EES catalysis最新文献_第6页

Au-decorated Sb2Se3 photocathodes for solar-driven CO2 reduction† 用于太阳能驱动的二氧化碳还原的金装饰 Sb2Se3 光电阴极

EES catalysis Pub Date : 2024-01-16 DOI: 10.1039/D3EY00222E

John Mark Christian M. Dela Cruz, Ádám Balog, Péter S. Tóth, Gábor Bencsik, Gergely F. Samu and Csaba Janáky

{"title":"Au-decorated Sb2Se3 photocathodes for solar-driven CO2 reduction†","authors":"John Mark Christian M. Dela Cruz, Ádám Balog, Péter S. Tóth, Gábor Bencsik, Gergely F. Samu and Csaba Janáky","doi":"10.1039/D3EY00222E","DOIUrl":"10.1039/D3EY00222E","url":null,"abstract":"Photoelectrodes with FTO/Au/Sb2Se3/TiO2/Au architecture were studied in photoelectrochemical CO2 reduction reaction (PEC CO2RR). The preparation is based on a simple spin coating technique, where nanorod-like structures were obtained for Sb2Se3, as confirmed by SEM images. A thin conformal layer of TiO2 was coated on the Sb2Se3 nanorods via ALD, which acted as both an electron transfer layer and a protective coating. Au nanoparticles were deposited as co-catalysts via photo-assisted electrodeposition at different applied potentials to control their growth and morphology. The use of such architectures has not been explored in CO2RR yet. The photoelectrochemical performance for CO2RR was investigated with different Au catalyst loadings. A photocurrent density of ∼7.5 mA cm−2 at −0.57 V vs. RHE for syngas generation was achieved, with an average Faradaic efficiency of 25 ± 6% for CO and 63 ± 12% for H2. The presented results point toward the use of Sb2Se3-based photoelectrodes in solar CO2 conversion applications.","PeriodicalId":72877,"journal":{"name":"EES catalysis","volume":" 2","pages":" 664-674"},"PeriodicalIF":0.0,"publicationDate":"2024-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/ey/d3ey00222e?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139475432","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Direct biomass valorisation to γ-valerolactone by Ru-PNP catalysed hydrogenation in acid† 在酸性条件下通过 Ru-PNP 催化加氢直接将生物质转化为 γ-戊内酯

EES catalysis Pub Date : 2024-01-11 DOI: 10.1039/D3EY00247K

Sakhitha Koranchalil and Martin Nielsen

引用次数: 0

Amine functionalized surface frustrated Lewis pairs boost CO2 photocatalysis†‡ 胺官能化表面受挫路易斯对促进二氧化碳光催化

EES catalysis Pub Date : 2024-01-09 DOI: 10.1039/D3EY00261F

Qinhui Guan, Chengzhe Ni, Tingjiang Yan, Na Li, Lu Wang, Zhe Lu, Weiguang Ran, Yipin Zhang, Wenjuan Li, Lulu Zhang, Dapeng Zhang, Baibiao Huang and Geoffrey A. Ozin

{"title":"Amine functionalized surface frustrated Lewis pairs boost CO2 photocatalysis†‡","authors":"Qinhui Guan, Chengzhe Ni, Tingjiang Yan, Na Li, Lu Wang, Zhe Lu, Weiguang Ran, Yipin Zhang, Wenjuan Li, Lulu Zhang, Dapeng Zhang, Baibiao Huang and Geoffrey A. Ozin","doi":"10.1039/D3EY00261F","DOIUrl":"10.1039/D3EY00261F","url":null,"abstract":"The archetype surface frustrated Lewis pair (SFLP) that facilitates CO2 photocatalytic hydrogenation to methanol and carbon monoxide, is an InOH⋯In site positioned in the surface of a nanoscale indium oxide hydroxide, denoted In2O3−x(OH)y. Proximal Lewis acid In(III) and Lewis base InOH of this genre serve as surface active sites that enable the photochemical heterolytic H2 dissociation and reduction of CO2 to the mentioned products. The conversion rate enabled by light has been found to far exceed that enabled by heat. Efforts to enhance the CO2 photocatalytic performance of the SFLP have involved modifications of the Lewis acidity and basicity through isomorphic substitution of In(III) with Bi(III) and changes in the population of oxygen vacancies through control of oxide non-stoichiometry. Replacement of the Lewis base hydroxide InOH by the stronger Lewis base amine InNH2 heretofore remains unexplored. The strategy described herein to explore this opportunity begins with the synthesis of In2O3−x(EDA)y. This new material is proven to contain an InNH2⋯In SFLP and its CO2 photocatalytic performance is demonstrated to outperform that of its In2O3−x(OH)y progenitor. Tailored Lewis acidity and basicity surfaces bring CO2 photocatalysis another step closer to the vision of solar CO2 refineries.","PeriodicalId":72877,"journal":{"name":"EES catalysis","volume":" 2","pages":" 573-584"},"PeriodicalIF":0.0,"publicationDate":"2024-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/ey/d3ey00261f?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139397475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Metal halide perovskites for CO2 photoreduction: recent advances and future perspectives 用于二氧化碳光致还原的金属卤化物过氧化物：最新进展与未来展望

