中铟簇的可调控制

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-06-05 DOI: 10.1002/adsu.202500199

Senxiang Fang, Haoqing Ma, Ruohan Yu, Jinghui Chen, Lei Zhang, Kangning Zhao

引用次数: 0

Degradation of Tetracycline by Fe-N-Coordinated Porous Carbon Activated PMS: High Dispersibility and Stability 铁氮配位多孔炭活化PMS降解四环素：高分散性和稳定性

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-06-04 DOI: 10.1002/adsu.202500219

Shenghui Wang, Yanhua Song, Yansong Wu, Bin Wang, Xue Gao, Xingwang Zhu, Jinyuan Liu, Paul K. Chu

{"title":"Degradation of Tetracycline by Fe-N-Coordinated Porous Carbon Activated PMS: High Dispersibility and Stability","authors":"Shenghui Wang, Yanhua Song, Yansong Wu, Bin Wang, Xue Gao, Xingwang Zhu, Jinyuan Liu, Paul K. Chu","doi":"10.1002/adsu.202500219","DOIUrl":"10.1002/adsu.202500219","url":null,"abstract":"Advanced oxidation processes (AOPs) leverage the generation of reactive radicals or non-radical species, which exhibit strong oxidative potential, to effectively degrade recalcitrant pollutants. Herein, Fe5-NG is synthesized by a one-step calcination method for the degradation of tetracycline (TC). A large nitrogen concentration enhances the activation ability of Fe5-NG toward PMS, as manifested by 100% degradation of TC within 12 min for TC concentrations below 25 mg L−1 under visible light irradiation. The Fe5-NG/PMS system degrades TC via the generation of SO4•− and 1O2, and the presence of Fe(IV) = O species is confirmed. X-ray photoelectron spectroscopy performed on Fe5-NG before and after the treatment shows that pyridine nitrogen and graphite nitrogen are the primary active nitrogen species responsible for PMS activation, and PMS accelerates the Fe(III)/Fe(II) redox cycle by forming abundant active nitrogen species. The underlying degradation mechanism of the Fe5-NG/PMS system is investigated, and the non-free radical (1O2) pathway is dominant.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 8","pages":""},"PeriodicalIF":6.1,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144909972","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Etherification of Bio-Based Furanic Compounds via Continuous Flow 生物基呋喃化合物连续流醚化反应研究

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-06-04 DOI: 10.1002/adsu.202500526

Davide Dalla Torre, Giacomo Trapasso, Nathan Jourdainne, Nathanael Guigo, Fabio Aricò

{"title":"Etherification of Bio-Based Furanic Compounds via Continuous Flow","authors":"Davide Dalla Torre, Giacomo Trapasso, Nathan Jourdainne, Nathanael Guigo, Fabio Aricò","doi":"10.1002/adsu.202500526","DOIUrl":"https://doi.org/10.1002/adsu.202500526","url":null,"abstract":"The ultimate goal of biorefinery is to move away from a fossil-based industry aiming to a more sustainable one centered on the use of renewable feedstocks. It is well known that numerous bio-based platform chemicals can be obtained from biomass. Among them, 5-hydroxymethylfurfural (HMF) and 2,5-bis(hydroxymethyl)furan (FDCA) – achieved by HMF hydrogenation – are two of the most studied representatives. The etherification of these molecules with different alcohols yields 5-(alkoxymethyl)furfurals (AMFs) and 2,5-bis(alkoxymethyl) furans (BAMFs) respectively, both demonstrating potential application as fuel additives. In addition, HMF, when subjected to self-etherification, leads to 5,5′-[oxybis(methylene)]bis-2-furfural (OBMF), another bio-based monomer of growing interest. In this work, a comprehensive investigation on the etherification of HMF and 2,-5-bis(hydroxymethyl)furan (BHMF) promoted by a commercially available ion exchange resin – Purolite CT275DR – is conducted using a continuous flow apparatus. The reaction conditions are optimized for the etherification of BHMF with ethanol and then extended to achieve a library of BAMFs. In addition, HMF etherification and self-etherification are studied. HMF self-etherification to form OBMF is conducted using dimethyl carbonate in the presence of both heterogeneous and homogeneous acid catalysts. Finally green metrics are calculated for the etherification of BHMF with ethanol and the values are compared to previously published procedures.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 9","pages":""},"PeriodicalIF":6.1,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/adsu.202500526","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145135226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Porous Mo Modified Ni3N/Ni3S2 Hetero Interfacing for Facile Sulfur Oxidation Mediated Green H2 Production 多孔Mo修饰Ni3N/Ni3S2异质界面制备易氧化硫催化的绿色H2

IF 6.1 3区材料科学

Advanced Sustainable Systems Pub Date : 2025-06-04 DOI: 10.1002/adsu.202500407

Yukti Setia, Sanat Nalini Paltasingh, Saroj Kumar Nayak, Akhoury Sudhir Kumar Sinha, Umaprasana Ojha, Malaya K. Sahoo

{"title":"Porous Mo Modified Ni3N/Ni3S2 Hetero Interfacing for Facile Sulfur Oxidation Mediated Green H2 Production","authors":"Yukti Setia, Sanat Nalini Paltasingh, Saroj Kumar Nayak, Akhoury Sudhir Kumar Sinha, Umaprasana Ojha, Malaya K. Sahoo","doi":"10.1002/adsu.202500407","DOIUrl":"https://doi.org/10.1002/adsu.202500407","url":null,"abstract":"Development of nano catalyst systems with extended durability toward sulfion oxidation reaction (SOR) offers an energy efficient route to green H2 production and process harmful industrial waste to value added chemical. However, most of the reported nanocatalysts for the above operation suffer from sulfur poisoning leading to compromised durability. In this work, a Mo doped Ni3N/Ni3S2 heterointerface is designed that exhibits superior SOR activity and adequate durability together by combining the advantages of transition metal nitrides and sulphides. The study further revealed that a certain amount of Mo doping is desirable for the resulting Mo@Ni3N/Ni3S2 to exhibit optimized catalytic activity well supported by the density funtional theory (DFT) analysis. A current density (jSOR) value of 100 mA cm−2 is realized at low potential (VRHE) of 0.36 V in 1.0 M Na2S + 1.0 M NaOH solution. The heterostructure with a porous cactus like morphology possibly resisted S8 deposition and the SOR durability beyond 100 h is witnessed without compromising the efficiency. The efficacy is reflected in the two-electrode mode and jSOR value of 100 mA cm−2 is observed at a cell voltage value of 0.45 V in 1.0 M Na2S + 1.0 M NaOH supporting the viability of the system.","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"9 9","pages":""},"PeriodicalIF":6.1,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145135224","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0