用于太阳能驱动的二氧化碳还原的金装饰 Sb2Se3 光电阴极

EES catalysis Pub Date : 2024-01-16 DOI:10.1039/D3EY00222E
John Mark Christian M. Dela Cruz, Ádám Balog, Péter S. Tóth, Gábor Bencsik, Gergely F. Samu and Csaba Janáky
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引用次数: 0

摘要

在光电化学二氧化碳还原反应(PEC CO2RR)中研究了具有 FTO/Au/Sb2Se3/TiO2/Au 结构的光电极。制备方法基于一种简单的旋涂技术,Sb2Se3 的纳米棒状结构由 SEM 图像证实。通过 ALD 在 Sb2Se3 纳米棒上镀了一层薄薄的保形层 TiO2,它既是电子转移层,又是保护层。金纳米颗粒作为辅助催化剂,在不同的应用电位下通过光助电沉积沉积,以控制其生长和形态。这种结构在 CO2RR 中的应用尚未得到探索。我们研究了不同金催化剂负载量下 CO2RR 的光电极性能。在 -0.57 V 对比 RHE 条件下,用于合成气生成的光电流密度为 ~7.5 mA cm-2,CO 的平均远红外效率为 25 ± 6%,H2 的平均远红外效率为 63 ± 12%。这些结果表明,基于 Sb2Se3 的光电极可用于太阳能二氧化碳转换应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Au-decorated Sb2Se3 photocathodes for solar-driven CO2 reduction†

Au-decorated Sb2Se3 photocathodes for solar-driven CO2 reduction†

Photoelectrodes with FTO/Au/Sb2Se3/TiO2/Au architecture were studied in photoelectrochemical CO2 reduction reaction (PEC CO2RR). The preparation is based on a simple spin coating technique, where nanorod-like structures were obtained for Sb2Se3, as confirmed by SEM images. A thin conformal layer of TiO2 was coated on the Sb2Se3 nanorods via ALD, which acted as both an electron transfer layer and a protective coating. Au nanoparticles were deposited as co-catalysts via photo-assisted electrodeposition at different applied potentials to control their growth and morphology. The use of such architectures has not been explored in CO2RR yet. The photoelectrochemical performance for CO2RR was investigated with different Au catalyst loadings. A photocurrent density of ∼7.5 mA cm−2 at −0.57 V vs. RHE for syngas generation was achieved, with an average Faradaic efficiency of 25 ± 6% for CO and 63 ± 12% for H2. The presented results point toward the use of Sb2Se3-based photoelectrodes in solar CO2 conversion applications.

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