EES catalysis Pub Date : 2024-01-06 DOI: 10.1039/D3EY00187C

Zhongliang Dong, Bowen Li, Yinlong Zhu and Wanlin Guo

{"title":"Metal halide perovskites for CO2 photoreduction: recent advances and future perspectives","authors":"Zhongliang Dong, Bowen Li, Yinlong Zhu and Wanlin Guo","doi":"10.1039/D3EY00187C","DOIUrl":"10.1039/D3EY00187C","url":null,"abstract":"CO2 emission has inarguably become one of the greatest challenges ever faced by mankind since industrial revolution. Techniques aiming at capture, storage and utilization of CO2 have attracted tremendous interest from both industry and academia. Thermal, electrical and photo-catalytic conversion of CO2 to value-added chemicals and fuels is the most well-known approach for CO2 utilization. In particular, photocatalytic reduction of CO2 (CO2PR) directly employs solar energy as the driving force to activate CO2, yielding various products including CO, CH4 and C2+ hydrocarbons. CO2PR, which mimics photosynthesis occurring in nature, is also regarded as “artificial photosynthesis” and is believed to be a promising approach toward carbon neutral economy. Recently, metal halide perovskites (MHPs) have emerged as potential photocatalysts for CO2PR, owing to their flexible structures and excellent photoelectronic properties. This review presents a comprehensive overview of state-of-the-art developments in MHP-based catalysts for CO2PR. Firstly, the crystal structures and photoelectric properties of MHPs are reviewed in detail, as they are the key factors determining CO2PR catalytic performance. Secondly, design strategies to promote the catalytic efficiency of CO2PR to CO conversion for both lead-based and lead-free MHPs are discussed, including morphological modifications, co-catalyst modifications, ion doping and crystal plane modifications. Thirdly, this review addresses MHP-based CO2PR to CH4 and C2+ products, with special emphasis on approaches adopted to promote specific product selectivity. Lastly, our perspectives and opinions are given on current research challenges and future directions for CO2PR, which we consider are critical for its industrialization.","PeriodicalId":72877,"journal":{"name":"EES catalysis","volume":" 2","pages":" 448-474"},"PeriodicalIF":0.0,"publicationDate":"2024-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/ey/d3ey00187c?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139374942","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Crystalline carbon nitrides for photocatalysis 用于光催化的晶体氮化碳

EES catalysis Pub Date : 2024-01-06 DOI: 10.1039/D3EY00302G

Han Li, Bei Cheng, Jingsan Xu, Jiaguo Yu and Shaowen Cao

{"title":"Crystalline carbon nitrides for photocatalysis","authors":"Han Li, Bei Cheng, Jingsan Xu, Jiaguo Yu and Shaowen Cao","doi":"10.1039/D3EY00302G","DOIUrl":"10.1039/D3EY00302G","url":null,"abstract":"Photocatalysis is considered as an effective approach to address energy and environmental issues. Carbon nitride (CN) is a promising metal-free semiconductor photocatalyst because of its unique properties such as tunable electronic band structure, facile/cheap synthesis and high chemical stability. However, the pristine CN prepared by the traditional thermal polymerization method is usually an amorphous or semi-crystalline conjugated bulk with a high density of structural defects, resulting in its moderate photocatalytic activity. Increasing the crystallinity of CN is an effective strategy to enhance its photocatalytic activity, and a few methods have been proposed, including high-temperature and high-pressure treatment, ionothermal method, solvothermal synthesis and microwave-assisted thermal polymerization. This review summarizes recent advances in the preparation of crystalline carbon nitrides (CCNs) and the design of CCNs-based photocatalysts in terms of nanostructure design, molecular structure engineering and construction of CCNs-based heterojunctions. In addition, their applications in a range of photocatalysis fields such as water splitting, carbon dioxide reduction, degradation of pollutants, organic synthesis and H2O2 production are reviewed. Finally, the concluding remarks are presented as well as challenges and prospects for future development of CCNs-based photocatalysts.","PeriodicalId":72877,"journal":{"name":"EES catalysis","volume":" 2","pages":" 411-447"},"PeriodicalIF":0.0,"publicationDate":"2024-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/ey/d3ey00302g?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139374655","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Novel double-layer core–shell photocatalyst CdS–TiO2@NH2-MIL-101: enhanced conversion of CO2 and CH4 at ambient temperature† 新型双层核壳光催化剂 CdS-TiO2@NH2-MIL-101：在常温下提高二氧化碳和甲烷的转化率

EES catalysis Pub Date : 2024-01-04 DOI: 10.1039/D3EY00264K

Yufei Huang, Ling Tan, Hanyu Ma, Xuan Wang, Yangqiang Huang, Jinping Yin, Zhiwu Liang and Xiao Luo

{"title":"Novel double-layer core–shell photocatalyst CdS–TiO2@NH2-MIL-101: enhanced conversion of CO2 and CH4 at ambient temperature†","authors":"Yufei Huang, Ling Tan, Hanyu Ma, Xuan Wang, Yangqiang Huang, Jinping Yin, Zhiwu Liang and Xiao Luo","doi":"10.1039/D3EY00264K","DOIUrl":"10.1039/D3EY00264K","url":null,"abstract":"The conversion of CO2 and CH4 into high value-added chemical products by chemical means is regarded as an emerging industrial technology to solve the increasingly serious climate and energy crises. The solar-powered conversion of CO2 and CH4 to syngas is one such technology that holds promise for the production of renewable fuels. Here, ternary core–shell CdS–TiO2@NH2-MIL-101 composites were prepared using mild experimental methods and their physical and chemical properties were studied using a series of characterization methods. In addition, the interaction between the coupling of different mass fractions of MOF, TiO2, and CdS and the performance of photocatalytic, photothermal, and thermocatalytic CH4 reforming were investigated. The results show that the yields of CO and H2 of the CdS–TiO2@NH2-MIL-101 catalyst at room temperature are 364.46 μmol g−1 and 100.43 μmol g−1, respectively, which are 1200–1500% of the catalytic performance of TiO2. Moreover, the yields of CO and H2 of the CdS–TiO2@NH2-MIL-101 material at 150 °C are 2831.55 μmol g−1 and 1448.20 μmol g−1, respectively. Based on isotope tracer experiments and CO2 adsorption experiments, a possible comprehensive mechanism for CdS–TiO2@NH2-MIL-101 photocatalytic CH4 reforming is proposed. In addition to presenting a fresh research concept for achieving carbon neutrality, this work offers a new technical pathway for the quick conversion of CO2 and CH4 at room temperature.","PeriodicalId":72877,"journal":{"name":"EES catalysis","volume":" 2","pages":" 675-686"},"PeriodicalIF":0.0,"publicationDate":"2024-01-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/ey/d3ey00264k?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139096049","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Surpassing water-splitting potential in aqueous redox flow batteries: insights from kinetics and thermodynamics 超越水氧化还原流动电池中的分水势：动力学和热力学的启示

EES catalysis Pub Date : 2024-01-04 DOI: 10.1039/D3EY00231D

Vithiya Muralidharan, S. Jayasubramaniyan and Hyun-Wook Lee

{"title":"Surpassing water-splitting potential in aqueous redox flow batteries: insights from kinetics and thermodynamics","authors":"Vithiya Muralidharan, S. Jayasubramaniyan and Hyun-Wook Lee","doi":"10.1039/D3EY00231D","DOIUrl":"10.1039/D3EY00231D","url":null,"abstract":"Aqueous redox flow batteries (AQRFBs) employing non-flammable electrolytes are recognized for their inherent safety and eco-friendliness, making them promising candidates for large-scale energy storage systems. Furthermore, the unique architecture of this battery technology enables autonomous decoupling of power and energy, resulting in higher capacity and enhanced cost-effectiveness compared to other battery technologies. Nonetheless, the limited electrochemical stability of water leads to water electrolysis during the electrochemical process, triggering undesired parasitic reactions, namely, the hydrogen evolution reaction, and ion-cross-over. These reactions significantly affect the electrochemical performance of the system, giving rise to several challenges, including low Coulombic efficiency and a short cycle life, hindering the advancement of AQRFBs. To overcome these obstacles and achieve high-potential AQRFBs, it becomes essential to incorporate a reaction-inhibitor to encounter water electrolysis during battery operation. This perspective review focuses on addressing and mitigating the thermodynamic limitations through improved strategies, proposing effective approaches to suppress aforementioned side reactions.","PeriodicalId":72877,"journal":{"name":"EES catalysis","volume":" 2","pages":" 522-544"},"PeriodicalIF":0.0,"publicationDate":"2024-01-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/ey/d3ey00231d?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139096014","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The First Year of EES Catalysis EES 催化的第一年

EES catalysis Pub Date : 2024-01-03 DOI: 10.1039/D3EY90024J

Shi-Zhang Qiao

引用次数: 0

Effects of the delocalization state on electrocatalytic CO2 reduction: a mini-review 脱焦状态对电催化二氧化碳还原的影响：微型综述

EES catalysis Pub Date : 2024-01-03 DOI: 10.1039/D3EY00227F

Shuyi Kong, Ximeng Lv and Jiacheng Wang

{"title":"Effects of the delocalization state on electrocatalytic CO2 reduction: a mini-review","authors":"Shuyi Kong, Ximeng Lv and Jiacheng Wang","doi":"10.1039/D3EY00227F","DOIUrl":"10.1039/D3EY00227F","url":null,"abstract":"The electrochemical carbon dioxide reduction reaction (CO2RR) is a way to alleviate environmental pollution and realize carbon recycling, which converts CO2 into value-added chemicals and fuels. Recently, the delocalization state regulation of catalysts has emerged as an effective method to evaluate the catalytic performance in CO2RR. The delocalization state of catalysts has been found to promote the stability and selectivity of CO2RR, which is essentially based on enhancing the electron conductivity of catalysts or regulating the adsorption of intermediates. In this mini-review, we first discuss how the delocalization state of catalysts affects their catalytic properties. Then, we summarize recent progress on the subject in two parts: stability and selectivity of CO2RR. In particular, we have emphasized the selectivity part, breaking it into two components: hydrogen adsorption and CO2RR intermediates. Finally, we conclude the review with some observations by outlining the challenges and presenting our viewpoints on the future research directions in this field.","PeriodicalId":72877,"journal":{"name":"EES catalysis","volume":" 2","pages":" 556-563"},"PeriodicalIF":0.0,"publicationDate":"2024-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/ey/d3ey00227f?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139083359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Nanostructured single-atom catalysts derived from natural building blocks 源自天然构件的纳米结构单原子催化剂

EES catalysis Pub Date : 2024-01-03 DOI: 10.1039/D3EY00265A

Yajing Zhang, Guobin Yang, Jin Wang, Bin Zhao, Yunxiang He and Junling Guo

{"title":"Nanostructured single-atom catalysts derived from natural building blocks","authors":"Yajing Zhang, Guobin Yang, Jin Wang, Bin Zhao, Yunxiang He and Junling Guo","doi":"10.1039/D3EY00265A","DOIUrl":"10.1039/D3EY00265A","url":null,"abstract":"Single-atom catalysts (SACs) exhibit maximized atomic utilization with individual metal atoms anchored on supporting materials, where the pursuit of high performance and low cost presents challenges. In this case, carbon provides structural versatility and customizable properties as a supporting material, which has been extensively studied. Biomass materials have emerged as promising precursors for the preparation of carbon-based SACs due to their renewable nature for sustainability, abundance for low cost, and high carbon content for advanced performance. In this review, representative synthesis strategies and advanced characterization techniques for biomass-derived CS-SACs are summarized, which facilitate the establishment of guidelines for the rational design and fabrication of biomass-derived SACs. In addition, we provide a timely and comprehensive discussion on the use of a broad range of natural biomass for SACs, with insights into the specific carbon nature of biomass resources, including their carbon structures, metal-carbon coordination environment, and center metal species. Furthermore, the application areas of biomass-derived CS-SACs in various catalytic processes are reviewed. Overall, the challenges and future perspectives of using biomass as precursors for SACs are outlined. We hope that this review can offer a valuable overview of the current knowledge, recent progress, and directions of biomass-derived SACs.","PeriodicalId":72877,"journal":{"name":"EES catalysis","volume":" 2","pages":" 475-506"},"PeriodicalIF":0.0,"publicationDate":"2024-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/ey/d3ey00265a?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139083358","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0